{"id":"https://openalex.org/W7118916005","doi":"https://doi.org/10.1021/acs.langmuir.5c02978","title":"Enhanced Adsorptive Removal of Chlorpyrifos and Malathion by Functionalized Mesoporous Silica: A Detailed Insight Into Kinetics, Isotherm, and Statistical Surface Modeling","display_name":"Enhanced Adsorptive Removal of Chlorpyrifos and Malathion by Functionalized Mesoporous Silica: A Detailed Insight Into Kinetics, Isotherm, and Statistical Surface Modeling","publication_year":2026,"publication_date":"2026-01-05","ids":{"openalex":"https://openalex.org/W7118916005","doi":"https://doi.org/10.1021/acs.langmuir.5c02978","pmid":"https://pubmed.ncbi.nlm.nih.gov/41491017"},"language":"en","primary_location":{"id":"doi:10.1021/acs.langmuir.5c02978","doi":"https://doi.org/10.1021/acs.langmuir.5c02978","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.5c02978","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109788361","display_name":"Subhashree Mohanty","orcid":"https://orcid.org/0009-0002-1999-3690","observed_orcids":["https://orcid.org/0009-0002-1999-3690"]},"institutions":[{"id":"https://openalex.org/I70699430","display_name":"Utkal University","ror":"https://ror.org/0034eez47","country_code":"IN","type":"education","lineage":["https://openalex.org/I70699430"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Subhashree Mohanty","raw_affiliation_strings":["Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, Odisha, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, Odisha, India","institution_ids":["https://openalex.org/I70699430"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5075175545","display_name":"Sushanta K. Badamali","orcid":"https://orcid.org/0000-0003-0526-0146","observed_orcids":["https://orcid.org/0000-0003-0526-0146"]},"institutions":[{"id":"https://openalex.org/I70699430","display_name":"Utkal University","ror":"https://ror.org/0034eez47","country_code":"IN","type":"education","lineage":["https://openalex.org/I70699430"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Sushanta Kumar Badamali","raw_affiliation_strings":["Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, Odisha, India"],"raw_orcid":"https://orcid.org/0000-0003-0526-0146","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, Odisha, India","institution_ids":["https://openalex.org/I70699430"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5075175545"],"corresponding_institution_ids":["https://openalex.org/I70699430"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":7.1239,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":{"value":0.96481948,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":97,"max":98},"biblio":{"volume":"42","issue":"2","first_page":"1888","last_page":"1904"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10016","display_name":"Adsorption and biosorption for pollutant removal","score":0.9390000104904175,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10016","display_name":"Adsorption and biosorption for pollutant removal","score":0.9390000104904175,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11180","display_name":"Pesticide and Herbicide Environmental Studies","score":0.019899999722838402,"subfield":{"id":"https://openalex.org/subfields/2310","display_name":"Pollution"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.01810000091791153,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chlorpyrifos","display_name":"chlorpyrifos","score":0.996999979019165},{"id":"https://openalex.org/keywords/malathion","display_name":"malathion","score":1.0},{"id":"https://openalex.org/keywords/pesticide-adsorption","display_name":"pesticide adsorption","score":0.871999979019165},{"id":"https://openalex.org/keywords/mcm-48","display_name":"MCM-48","score":0.9120000004768372},{"id":"https://openalex.org/keywords/3-aminopropyltriethoxysilane","display_name":"3-aminopropyltriethoxysilane","score":0.9139999747276306},{"id":"https://openalex.org/keywords/mesoporous-silica","display_name":"mesoporous silica","score":0.75},{"id":"https://openalex.org/keywords/adsorption-kinetics","display_name":"adsorption kinetics","score":0.7760000228881836},{"id":"https://openalex.org/keywords/adsorption-isotherms","display_name":"adsorption isotherms","score":0.8709999918937683},{"id":"https://openalex.org/keywords/adsorption-thermodynamics","display_name":"adsorption thermodynamics","score":0.8569999933242798},{"id":"https://openalex.org/keywords/adsorbent-reusability","display_name":"adsorbent reusability","score":0.8579999804496765},{"id":"https://openalex.org/keywords/desorption","display_name":"desorption","score":0.5379999876022339},{"id":"https://openalex.org/keywords/surface-functionalization","display_name":"surface functionalization","score":0.4180000126361847},{"id":"https://openalex.org/keywords/wastewater-treatment","display_name":"wastewater treatment","score":0.3310000002384186}],"concepts":[{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.848800003528595},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7885000109672546},{"id":"https://openalex.org/C2776638905","wikidata":"https://www.wikidata.org/wiki/Q423005","display_name":"Malathion","level":3,"score":0.6740999817848206},{"id":"https://openalex.org/C2776304672","wikidata":"https://www.wikidata.org/wiki/Q414915","display_name":"Chlorpyrifos","level":3,"score":0.6175000071525574},{"id":"https://openalex.org/C161176658","wikidata":"https://www.wikidata.org/wiki/Q131656","display_name":"Pesticide","level":2,"score":0.5149999856948853},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.49570000171661377},{"id":"https://openalex.org/C12143843","wikidata":"https://www.wikidata.org/wiki/Q6486358","display_name":"Langmuir adsorption model","level":3,"score":0.48919999599456787},{"id":"https://openalex.org/C82776694","wikidata":"https://www.wikidata.org/wiki/Q380049","display_name":"Mesoporous material","level":3,"score":0.47589999437332153},{"id":"https://openalex.org/C115958267","wikidata":"https://www.wikidata.org/wiki/Q464196","display_name":"Langmuir","level":3,"score":0.43860000371932983},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.40869998931884766},{"id":"https://openalex.org/C150581940","wikidata":"https://www.wikidata.org/wiki/Q622205","display_name":"Specific surface area","level":3,"score":0.362199991941452},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3569999933242798},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.35190001130104065},{"id":"https://openalex.org/C2776051353","wikidata":"https://www.wikidata.org/wiki/Q415090","display_name":"Carbaryl","level":3,"score":0.3472999930381775},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.33959999680519104},{"id":"https://openalex.org/C45119746","wikidata":"https://www.wikidata.org/wiki/Q205949","display_name":"Exothermic reaction","level":2,"score":0.3325999975204468},{"id":"https://openalex.org/C27923307","wikidata":"https://www.wikidata.org/wiki/Q795838","display_name":"BET theory","level":3,"score":0.33000001311302185},{"id":"https://openalex.org/C58226133","wikidata":"https://www.wikidata.org/wiki/Q1324199","display_name":"Pulmonary surfactant","level":2,"score":0.3093000054359436},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.2989000082015991},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2581999897956848},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.25589999556541443}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.langmuir.5c02978","doi":"https://doi.org/10.1021/acs.langmuir.5c02978","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.5c02978","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:41491017","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/41491017","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.833299994468689,"id":"https://metadata.un.org/sdg/12","display_name":"Responsible consumption and production"},{"score":0.6618000268936157,"id":"https://metadata.un.org/sdg/6","display_name":"Clean water and sanitation"}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F6997931735","display_name":"Government of Odisha","ror":null}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W1993234562","https://openalex.org/W2019072197","https://openalex.org/W2025686336","https://openalex.org/W2043011451","https://openalex.org/W2058504427","https://openalex.org/W2076466860","https://openalex.org/W2088501253","https://openalex.org/W2092410844","https://openalex.org/W2093481442","https://openalex.org/W2288734410","https://openalex.org/W2326416260","https://openalex.org/W2327349393","https://openalex.org/W2755577988","https://openalex.org/W2782336314","https://openalex.org/W2797198702","https://openalex.org/W2895077284","https://openalex.org/W2946626424","https://openalex.org/W2963494278","https://openalex.org/W3015585889","https://openalex.org/W3084154897","https://openalex.org/W3122132581","https://openalex.org/W4211093768","https://openalex.org/W4225706851","https://openalex.org/W4282033635","https://openalex.org/W4293107507","https://openalex.org/W4297503047","https://openalex.org/W4307189301","https://openalex.org/W4323653538","https://openalex.org/W4365458642","https://openalex.org/W4366606894","https://openalex.org/W4366817307","https://openalex.org/W4383998268","https://openalex.org/W4388126749","https://openalex.org/W4393192512","https://openalex.org/W4400217284","https://openalex.org/W4404135725","https://openalex.org/W4404413103","https://openalex.org/W4406387968","https://openalex.org/W4407943018"],"related_works":["https://openalex.org/W4392926399","https://openalex.org/W4415045011","https://openalex.org/W4404413103","https://openalex.org/W4407867907","https://openalex.org/W7213398834","https://openalex.org/W7033521178","https://openalex.org/W4392452909","https://openalex.org/W4379409565","https://openalex.org/W2070780782","https://openalex.org/W4296380330"],"abstract_inverted_index":{"Chlorpyrifos":[0],"and":[1,34,41,63,87,96,108,180,193,200,223,258],"malathion":[2,97],"are":[3],"both":[4,247],"widely":[5],"used":[6],"pesticides":[7,248],"that":[8,94,209],"pose":[9],"significant":[10,243],"hazards":[11],"to":[12,85],"the":[13,51,70,73,82,102,112,177,198,210],"environment.":[14],"Siliceous":[15],"MCM-48":[16],"functionalized":[17],"with":[18,57,140,159],"3-Aminopropyltriethoxysilane":[19],"modification":[20],"(AMCM-48)":[21],"was":[22,126,138,150,157,212],"employed":[23],"as":[24],"a":[25,256],"highly":[26],"efficient":[27,262],"adsorbent,":[28],"achieving":[29],"removal":[30,121],"capacities":[31,245],"of":[32,46,61,72,105,114,123,136,143,162,203],"957":[33],"540":[35],"mg":[36,133,142,154,161],"g":[37,67,91],"\u20131":[38,92,135,156],"for":[39,246,261],"chlorpyrifos":[40,95],"malathion,":[42],"respectively.":[43],"The":[44,119,170,184,205],"presence":[45],"characteristic":[47],"XRD":[48],"patterns":[49],"in":[50,81],"range":[52],"2\u03b8":[53],"=":[54],"2\u20135\u00b0,":[55],"along":[56],"BET":[58],"surface":[59,83,217],"areas":[60],"787":[62],"593":[64],"m":[65,89],"2":[66,90],"\u20131,":[68],"ascertained":[69],"retention":[71],"mesoporous":[74],"structure":[75],"during":[76],"functionalization.":[77],"A":[78],"subsequent":[79],"drop":[80],"area":[84],"197":[86],"191":[88],"indicates":[93],"are,":[98],"respectively,":[99],"adsorbed":[100],"onto":[101],"internal":[103],"pores":[104],"AMCM-48.":[106,118],"FTIR":[107],"EDX":[109],"characterization":[110],"confirmed":[111],"uptake":[113,149],"pesticide":[115,263],"molecules":[116],"by":[117,168,215],"maximum":[120],"efficiency":[122],"CP":[124,137],"(90.02%)":[125],"obtained":[127],"within":[128],"27":[129],"min,":[130],"when":[131,152],"90":[132],"L":[134,155],"contacted":[139,158],"40":[141],"AMCM-48,":[144],"at":[145,164,227],"31":[146],"\u00b0C.":[147],"MTH":[148],"86.24%":[151],"12":[153],"35":[160],"adsorbent":[163,260],"41":[165],"\u00b0C,":[166],"optimized":[167],"RSM-CCD.":[169],"adsorption":[171,211,244],"parametric":[172],"studies":[173],"fitted":[174],"well":[175],"into":[176],"Langmuir":[178],"model":[179],"pseudo-second":[181],"order":[182],"kinetics.":[183],"thermodynamic":[185],"parameters":[186],"(\u0394":[187],"G":[188],"\u00b0,":[189,192],"\u0394":[190,194],"H":[191],"S":[195],"\u00b0)":[196],"indicated":[197,208],"exothermic":[199],"spontaneous":[201],"nature":[202],"adsorption.":[204],"above":[206],"analyses":[207],"primarily":[213],"driven":[214],"high":[216],"area,":[218],"hydrogen":[219],"bonding,":[220],"dipole\u2013dipole":[221],"interactions,":[222],"electrostatic":[224],"forces.":[225],"Desorption":[226],"higher":[228],"pH":[229],"achieved":[230],"approximately":[231],"85%":[232],"recovery,":[233],"reflecting":[234],"reversible":[235],"physical":[236],"interactions.":[237],"AMCM-48":[238,254],"demonstrated":[239],"excellent":[240],"reusability,":[241],"maintaining":[242],"over":[249],"seven":[250],"consecutive":[251],"cycles.":[252],"Overall,":[253],"is":[255],"simple":[257],"sustainable":[259],"removal.":[264]},"counts_by_year":[{"year":2026,"cited_by_count":5}],"updated_date":"2026-11-13T13:42:25.865203","created_date":"2026-01-08T00:00:00"}