{"id":"https://openalex.org/W6944548742","doi":"https://doi.org/10.17615/rg0g-9p21","title":"Palladium-Tin Cations Enable the Formation of Palladium-Aryl Species","display_name":"Palladium-Tin Cations Enable the Formation of Palladium-Aryl Species","publication_year":2025,"publication_date":"2025-06-17","ids":{"openalex":"https://openalex.org/W6944548742","doi":"https://doi.org/10.17615/rg0g-9p21"},"language":"en","primary_location":{"id":"pmh:cdr.lib.unc.edu:6w924s85z","doi":null,"is_oa":true,"landing_page_url":"https://doi.org/10.17615/rg0g-9p21","pdf_url":"https://cdr.lib.unc.edu/downloads/th83md35s","source":{"id":"https://openalex.org/S4306401075","display_name":"Carolina Digital Repository (University of North Carolina at Chapel Hill)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114027177","host_organization_name":"University of North Carolina at Chapel Hill","host_organization_lineage":["https://openalex.org/I114027177"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Honors Thesis"},"volume":null,"type":"dissertation","indexed_in":["datacite"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://cdr.lib.unc.edu/downloads/th83md35s","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Agarwal, Amil","orcid":"https://orcid.org/0000-0002-3059-6701","observed_orcids":["https://orcid.org/0000-0002-3059-6701"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Agarwal, Amil","raw_affiliation_strings":["University of North Carolina at Chapel Hill"],"raw_orcid":"https://orcid.org/0000-0002-3059-6701","affiliations":[{"raw_affiliation_string":"University of North Carolina at Chapel Hill","institution_ids":["https://openalex.org/I114027177"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I114027177"],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":true,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.6309000253677368,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.6309000253677368,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.3488999903202057,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.008999999612569809,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/xantphos-ligand","display_name":"Xantphos ligand","score":0.7889999747276306},{"id":"https://openalex.org/keywords/sigma-bond-metathesis","display_name":"sigma-bond metathesis","score":0.996999979019165},{"id":"https://openalex.org/keywords/ambient-stability","display_name":"air stability","score":0.6179999709129333},{"id":"https://openalex.org/keywords/diene-addition","display_name":"diene addition","score":0.4449999928474426},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5429999828338623}],"concepts":[{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.838699996471405},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8123000264167786},{"id":"https://openalex.org/C19014433","wikidata":"https://www.wikidata.org/wiki/Q5130995","display_name":"Cleave","level":3,"score":0.7458000183105469},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.7038000226020813},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.6363999843597412},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5533000230789185},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.5476999878883362},{"id":"https://openalex.org/C2776241998","wikidata":"https://www.wikidata.org/wiki/Q418088","display_name":"Aryl halide","level":4,"score":0.5055000185966492},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.44530001282691956},{"id":"https://openalex.org/C112613896","wikidata":"https://www.wikidata.org/wiki/Q898370","display_name":"Conjugated system","level":3,"score":0.4375999867916107},{"id":"https://openalex.org/C94882840","wikidata":"https://www.wikidata.org/wiki/Q2123471","display_name":"Oxidative addition","level":3,"score":0.4237000048160553},{"id":"https://openalex.org/C2781048764","wikidata":"https://www.wikidata.org/wiki/Q107429","display_name":"Peroxide","level":2,"score":0.4068000018596649},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.3912000060081482},{"id":"https://openalex.org/C57600042","wikidata":"https://www.wikidata.org/wiki/Q227564","display_name":"Oxidative phosphorylation","level":2,"score":0.290800005197525},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.27810001373291016},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.26420000195503235},{"id":"https://openalex.org/C3019440265","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Complex formation","level":2,"score":0.2621000111103058},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.2565000057220459},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.25609999895095825},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.25279998779296875},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.2513999938964844}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:cdr.lib.unc.edu:6w924s85z","doi":null,"is_oa":true,"landing_page_url":"https://doi.org/10.17615/rg0g-9p21","pdf_url":"https://cdr.lib.unc.edu/downloads/th83md35s","source":{"id":"https://openalex.org/S4306401075","display_name":"Carolina Digital Repository (University of North Carolina at Chapel Hill)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114027177","host_organization_name":"University of North Carolina at Chapel Hill","host_organization_lineage":["https://openalex.org/I114027177"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Honors Thesis"},{"id":"doi:10.17615/rg0g-9p21","doi":"https://doi.org/10.17615/rg0g-9p21","is_oa":true,"landing_page_url":"https://doi.org/10.17615/rg0g-9p21","pdf_url":null,"source":{"id":"https://openalex.org/S7407051488","display_name":"UNC Libraries","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":null,"raw_source_name":null,"raw_type":"article-journal"}],"best_oa_location":{"id":"pmh:cdr.lib.unc.edu:6w924s85z","doi":null,"is_oa":true,"landing_page_url":"https://doi.org/10.17615/rg0g-9p21","pdf_url":"https://cdr.lib.unc.edu/downloads/th83md35s","source":{"id":"https://openalex.org/S4306401075","display_name":"Carolina Digital Repository (University of North Carolina at Chapel Hill)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114027177","host_organization_name":"University of North Carolina at Chapel Hill","host_organization_lineage":["https://openalex.org/I114027177"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Honors Thesis"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/15","score":0.5075965523719788,"display_name":"Life on land"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W6944548742.pdf","grobid_xml":"https://content.openalex.org/works/W6944548742.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":[],"abstract_inverted_index":{"A":[0],"silylpalladium":[1,132],"cationic":[2,133],"complex":[3,12,29,36,45,80,134],"was":[4,19,30,37,46,56,135],"recently":[5],"developed":[6],"by":[7],"the":[8,50,71,78,116,146],"Gagne":[9],"Lab.":[10],"The":[11,44,89,131],"could":[13],"cleave":[14],"C(sp3)-O":[15],"bonds":[16],"however":[17],"it":[18,55,59],"not":[20],"stable":[21,41],"to":[22,39,42,48,66,77,85,141],"air.":[23,43],"In":[24],"this":[25,106],"work,":[26],"a":[27,97],"[(XantPhos)Pd-SnBu3][BArF24]":[28],"synthesized":[31],"and":[32,63,91],"characterized.":[33],"This":[34],"Pd-Sn":[35,79,147],"found":[38,57],"be":[40],"unable":[47],"complete":[49],"C(sp3/sp2)-O":[51],"bond":[52],"cleavage,":[53],"yet":[54],"that":[58],"reacts":[60],"with":[61,115,138,145],"conjugated":[62],"isolated":[64],"dienes":[65],"form":[67,86],"Pd-allyl":[68],"species.":[69],"Additionally,":[70],"addition":[72],"of":[73,127],"electron-deficient":[74],"aryl":[75,139],"halides":[76,140],"resulted":[81],"in":[82,93],"ligand":[83],"substitution":[84],"Pd-Aryl":[87,129],"bonds.":[88],"reactant":[90],"product":[92],"these":[94,128],"reactions":[95],"have":[96],"Pd(II)":[98],"oxidation":[99],"state,":[100],"indicating":[101],"two":[102],"possible":[103],"mechanisms":[104],"for":[105,125],"reactivity.":[107],"One":[108],"pathway":[109],"is":[110],"an":[111],"oxidative":[112],"addition/reductive":[113],"elimination,":[114],"other":[117],"being":[118],"sigma-bond":[119],"metathesis.":[120],"Crystal":[121],"structures":[122],"were":[123],"acquired":[124],"some":[126],"products.":[130],"also":[136],"reacted":[137],"compare":[142],"its":[143],"reactivity":[144],"complex.":[148]},"counts_by_year":[],"updated_date":"2026-09-09T07:26:56.047234","created_date":"2025-10-10T00:00:00"}