{"id":"https://openalex.org/W7121905005","doi":"https://doi.org/10.1134/s0022476625120029","title":"Synthesis of a Layered Terbium(III) Metal-Organic Framework with bis(pyrazol-1-yl)Methane-4,4\u2032-Dicarboxylic Acid and its Sensory Properties as a Biomarker for Spore-Forming Bacteria","display_name":"Synthesis of a Layered Terbium(III) Metal-Organic Framework with bis(pyrazol-1-yl)Methane-4,4\u2032-Dicarboxylic Acid and its Sensory Properties as a Biomarker for Spore-Forming Bacteria","publication_year":2025,"publication_date":"2025-12-01","ids":{"openalex":"https://openalex.org/W7121905005","doi":"https://doi.org/10.1134/s0022476625120029"},"language":"en","primary_location":{"id":"doi:10.1134/s0022476625120029","doi":"https://doi.org/10.1134/s0022476625120029","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0022476625120029","pdf_url":null,"source":{"id":"https://openalex.org/S111479809","display_name":"Journal of Structural Chemistry","issn_l":"0022-4766","issn":["0022-4766","1573-8779"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Structural Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5122727525","display_name":"A. I. Nesterova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. I. Nesterova","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5122741115","display_name":"Alexey A. Ryadun","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. A. Ryadun","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5122727822","display_name":"Dmitry I. Pavlov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"D. I. Pavlov","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5122723046","display_name":"A. S. Potapov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"A. S. Potapov","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5122723046"],"corresponding_institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"],"apc_list":null,"apc_paid":null,"fwci":0.4336,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.57993515,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":96,"max":97},"biblio":{"volume":"66","issue":"12","first_page":"2487","last_page":"2494"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11279","display_name":"Lanthanide and Transition Metal Complexes","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/layered-mofs","display_name":"layered MOFs","score":0.9449999928474426},{"id":"https://openalex.org/keywords/pyrazole-ligands","display_name":"pyrazole ligands","score":0.6019999980926514},{"id":"https://openalex.org/keywords/luminescent-mofs","display_name":"luminescent MOFs","score":0.75},{"id":"https://openalex.org/keywords/luminescent-sensing","display_name":"luminescence sensing","score":0.6899999976158142},{"id":"https://openalex.org/keywords/dipicolinic-acid","display_name":"dipicolinic acid","score":0.9380000233650208},{"id":"https://openalex.org/keywords/hydrogen-bonded-layers","display_name":"hydrogen-bonded layers","score":0.6890000104904175},{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.7519999742507935},{"id":"https://openalex.org/keywords/solvothermal-synthesis","display_name":"solvothermal synthesis","score":0.7549999952316284}],"concepts":[{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.7674000263214111},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7131999731063843},{"id":"https://openalex.org/C60100273","wikidata":"https://www.wikidata.org/wiki/Q902806","display_name":"Thermogravimetric analysis","level":2,"score":0.6618000268936157},{"id":"https://openalex.org/C148869448","wikidata":"https://www.wikidata.org/wiki/Q184240","display_name":"Luminescence","level":2,"score":0.572700023651123},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.5616999864578247},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5489000082015991},{"id":"https://openalex.org/C2778074193","wikidata":"https://www.wikidata.org/wiki/Q3498942","display_name":"Carboxylate","level":2,"score":0.5372999906539917},{"id":"https://openalex.org/C59061564","wikidata":"https://www.wikidata.org/wiki/Q7783071","display_name":"Thermal stability","level":2,"score":0.5321000218391418},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.5138000249862671},{"id":"https://openalex.org/C166950319","wikidata":"https://www.wikidata.org/wiki/Q245031","display_name":"Intermolecular force","level":3,"score":0.4375999867916107},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.40540000796318054},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3873000144958496},{"id":"https://openalex.org/C171001562","wikidata":"https://www.wikidata.org/wiki/Q2856048","display_name":"Quantum yield","level":3,"score":0.37630000710487366},{"id":"https://openalex.org/C2781197716","wikidata":"https://www.wikidata.org/wiki/Q864574","display_name":"Biomarker","level":2,"score":0.35749998688697815},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.3488999903202057},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.34439998865127563},{"id":"https://openalex.org/C160756335","wikidata":"https://www.wikidata.org/wiki/Q669391","display_name":"Biosensor","level":2,"score":0.32600000500679016},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.31630000472068787},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.3142000138759613},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2808000147342682},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.2694000005722046},{"id":"https://openalex.org/C523546767","wikidata":"https://www.wikidata.org/wiki/Q10876","display_name":"Bacteria","level":2,"score":0.2689000070095062},{"id":"https://openalex.org/C7082614","wikidata":"https://www.wikidata.org/wiki/Q849523","display_name":"Calcination","level":3,"score":0.25099998712539673}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1134/s0022476625120029","doi":"https://doi.org/10.1134/s0022476625120029","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0022476625120029","pdf_url":null,"source":{"id":"https://openalex.org/S111479809","display_name":"Journal of Structural Chemistry","issn_l":"0022-4766","issn":["0022-4766","1573-8779"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Structural Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6","score":0.7311217188835144}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W1969360633","https://openalex.org/W2011008582","https://openalex.org/W2087569879","https://openalex.org/W2132454074","https://openalex.org/W2146426024","https://openalex.org/W2545027704","https://openalex.org/W2584354701","https://openalex.org/W3120568214","https://openalex.org/W3169816273","https://openalex.org/W3175596167","https://openalex.org/W3214996386","https://openalex.org/W4200305630","https://openalex.org/W4283015445","https://openalex.org/W4311505933","https://openalex.org/W4386873153","https://openalex.org/W4389153192","https://openalex.org/W4390726856","https://openalex.org/W4392806767","https://openalex.org/W4400212919","https://openalex.org/W4403943007","https://openalex.org/W4404234871","https://openalex.org/W4404762136","https://openalex.org/W4409300214","https://openalex.org/W4409666066","https://openalex.org/W4410830062","https://openalex.org/W4411353988","https://openalex.org/W4413821232","https://openalex.org/W4414302393"],"related_works":[],"abstract_inverted_index":{"Abstract":[0],"A":[1],"new":[2],"layered":[3,25],"metal-organic":[4],"framework":[5,26],"(MOF)":[6],"{[Tb2(H2O)2L3]\u00b7H2O\u00b7CH3CN}n":[7],"is":[8,23,84,90,96],"obtained":[9],"by":[10,38,48,56],"the":[11,71,87,99,104],"solvothermal":[12],"synthesis":[13],"from":[14],"terbium(III)":[15],"nitrate":[16],"and":[17,52,58,86],"bis(pyrazol-1-yl)methane-4,4\u2032-dicarboxylic":[18],"acid":[19,111],"(H2L).":[20],"The":[21,44,61,80,93],"compound":[22],"a":[24,65,113],"formed":[27],"of":[28,31,41,73,98,103,116],"two":[29],"types":[30],"binuclear":[32],"secondary":[33],"building":[34],"units":[35],"{Tb2}":[36],"linked":[37],"carboxylate":[39],"groups":[40],"L2\u2013":[42],"ligands.":[43],"layers":[45],"are":[46],"stabilized":[47],"intermolecular":[49],"hydrogen":[50],"bonds":[51],"contain":[53],"channels":[54],"occupied":[55],"water":[57],"acetonitrile":[59,108],"molecules.":[60],"thermogravimetric":[62],"analysis":[63],"shows":[64],"high":[66,94],"thermal":[67],"MOF":[68,105],"stability":[69],"after":[70],"removal":[72],"guest":[74],"molecules":[75],"up":[76],"to":[77,109],"400":[78],"\u00b0C.":[79],"luminescence":[81,100],"quantum":[82],"yield":[83],"25%,":[85],"excited-state":[88],"lifetime":[89],"1.19":[91],"ms.":[92],"selectivity":[95],"demonstrated":[97],"sensory":[101],"response":[102],"suspension":[106],"in":[107],"2,6-pyridinedicarboxylic":[110],"(DPA),":[112],"key":[114],"biomarker":[115],"spore-forming":[117],"bacteria.":[118]},"counts_by_year":[{"year":2026,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2026-01-11T00:00:00"}