{"id":"https://openalex.org/W7127037652","doi":"https://doi.org/10.1002/anie.202523731","title":"Substituent\u2010Induced Secondary Interactions Reprogram Ion Permselectivity in Cationic Covalent Organic Framework Membranes","display_name":"Substituent\u2010Induced Secondary Interactions Reprogram Ion Permselectivity in Cationic Covalent Organic Framework Membranes","publication_year":2026,"publication_date":"2026-02-01","ids":{"openalex":"https://openalex.org/W7127037652","doi":"https://doi.org/10.1002/anie.202523731","pmid":"https://pubmed.ncbi.nlm.nih.gov/41622591"},"language":"en","primary_location":{"id":"doi:10.1002/anie.202523731","doi":"https://doi.org/10.1002/anie.202523731","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202523731","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202523731","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202523731","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5124731223","display_name":"Jiaming Yi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiaming Yi","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5124740234","display_name":"Zhiwei Xing","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhiwei Xing","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101258966","display_name":"Zhuozhi Lai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhuozhi Lai","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5124711569","display_name":"Qing Guo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qing Guo","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5124728249","display_name":"Huixia Lv","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Huixia Lv","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5133573738","display_name":"Sai Wang","orcid":"https://orcid.org/0000-0003-3849-0511","observed_orcids":["https://orcid.org/0000-0003-3849-0511"]},"institutions":[{"id":"https://openalex.org/I135237710","display_name":"Zhejiang Normal University","ror":"https://ror.org/01vevwk45","country_code":"CN","type":"education","lineage":["https://openalex.org/I135237710"]},{"id":"https://openalex.org/I163151501","display_name":"Hangzhou Normal University","ror":"https://ror.org/014v1mr15","country_code":"CN","type":"education","lineage":["https://openalex.org/I163151501"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Sai Wang","raw_affiliation_strings":["Hangzhou Institute of Advanced Studies Zhejiang Normal University  Hangzhou China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Hangzhou Institute of Advanced Studies Zhejiang Normal University  Hangzhou China","institution_ids":["https://openalex.org/I135237710","https://openalex.org/I163151501"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5124697728","display_name":"Qi Sun","orcid":"https://orcid.org/0000-0001-9230-3487","observed_orcids":["https://orcid.org/0000-0001-9230-3487","https://orcid.org/0000-0002-1698-8741"]},"institutions":[{"id":"https://openalex.org/I76130692","display_name":"Zhejiang University","ror":"https://ror.org/00a2xv884","country_code":"CN","type":"education","lineage":["https://openalex.org/I76130692"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qi Sun","raw_affiliation_strings":["Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China"],"raw_orcid":"https://orcid.org/0000-0001-9230-3487","affiliations":[{"raw_affiliation_string":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou China","institution_ids":["https://openalex.org/I76130692"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5124697728"],"corresponding_institution_ids":["https://openalex.org/I76130692"],"apc_list":{"value":5510,"currency":"USD","value_usd":5510},"apc_paid":null,"fwci":5.7868,"has_fulltext":true,"cited_by_count":4,"citation_normalized_percentile":{"value":0.95586549,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":99},"biblio":{"volume":"65","issue":"11","first_page":"e23731","last_page":"e23731"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.9434000253677368,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.9434000253677368,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11582","display_name":"Nanopore and Nanochannel Transport Studies","score":0.027499999850988388,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12074","display_name":"Membrane-based Ion Separation Techniques","score":0.01889999955892563,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/covalent-organic-framework-membranes","display_name":"covalent organic framework membranes","score":0.8759999871253967},{"id":"https://openalex.org/keywords/substituent-effects","display_name":"substituent effects","score":0.6669999957084656},{"id":"https://openalex.org/keywords/secondary-interactions","display_name":"secondary interactions","score":0.8309999704360962},{"id":"https://openalex.org/keywords/anion-selectivity","display_name":"anion selectivity","score":0.6230000257492065},{"id":"https://openalex.org/keywords/cation-selectivity","display_name":"cation selectivity","score":0.7649999856948853},{"id":"https://openalex.org/keywords/surface-potential","display_name":"surface potential","score":0.49300000071525574},{"id":"https://openalex.org/keywords/ionic-thermoelectricity","display_name":"ionic thermoelectricity","score":0.7519999742507935},{"id":"https://openalex.org/keywords/ion-transport","display_name":"ion transport","score":0.460999995470047}],"concepts":[{"id":"https://openalex.org/C41625074","wikidata":"https://www.wikidata.org/wiki/Q176088","display_name":"Membrane","level":2,"score":0.7954000234603882},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7484999895095825},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.6381000280380249},{"id":"https://openalex.org/C130349721","wikidata":"https://www.wikidata.org/wiki/Q5434705","display_name":"Faraday efficiency","level":4,"score":0.5669999718666077},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.555400013923645},{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.5335999727249146},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.5324000120162964},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.5187000036239624},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4011000096797943},{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.35499998927116394},{"id":"https://openalex.org/C2779825165","wikidata":"https://www.wikidata.org/wiki/Q101497","display_name":"Aldehyde","level":3,"score":0.34790000319480896},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3458000123500824},{"id":"https://openalex.org/C99975950","wikidata":"https://www.wikidata.org/wiki/Q911011","display_name":"Ion transporter","level":3,"score":0.32440000772476196},{"id":"https://openalex.org/C125501631","wikidata":"https://www.wikidata.org/wiki/Q1587185","display_name":"Biological membrane","level":3,"score":0.3158000111579895},{"id":"https://openalex.org/C155515750","wikidata":"https://www.wikidata.org/wiki/Q1059955","display_name":"Synthetic membrane","level":3,"score":0.29750001430511475},{"id":"https://openalex.org/C94421946","wikidata":"https://www.wikidata.org/wiki/Q17043863","display_name":"Donnan potential","level":4,"score":0.29440000653266907},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.29330000281333923},{"id":"https://openalex.org/C50254741","wikidata":"https://www.wikidata.org/wiki/Q62536","display_name":"Ion channel","level":3,"score":0.2930000126361847},{"id":"https://openalex.org/C181911157","wikidata":"https://www.wikidata.org/wiki/Q389844","display_name":"Membrane potential","level":2,"score":0.2874000072479248},{"id":"https://openalex.org/C107511713","wikidata":"https://www.wikidata.org/wiki/Q866317","display_name":"Semipermeable membrane","level":3,"score":0.28610000014305115},{"id":"https://openalex.org/C3128022","wikidata":"https://www.wikidata.org/wiki/Q2290646","display_name":"Electrodialysis","level":3,"score":0.2734000086784363},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.26899999380111694},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.2653000056743622},{"id":"https://openalex.org/C2777893391","wikidata":"https://www.wikidata.org/wiki/Q5178887","display_name":"Covalent organic framework","level":3,"score":0.26249998807907104},{"id":"https://openalex.org/C179366358","wikidata":"https://www.wikidata.org/wiki/Q909212","display_name":"Metal-organic framework","level":3,"score":0.25279998779296875}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/anie.202523731","doi":"https://doi.org/10.1002/anie.202523731","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202523731","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202523731","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:41622591","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/41622591","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1002/anie.202523731","doi":"https://doi.org/10.1002/anie.202523731","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202523731","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202523731","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-3","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.9051496386528015}],"study_designs":[],"awards":[{"id":"https://openalex.org/G3659998680","display_name":null,"funder_award_id":"22421004","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G5657283803","display_name":null,"funder_award_id":"2022YFA1503004","funder_id":"https://openalex.org/F4320335777","funder_display_name":"National Key Research and Development Program of China"},{"id":"https://openalex.org/G5794890067","display_name":null,"funder_award_id":"2024YFB3815700","funder_id":"https://openalex.org/F4320335777","funder_display_name":"National Key Research and Development Program of China"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320335777","display_name":"National Key Research and Development Program of China","ror":null}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W7127037652.pdf","grobid_xml":"https://content.openalex.org/works/W7127037652.grobid-xml"},"referenced_works_count":63,"referenced_works":["https://openalex.org/W1596571618","https://openalex.org/W1987475238","https://openalex.org/W1999838269","https://openalex.org/W2012037219","https://openalex.org/W2033465655","https://openalex.org/W2091701866","https://openalex.org/W2094310458","https://openalex.org/W2121116991","https://openalex.org/W2266412763","https://openalex.org/W2340538439","https://openalex.org/W2594238106","https://openalex.org/W2626386330","https://openalex.org/W2755639092","https://openalex.org/W2781831224","https://openalex.org/W2944409279","https://openalex.org/W2958827861","https://openalex.org/W2971665593","https://openalex.org/W2975789532","https://openalex.org/W2989998378","https://openalex.org/W2996675094","https://openalex.org/W2999677060","https://openalex.org/W3021989619","https://openalex.org/W3119829667","https://openalex.org/W3127427817","https://openalex.org/W3149833912","https://openalex.org/W3154531792","https://openalex.org/W3187512732","https://openalex.org/W3203181187","https://openalex.org/W3217191737","https://openalex.org/W4212905264","https://openalex.org/W4283652416","https://openalex.org/W4285801787","https://openalex.org/W4304193560","https://openalex.org/W4305040310","https://openalex.org/W4315786542","https://openalex.org/W4381549487","https://openalex.org/W4384627056","https://openalex.org/W4391450019","https://openalex.org/W4391973305","https://openalex.org/W4392283131","https://openalex.org/W4399922639","https://openalex.org/W4400079881","https://openalex.org/W4400179489","https://openalex.org/W4401441762","https://openalex.org/W4404125243","https://openalex.org/W4404418320","https://openalex.org/W4406475890","https://openalex.org/W4407037591","https://openalex.org/W4408244940","https://openalex.org/W4408622516","https://openalex.org/W4409055554","https://openalex.org/W4409074043","https://openalex.org/W4409172503","https://openalex.org/W4409349831","https://openalex.org/W4409622975","https://openalex.org/W4409835023","https://openalex.org/W4410174891","https://openalex.org/W4410175477","https://openalex.org/W4410709558","https://openalex.org/W4411025392","https://openalex.org/W4411208211","https://openalex.org/W4411904063","https://openalex.org/W4412757636"],"related_works":[],"abstract_inverted_index":{"ABSTRACT":[0],"Precise":[1],"modulation":[2],"of":[3,30,63,209],"ion":[4,28,145,200],"permselectivity":[5,146],"in":[6],"synthetic":[7],"membranes":[8,36,212],"is":[9],"crucial":[10],"for":[11,166,176,198,213],"advancing":[12],"separation":[13],"and":[14,61,83,103,143,170,195,216],"energy":[15,214],"conversion":[16],"technologies.":[17],"Here,":[18],"we":[19,55,156],"demonstrate":[20],"that":[21,42,74],"neutral":[22],"substituents":[23,64,70],"can":[24],"reprogram":[25],"the":[26,59,76,96,105,115,137,149,207],"intrinsic":[27],"selectivity":[29,204],"cationic":[31],"covalent":[32],"organic":[33],"framework":[34,151],"(COF)":[35],"by":[37],"introducing":[38],"secondary":[39,72,190],"local":[40,138],"interactions":[41,73,79,100,191],"compete":[43],"with":[44,206],"long\u2010range":[45],"Coulombic":[46,78,128],"forces.":[47],"Using":[48],"triaminoguanidinium\u2010based":[49],"COFs":[50],"as":[51,192],"a":[52,167,177,181,193],"model":[53],"system,":[54],"systematically":[56],"varied":[57],"both":[58],"number":[60],"type":[62],"on":[65,95],"1,3,5\u2010trialdehyde":[66],"linkers.":[67],"The":[68],"introduced":[69],"generated":[71],"modulated":[75],"primary":[77],"between":[80],"guanidinium":[81],"cations":[82],"Cl":[84],"\u2013":[85],"counterions.":[86],"When":[87],"two":[88],"or":[89],"more":[90],"hydroxyl":[91],"groups":[92],"were":[93],"present":[94],"aldehyde":[97],"linkers,":[98],"these":[99],"immobilized":[101],"anions":[102],"inverted":[104],"effective":[106],"surface":[107],"potential":[108],"from":[109,118],"positive":[110],"to":[111,120],"negative,":[112],"thereby":[113],"switching":[114],"transport":[116],"polarity":[117],"anion\u2010":[119],"cation\u2010selective":[121],"behavior.":[122],"In":[123],"contrast,":[124],"methoxy":[125],"substitution":[126],"weakened":[127],"interactions,":[129],"enhancing":[130],"anion":[131],"selectivity.":[132],"This":[133,186],"tunable":[134],"control":[135],"over":[136],"chemical":[139],"microenvironment":[140],"enabled":[141],"programmable":[142],"reversible":[144],"without":[147],"altering":[148],"permanent":[150],"charge.":[152],"Leveraging":[153],"this":[154],"mechanism,":[155],"achieved":[157],"record\u2010high":[158],"ionic":[159],"thermoelectric":[160],"performance,":[161],"25.9":[162],"W":[163,172],"m":[164,173],"\u22122":[165],"single":[168],"membrane":[169],"39.1":[171],"\u2212":[174],"2":[175],"stacked":[178],"configuration":[179],"under":[180],"50":[182],"K":[183],"temperature":[184],"gradient.":[185],"work":[187],"establishes":[188],"substituent\u2010mediated":[189],"general":[194],"powerful":[196],"strategy":[197],"programming":[199],"transport,":[201],"bridging":[202],"biological":[203],"principles":[205],"design":[208],"adaptive":[210],"COF\u2010based":[211],"harvesting":[215],"separation.":[217]},"counts_by_year":[{"year":2026,"cited_by_count":4}],"updated_date":"2026-09-27T08:07:27.782135","created_date":"2026-02-03T00:00:00"}