{"id":"https://openalex.org/W7166325077","doi":"https://doi.org/10.1021/acscatal.6c02914","title":"Synergistic Interplay between Two Iron Centers and a Doubly N-Confused Hexaphyrin Ligand for Highly Efficient Photocatalytic Water Oxidation","display_name":"Synergistic Interplay between Two Iron Centers and a Doubly N-Confused Hexaphyrin Ligand for Highly Efficient Photocatalytic Water Oxidation","publication_year":2026,"publication_date":"2026-06-27","ids":{"openalex":"https://openalex.org/W7166325077","doi":"https://doi.org/10.1021/acscatal.6c02914"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.6c02914","doi":"https://doi.org/10.1021/acscatal.6c02914","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acscatal.6c02914","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acscatal.6c02914?ref=article_openPDF","source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://pubs.acs.org/doi/pdf/10.1021/acscatal.6c02914?ref=article_openPDF","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5023787328","display_name":"Daichi Sugawara","orcid":"https://orcid.org/0000-0002-0673-4342","observed_orcids":["https://orcid.org/0000-0002-0673-4342"]},"institutions":[{"id":"https://openalex.org/I133557312","display_name":"Rikkyo University","ror":"https://ror.org/00x194q47","country_code":"JP","type":"education","lineage":["https://openalex.org/I133557312"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Daichi Sugawara","raw_affiliation_strings":["Rikkyo University , , 3-34-1, Toshima-ku , ,"],"raw_orcid":"https://orcid.org/0000-0002-0673-4342","affiliations":[{"raw_affiliation_string":"Rikkyo University , , 3-34-1, Toshima-ku , ,","institution_ids":["https://openalex.org/I133557312"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028192877","display_name":"Takashi Nakazono","orcid":"https://orcid.org/0000-0001-6244-6399","observed_orcids":["https://orcid.org/0000-0001-6244-6399"]},"institutions":[{"id":"https://openalex.org/I4387152983","display_name":"Osaka Metropolitan University","ror":"https://ror.org/01hvx5h04","country_code":"JP","type":"education","lineage":["https://openalex.org/I4387152983"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Takashi Nakazono","raw_affiliation_strings":["Osaka Metropolitan University , , 3-3-138 Sugimoto , ,"],"raw_orcid":"https://orcid.org/0000-0001-6244-6399","affiliations":[{"raw_affiliation_string":"Osaka Metropolitan University , , 3-3-138 Sugimoto , ,","institution_ids":["https://openalex.org/I4387152983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021226320","display_name":"Takuya Shiga","orcid":"https://orcid.org/0000-0002-6834-6011","observed_orcids":["https://orcid.org/0000-0002-6834-6011"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takuya Shiga","raw_affiliation_strings":["University of Tsukuba , , 1-1-1, Tennodai , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Tsukuba , , 1-1-1, Tennodai , , ,","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029216071","display_name":"Masayuki Nihei","orcid":"https://orcid.org/0000-0002-3461-0187","observed_orcids":["https://orcid.org/0000-0002-3461-0187"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masayuki Nihei","raw_affiliation_strings":["University of Tsukuba , , 1-1-1, Tennodai , , ,"],"raw_orcid":"https://orcid.org/0000-0002-3461-0187","affiliations":[{"raw_affiliation_string":"University of Tsukuba , , 1-1-1, Tennodai , , ,","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055353829","display_name":"Yusuke Yamada","orcid":"https://orcid.org/0000-0001-6259-5255","observed_orcids":["https://orcid.org/0000-0001-6259-5255"]},"institutions":[{"id":"https://openalex.org/I4387152983","display_name":"Osaka Metropolitan University","ror":"https://ror.org/01hvx5h04","country_code":"JP","type":"education","lineage":["https://openalex.org/I4387152983"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yusuke Yamada","raw_affiliation_strings":["Graduate School of Engineering, Osaka Metropolitan University , , 3-3-138, Sugimoto, Sumiyoshi , ,","Osaka Metropolitan University , , 3-3-138 Sugimoto , ,"],"raw_orcid":"https://orcid.org/0000-0001-6259-5255","affiliations":[{"raw_affiliation_string":"Graduate School of Engineering, Osaka Metropolitan University , , 3-3-138, Sugimoto, Sumiyoshi , ,","institution_ids":["https://openalex.org/I4387152983"]},{"raw_affiliation_string":"Osaka Metropolitan University , , 3-3-138 Sugimoto , ,","institution_ids":["https://openalex.org/I4387152983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036171122","display_name":"Koichi Miyagawa","orcid":"https://orcid.org/0000-0002-7409-3727","observed_orcids":["https://orcid.org/0000-0002-7409-3727"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Koichi Miyagawa","raw_affiliation_strings":["University of Tsukuba , , 1-1-1, Tennodai , , ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Tsukuba , , 1-1-1, Tennodai , , ,","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051961689","display_name":"Mitsuo Shoji","orcid":"https://orcid.org/0000-0001-7465-6326","observed_orcids":["https://orcid.org/0000-0001-7465-6326"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Mitsuo Shoji","raw_affiliation_strings":["University of Tsukuba , , 1-1-1, Tennodai , , ,"],"raw_orcid":"https://orcid.org/0000-0001-7465-6326","affiliations":[{"raw_affiliation_string":"University of Tsukuba , , 1-1-1, Tennodai , , ,","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5078158837","display_name":"Tohru Wada","orcid":"https://orcid.org/0000-0003-4123-2169","observed_orcids":["https://orcid.org/0000-0003-4123-2169"]},"institutions":[{"id":"https://openalex.org/I133557312","display_name":"Rikkyo University","ror":"https://ror.org/00x194q47","country_code":"JP","type":"education","lineage":["https://openalex.org/I133557312"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Tohru Wada","raw_affiliation_strings":["Rikkyo University , , 3-34-1, Toshima-ku , ,"],"raw_orcid":"https://orcid.org/0000-0003-4123-2169","affiliations":[{"raw_affiliation_string":"Rikkyo University , , 3-34-1, Toshima-ku , ,","institution_ids":["https://openalex.org/I133557312"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5028192877","https://openalex.org/A5051961689","https://openalex.org/A5078158837"],"corresponding_institution_ids":["https://openalex.org/I133557312","https://openalex.org/I146399215","https://openalex.org/I4387152983"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":{"value":4500,"currency":"USD","value_usd":4500},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.35787787,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"16","issue":"16","first_page":"15801","last_page":"15815"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.6894999742507935,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.6894999742507935,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.08609999716281891,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.08370000123977661,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photocatalytic-water-oxidation","display_name":"photocatalytic water oxidation","score":0.9449999928474426},{"id":"https://openalex.org/keywords/dinuclear-iron-complexes","display_name":"dinuclear iron complexes","score":0.9810000061988831},{"id":"https://openalex.org/keywords/o-o-bond-formation","display_name":"O-O bond formation","score":0.7979999780654907},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.4480000138282776}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8671000003814697},{"id":"https://openalex.org/C2780192469","wikidata":"https://www.wikidata.org/wiki/Q413093","display_name":"Peroxydisulfate","level":3,"score":0.8228999972343445},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7960000038146973},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.7376000285148621},{"id":"https://openalex.org/C63338738","wikidata":"https://www.wikidata.org/wiki/Q287862","display_name":"Catalytic cycle","level":3,"score":0.656499981880188},{"id":"https://openalex.org/C73969872","wikidata":"https://www.wikidata.org/wiki/Q899698","display_name":"Turnover number","level":3,"score":0.6503999829292297},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6392999887466431},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.63919997215271},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6187999844551086},{"id":"https://openalex.org/C2781469039","wikidata":"https://www.wikidata.org/wiki/Q18388377","display_name":"Photosensitizer","level":2,"score":0.5917999744415283},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5583999752998352},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.44780001044273376},{"id":"https://openalex.org/C78030364","wikidata":"https://www.wikidata.org/wiki/Q5051391","display_name":"Catalytic oxidation","level":3,"score":0.4255000054836273},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.39419999718666077},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3869999945163727},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.37619999051094055},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.36910000443458557},{"id":"https://openalex.org/C105768512","wikidata":"https://www.wikidata.org/wiki/Q7458208","display_name":"Reaction intermediate","level":3,"score":0.33980000019073486},{"id":"https://openalex.org/C35590869","wikidata":"https://www.wikidata.org/wiki/Q2697332","display_name":"Water splitting","level":4,"score":0.33550000190734863},{"id":"https://openalex.org/C2777498215","wikidata":"https://www.wikidata.org/wiki/Q910291","display_name":"Polyoxometalate","level":3,"score":0.2992999851703644},{"id":"https://openalex.org/C190960625","wikidata":"https://www.wikidata.org/wiki/Q1058719","display_name":"Water treatment","level":2,"score":0.2969000041484833},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.28040000796318054},{"id":"https://openalex.org/C2778861492","wikidata":"https://www.wikidata.org/wiki/Q16825190","display_name":"Active center","level":3,"score":0.2556999921798706},{"id":"https://openalex.org/C87803896","wikidata":"https://www.wikidata.org/wiki/Q654623","display_name":"Artificial photosynthesis","level":4,"score":0.2513999938964844}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acscatal.6c02914","doi":"https://doi.org/10.1021/acscatal.6c02914","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acscatal.6c02914","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acscatal.6c02914?ref=article_openPDF","source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1021/acscatal.6c02914","doi":"https://doi.org/10.1021/acscatal.6c02914","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acscatal.6c02914","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acscatal.6c02914?ref=article_openPDF","source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/6","display_name":"Clean water and sanitation","score":0.6618000268936157}],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/6","display_name":"Clean water and sanitation","score":0.8231589794158936}],"study_designs":[],"awards":[{"id":"https://openalex.org/G135288740","display_name":"Elucidation of the mechanisms for light-induced water-splitting and light energy utilization in photosynthesis","funder_award_id":"22H04916","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G3218297869","display_name":null,"funder_award_id":"20H05116","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G3585684931","display_name":null,"funder_award_id":"KJ-3203","funder_id":"https://openalex.org/F4320322318","funder_display_name":"Kato Foundation for Promotion of Science"},{"id":"https://openalex.org/G410618756","display_name":"\u5206\u5b50\u5185\u52b1\u8d77\u30a8\u30cd\u30eb\u30ae\u30fc\u79fb\u52d5\u3092\u6d3b\u7528\u3057\u305f\u9ad8\u6d3b\u6027\u306a\u5149\u5316\u5b66\u7684\u4e8c\u9178\u5316\u70ad\u7d20\u9084\u5143\u89e6\u5a92\u306e\u958b\u767a","funder_award_id":"24K08453","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G5539417194","display_name":"\u5927\u74b0\u72b6\u4e8c\u6838\u932f\u4f53\u3092\u7528\u3044\u305f\u65b0\u898f\u53ef\u8996\u5149\u99c6\u52d5\u578b\u904e\u9178\u5316\u6c34\u7d20\u751f\u6210\u7cfb\u306e\u958b\u767a","funder_award_id":"23K04770","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G5567288086","display_name":null,"funder_award_id":"20H05088","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G5590256582","display_name":null,"funder_award_id":"I4LEC","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G946247319","display_name":null,"funder_award_id":"25H02239","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320319217","display_name":"Foundation for the Promotion of Ion Engineering","ror":"https://ror.org/036jb8273"},{"id":"https://openalex.org/F4320322318","display_name":"Kato Foundation for Promotion of Science","ror":"https://ror.org/01p7hf548"},{"id":"https://openalex.org/F4320323954","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07"},{"id":"https://openalex.org/F4320324170","display_name":"Rikkyo University","ror":"https://ror.org/00x194q47"},{"id":"https://openalex.org/F4320324591","display_name":"Iwatani Naoji Foundation","ror":"https://ror.org/035yy6m30"},{"id":"https://openalex.org/F4320325276","display_name":"Iketani Science and Technology Foundation","ror":"https://ror.org/0382jhd52"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7166325077.pdf","grobid_xml":"https://content.openalex.org/works/W7166325077.grobid-xml"},"referenced_works_count":75,"referenced_works":["https://openalex.org/W956225155","https://openalex.org/W1965092590","https://openalex.org/W1971275758","https://openalex.org/W1978289453","https://openalex.org/W1979712045","https://openalex.org/W1984851952","https://openalex.org/W1986412806","https://openalex.org/W1993551830","https://openalex.org/W1998965253","https://openalex.org/W2007200392","https://openalex.org/W2008161975","https://openalex.org/W2015681936","https://openalex.org/W2022884415","https://openalex.org/W2030938880","https://openalex.org/W2035402871","https://openalex.org/W2035506800","https://openalex.org/W2035791914","https://openalex.org/W2043124411","https://openalex.org/W2045894490","https://openalex.org/W2046467289","https://openalex.org/W2049638592","https://openalex.org/W2055563809","https://openalex.org/W2055663482","https://openalex.org/W2059205366","https://openalex.org/W2059832632","https://openalex.org/W2063074480","https://openalex.org/W2064729225","https://openalex.org/W2075381847","https://openalex.org/W2077125664","https://openalex.org/W2081924005","https://openalex.org/W2099037802","https://openalex.org/W2104596935","https://openalex.org/W2105221844","https://openalex.org/W2113571323","https://openalex.org/W2120236380","https://openalex.org/W2132454074","https://openalex.org/W2136831051","https://openalex.org/W2137349118","https://openalex.org/W2137487093","https://openalex.org/W2143981217","https://openalex.org/W2145249115","https://openalex.org/W2164318957","https://openalex.org/W2257763451","https://openalex.org/W2258326036","https://openalex.org/W2301276888","https://openalex.org/W2313252074","https://openalex.org/W2323588101","https://openalex.org/W2324881452","https://openalex.org/W2335331878","https://openalex.org/W2344621395","https://openalex.org/W2347142480","https://openalex.org/W2547894877","https://openalex.org/W2625969433","https://openalex.org/W2794990609","https://openalex.org/W2806312329","https://openalex.org/W2914844244","https://openalex.org/W2952649137","https://openalex.org/W2995181333","https://openalex.org/W3008264207","https://openalex.org/W3048874025","https://openalex.org/W3090213709","https://openalex.org/W3112053820","https://openalex.org/W3147369568","https://openalex.org/W3161240762","https://openalex.org/W4200212811","https://openalex.org/W4225115459","https://openalex.org/W4283274608","https://openalex.org/W4292331929","https://openalex.org/W4313272534","https://openalex.org/W4376108392","https://openalex.org/W4387855945","https://openalex.org/W4390947271","https://openalex.org/W4391268552","https://openalex.org/W4392105870","https://openalex.org/W4404994780"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"Transition-metal":[1],"complexes":[2],"featuring":[3],"multiple":[4],"redox-active":[5],"centers":[6,294],"have":[7],"the":[8,27,71,75,83,91,95,156,188,201,211,228,242,247,256,276,287,291,296],"ability":[9],"to":[10,135,182,187,268],"cooperatively":[11],"accumulate":[12],"positive":[13],"charges,":[14],"making":[15],"them":[16],"promising":[17],"candidates":[18],"for":[19,283],"water":[20,29,147,177],"oxidation":[21,30,148,178,195],"catalysis":[22],"(WOCs).":[23],"Herein,":[24],"we":[25,67],"report":[26],"high":[28,107,277],"activity":[31],"and":[32,58,69,114,128,153,174,198,205,279,295],"detailed":[33],"reaction":[34],"mechanism":[35],"of":[36,74,82,86,146,192,203],"a":[37,42,49,56,63,106,123,129,215,251,262],"dinuclear":[38,292],"iron":[39,293],"complex":[40],"bearing":[41],"doubly":[43],"N-confused":[44],"hexaphyrin":[45],"ligand":[46,230],"([Fe2(DNCH)])":[47],"in":[48,79,126,132,254],"photocatalytic":[50,102],"system":[51,213],"employing":[52],"tris(2,2\u2032-bipyridine)ruthenium(II)":[53],"([RuII(bpy)3]2+)":[54],"as":[55,62,232],"photosensitizer":[57],"peroxydisulfate":[59],"ion":[60],"(S2O82\u2212)":[61],"sacrificial":[64],"oxidant.":[65],"Furthermore,":[66],"synthesized":[68],"investigated":[70],"catalytic":[72],"performance":[73],"heterobimetallic":[76],"analogue":[77],"[FeZn(DNCH)],":[78],"which":[80],"one":[81],"FeIII":[84],"ions":[85],"[Fe2(DNCH)]":[87,104,121,152,173,197,212,284],"is":[88],"substituted":[89],"with":[90],"redox-inactive":[92],"ZnII.":[93],"Among":[94],"molecular":[96],"WOCs":[97],"previously":[98],"studied":[99],"under":[100],"similar":[101],"conditions,":[103],"showed":[105],"turnover":[108,115],"frequency":[109],"(TOF":[110,137],"=":[111,118,138,142],"8.7":[112],"s\u22121)":[113],"number":[116],"(TON":[117],"2730).":[119],"Notably,":[120],"displayed":[122],"sixfold":[124],"enhancement":[125],"TOF":[127,278],"fifteenfold":[130],"increase":[131],"TON":[133,141,280],"relative":[134,267],"[FeZn(DNCH)]":[136,154,175,199],"1.4":[139],"s\u22121,":[140],"180).":[143],"Kinetic":[144],"analyses":[145],"reactions":[149],"catalyzed":[150],"by":[151,196],"support":[155],"hypothesis":[157],"that":[158,171,210,227,275],"O\u2212O":[159,243],"bond":[160],"formation":[161],"proceeds":[162],"via":[163],"an":[164,233],"atom-proton-transfer":[165],"(APT)":[166],"mechanism.":[167],"Electrochemical":[168],"measurements":[169],"revealed":[170,274],"both":[172],"promote":[176],"at":[179],"potentials":[180],"up":[181],"approximately":[183],"1.2":[184],"V,":[185],"comparable":[186],"RuII/RuIII":[189],"redox":[190],"couple":[191],"[RuII(bpy)3]2+.":[193],"Water":[194],"involves":[200],"removal":[202],"four":[204],"three":[206],"electrons,":[207],"respectively,":[208],"suggesting":[209],"generates":[214],"more":[216],"electrophilic":[217],"oxidized":[218],"species.":[219],"Density":[220],"functional":[221],"theory":[222],"(DFT)":[223],"calculations":[224],"further":[225],"reveal":[226],"DNCH":[229],"acts":[231],"effective":[234],"electron-accepting":[235],"scaffold,":[236],"stabilizing":[237],"key":[238],"transition":[239],"states":[240],"during":[241],"bond-forming":[244],"steps.":[245],"Moreover,":[246],"FeIV=O":[248],"moiety":[249],"plays":[250],"pivotal":[252],"role":[253],"reducing":[255],"overall":[257],"energy":[258],"barrier,":[259],"thereby":[260],"facilitating":[261],"markedly":[263],"faster":[264],"water-oxidation":[265],"process":[266],"its":[269],"FeZn":[270],"counterpart.":[271],"Our":[272],"study":[273],"values":[281],"observed":[282],"originate":[285],"from":[286],"synergistic":[288],"interplay":[289],"between":[290],"\u03c0-conjugated":[297],"ligand.":[298]},"counts_by_year":[],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2026-06-28T00:00:00"}
