{"id":"https://openalex.org/W7166014656","doi":"https://doi.org/10.1002/anie.6681773","title":"Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O 2 and NO x","display_name":"Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O 2 and NO x","publication_year":2026,"publication_date":"2026-06-26","ids":{"openalex":"https://openalex.org/W7166014656","doi":"https://doi.org/10.1002/anie.6681773","pmid":"https://pubmed.ncbi.nlm.nih.gov/42360111"},"language":"en","primary_location":{"id":"doi:10.1002/anie.6681773","doi":"https://doi.org/10.1002/anie.6681773","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.6681773","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1002/anie.6681773","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5036288284","display_name":"T.J. Smak","orcid":"https://orcid.org/0009-0005-2499-4964","observed_orcids":["https://orcid.org/0009-0005-2499-4964"]},"institutions":[{"id":"https://openalex.org/I193662353","display_name":"Utrecht University","ror":"https://ror.org/04pp8hn57","country_code":"NL","type":"education","lineage":["https://openalex.org/I193662353"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Tom J. Smak","raw_affiliation_strings":["Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands","institution_ids":["https://openalex.org/I193662353"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067503196","display_name":"Rinke M. Altink","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I148297040","display_name":"Netherlands Organisation for Applied Scientific Research","ror":"https://ror.org/01bnjb948","country_code":"NL","type":"nonprofit","lineage":["https://openalex.org/I148297040"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Rinke Altink","raw_affiliation_strings":["TNO Brightsite  Geleen the Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"TNO Brightsite  Geleen the Netherlands","institution_ids":["https://openalex.org/I148297040"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085419588","display_name":"Ina Vollmer","orcid":"https://orcid.org/0000-0001-9917-1499","observed_orcids":["https://orcid.org/0000-0001-9917-1499"]},"institutions":[{"id":"https://openalex.org/I193662353","display_name":"Utrecht University","ror":"https://ror.org/04pp8hn57","country_code":"NL","type":"education","lineage":["https://openalex.org/I193662353"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Ina Vollmer","raw_affiliation_strings":["Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands"],"raw_orcid":"https://orcid.org/0000-0001-9917-1499","affiliations":[{"raw_affiliation_string":"Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands","institution_ids":["https://openalex.org/I193662353"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5053188243","display_name":"Bert Marc Weckhuysen","orcid":"https://orcid.org/0000-0001-5245-1426","observed_orcids":["https://orcid.org/0000-0001-5245-1426"]},"institutions":[{"id":"https://openalex.org/I193662353","display_name":"Utrecht University","ror":"https://ror.org/04pp8hn57","country_code":"NL","type":"education","lineage":["https://openalex.org/I193662353"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Bert M. Weckhuysen","raw_affiliation_strings":["Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands"],"raw_orcid":"https://orcid.org/0000-0001-5245-1426","affiliations":[{"raw_affiliation_string":"Inorganic Chemistry and Catalysis group Institute for Sustainable and Circular Chemistry Department of Chemistry Faculty of Science Utrecht University  Utrecht the Netherlands","institution_ids":["https://openalex.org/I193662353"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":{"value":5510,"currency":"USD","value_usd":5510},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.38650269,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"65","issue":"34","first_page":"e6681773","last_page":"e6681773"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.31369999051094055,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.31369999051094055,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.21080000698566437,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11009","display_name":"Catalysis for Biomass Conversion","score":0.05350000038743019,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dicarboxylic-acids","display_name":"dicarboxylic acids","score":0.878000020980835},{"id":"https://openalex.org/keywords/catalytic-oxidation","display_name":"catalytic oxidation","score":0.9350000023841858},{"id":"https://openalex.org/keywords/nox","display_name":"NOx","score":0.5759999752044678},{"id":"https://openalex.org/keywords/plastic-waste","display_name":"plastic waste","score":0.5320000052452087},{"id":"https://openalex.org/keywords/polypropylene","display_name":"polypropylene","score":0.7200000286102295},{"id":"https://openalex.org/keywords/carbon-recovery","display_name":"carbon recovery","score":0.8659999966621399},{"id":"https://openalex.org/keywords/catalyst-robustness","display_name":"catalyst robustness","score":0.6610000133514404}],"concepts":[{"id":"https://openalex.org/C2779751980","wikidata":"https://www.wikidata.org/wiki/Q143429","display_name":"Polyethylene","level":2,"score":0.8797000050544739},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7692000269889832},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.7566999793052673},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6800000071525574},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.49900001287460327},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.4318999946117401},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4004000127315521},{"id":"https://openalex.org/C2779146789","wikidata":"https://www.wikidata.org/wiki/Q422050","display_name":"Dicarboxylic acid","level":2,"score":0.3382999897003174},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.33739998936653137},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.29820001125335693},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.2689000070095062},{"id":"https://openalex.org/C2991944050","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Reaction conditions","level":3,"score":0.2565000057220459}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/anie.6681773","doi":"https://doi.org/10.1002/anie.6681773","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.6681773","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:42360111","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42360111","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:13480809","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC13480809/","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Angew Chem Int Ed Engl","raw_type":"Text"}],"best_oa_location":{"id":"doi:10.1002/anie.6681773","doi":"https://doi.org/10.1002/anie.6681773","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.6681773","pdf_url":null,"source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","display_name":"Responsible consumption and production","score":0.833299994468689}],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W1998322305","https://openalex.org/W2007053437","https://openalex.org/W2046743277","https://openalex.org/W2055031803","https://openalex.org/W2068041429","https://openalex.org/W2069044147","https://openalex.org/W2071587067","https://openalex.org/W2121547653","https://openalex.org/W2324621407","https://openalex.org/W2330276860","https://openalex.org/W2576773461","https://openalex.org/W2725330151","https://openalex.org/W2749550903","https://openalex.org/W2774466554","https://openalex.org/W2913724391","https://openalex.org/W2986718711","https://openalex.org/W3012481340","https://openalex.org/W3086260418","https://openalex.org/W3110953338","https://openalex.org/W3210254141","https://openalex.org/W4288061645","https://openalex.org/W4305040595","https://openalex.org/W4321792833","https://openalex.org/W4385884120","https://openalex.org/W4386506187","https://openalex.org/W4389058170","https://openalex.org/W4398214134","https://openalex.org/W4401631518","https://openalex.org/W4403112477","https://openalex.org/W4407722336","https://openalex.org/W4408910827","https://openalex.org/W4409465610","https://openalex.org/W4411383480","https://openalex.org/W4416791751","https://openalex.org/W7125376648","https://openalex.org/W7128435957","https://openalex.org/W7165533631"],"related_works":[],"abstract_inverted_index":{"ABSTRACT":[0],"A":[1],"promising":[2],"strategy":[3],"to":[4,10,76,126],"valorize":[5],"polyethylene":[6,33,104,162],"is":[7,93],"its":[8],"oxidation":[9],"dicarboxylic":[11,30,66,109],"acids":[12,31,67,110],"with":[13,72],"O":[14],"2":[15,81],"and":[16,25,40,56,79,150,163],"NO":[17,85],"x":[18],".":[19,82],"However,":[20],"it":[21,47],"remains":[22],"unclear":[23],"whether":[24],"how":[26],"the":[27,58,63,88,116,133,144,153],"formation":[28,89],"of":[29,60,90,103,118,155,161],"from":[32],"can":[34,111,137],"be":[35,112,138],"increased":[36],"through":[37,51,115],"catalyst":[38,62,124,145],"design":[39],"reaction":[41,53],"parameters":[42],"adjustment.":[43],"In":[44],"this":[45],"work,":[46],"was":[48,141,147],"found":[49,142],"that":[50,143],"proper":[52],"condition":[54],"selection":[55],"in":[57],"absence":[59],"a":[61,101,119,159,166],"yield":[64,107],"toward":[65,108],"could":[68],"reach":[69],"\u223c29":[70],"mol%":[71,128],"only":[73],"little":[74],"overoxidation":[75],"undesired":[77],"CO":[78,80],"At":[83],"high":[84],"partial":[86],"pressure,":[87],"gaseous":[91],"products":[92],"suppressed,":[94],"yielding":[95],"an":[96],"excellent":[97,134],"carbon":[98,135],"recovery":[99,136],"for":[100],"variety":[102],"types.":[105],"The":[106],"further":[113],"enhanced":[114],"addition":[117],"Cu":[120],"2+":[121],"/V":[122],"5+":[123],"up":[125],"\u223c51":[127],"(>90%":[129],"wt.%":[130],"diacid),":[131],"while":[132],"maintained.":[139],"It":[140],"system":[146],"both":[148],"robust":[149],"tolerant":[151],"as":[152],"use":[154],"post\u2010consumer":[156],"plastic":[157],"waste,":[158],"mixture":[160],"polypropylene,":[164],"yielded":[165],"similar":[167],"product":[168],"slate.":[169]},"counts_by_year":[],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2026-06-27T00:00:00"}