{"id":"https://openalex.org/W7148627985","doi":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","title":"Surfaces de silice fonctionnalis\u00e9es par voie CO2 supercritique : effets du confinement et comportement en solution aqueuse","display_name":"Surfaces de silice fonctionnalis\u00e9es par voie CO2 supercritique : effets du confinement et comportement en solution aqueuse","publication_year":2018,"publication_date":"2018-09-18","ids":{"openalex":"https://openalex.org/W7148627985","doi":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","mag":"2902829967"},"language":"fr","primary_location":{"id":"doi:10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","doi":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","is_oa":false,"landing_page_url":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","pdf_url":null,"source":{"id":"https://openalex.org/S4406923047","display_name":"theses.fr (ABES)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Montpellier","raw_type":"dissertation"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://www.theses.fr/2018MONTS137/document","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5070283929","display_name":"Susan Sananes\u2010Israel","orcid":"https://orcid.org/0000-0002-0580-0627","observed_orcids":["https://orcid.org/0000-0002-0580-0627"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Susan Sananes israel","raw_affiliation_strings":["Montpellier"],"raw_orcid":"https://orcid.org/0000-0002-0580-0627","affiliations":[{"raw_affiliation_string":"Montpellier","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5070283929"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.7045999765396118,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.7045999765396118,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.056299999356269836,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.02889999933540821,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silica-surfaces","display_name":"silica surfaces","score":0.9390000104904175},{"id":"https://openalex.org/keywords/alkoxysilanes","display_name":"alkoxysilanes","score":0.8820000290870667},{"id":"https://openalex.org/keywords/surface-grafting","display_name":"surface grafting","score":0.6050000190734863},{"id":"https://openalex.org/keywords/confined-spaces","display_name":"confined spaces","score":0.4569999873638153},{"id":"https://openalex.org/keywords/nanochannels","display_name":"nanochannels","score":0.9139999747276306},{"id":"https://openalex.org/keywords/sba-15","display_name":"SBA-15","score":0.8730000257492065},{"id":"https://openalex.org/keywords/mesoporous-silica","display_name":"mesoporous silica","score":0.8009999990463257},{"id":"https://openalex.org/keywords/3-mercaptopropyl-trimethoxysilane","display_name":"3-mercaptopropyltrimethoxysilane","score":0.9240000247955322},{"id":"https://openalex.org/keywords/self-assembled-monolayers","display_name":"self-assembled monolayers","score":0.8960000276565552},{"id":"https://openalex.org/keywords/multilayer-formation","display_name":"multilayer formation","score":0.6819999814033508},{"id":"https://openalex.org/keywords/physisorption","display_name":"physisorption","score":0.5450000166893005},{"id":"https://openalex.org/keywords/ion-exchange","display_name":"ion exchange","score":0.3610000014305115},{"id":"https://openalex.org/keywords/aqueous-solution-behavior","display_name":"aqueous solution behavior","score":0.4650000035762787}],"concepts":[{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5108000040054321},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4368000030517578},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3799999952316284},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.2522999942302704},{"id":"https://openalex.org/C2994041443","wikidata":"https://www.wikidata.org/wiki/Q5447188","display_name":"Chemical solution","level":2,"score":0.20550000667572021},{"id":"https://openalex.org/C66882249","wikidata":"https://www.wikidata.org/wiki/Q169336","display_name":"Homogeneous","level":2,"score":0.20160000026226044},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.19259999692440033},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.1860000044107437},{"id":"https://openalex.org/C499950583","wikidata":"https://www.wikidata.org/wiki/Q183252","display_name":"Morphology (biology)","level":2,"score":0.1695999950170517},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.163100004196167}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","doi":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","is_oa":false,"landing_page_url":"https://doi.org/10.70675/961dfb6cz8148z4e74za2a7z26360c49a460","pdf_url":null,"source":{"id":"https://openalex.org/S4406923047","display_name":"theses.fr (ABES)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Montpellier","raw_type":"dissertation"},{"id":"pmh:2018MONTS137","doi":null,"is_oa":true,"landing_page_url":"http://www.theses.fr/2018MONTS137/document","pdf_url":null,"source":{"id":"https://openalex.org/S4406923047","display_name":"theses.fr (ABES)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Electronic Thesis or Dissertation"},{"id":"pmh:oai:HAL:tel-02285345v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/tel-02285345v1","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Autre. Universit\u00e9 Montpellier, 2018. Fran\u00e7ais. ⟨NNT : 2018MONTS137⟩","raw_type":"info:eu-repo/semantics/doctoralThesis"},{"id":"mag:2902829967","doi":null,"is_oa":false,"landing_page_url":"https://tel.archives-ouvertes.fr/tel-02285345","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:2018MONTS137","doi":null,"is_oa":true,"landing_page_url":"http://www.theses.fr/2018MONTS137/document","pdf_url":null,"source":{"id":"https://openalex.org/S4406923047","display_name":"theses.fr (ABES)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Electronic Thesis or Dissertation"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":145,"referenced_works":["https://openalex.org/W64222769","https://openalex.org/W164879468","https://openalex.org/W359237793","https://openalex.org/W621500528","https://openalex.org/W1063045800","https://openalex.org/W1176460881","https://openalex.org/W1963842392","https://openalex.org/W1964029894","https://openalex.org/W1964683225","https://openalex.org/W1967772694","https://openalex.org/W1968367250","https://openalex.org/W1969896770","https://openalex.org/W1970838735","https://openalex.org/W1971809936","https://openalex.org/W1973302955","https://openalex.org/W1974063942","https://openalex.org/W1974199519","https://openalex.org/W1974683686","https://openalex.org/W1975872749","https://openalex.org/W1976510248","https://openalex.org/W1976702488","https://openalex.org/W1982074693","https://openalex.org/W1983913339","https://openalex.org/W1984009564","https://openalex.org/W1984034210","https://openalex.org/W1984651430","https://openalex.org/W1985248660","https://openalex.org/W1985956580","https://openalex.org/W1986708993","https://openalex.org/W1987388741","https://openalex.org/W1991555621","https://openalex.org/W1991864655","https://openalex.org/W1993737814","https://openalex.org/W1995041236","https://openalex.org/W1995426255","https://openalex.org/W1995892768","https://openalex.org/W1995962827","https://openalex.org/W1998612466","https://openalex.org/W1999983836","https://openalex.org/W2000883834","https://openalex.org/W2003052830","https://openalex.org/W2004178680","https://openalex.org/W2005151696","https://openalex.org/W2008733754","https://openalex.org/W2011254969","https://openalex.org/W2011765883","https://openalex.org/W2013141948","https://openalex.org/W2015430760","https://openalex.org/W2015595026","https://openalex.org/W2016211583","https://openalex.org/W2016689810","https://openalex.org/W2017654210","https://openalex.org/W2022334791","https://openalex.org/W2022514310","https://openalex.org/W2028401570","https://openalex.org/W2028908346","https://openalex.org/W2029314349","https://openalex.org/W2030674380","https://openalex.org/W2033481921","https://openalex.org/W2034105359","https://openalex.org/W2037219273","https://openalex.org/W2042316570","https://openalex.org/W2042602209","https://openalex.org/W2043489058","https://openalex.org/W2043764486","https://openalex.org/W2046142803","https://openalex.org/W2046430541","https://openalex.org/W2047600150","https://openalex.org/W2048245985","https://openalex.org/W2049215076","https://openalex.org/W2049667872","https://openalex.org/W2051884285","https://openalex.org/W2052743287","https://openalex.org/W2053429036","https://openalex.org/W2057702685","https://openalex.org/W2058181019","https://openalex.org/W2058629929","https://openalex.org/W2059267534","https://openalex.org/W2059683854","https://openalex.org/W2061015407","https://openalex.org/W2062449195","https://openalex.org/W2062662037","https://openalex.org/W2064364396","https://openalex.org/W2064419385","https://openalex.org/W2064526371","https://openalex.org/W2065197713","https://openalex.org/W2065756415","https://openalex.org/W2066866874","https://openalex.org/W2067539251","https://openalex.org/W2069573714","https://openalex.org/W2070580681","https://openalex.org/W2070828761","https://openalex.org/W2074335237","https://openalex.org/W2075513979","https://openalex.org/W2077775281","https://openalex.org/W2080383516","https://openalex.org/W2083428605","https://openalex.org/W2086616066","https://openalex.org/W2087451707","https://openalex.org/W2092405423","https://openalex.org/W2092685342","https://openalex.org/W2093701490","https://openalex.org/W2093855957","https://openalex.org/W2093914900","https://openalex.org/W2095192328","https://openalex.org/W2100334428","https://openalex.org/W2100577901","https://openalex.org/W2102498367","https://openalex.org/W2103915897","https://openalex.org/W2111993171","https://openalex.org/W2112272805","https://openalex.org/W2112641659","https://openalex.org/W2112658297","https://openalex.org/W2115487025","https://openalex.org/W2127715144","https://openalex.org/W2130347844","https://openalex.org/W2131424292","https://openalex.org/W2131500821","https://openalex.org/W2132480710","https://openalex.org/W2133173362","https://openalex.org/W2135016620","https://openalex.org/W2137737658","https://openalex.org/W2138765842","https://openalex.org/W2139993551","https://openalex.org/W2166072404","https://openalex.org/W2168485573","https://openalex.org/W2171463093","https://openalex.org/W2173934805","https://openalex.org/W2184760871","https://openalex.org/W2277944030","https://openalex.org/W2312199777","https://openalex.org/W2316814059","https://openalex.org/W2321323354","https://openalex.org/W2337256711","https://openalex.org/W2527243181","https://openalex.org/W2573147781","https://openalex.org/W2604943129","https://openalex.org/W2741624882","https://openalex.org/W2910512048","https://openalex.org/W2952644228","https://openalex.org/W4210856718","https://openalex.org/W4238361716","https://openalex.org/W4239073301","https://openalex.org/W4255654413","https://openalex.org/W4256025129"],"related_works":["https://openalex.org/W4392309464","https://openalex.org/W7047478173","https://openalex.org/W50954692","https://openalex.org/W2529605262","https://openalex.org/W3123149573","https://openalex.org/W2739283665","https://openalex.org/W2027487303","https://openalex.org/W2949498876","https://openalex.org/W4393522836","https://openalex.org/W2950531504"],"abstract_inverted_index":{"La":[0],"fonctionnalisation":[1,54,72],"des":[2,8,28,59,64,74,101,106,114,131,191,222,235,240,249,291,318,336,359,372,422,437,460,472,477],"surfaces":[3,60,102,107,158,254,349],"de":[4,14,42,47,51,61,66,70,76,80,91,104,110,120,128,160,164,170,176,203,224,230,237,256,282,308,381,389,415,420,442,447,458,468,480],"silice":[5,26,92,122,161,257,369],"permet":[6],"d\u2019obtenir":[7],"mat\u00e9riaux":[9],"comp\u00e9titifs":[10],"dans":[11,73,275,315,347,352,384,412,439],"le":[12,68,144,150,173,179,220,269,293,357,363,445],"cadre":[13],"l\u2019extraction":[15],"sp\u00e9cifique":[16],"d\u2019ions.":[17],"Cependant,":[18],"les":[19,157,247,253,280,326,348,353,405,413,440,463],"solvants":[20,43],"g\u00e9n\u00e9ralement":[21],"utilis\u00e9s":[22,95,140],"pour":[23],"fonctionnaliser":[24],"la":[25,53,121,135,199,227,276,289,309,331,334,342,377,396,416,428,432,435],"pr\u00e9sentent":[27],"contraintes":[29],"\u00e9conomiques":[30],"comme":[31,96,351],"environnementales.":[32],"Le":[33,233],"CO2":[34,57],"supercritique":[35,58],"est":[36,185,345,452],"une":[37,207,316,368],"alternative":[38],"verte":[39],"\u00e0":[40,89,123,187,212,288,367,400,456],"l\u2019utilisation":[41],"organiques.":[44],"Les":[45,153,387,418],"objectifs":[46],"cette":[48,71,450],"th\u00e8se":[49],"sont":[50,194],"caract\u00e9riser":[52],"par":[55,63,325,341],"voie":[56],"silices":[62,241,354,360],"alcoxysilanes,":[65],"d\u00e9terminer":[67,129,165],"devenir":[69],"milieux":[75,115],"quelques":[77,111],"nanom\u00e8tres":[78,112],"et":[79,119,149,168,271,379,403],"pr\u00e9ciser":[81],"leur":[82,297,390],"comportement":[83],"en":[84,286,304,339,392,430],"solution.":[85],"Plusieurs":[86],"syst\u00e8mes":[87],"mod\u00e8les":[88],"base":[90],"ont":[93,138,162,217,394,425],"\u00e9t\u00e9":[94,139,210,266,313],"support":[97],"au":[98],"greffage":[99,238,294],":":[100,143],"planes":[103,108,159,255,350],"silice,":[105,225],"espac\u00e9s":[109],"simulant":[113],"confin\u00e9s":[116],"plans":[117],"(nanocanaux)":[118],"m\u00e9soporosit\u00e9":[124],"organis\u00e9e":[125],"(SBA-15).":[126],"Afin":[127],"l\u2019impact":[130],"groupements":[132,337,382,464],"fonctionnels":[133],"sur":[134,156,239,252,296],"fonctionnalisation,":[136,429],"plusieurs":[137],"ou":[141,409],"pr\u00e9par\u00e9s":[142],"3-(mercaptopropyl)trim\u00e9thoxysilane":[145],"(MPTMS),":[146],"3-[amino(\u00e9thylamino)propyl]trim\u00e9thoxysilane":[147],"(AEAPTMS)":[148],"3-(iodopropyl)tri\u00e9thoxysilane":[151],"(IPTES).":[152],"r\u00e9sultats":[154],"obtenus":[155],"permis":[163,218],"diff\u00e9rentes":[166],"morphologies":[167,216,248],"structures":[169],"couche":[171],"selon":[172],"groupement":[174],"fonctionnel":[175],"l\u2019alcoxysilane.":[177],"Pour":[178,189,205],"MPTMS,":[180],"l\u2019obtention":[181],"d\u2019une":[182],"monocouche":[183,287],"auto-assembl\u00e9e":[184],"possible":[186],"60\u00baC.":[188],"l\u2019AEAPTMS,":[190],"couches":[192,250],"polycondens\u00e9es":[193],"obtenues":[195,251],"quelle":[196],"que":[197,246,268,279,404,427,471],"soit":[198],"temp\u00e9rature":[200],"du":[201,398],"proc\u00e9d\u00e9":[202],"greffage.":[204],"l\u2019IPTES,":[206],"bicouche":[208],"a":[209,244,265,311],"obtenue":[211],"120\u00b0C.":[213],"Ces":[214],"m\u00eames":[215,327],"d\u2019expliquer":[219],"remplissage":[221],"nanocanaux":[223],"avec":[226,462],"pr\u00e9sence":[228],"additionnelle":[229],"mol\u00e9cules":[231,281],"physisorb\u00e9es.":[232],"transfert":[234],"proc\u00e9d\u00e9s":[236],"m\u00e9soporeuses":[242],"SBA-15":[243,361,370],"montr\u00e9":[245,267,395],"n\u2019\u00e9taient":[258],"pas":[259,300,323],"strictement":[260],"transposables.":[261],"En":[262],"effet,":[263],"il":[264],"MPTMS":[270,283],"l\u2019IPTES":[272],"se":[273,284],"greffaient":[274],"microporosit\u00e9.":[277],"Alors":[278],"greffent":[285],"surface":[290,298],"m\u00e9sopores,":[292],"d\u2019IPTES":[295],"n\u2019a":[299],"pu":[301],"\u00eatre":[302],"mis":[303],"\u00e9vidence.":[305],"De":[306],"plus,":[307],"polycondensation":[310,321],"aussi":[312],"caract\u00e9ris\u00e9e":[314],"fraction":[317],"m\u00e9sopores.":[319],"Cette":[320],"n\u2019est":[322],"pilot\u00e9e":[324],"param\u00e8tres":[328],"exp\u00e9rimentaux":[329],"suivant":[330],"mol\u00e9cule.Par":[332],"ailleurs":[333],"post-fonctionnalisation":[335,378],"iodo":[338],"phosphonate":[340],"r\u00e9action":[343],"d\u2019Arbuzov-Michaelis":[344],"av\u00e9r\u00e9e":[346],"m\u00e9soporeuses.":[355],"Dans":[356,444],"cas":[358,446],"post-fonctionnalis\u00e9es,":[362],"mat\u00e9riau":[364,399],"final":[365],"correspond":[366],"ayant":[371],"pores":[373],"plus":[374,408,453],"grands":[375],"qu\u2019avant":[376],"pr\u00e9sentant":[380],"phosphonates":[383],"ses":[385],"murs.":[386],"mesures":[388],"\u00e9volution":[391],"solution":[393],"stabilit\u00e9":[397],"diff\u00e9rents":[401],"pH":[402],"solutions":[406,423,438,448],"diffusaient":[407],"moins":[410],"vite":[411],"murs":[414,441],"silice.":[417,443],"coefficients":[419],"diffusion":[421,436,451],"calcul\u00e9s":[424],"prouv\u00e9":[426],"bouchant":[431],"microporosit\u00e9,":[433],"ralentissait":[434],"basiques,":[449],"\u00e9lev\u00e9e":[454],"probablement":[455],"cause":[457],"l\u2019affinit\u00e9":[459],"cations":[461],"phosphonates.":[465],"Des":[466],"\u00e9tudes":[467],"sorption":[469],"ainsi":[470],"effets":[473],"d'irradiations":[474],"\u03b3":[475],"seraient":[476],"perspectives":[478],"int\u00e9ressantes":[479],"ce":[481],"travail.":[482]},"counts_by_year":[],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2026-04-03T00:00:00"}