{"id":"https://openalex.org/W7128300010","doi":"https://doi.org/10.26599/nr.2026.94908533","title":"Divergent catalysis powered by external thermal fluctuations: A novel molecular ferroelectric approach","display_name":"Divergent catalysis powered by external thermal fluctuations: A novel molecular ferroelectric approach","publication_year":2026,"publication_date":"2026-02-07","ids":{"openalex":"https://openalex.org/W7128300010","doi":"https://doi.org/10.26599/nr.2026.94908533"},"language":"en","primary_location":{"id":"doi:10.26599/nr.2026.94908533","doi":"https://doi.org/10.26599/nr.2026.94908533","is_oa":true,"landing_page_url":"https://doi.org/10.26599/nr.2026.94908533","pdf_url":null,"source":{"id":"https://openalex.org/S173461644","display_name":"Nano Research","issn_l":"1998-0000","issn":["1998-0000","1998-0124"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-2","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nano Research","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.26599/nr.2026.94908533","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5125342341","display_name":"Huihui Hu","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Huihui Hu","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049818667","display_name":"Rui-Chao Yao","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Rui-Chao Yao","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103520814","display_name":"Xiao-xing Cao","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Xiao-Xing Cao","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052707150","display_name":"Lin-Yu Zhao","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Lin-Yu Zhao","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036188105","display_name":"Tai\u2010Ting Sha","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Tai-Ting Sha","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5005569088","display_name":"Yu\u2010Meng You","orcid":"https://orcid.org/0000-0002-4258-8733","observed_orcids":["https://orcid.org/0000-0002-4258-8733"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Yu-Meng You","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":5290,"currency":"USD","value_usd":5290},"apc_paid":{"value":5290,"currency":"USD","value_usd":5290},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.05204461,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"19","issue":"6","first_page":"94908533","last_page":"94908533"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.4318999946117401,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.4318999946117401,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10107","display_name":"Ferroelectric and Piezoelectric Materials","score":0.065700002014637,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.053700000047683716,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/molecular-ferroelectrics","display_name":"molecular ferroelectrics","score":0.9589999914169312},{"id":"https://openalex.org/keywords/pyroelectric-response","display_name":"pyroelectric response","score":0.7250000238418579},{"id":"https://openalex.org/keywords/copper-complexes","display_name":"copper complexes","score":0.7730000019073486},{"id":"https://openalex.org/keywords/low-grade-heat-utilization","display_name":"low-grade heat utilization","score":0.46399998664855957},{"id":"https://openalex.org/keywords/co2-cycloaddition","display_name":"CO2 cycloaddition","score":0.7279999852180481},{"id":"https://openalex.org/keywords/propargylamines","display_name":"propargylamines","score":0.9629999995231628},{"id":"https://openalex.org/keywords/c-o-cross-coupling","display_name":"C\u2013O coupling","score":0.9150000214576721},{"id":"https://openalex.org/keywords/diphenyl-ether","display_name":"diphenyl ether","score":0.7089999914169312},{"id":"https://openalex.org/keywords/coordination-environment","display_name":"coordination environment","score":0.5519999861717224},{"id":"https://openalex.org/keywords/dipole-orientation","display_name":"dipole orientation","score":0.7450000047683716},{"id":"https://openalex.org/keywords/structural-polarization","display_name":"structural polarization","score":0.8230000138282776},{"id":"https://openalex.org/keywords/coordination-flexibility","display_name":"coordination flexibility","score":0.6990000009536743},{"id":"https://openalex.org/keywords/diurnal-temperature-variation","display_name":"diurnal temperature range","score":0.6610000133514404}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7530999779701233},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5699999928474426},{"id":"https://openalex.org/C182762160","wikidata":"https://www.wikidata.org/wiki/Q858318","display_name":"Pyroelectricity","level":4,"score":0.5425999760627747},{"id":"https://openalex.org/C204530211","wikidata":"https://www.wikidata.org/wiki/Q752823","display_name":"Thermal","level":2,"score":0.5056999921798706},{"id":"https://openalex.org/C79090758","wikidata":"https://www.wikidata.org/wiki/Q1045739","display_name":"Ferroelectricity","level":3,"score":0.4932999908924103},{"id":"https://openalex.org/C173523689","wikidata":"https://www.wikidata.org/wiki/Q215589","display_name":"Dipole","level":2,"score":0.4666999876499176},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.4424000084400177},{"id":"https://openalex.org/C205049153","wikidata":"https://www.wikidata.org/wiki/Q2698605","display_name":"Polarization (electrochemistry)","level":2,"score":0.42010000348091125},{"id":"https://openalex.org/C2780598303","wikidata":"https://www.wikidata.org/wiki/Q65921492","display_name":"Flexibility (engineering)","level":2,"score":0.3928000032901764},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.3903000056743622},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.3675999939441681},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.36149999499320984},{"id":"https://openalex.org/C175583648","wikidata":"https://www.wikidata.org/wiki/Q903156","display_name":"Heterogeneous catalysis","level":3,"score":0.3499000072479248},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.34630000591278076},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.3411000072956085},{"id":"https://openalex.org/C2781432337","wikidata":"https://www.wikidata.org/wiki/Q5168035","display_name":"Coordination polymer","level":3,"score":0.32499998807907104},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3246999979019165},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.3244999945163727},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3181000053882599},{"id":"https://openalex.org/C2778150588","wikidata":"https://www.wikidata.org/wiki/Q8884513","display_name":"Azobenzene","level":3,"score":0.3160000145435333},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.31220000982284546},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.3059000074863434},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.28439998626708984},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.2818000018596649},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.2809999883174896},{"id":"https://openalex.org/C114834414","wikidata":"https://www.wikidata.org/wiki/Q15477170","display_name":"Thermal management of electronic devices and systems","level":2,"score":0.27959999442100525},{"id":"https://openalex.org/C2780557392","wikidata":"https://www.wikidata.org/wiki/Q523796","display_name":"Linker","level":2,"score":0.2687999904155731},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.250900000333786}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.26599/nr.2026.94908533","doi":"https://doi.org/10.26599/nr.2026.94908533","is_oa":true,"landing_page_url":"https://doi.org/10.26599/nr.2026.94908533","pdf_url":null,"source":{"id":"https://openalex.org/S173461644","display_name":"Nano Research","issn_l":"1998-0000","issn":["1998-0000","1998-0124"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-2","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nano Research","raw_type":"journal-article"},{"id":"pmh:oai:doaj.org/article:1cd06197e0544376b23da8d9f131c5f7","doi":null,"is_oa":false,"landing_page_url":"https://doaj.org/article/1cd06197e0544376b23da8d9f131c5f7","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Nano Research, Vol 19, Iss 6, p 94908533 (2026)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.26599/nr.2026.94908533","doi":"https://doi.org/10.26599/nr.2026.94908533","is_oa":true,"landing_page_url":"https://doi.org/10.26599/nr.2026.94908533","pdf_url":null,"source":{"id":"https://openalex.org/S173461644","display_name":"Nano Research","issn_l":"1998-0000","issn":["1998-0000","1998-0124"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","jufo-2","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nano Research","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/12","score":0.4234151542186737,"display_name":"Responsible consumption and production"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":47,"referenced_works":["https://openalex.org/W1984023130","https://openalex.org/W2020523448","https://openalex.org/W2058417637","https://openalex.org/W2094325514","https://openalex.org/W2132539996","https://openalex.org/W2134711611","https://openalex.org/W2199635494","https://openalex.org/W2302249387","https://openalex.org/W2566658599","https://openalex.org/W2793079479","https://openalex.org/W2797529406","https://openalex.org/W2884271876","https://openalex.org/W2922308410","https://openalex.org/W2990870353","https://openalex.org/W3003174300","https://openalex.org/W3004077490","https://openalex.org/W3012064499","https://openalex.org/W3096154196","https://openalex.org/W3156758874","https://openalex.org/W3193568471","https://openalex.org/W4224103444","https://openalex.org/W4283587053","https://openalex.org/W4313340484","https://openalex.org/W4318198317","https://openalex.org/W4381515509","https://openalex.org/W4385477615","https://openalex.org/W4389167453","https://openalex.org/W4389274962","https://openalex.org/W4390616305","https://openalex.org/W4391014978","https://openalex.org/W4391280942","https://openalex.org/W4391509136","https://openalex.org/W4392643589","https://openalex.org/W4396561069","https://openalex.org/W4399541103","https://openalex.org/W4399558887","https://openalex.org/W4399757306","https://openalex.org/W4400183738","https://openalex.org/W4400772163","https://openalex.org/W4401715364","https://openalex.org/W4402013389","https://openalex.org/W4406188068","https://openalex.org/W4406587560","https://openalex.org/W4406845160","https://openalex.org/W4407035280","https://openalex.org/W4408030118","https://openalex.org/W4409544408"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"Converting":[1],"ambient":[2],"thermal":[3,179],"fluctuations":[4],"into":[5],"selective":[6],"chemical":[7],"transformations":[8],"represents":[9],"an":[10],"emerging":[11],"strategy":[12],"in":[13,140,165],"sustainable":[14],"catalysis.":[15],"Unlike":[16],"conventional":[17],"thermocatalysis":[18],"that":[19,30],"requires":[20],"continuous":[21],"high-temperature":[22],"input,":[23],"we":[24],"report":[25],"a":[26,101,141,175],"molecular":[27,51,184],"ferroelectric":[28],"platform":[29],"harnesses":[31],"low-grade":[32],"temperature":[33,135],"fluctuations,":[34],"spanning":[35],"industrial,":[36],"environmental,":[37],"biological,":[38],"and":[39,45,55,68,89,111,162,188,197],"mechanical":[40],"sources,":[41],"to":[42,61,191],"drive":[43],"efficient":[44],"tunable":[46,189],"catalytic":[47,73,169],"reactions.":[48],"Two":[49],"copper-based":[50],"ferroelectrics,":[52,185],"[Cu(L-His)(bpy)]ClO4":[53],"(Cu-FE-1)":[54],"[Cu(L-phe)(bpy)(H2O)]PF6\u00b7H2O":[56],"(Cu-FE-2),":[57],"were":[58],"rationally":[59],"designed":[60],"elucidate":[62],"the":[63,69,92,123,156],"impact":[64],"of":[65,94,105,109,117,126,143,159,178],"coordination":[66,163],"environment":[67],"dipolar":[70],"orientation":[71],"on":[72,183],"performance.":[74],"For":[75],"example,":[76],"under":[77,131,195],"simulated":[78],"industrial":[79],"waste":[80],"heat":[81],"cycling,":[82],"both":[83],"compounds":[84],"exhibited":[85],"pronounced":[86],"pyroelectric":[87],"responses":[88],"efficiently":[90],"catalyzed":[91],"cycloaddition":[93],"CO2":[95],"with":[96,98,128],"propargylamine,":[97],"Cu-FE-1":[99,149],"achieving":[100],"turnover":[102],"number":[103],"(TON)":[104],"5064":[106],"(a":[107,115],"yield":[108,116,142],"98%)":[110],"Cu-FE-2":[112,120],"reaching":[113],"4876":[114],"94%).":[118],"Notably,":[119],"further":[121],"enabled":[122],"C\u2013O":[124],"cross-coupling":[125],"phenol":[127],"aryl":[129],"bromides":[130],"conditions":[132],"mimicking":[133],"diurnal":[134],"variations,":[136],"delivering":[137],"diphenyl":[138],"ether":[139],"98%":[144],"(TON":[145],"=":[146],"4742),":[147],"whereas":[148],"was":[150],"inactive.":[151],"This":[152],"divergent":[153],"reactivity":[154],"underscores":[155],"critical":[157],"role":[158],"structural":[160],"polarization":[161],"flexibility":[164],"dictating":[166],"thermally":[167],"induced":[168],"pathways.":[170],"Overall,":[171],"this":[172],"work":[173],"introduces":[174],"new":[176],"paradigm":[177],"fluctuation-driven":[180],"catalysis":[181],"based":[182],"offering":[186],"programmable":[187],"access":[190],"multiple":[192],"reaction":[193],"types":[194],"mild":[196],"field-free":[198],"conditions.":[199]},"counts_by_year":[],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2026-02-08T00:00:00"}