{"id":"https://openalex.org/W7129005737","doi":"https://doi.org/10.1038/s41467-026-78292-4","title":"Post-fabrication reconfiguration of hydrogels through thermodynamic asymmetry in dynamic chemistry","display_name":"Post-fabrication reconfiguration of hydrogels through thermodynamic asymmetry in dynamic chemistry","publication_year":2026,"publication_date":"2026-10-07","ids":{"openalex":"https://openalex.org/W7129005737","doi":"https://doi.org/10.1038/s41467-026-78292-4","pmid":"https://pubmed.ncbi.nlm.nih.gov/42844294","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/13645739"},"language":"en","primary_location":{"id":"doi:10.1038/s41467-026-78292-4","doi":"https://doi.org/10.1038/s41467-026-78292-4","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-78292-4","pdf_url":"https://www.nature.com/articles/s41467-026-78292-4.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","datacite","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://www.nature.com/articles/s41467-026-78292-4.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5126071034","display_name":"Davide Campagna","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Davide Campagna","raw_affiliation_strings":["Life-Like Materials and Systems, University of Mainz, Mainz, Germany. davide.campagna@uni-mainz.de"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Life-Like Materials and Systems, University of Mainz, Mainz, Germany. davide.campagna@uni-mainz.de","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021366465","display_name":"Diego Ciardi","orcid":"https://orcid.org/0000-0001-7303-8569","observed_orcids":["https://orcid.org/0000-0001-7303-8569"]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Diego Ciardi","raw_affiliation_strings":["Life-Like Materials and Systems, University of Mainz, Mainz, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Life-Like Materials and Systems, University of Mainz, Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007145919","display_name":"Weixiang Chen","orcid":"https://orcid.org/0009-0000-5518-0799","observed_orcids":["https://orcid.org/0009-0000-5518-0799"]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Weixiang Chen","raw_affiliation_strings":["Life-Like Materials and Systems, University of Mainz, Mainz, Germany"],"raw_orcid":"https://orcid.org/0009-0000-5518-0799","affiliations":[{"raw_affiliation_string":"Life-Like Materials and Systems, University of Mainz, Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5060067635","display_name":"Andreas Walther","orcid":"https://orcid.org/0000-0003-2170-3306","observed_orcids":["https://orcid.org/0000-0003-2170-3306"]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Andreas Walther","raw_affiliation_strings":["Life-Like Materials and Systems, University of Mainz, Mainz, Germany. andreas.walther@uni-mainz.de"],"raw_orcid":"https://orcid.org/0000-0003-2170-3306","affiliations":[{"raw_affiliation_string":"Life-Like Materials and Systems, University of Mainz, Mainz, Germany. andreas.walther@uni-mainz.de","institution_ids":["https://openalex.org/I197323543"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5060067635","https://openalex.org/A5126071034"],"corresponding_institution_ids":["https://openalex.org/I197323543"],"apc_list":{"value":6990,"currency":"USD","value_usd":6990},"apc_paid":{"value":6990,"currency":"USD","value_usd":6990},"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.04770325,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"17","issue":"1","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.6294000148773193,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.6294000148773193,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10810","display_name":"Polymer composites and self-healing","score":0.30079999566078186,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11419","display_name":"Supramolecular Self-Assembly in Materials","score":0.03139999881386757,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrogels","display_name":"hydrogels","score":0.7670000195503235},{"id":"https://openalex.org/keywords/dynamic-covalent-chemistry","display_name":"dynamic covalent chemistry","score":0.9369999766349792},{"id":"https://openalex.org/keywords/hydrazones","display_name":"hydrazones","score":0.8569999933242798},{"id":"https://openalex.org/keywords/oximes","display_name":"oximes","score":0.9940000176429749},{"id":"https://openalex.org/keywords/alkoxyamines","display_name":"alkoxyamines","score":0.9490000009536743},{"id":"https://openalex.org/keywords/kinetic-modeling","display_name":"kinetic modeling","score":0.8080000281333923},{"id":"https://openalex.org/keywords/network-reprogramming","display_name":"network reprogramming","score":0.6039999723434448},{"id":"https://openalex.org/keywords/self-healing-materials","display_name":"self-healing materials","score":0.5580000281333923}],"concepts":[{"id":"https://openalex.org/C46305533","wikidata":"https://www.wikidata.org/wiki/Q5318960","display_name":"Dynamic covalent chemistry","level":4,"score":0.7383000254631042},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.6980000138282776},{"id":"https://openalex.org/C108586683","wikidata":"https://www.wikidata.org/wiki/Q17164826","display_name":"Self-healing hydrogels","level":2,"score":0.6676999926567078},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6342999935150146},{"id":"https://openalex.org/C119701452","wikidata":"https://www.wikidata.org/wiki/Q5165881","display_name":"Control reconfiguration","level":2,"score":0.5559999942779541},{"id":"https://openalex.org/C38976095","wikidata":"https://www.wikidata.org/wiki/Q752641","display_name":"Asymmetry","level":2,"score":0.48919999599456787},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.4528000056743622},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.42800000309944153},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.423799991607666},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.3869999945163727},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.37130001187324524},{"id":"https://openalex.org/C177801218","wikidata":"https://www.wikidata.org/wiki/Q36534","display_name":"Chemical reaction","level":2,"score":0.3395000100135803},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.329800009727478},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3287000060081482},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.32120001316070557},{"id":"https://openalex.org/C178213299","wikidata":"https://www.wikidata.org/wiki/Q44424","display_name":"Chemical bond","level":2,"score":0.3061000108718872},{"id":"https://openalex.org/C186060115","wikidata":"https://www.wikidata.org/wiki/Q30336093","display_name":"Biological system","level":1,"score":0.28380000591278076},{"id":"https://openalex.org/C188198153","wikidata":"https://www.wikidata.org/wiki/Q1613840","display_name":"Limiting","level":2,"score":0.2777999937534332},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.27399998903274536},{"id":"https://openalex.org/C135136745","wikidata":"https://www.wikidata.org/wiki/Q908074","display_name":"Dynamic equilibrium","level":2,"score":0.26820001006126404},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2572999894618988},{"id":"https://openalex.org/C124223222","wikidata":"https://www.wikidata.org/wiki/Q2281940","display_name":"Chemical process","level":2,"score":0.2572000026702881},{"id":"https://openalex.org/C70636015","wikidata":"https://www.wikidata.org/wiki/Q4300350","display_name":"Molecular biophysics","level":2,"score":0.2542000114917755}],"mesh":[],"locations_count":7,"locations":[{"id":"doi:10.1038/s41467-026-78292-4","doi":"https://doi.org/10.1038/s41467-026-78292-4","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-78292-4","pdf_url":"https://www.nature.com/articles/s41467-026-78292-4.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv.15000114/v1","doi":"https://doi.org/10.26434/chemrxiv.15000114/v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.15000114/v1","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmh:oai:pubmedcentral.nih.gov:13645739","doi":null,"is_oa":true,"landing_page_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC13645739/","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC13645739/pdf/41467_2026_Article_78292.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nat Commun","raw_type":"Text"},{"id":"pmid:42844294","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/42844294","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature communications","raw_type":"Journal Article"},{"id":"pmh:oai:doaj.org/article:21ce406c1ac24e3fa303b615ade91ea1","doi":null,"is_oa":false,"landing_page_url":"https://doaj.org/article/21ce406c1ac24e3fa303b615ade91ea1","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Nature Communications, Vol 17, Iss 1 (2026)","raw_type":"article"},{"id":"doi:10.5281/zenodo.22008370","doi":"https://doi.org/10.5281/zenodo.22008370","is_oa":true,"landing_page_url":"https://doi.org/10.5281/zenodo.22008370","pdf_url":null,"source":{"id":"https://openalex.org/S4306400562","display_name":"Zenodo (CERN European Organization for Nuclear Research)","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I67311998","host_organization_name":"European Organization for Nuclear Research","host_organization_lineage":["https://openalex.org/I67311998"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Dataset"},{"id":"doi:10.5281/zenodo.22008371","doi":"https://doi.org/10.5281/zenodo.22008371","is_oa":true,"landing_page_url":"https://doi.org/10.5281/zenodo.22008371","pdf_url":null,"source":{"id":"https://openalex.org/S4306400562","display_name":"Zenodo (CERN European Organization for Nuclear Research)","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I67311998","host_organization_name":"European Organization for Nuclear Research","host_organization_lineage":["https://openalex.org/I67311998"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Dataset"}],"best_oa_location":{"id":"doi:10.1038/s41467-026-78292-4","doi":"https://doi.org/10.1038/s41467-026-78292-4","is_oa":true,"landing_page_url":"https://doi.org/10.1038/s41467-026-78292-4","pdf_url":"https://www.nature.com/articles/s41467-026-78292-4.pdf","source":{"id":"https://openalex.org/S64187185","display_name":"Nature Communications","issn_l":"2041-1723","issn":["2041-1723"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","dongbi-a","doyens","jufo-3","ki-jl-3","medline","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310319908","host_organization_name":"Nature Portfolio","host_organization_lineage":["https://openalex.org/P4310319908","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Nature Portfolio","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nature Communications","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3789636019","display_name":null,"funder_award_id":"9C 833","funder_id":"https://openalex.org/F4320320882","funder_display_name":"Volkswagen Foundation"}],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320320882","display_name":"Volkswagen Foundation","ror":"https://ror.org/03bsmfz84"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7129005737.pdf","grobid_xml":"https://content.openalex.org/works/W7129005737.grobid-xml"},"referenced_works_count":45,"referenced_works":["https://openalex.org/W1961347528","https://openalex.org/W2010621614","https://openalex.org/W2015232449","https://openalex.org/W2037432389","https://openalex.org/W2060299760","https://openalex.org/W2079296603","https://openalex.org/W2094615888","https://openalex.org/W2125655640","https://openalex.org/W2136995813","https://openalex.org/W2142607208","https://openalex.org/W2142721038","https://openalex.org/W2160675920","https://openalex.org/W2267080583","https://openalex.org/W2315234938","https://openalex.org/W2589847527","https://openalex.org/W2718524622","https://openalex.org/W2800603315","https://openalex.org/W2804792494","https://openalex.org/W2909091922","https://openalex.org/W2937715510","https://openalex.org/W2949611276","https://openalex.org/W2980037015","https://openalex.org/W2985369922","https://openalex.org/W2988139359","https://openalex.org/W2989982684","https://openalex.org/W3003219383","https://openalex.org/W3005250601","https://openalex.org/W3118403798","https://openalex.org/W3161597832","https://openalex.org/W3169707058","https://openalex.org/W3200665803","https://openalex.org/W3203774558","https://openalex.org/W3205029262","https://openalex.org/W3214379612","https://openalex.org/W4220795384","https://openalex.org/W4385774012","https://openalex.org/W4387744932","https://openalex.org/W4391428180","https://openalex.org/W4393990285","https://openalex.org/W4394875144","https://openalex.org/W4401729059","https://openalex.org/W4403041894","https://openalex.org/W4408612465","https://openalex.org/W4412695655","https://openalex.org/W4412726320"],"related_works":["https://openalex.org/W4295886933","https://openalex.org/W7207768188","https://openalex.org/W4241670235","https://openalex.org/W2751070317","https://openalex.org/W4403041894","https://openalex.org/W7138862085","https://openalex.org/W4409084020","https://openalex.org/W7220850696","https://openalex.org/W2909177804","https://openalex.org/W4385725798"],"abstract_inverted_index":{"Designing":[0],"soft":[1],"materials":[2],"with":[3,97,123],"adaptive":[4],"properties":[5],"requires":[6],"internal":[7],"chemical":[8],"processes":[9],"that":[10,88],"enable":[11,56],"reconfiguration":[12],"across":[13],"multiple":[14],"system":[15],"levels.":[16],"Dynamic":[17],"covalent":[18,53,141],"chemistry":[19,54,103],"has":[20],"provided":[21],"powerful":[22],"routes":[23],"to":[24,55,162],"dynamic":[25,42,52,140],"polymer":[26],"networks,":[27],"yet":[28],"it":[29],"is":[30,91],"typically":[31],"employed":[32],"in":[33,51],"an":[34],"equilibrium-based":[35],"manner":[36],"where":[37],"the":[38,41,57,89],"identity":[39],"of":[40,59,73],"bond":[43,69],"remains":[44],"unchanged.":[45],"Here,":[46],"we":[47,77],"introduce":[48],"thermodynamic":[49],"asymmetry":[50],"replacement":[58,115],"network-defining":[60],"linkages":[61],"after":[62,109],"material":[63,117],"formation,":[64],"rather":[65],"than":[66],"their":[67,110],"mere":[68],"shuffling.":[70],"For":[71],"combinations":[72],"hydrazones":[74],"and":[75,129,166],"oximes,":[76],"demonstrate":[78],"near-quantitative":[79],"hydrazone-to-oxime":[80],"exchange":[81,90,142],"under":[82],"aqueous":[83],"conditions.":[84],"Kinetic":[85],"modeling":[86],"elucidates":[87],"dominated":[92],"by":[93],"a":[94,98,144],"hydrolytic":[95],"pathway":[96],"non-trivial":[99],"concentration":[100],"dependence.":[101],"This":[102,135],"enables":[104,126],"diverse":[105],"reconfigurations":[106],"within":[107],"hydrogels":[108],"initial":[111],"synthesis,":[112],"achieving":[113],"near-complete":[114],"at":[116],"scale.":[118],"Treating":[119],"pre-formed":[120],"hydrazone":[121],"gels":[122],"functional":[124,130,167],"alkoxyamines":[125],"topological,":[127],"mechanical,":[128],"reprogramming":[131],"without":[132],"network":[133],"deconstruction.":[134],"work":[136],"establishes":[137],"thermodynamically":[138],"biased":[139],"as":[143],"generalizable":[145],"principle":[146],"for":[147],"materials,":[148],"surface":[149],"functions,":[150],"or":[151],"self-assembling":[152],"systems,":[153],"illustrating":[154],"how":[155],"molecular":[156],"reaction":[157],"pathways":[158],"can":[159],"be":[160],"harnessed":[161],"deterministically":[163],"alter":[164],"structural":[165],"identity.":[168]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2026-02-17T00:00:00"}
