{"id":"https://openalex.org/W61808192","doi":null,"title":"Reaction of chloroform with ethylene in the presence of the system iron-nucleophilic coinitiator","display_name":"Reaction of chloroform with ethylene in the presence of the system iron-nucleophilic coinitiator","publication_year":1988,"publication_date":"1988-01-10","ids":{"openalex":"https://openalex.org/W61808192","mag":"61808192"},"language":"en","primary_location":{"id":"mag:61808192","doi":null,"is_oa":false,"landing_page_url":"http://www.osti.gov/scitech/biblio/6333176","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"J. Appl. Chem. USSR (Engl. Transl.); (United States)","raw_type":null},"volume":null,"type":"article","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5035997221","display_name":"N. V. Kruglova","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"N. V. Kruglova","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5066728169","display_name":"\u041d\u0430\u0442\u0430\u043b\u044c\u044f \u0410\u043b\u0435\u043a\u0441\u0430\u043d\u0434\u0440\u043e\u0432\u043d\u0430 \u041f\u0435\u0442\u0440\u043e\u0432\u0430","orcid":"https://orcid.org/0000-0001-8475-1415","observed_orcids":["https://orcid.org/0000-0001-8475-1415"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"N.A. Petrova","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0001-8475-1415","affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.00219888,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8978999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8978999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.07440000027418137,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.00559999980032444,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chloroform","display_name":"chloroform","score":0.9750000238418579},{"id":"https://openalex.org/keywords/ethylene","display_name":"ethylene","score":0.9980000257492065},{"id":"https://openalex.org/keywords/iron-pentacarbonyl","display_name":"iron pentacarbonyl","score":0.8930000066757202},{"id":"https://openalex.org/keywords/dimethylformamide","display_name":"dimethylformamide","score":0.7929999828338623},{"id":"https://openalex.org/keywords/hexamethylphosphoramide","display_name":"hexamethylphosphoramide","score":0.9179999828338623},{"id":"https://openalex.org/keywords/c-cl-bond-cleavage","display_name":"C-Cl bond cleavage","score":0.7609999775886536},{"id":"https://openalex.org/keywords/telomers","display_name":"telomers","score":0.656000018119812},{"id":"https://openalex.org/keywords/13c-nmr-spectroscopy","display_name":"13C NMR","score":0.753000020980835},{"id":"https://openalex.org/keywords/free-radical-polymerization","display_name":"radical polymerization","score":0.44600000977516174},{"id":"https://openalex.org/keywords/one-step-synthesis","display_name":"one-step synthesis","score":0.5120000243186951}],"concepts":[{"id":"https://openalex.org/C2781144210","wikidata":"https://www.wikidata.org/wiki/Q172275","display_name":"Chloroform","level":2,"score":0.9080960154533386},{"id":"https://openalex.org/C2778597550","wikidata":"https://www.wikidata.org/wiki/Q151313","display_name":"Ethylene","level":3,"score":0.7911896705627441},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7755985260009766},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7236303687095642},{"id":"https://openalex.org/C2994067411","wikidata":"https://www.wikidata.org/wiki/Q125264","display_name":"Molar ratio","level":3,"score":0.5778259634971619},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.5179551839828491},{"id":"https://openalex.org/C2777712214","wikidata":"https://www.wikidata.org/wiki/Q409298","display_name":"Dimethylformamide","level":3,"score":0.4270121455192566},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3859592080116272},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.35811275243759155},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3474724590778351},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1722317934036255},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"mag:61808192","doi":null,"is_oa":false,"landing_page_url":"http://www.osti.gov/scitech/biblio/6333176","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"J. Appl. Chem. USSR (Engl. Transl.); (United States)","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2006985577","https://openalex.org/W2332811024","https://openalex.org/W2002776220","https://openalex.org/W2043616099","https://openalex.org/W2051770870","https://openalex.org/W2049514007","https://openalex.org/W2330786845","https://openalex.org/W2086605759","https://openalex.org/W2022762292","https://openalex.org/W1973625741"],"abstract_inverted_index":{"The":[0,12,42,81],"nucleophilic":[1],"coinitiators":[2],"(NC)":[3],"chosen":[4],"were":[5,19,40],"propan-2-o1,":[6],"hexame-thylphosphorotriamide":[7],"(HMPA),":[8],"and":[9,71,96],"dimethylformamide":[10],"(DMF).":[11],"effects":[13],"of":[14,27,68,74,92],"the":[15,22,47,62,69,75,87],"Fe(CO)/sub":[16,44],"5/-NC":[17],"system":[18,43],"examined":[20],"on":[21],"reaction":[23,82],"over":[24],"molar":[25],"ratios":[26],"NC:Fe(CO)/sub":[28],"5/,":[29],"1":[30],"to":[31,79],"100.":[32],"C-13":[33],"NMR":[34],"spectral":[35],"data":[36],"for":[37,86],"telomers":[38],"isolated":[39],"presented.":[41],"5/-DMF":[45],"is":[46],"most":[48],"active":[49],"system.":[50],"In":[51],"its":[52],"presence,":[53],"chloroform":[54,95],"reacts":[55],"with":[56,58,65,72],"ethylene":[57],"high":[59,66],"selectivity":[60],"at":[61],"C-Cl":[63],"bond,":[64],"conversions":[67],"reactants":[70],"yields":[73],"first":[76],"telomer":[77],"close":[78],"quantitative.":[80],"can":[83],"be":[84],"used":[85],"preparative,":[88],"single":[89],"stage":[90],"synthesis":[91],"1,1,3-trichloropropane":[93],"from":[94],"ethylene.":[97]},"counts_by_year":[],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}
