{"id":"https://openalex.org/W7130516220","doi":"https://doi.org/10.1002/aenm.70779","title":"Harnessing Thermodynamic Decoupling in Ion Intercalation Chemistry to Unlock Unprecedented Energy Storage","display_name":"Harnessing Thermodynamic Decoupling in Ion Intercalation Chemistry to Unlock Unprecedented Energy Storage","publication_year":2026,"publication_date":"2026-02-18","ids":{"openalex":"https://openalex.org/W7130516220","doi":"https://doi.org/10.1002/aenm.70779"},"language":"en","primary_location":{"id":"doi:10.1002/aenm.70779","doi":"https://doi.org/10.1002/aenm.70779","is_oa":false,"landing_page_url":"https://doi.org/10.1002/aenm.70779","pdf_url":null,"source":{"id":"https://openalex.org/S2502627819","display_name":"Advanced Energy Materials","issn_l":"1614-6832","issn":["1614-6832","1614-6840"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Advanced Energy Materials","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110918984","display_name":"Yaqiao Luo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I113940042","display_name":"Shanghai University","ror":"https://ror.org/006teas31","country_code":"CN","type":"education","lineage":["https://openalex.org/I113940042"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yaqiao Luo","raw_affiliation_strings":["State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5138566029","display_name":"Kai Guo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I113940042","display_name":"Shanghai University","ror":"https://ror.org/006teas31","country_code":"CN","type":"education","lineage":["https://openalex.org/I113940042"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Kai Guo","raw_affiliation_strings":["State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5126375476","display_name":"Haotian Li","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I113940042","display_name":"Shanghai University","ror":"https://ror.org/006teas31","country_code":"CN","type":"education","lineage":["https://openalex.org/I113940042"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Haotian Li","raw_affiliation_strings":["State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022192867","display_name":"Yuxiao Lin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I118574674","display_name":"Jiangsu Normal University","ror":"https://ror.org/051hvcm98","country_code":"CN","type":"education","lineage":["https://openalex.org/I118574674"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuxiao Lin","raw_affiliation_strings":["School of Physics and Electronic Engineering Jiangsu Normal University  Xuzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Physics and Electronic Engineering Jiangsu Normal University  Xuzhou China","institution_ids":["https://openalex.org/I118574674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5126398635","display_name":"Da Wang","orcid":"https://orcid.org/0000-0002-4512-7860","observed_orcids":["https://orcid.org/0000-0002-4512-7860"]},"institutions":[{"id":"https://openalex.org/I113940042","display_name":"Shanghai University","ror":"https://ror.org/006teas31","country_code":"CN","type":"education","lineage":["https://openalex.org/I113940042"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Da Wang","raw_affiliation_strings":["Materials Genome Institute Shanghai University  Shanghai China","State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China"],"raw_orcid":"https://orcid.org/0000-0002-4512-7860","affiliations":[{"raw_affiliation_string":"Materials Genome Institute Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]},{"raw_affiliation_string":"State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101604337","display_name":"Liquan Chen","orcid":"https://orcid.org/0000-0001-5058-9552","observed_orcids":["https://orcid.org/0000-0001-5058-9552","https://orcid.org/0000-0002-6557-1213"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210159876","display_name":"Institute of Physics","ror":"https://ror.org/05cvf7v30","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210159876"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Liquan Chen","raw_affiliation_strings":["Beijing National Laboratory For Condensed Matter Physics Institute of Physics Chinese Academy of Sciences  Beijing China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory For Condensed Matter Physics Institute of Physics Chinese Academy of Sciences  Beijing China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210159876"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5121597991","display_name":"Siqi Shi","orcid":"https://orcid.org/0000-0001-8988-9763","observed_orcids":["https://orcid.org/0000-0001-8988-9763"]},"institutions":[{"id":"https://openalex.org/I113940042","display_name":"Shanghai University","ror":"https://ror.org/006teas31","country_code":"CN","type":"education","lineage":["https://openalex.org/I113940042"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Siqi Shi","raw_affiliation_strings":["Materials Genome Institute Shanghai University  Shanghai China","State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China"],"raw_orcid":"https://orcid.org/0000-0001-8988-9763","affiliations":[{"raw_affiliation_string":"Materials Genome Institute Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]},{"raw_affiliation_string":"State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering Shanghai University  Shanghai China","institution_ids":["https://openalex.org/I113940042"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5121597991","https://openalex.org/A5126398635"],"corresponding_institution_ids":["https://openalex.org/I113940042"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":5.297,"has_fulltext":false,"cited_by_count":3,"citation_normalized_percentile":{"value":0.94858333,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":97,"max":98},"biblio":{"volume":"16","issue":"17","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12875","display_name":"Thermal Expansion and Ionic Conductivity","score":0.002400000113993883,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ion-intercalation","display_name":"ion intercalation","score":0.9639999866485596},{"id":"https://openalex.org/keywords/mechanical-degradation","display_name":"mechanical degradation","score":0.640999972820282},{"id":"https://openalex.org/keywords/phase-stability","display_name":"phase stability","score":0.5460000038146973},{"id":"https://openalex.org/keywords/sodium-ion-batteries","display_name":"sodium-ion batteries","score":0.4819999933242798},{"id":"https://openalex.org/keywords/carbon-electrodes","display_name":"carbon electrodes","score":0.6420000195503235},{"id":"https://openalex.org/keywords/rocking-chair-batteries","display_name":"rocking-chair batteries","score":0.6439999938011169}],"concepts":[{"id":"https://openalex.org/C137824038","wikidata":"https://www.wikidata.org/wiki/Q175562","display_name":"Intercalation (chemistry)","level":2,"score":0.8216000199317932},{"id":"https://openalex.org/C205606062","wikidata":"https://www.wikidata.org/wiki/Q5249645","display_name":"Decoupling (probability)","level":2,"score":0.6743999719619751},{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.5812000036239624},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5712000131607056},{"id":"https://openalex.org/C2779698641","wikidata":"https://www.wikidata.org/wiki/Q5309","display_name":"Graphite","level":2,"score":0.49619999527931213},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.49309998750686646},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.4878999888896942},{"id":"https://openalex.org/C73916439","wikidata":"https://www.wikidata.org/wiki/Q837718","display_name":"Energy storage","level":3,"score":0.47040000557899475},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.428600013256073},{"id":"https://openalex.org/C149288129","wikidata":"https://www.wikidata.org/wiki/Q185357","display_name":"Phase transition","level":2,"score":0.420199990272522},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.4185999929904938},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.39160001277923584},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.35580000281333923},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.34929999709129333},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.32010000944137573},{"id":"https://openalex.org/C65604355","wikidata":"https://www.wikidata.org/wiki/Q3523861","display_name":"Molecular engineering","level":2,"score":0.31869998574256897},{"id":"https://openalex.org/C165801399","wikidata":"https://www.wikidata.org/wiki/Q25428","display_name":"Voltage","level":2,"score":0.305400013923645},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.2847000062465668},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.2827000021934509},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.2777000069618225},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.27720001339912415},{"id":"https://openalex.org/C185798385","wikidata":"https://www.wikidata.org/wiki/Q1161707","display_name":"Benchmark (surveying)","level":2,"score":0.26660001277923584},{"id":"https://openalex.org/C61696701","wikidata":"https://www.wikidata.org/wiki/Q770766","display_name":"Engineering physics","level":1,"score":0.2529999911785126},{"id":"https://openalex.org/C106782819","wikidata":"https://www.wikidata.org/wiki/Q6501076","display_name":"Electron mobility","level":2,"score":0.2515999972820282}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/aenm.70779","doi":"https://doi.org/10.1002/aenm.70779","is_oa":false,"landing_page_url":"https://doi.org/10.1002/aenm.70779","pdf_url":null,"source":{"id":"https://openalex.org/S2502627819","display_name":"Advanced Energy Materials","issn_l":"1614-6832","issn":["1614-6832","1614-6840"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Advanced Energy Materials","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.75}],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.8930643796920776}],"study_designs":[],"awards":[{"id":"https://openalex.org/G163595699","display_name":null,"funder_award_id":"52372208","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G2323951130","display_name":null,"funder_award_id":"92472207","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G8107814947","display_name":null,"funder_award_id":"52472223","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":45,"referenced_works":["https://openalex.org/W1981902098","https://openalex.org/W1982133696","https://openalex.org/W1988080928","https://openalex.org/W2021403769","https://openalex.org/W2034536417","https://openalex.org/W2044591029","https://openalex.org/W2064440479","https://openalex.org/W2073531811","https://openalex.org/W2083222334","https://openalex.org/W2117499552","https://openalex.org/W2122427541","https://openalex.org/W2154232712","https://openalex.org/W2161535857","https://openalex.org/W2164345903","https://openalex.org/W2170446057","https://openalex.org/W2305017215","https://openalex.org/W2472293555","https://openalex.org/W2568200292","https://openalex.org/W2613600499","https://openalex.org/W2793883299","https://openalex.org/W2906740191","https://openalex.org/W2940358154","https://openalex.org/W2957634391","https://openalex.org/W3023435578","https://openalex.org/W3033223480","https://openalex.org/W3033770664","https://openalex.org/W3045902663","https://openalex.org/W3047483024","https://openalex.org/W3142656322","https://openalex.org/W3171967633","https://openalex.org/W3206177057","https://openalex.org/W3206606417","https://openalex.org/W4236038073","https://openalex.org/W4310011473","https://openalex.org/W4315433689","https://openalex.org/W4386374620","https://openalex.org/W4386714638","https://openalex.org/W4390988939","https://openalex.org/W4396545815","https://openalex.org/W4404078190","https://openalex.org/W4405586273","https://openalex.org/W4406497371","https://openalex.org/W4407981484","https://openalex.org/W4410246175","https://openalex.org/W4412950898"],"related_works":[],"abstract_inverted_index":{"ABSTRACT":[0],"Reversible":[1],"ion":[2],"intercalation":[3,14,74,193],"chemistry":[4,194],"underpins":[5],"rocking\u2010chair":[6],"batteries":[7],"and":[8,20,29,36,89,104,118,213],"smart":[9],"ionic":[10],"switching":[11],"devices.":[12],"Conventional":[13],"activation":[15,75,195],"relies":[16],"on":[17,137],"ion\u2010host":[18,63,132],"distance":[19],"electronegativity,":[21],"confining":[22],"regulations":[23],"to":[24,85,95,114,125],"stress\u2010release":[25],"dimension":[26],"in":[27,43],"carbon":[28],"silicon\u2010based":[30],"materials":[31,46,212],"associated":[32],"with":[33,172],"high":[34],"expansion":[35],"mechanical":[37],"degradation.":[38],"However,":[39],"this":[40],"paradigm":[41],"fails":[42],"regulating":[44],"low\u2010expansion":[45],"for":[47,205],"mitigating":[48],"degradation,":[49],"because":[50],"stress":[51],"arising":[52],"from":[53,67,121,151],"the":[54,97,101,177,192,203,206],"constrained":[55],"volume":[56],"blocks":[57],"functional":[58],"intercalation.":[59],"Herein,":[60],"we":[61,108],"harness":[62],"binding":[64,102,133],"strength":[65,103,134],"derived":[66],"thermodynamic":[68],"decoupling":[69],"as":[70],"a":[71,164],"widely":[72],"applicable":[73],"dimension,":[76,201],"whose":[77],"regulation":[78,200],"can":[79],"be":[80],"realized":[81],"by":[82,186,197],"transferring":[83],"electrons":[84],"host":[86],"low\u2010energy":[87],"orbital,":[88],"thus":[90],"propose":[91],"two":[92],"quantitative":[93],"descriptors":[94],"coordinate":[96],"antagonistic":[98],"conflict":[99],"between":[100],"phase":[105],"stability.":[106],"Accordingly,":[107],"provide":[109],"three":[110],"types":[111],"of":[112,131,167,209],"cases":[113],"demonstrate":[115],"its":[116],"utility":[117],"applications,":[119],"ranging":[120],"commercial":[122],"carbon\u2010based":[123],"electrodes":[124],"intractable":[126],"covalent":[127],"nitrides.":[128],"The":[129],"consideration":[130],"sheds":[135],"light":[136],"why":[138],"graphite":[139],"accommodates":[140],"Li\u2010":[141],"but":[142],"not":[143],"Na\u2010ion.":[144],"\u03b1\u2010VSi":[145],"2":[146,154],"N":[147,155],"4":[148,156,180],"prototype":[149],"tuned":[150],"M":[152,158],"Si":[153],"(":[157],"=":[159],"Transition":[160],"metal)":[161],"family":[162],"achieves":[163],"Na\u2010ion":[165],"capacity":[166],"163":[168],"mAh":[169],"g":[170],"\u22121":[171],"merely":[173],"5.6%":[174],"expansion,":[175],"surpassing":[176],"near\u2010zero\u2010expansion":[178],"Na":[179],"Ti":[181],"5":[182],"O":[183],"12":[184],"benchmark":[185],"over":[187],"30%.":[188],"This":[189],"work":[190],"establishes":[191],"landscape":[196],"exploring":[198],"unprecedented":[199],"broadening":[202],"scope":[204],"selective":[207],"design":[208],"energy":[210],"storage":[211],"beyond.":[214]},"counts_by_year":[{"year":2026,"cited_by_count":3}],"updated_date":"2026-09-26T08:19:03.415552","created_date":"2026-02-19T00:00:00"}