{"id":"https://openalex.org/W6980927060","doi":null,"title":"Demystifying Denitrification: Coordination Complexes Give Valuable Insight into the Reduction of Nitrogen Oxides","display_name":"Demystifying Denitrification: Coordination Complexes Give Valuable Insight into the Reduction of Nitrogen Oxides","publication_year":2021,"publication_date":"2021-01-01","ids":{"openalex":"https://openalex.org/W6980927060"},"language":"en","primary_location":{"id":"pmh:oai:cedar.wwu.edu:wwuet-2047","doi":null,"is_oa":true,"landing_page_url":"https://cedar.wwu.edu/wwuet/1019","pdf_url":"https://cedar.wwu.edu/wwuet/1019","source":{"id":"https://openalex.org/S4377196384","display_name":"Western CEDAR (Western Washington University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52669646","host_organization_name":"Western Washington University","host_organization_lineage":["https://openalex.org/I52669646"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"WWU Graduate School Collection","raw_type":"text"},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://cedar.wwu.edu/wwuet/1019","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5001461226","display_name":"Walker R. Marks","orcid":"https://orcid.org/0000-0002-0412-7047","observed_orcids":["https://orcid.org/0000-0002-0412-7047"]},"institutions":[{"id":"https://openalex.org/I52669646","display_name":"Western Washington University","ror":"https://ror.org/05wn7r715","country_code":"US","type":"education","lineage":["https://openalex.org/I52669646"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Marks, Walker R.","raw_affiliation_strings":["Western Washington University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Western Washington University","institution_ids":["https://openalex.org/I52669646"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5001461226"],"corresponding_institution_ids":["https://openalex.org/I52669646"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":true,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.67330002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.67330002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.17080000042915344,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.038100000470876694,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/denitrification","display_name":"denitrification","score":0.9890000224113464},{"id":"https://openalex.org/keywords/dinitrosyl-iron-complexes","display_name":"dinitrosyl iron complexes","score":0.9120000004768372},{"id":"https://openalex.org/keywords/dinuclear-iron-complexes","display_name":"dinuclear iron complexes","score":0.7070000171661377},{"id":"https://openalex.org/keywords/nitric-oxide-release","display_name":"nitric oxide release","score":0.9150000214576721},{"id":"https://openalex.org/keywords/nitrous-oxide-mitigation","display_name":"nitrous oxide reduction","score":0.8379999995231628},{"id":"https://openalex.org/keywords/samarium-complexes","display_name":"samarium complexes","score":0.7080000042915344},{"id":"https://openalex.org/keywords/nitrate-reduction","display_name":"nitrate reduction","score":0.9200000166893005},{"id":"https://openalex.org/keywords/nitrogen-oxides","display_name":"nitrogen oxides","score":0.7110000252723694},{"id":"https://openalex.org/keywords/nitrogen-cycle","display_name":"nitrogen cycling","score":0.6539999842643738},{"id":"https://openalex.org/keywords/nitrogen-fertilization","display_name":"nitrogen fertilization","score":0.6460000276565552},{"id":"https://openalex.org/keywords/iron-nitrosyl-complexes","display_name":"iron nitrosyl complexes","score":0.421999990940094}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7512999773025513},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.6872000098228455},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.6722000241279602},{"id":"https://openalex.org/C73593433","wikidata":"https://www.wikidata.org/wiki/Q742637","display_name":"Denitrification","level":3,"score":0.5670999884605408},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5418999791145325},{"id":"https://openalex.org/C74884574","wikidata":"https://www.wikidata.org/wiki/Q171407","display_name":"Divalent","level":2,"score":0.45100000500679016},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.43160000443458557},{"id":"https://openalex.org/C2908647359","wikidata":"https://www.wikidata.org/wiki/Q2625603","display_name":"Population","level":2,"score":0.42640000581741333},{"id":"https://openalex.org/C2777573673","wikidata":"https://www.wikidata.org/wiki/Q905750","display_name":"Nitrous oxide","level":2,"score":0.40619999170303345},{"id":"https://openalex.org/C107872376","wikidata":"https://www.wikidata.org/wiki/Q321355","display_name":"Environmental chemistry","level":1,"score":0.4002000093460083},{"id":"https://openalex.org/C519581460","wikidata":"https://www.wikidata.org/wiki/Q207843","display_name":"Nitric oxide","level":2,"score":0.3968000113964081},{"id":"https://openalex.org/C536819264","wikidata":"https://www.wikidata.org/wiki/Q1819","display_name":"Samarium","level":2,"score":0.38429999351501465},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.3637999892234802},{"id":"https://openalex.org/C2776179834","wikidata":"https://www.wikidata.org/wiki/Q72158415","display_name":"Nitrite","level":3,"score":0.3598000109195709},{"id":"https://openalex.org/C49045045","wikidata":"https://www.wikidata.org/wiki/Q82551","display_name":"Nitrogen cycle","level":3,"score":0.3474999964237213},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.28929999470710754},{"id":"https://openalex.org/C111335779","wikidata":"https://www.wikidata.org/wiki/Q3454686","display_name":"Reduction (mathematics)","level":2,"score":0.28690001368522644},{"id":"https://openalex.org/C116119225","wikidata":"https://www.wikidata.org/wiki/Q7300316","display_name":"Reactive nitrogen","level":3,"score":0.2728999853134155},{"id":"https://openalex.org/C3019581552","wikidata":"https://www.wikidata.org/wiki/Q424418","display_name":"Nitrogen oxides","level":2,"score":0.2646999955177307},{"id":"https://openalex.org/C82685317","wikidata":"https://www.wikidata.org/wiki/Q19829510","display_name":"Pollutant","level":2,"score":0.2628999948501587}],"mesh":[],"locations_count":1,"locations":[{"id":"pmh:oai:cedar.wwu.edu:wwuet-2047","doi":null,"is_oa":true,"landing_page_url":"https://cedar.wwu.edu/wwuet/1019","pdf_url":"https://cedar.wwu.edu/wwuet/1019","source":{"id":"https://openalex.org/S4377196384","display_name":"Western CEDAR (Western Washington University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52669646","host_organization_name":"Western Washington University","host_organization_lineage":["https://openalex.org/I52669646"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"WWU Graduate School Collection","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:cedar.wwu.edu:wwuet-2047","doi":null,"is_oa":true,"landing_page_url":"https://cedar.wwu.edu/wwuet/1019","pdf_url":"https://cedar.wwu.edu/wwuet/1019","source":{"id":"https://openalex.org/S4377196384","display_name":"Western CEDAR (Western Washington University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I52669646","host_organization_name":"Western Washington University","host_organization_lineage":["https://openalex.org/I52669646"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"WWU Graduate School Collection","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W6980927060.pdf","grobid_xml":"https://content.openalex.org/works/W6980927060.grobid-xml"},"referenced_works_count":73,"referenced_works":["https://openalex.org/W1482867610","https://openalex.org/W1671614471","https://openalex.org/W1696146127","https://openalex.org/W1764308599","https://openalex.org/W1800678382","https://openalex.org/W1970225878","https://openalex.org/W1976428217","https://openalex.org/W1978895741","https://openalex.org/W1988841674","https://openalex.org/W1993371834","https://openalex.org/W2002578376","https://openalex.org/W2005840432","https://openalex.org/W2017687172","https://openalex.org/W2017809629","https://openalex.org/W2020768047","https://openalex.org/W2021571036","https://openalex.org/W2023421218","https://openalex.org/W2027056314","https://openalex.org/W2033327084","https://openalex.org/W2036685483","https://openalex.org/W2038578435","https://openalex.org/W2040569466","https://openalex.org/W2041340082","https://openalex.org/W2043718991","https://openalex.org/W2046107732","https://openalex.org/W2064802764","https://openalex.org/W2072931007","https://openalex.org/W2074827192","https://openalex.org/W2075370690","https://openalex.org/W2076925790","https://openalex.org/W2085719171","https://openalex.org/W2093095005","https://openalex.org/W2103029770","https://openalex.org/W2112242238","https://openalex.org/W2113507655","https://openalex.org/W2113990685","https://openalex.org/W2116472408","https://openalex.org/W2116749397","https://openalex.org/W2145278346","https://openalex.org/W2163591521","https://openalex.org/W2173659232","https://openalex.org/W2253574282","https://openalex.org/W2320526095","https://openalex.org/W2324119506","https://openalex.org/W2332921714","https://openalex.org/W2333803515","https://openalex.org/W2437533993","https://openalex.org/W2508584043","https://openalex.org/W2512345475","https://openalex.org/W2515566083","https://openalex.org/W2519658889","https://openalex.org/W2541573204","https://openalex.org/W2605132297","https://openalex.org/W2759537149","https://openalex.org/W2766918151","https://openalex.org/W2781844409","https://openalex.org/W2785925223","https://openalex.org/W2790912435","https://openalex.org/W2796142643","https://openalex.org/W2889488205","https://openalex.org/W2897780512","https://openalex.org/W2901779357","https://openalex.org/W2912687225","https://openalex.org/W2938162198","https://openalex.org/W2945959558","https://openalex.org/W2947264857","https://openalex.org/W2961813784","https://openalex.org/W2970489780","https://openalex.org/W3011869200","https://openalex.org/W3080265735","https://openalex.org/W3089098032","https://openalex.org/W3129110932","https://openalex.org/W4233810638"],"related_works":["https://openalex.org/W7112472335","https://openalex.org/W7046241605","https://openalex.org/W7070837968","https://openalex.org/W4411984855","https://openalex.org/W7111583934","https://openalex.org/W4398167149","https://openalex.org/W2901045261","https://openalex.org/W2623545207","https://openalex.org/W7015316524","https://openalex.org/W4415717117"],"abstract_inverted_index":{"Increasing":[0],"human":[1],"population":[2],"is":[3,40,73,107,121,162],"driving":[4],"the":[5,14,26,44,57,84,98,134,188],"need":[6,75],"to":[7,16,66,76,112],"produce":[8],"increasing":[9,29],"amounts":[10,30,50],"of":[11,28,31,51,83,86,100,109,118,125,133,141,153,167,174],"food":[12],"without":[13],"ability":[15],"dramatically":[17],"increase":[18],"farmland":[19],"area.":[20],"This":[21,94],"has":[22],"been":[23],"accomplished":[24],"by":[25,155],"application":[27],"nitrogen":[32,46,54],"containing":[33],"fertilizers":[34],"onto":[35],"croplands.":[36],"Nitrogen":[37],"fertilizer":[38],"overuse":[39],"causing":[41],"imbalance":[42],"in":[43,158],"natural":[45],"cycle":[47],"via":[48],"excessive":[49],"high":[52],"oxidation-state":[53],"entering":[55],"both":[56],"atmosphere":[58],"and":[59,69,182],"aquatic":[60],"ecosystems,":[61],"which":[62,80,106,138,164],"are":[63,81,172,196],"major":[64],"contributors":[65],"global":[67],"warming":[68],"environmental":[70],"damage.":[71],"There":[72],"a":[74,101,146,159],"explore":[77,97],"synthetic":[78,169],"systems":[79,170],"capable":[82,108,173],"reduction":[85],"these":[87],"pollutants":[88],"through":[89,123],"pathways":[90],"such":[91,175],"as":[92,129,131],"denitrification.":[93],"thesis":[95],"will":[96],"functionalization":[99],"dinuclear":[102,147],"dinitrosyl":[103,127,148],"iron":[104,184],"complex":[105],"coupling":[110],"nitrosyl":[111],"release":[113],"nitric":[114],"oxide.":[115],"The":[116,150],"activity":[117],"this":[119],"system":[120],"explored":[122],"examination":[124],"mono-nuclear":[126],"complexes":[128,185],"well":[130],"modification":[132],"secondary-sphere":[135,194],"ligand":[136,190],"interactions":[137,195],"allow":[139],"control":[140],"nitrous":[142],"oxide":[143],"evolution":[144],"from":[145],"complex.":[149],"complete":[151],"denitrification":[152],"nitrate":[154,180],"divalent":[156],"samarium":[157],"\u201csingle":[160],"pot\u201d":[161],"presented,":[163],"represents":[165],"one":[166],"few":[168],"that":[171],"reactivity.":[176],"Preliminary":[177],"results":[178],"on":[179,187],"binding":[181],"activating":[183],"based":[186],"pyridinediimine":[189],"scaffold":[191],"with":[192],"tunable":[193],"introduced.":[197]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2025-10-10T00:00:00"}