{"id":"https://openalex.org/W7043715745","doi":null,"title":"The surface chemistry of oxides, hydroxides, and oxide minerals","display_name":"The surface chemistry of oxides, hydroxides, and oxide minerals","publication_year":1987,"publication_date":"1987-01-01","ids":{"openalex":"https://openalex.org/W7043715745"},"language":"en","primary_location":{"id":"pmh:oai:dora:eawag_11101","doi":null,"is_oa":false,"landing_page_url":"https://www.dora.lib4ri.ch/eawag/islandora/object/eawag%3A11101","pdf_url":null,"source":{"id":"https://openalex.org/S4306400127","display_name":"DORA Eawag (Swiss Federal Institute of Aquatic Science and Technology (Eawag))","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I63664421","host_organization_name":"Swiss Federal Institute of Aquatic Science and Technology","host_organization_lineage":["https://openalex.org/I63664421"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Book Chapter"},"volume":null,"type":"book-chapter","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109540542","display_name":"PAUL W. SCHINDLER","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Schindler, Paul W. (author)","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5046774809","display_name":"Werner Stumm","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Stumm, Werner (author)","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":12.5992,"has_fulltext":false,"cited_by_count":218,"citation_normalized_percentile":{"value":0.9898167,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":true,"primary_topic":{"id":"https://openalex.org/T11740","display_name":"Geochemistry and Elemental Analysis","score":0.3467000126838684,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11740","display_name":"Geochemistry and Elemental Analysis","score":0.3467000126838684,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.12389999628067017,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11877","display_name":"Iron oxide chemistry and applications","score":0.0877000018954277,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydroxide","display_name":"hydroxide","score":0.7170000076293945},{"id":"https://openalex.org/keywords/oxide-minerals","display_name":"oxide minerals","score":0.9900000095367432},{"id":"https://openalex.org/keywords/oxide-water-interface","display_name":"oxide-water interface","score":0.8500000238418579},{"id":"https://openalex.org/keywords/surface-hydroxyl-groups","display_name":"surface hydroxyl groups","score":0.9509999752044678},{"id":"https://openalex.org/keywords/lewis-acid-sites","display_name":"Lewis acid sites","score":0.6759999990463257},{"id":"https://openalex.org/keywords/metal-ion-adsorption","display_name":"metal ion adsorption","score":0.796999990940094},{"id":"https://openalex.org/keywords/anion-adsorption","display_name":"anion adsorption","score":0.9470000267028809},{"id":"https://openalex.org/keywords/ligand-adsorption","display_name":"ligand adsorption","score":0.8009999990463257},{"id":"https://openalex.org/keywords/ph-dependence","display_name":"pH dependence","score":0.7149999737739563},{"id":"https://openalex.org/keywords/surface-complexation","display_name":"surface complexation","score":0.625},{"id":"https://openalex.org/keywords/inner-sphere-complexes","display_name":"inner-sphere complexes","score":0.7910000085830688},{"id":"https://openalex.org/keywords/ternary-surface-complexes","display_name":"ternary surface complexes","score":0.828000009059906},{"id":"https://openalex.org/keywords/heterogeneous-nucleation","display_name":"heterogeneous nucleation","score":0.7850000262260437},{"id":"https://openalex.org/keywords/mineral-dissolution","display_name":"mineral dissolution","score":0.9559999704360962},{"id":"https://openalex.org/keywords/rock-weathering","display_name":"rock weathering","score":0.7829999923706055},{"id":"https://openalex.org/keywords/metal-corrosion","display_name":"metal corrosion","score":0.6769999861717224},{"id":"https://openalex.org/keywords/pedogenesis","display_name":"soil formation","score":0.4569999873638153}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8129000067710876},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.6884999871253967},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.6825000047683716},{"id":"https://openalex.org/C88380143","wikidata":"https://www.wikidata.org/wiki/Q416674","display_name":"Dissolution","level":2,"score":0.6711000204086304},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.6466000080108643},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6373999714851379},{"id":"https://openalex.org/C199164860","wikidata":"https://www.wikidata.org/wiki/Q6822745","display_name":"Metal ions in aqueous solution","level":3,"score":0.49729999899864197},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.4821999967098236},{"id":"https://openalex.org/C64452783","wikidata":"https://www.wikidata.org/wiki/Q1524945","display_name":"Ternary operation","level":2,"score":0.4778999984264374},{"id":"https://openalex.org/C107054158","wikidata":"https://www.wikidata.org/wiki/Q25257","display_name":"Precipitation","level":2,"score":0.44830000400543213},{"id":"https://openalex.org/C20625102","wikidata":"https://www.wikidata.org/wiki/Q137056","display_name":"Corrosion","level":2,"score":0.4478999972343445},{"id":"https://openalex.org/C10710636","wikidata":"https://www.wikidata.org/wiki/Q857809","display_name":"Equilibrium constant","level":2,"score":0.4465999901294708},{"id":"https://openalex.org/C168191866","wikidata":"https://www.wikidata.org/wiki/Q4551818","display_name":"Stability constants of complexes","level":3,"score":0.4007999897003174},{"id":"https://openalex.org/C535960306","wikidata":"https://www.wikidata.org/wiki/Q945532","display_name":"Oxide minerals","level":3,"score":0.39469999074935913},{"id":"https://openalex.org/C186399102","wikidata":"https://www.wikidata.org/wiki/Q903517","display_name":"Chemical stability","level":2,"score":0.38670000433921814},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.3682999908924103},{"id":"https://openalex.org/C2776432453","wikidata":"https://www.wikidata.org/wiki/Q7946","display_name":"Mineral","level":2,"score":0.35580000281333923},{"id":"https://openalex.org/C40724407","wikidata":"https://www.wikidata.org/wiki/Q179177","display_name":"Weathering","level":2,"score":0.3248000144958496},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.30660000443458557},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.3000999987125397},{"id":"https://openalex.org/C106773901","wikidata":"https://www.wikidata.org/wiki/Q19588","display_name":"Transition metal","level":3,"score":0.29750001430511475},{"id":"https://openalex.org/C511782168","wikidata":"https://www.wikidata.org/wiki/Q725","display_name":"Chromium","level":2,"score":0.27090001106262207},{"id":"https://openalex.org/C5277695","wikidata":"https://www.wikidata.org/wiki/Q36710","display_name":"Qualitative inorganic analysis","level":3,"score":0.2581000030040741},{"id":"https://openalex.org/C3019440265","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Complex formation","level":2,"score":0.2554999887943268},{"id":"https://openalex.org/C56566620","wikidata":"https://www.wikidata.org/wiki/Q863829","display_name":"Solubility equilibrium","level":3,"score":0.25369998812675476}],"mesh":[],"locations_count":1,"locations":[{"id":"pmh:oai:dora:eawag_11101","doi":null,"is_oa":false,"landing_page_url":"https://www.dora.lib4ri.ch/eawag/islandora/object/eawag%3A11101","pdf_url":null,"source":{"id":"https://openalex.org/S4306400127","display_name":"DORA Eawag (Swiss Federal Institute of Aquatic Science and Technology (Eawag))","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I63664421","host_organization_name":"Swiss Federal Institute of Aquatic Science and Technology","host_organization_lineage":["https://openalex.org/I63664421"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Book Chapter"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2054002229","https://openalex.org/W2505361796","https://openalex.org/W7097925334","https://openalex.org/W1539431502","https://openalex.org/W2109688386","https://openalex.org/W153948305","https://openalex.org/W576718555","https://openalex.org/W2058383215","https://openalex.org/W2472354836","https://openalex.org/W7001209098"],"abstract_inverted_index":{"The":[0,160],"initial":[1],"and":[2,22,48,72,94,103,139,148,173,191,197],"reversible":[3],"steps":[4],"of":[5,8,29,33,44,69,90,97,100,104,130,144,146,149,156,162,176,180,185,189,195],"the":[6,30,34,66,87,95,128,142,157,174,183,187,193,205],"interaction":[7],"(hydr)oxide":[9],"surfaces":[10],"with":[11,17],"electrolytes,":[12],"that":[13],"is,":[14],"adsorption-desorption":[15],"equilibria":[16,56],"H+":[18],"(OH-),":[19],"metal":[20,70,98,150],"ions,":[21],"ligands":[23,147],"(anions),":[24],"are":[25,109,153,201],"discussed":[26],"in":[27,123,182],"terms":[28],"coordination":[31],"chemistry":[32],"oxide-water":[35],"interface.":[36],"This":[37],"interface":[38],"is":[39],"characterized":[40],"by":[41],"different":[42],"types":[43],"surface":[45,83,91,106,132],"hydroxyl":[46,92],"groups,":[47],"metallic":[49],"centers":[50],"(Lewis":[51],"acids).":[52],"Competitive":[53],"complex":[54],"formation":[55,188],"(metal":[57],"ion":[58,71],"versus":[59,63],"H+,":[60],"or":[61],"anion":[62,73,101],"OH-)":[64],"explain":[65],"strong":[67],"dependence":[68],"binding,":[74],"respectively,":[75,108],"on":[76,141,204,210],"pH.":[77],"Some":[78],"experimentally":[79],"determined":[80],"representative":[81],"intrinsic":[82],"equililbrium":[84],"constants":[85,112,119],"reflecting":[86],"acid-base":[88],"characteristics":[89],"groups":[93],"stability":[96],"complexes,":[99,102,107],"ternary":[105],"tabulated.":[110],"Such":[111],"can":[113],"also":[114],"be":[115],"estimated":[116],"from":[117,135],"equilibrium":[118],"for":[120,127],"corresponding":[121],"reactions":[122],"solution.":[124],"Additional":[125],"support":[126],"existence":[129],"inner-sphere":[131],"complexes":[133],"comes":[134],"molecular":[136],"methods":[137],"(spectroscopy)":[138],"investigations":[140],"kinetics":[143],"adsorption":[145],"ions.":[151],"(Hydr)oxides":[152],"abundant":[154],"components":[155],"earth's":[158],"crust.":[159],"rates":[161],"processes":[163],"occurring":[164],"at":[165],"these":[166,211],"surfaces,":[167],"such":[168],"as":[169],"precipitation":[170],"(heterogeneous":[171],"nucleation)":[172],"dissolution":[175],"mineral":[177],"phases":[178],"-":[179,200],"importance":[181],"weathering":[184],"rocks,":[186],"soils":[190],"sediments,":[192],"corrosion":[194],"metals,":[196],"their":[198],"inhibition":[199],"critically":[202],"dependent":[203],"coordinative":[206],"interactions":[207],"taking":[208],"place":[209],"surfaces.":[212]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":7},{"year":2015,"cited_by_count":3},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":5}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2025-10-10T00:00:00"}