{"id":"https://openalex.org/W595584802","doi":"https://doi.org/10.13140/rg.2.1.2985.3604","title":"Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium","display_name":"Thermodynamic, Kinetic and Mechanistic Investigations of Ruthenium(III) Catalyzed Methylparaben Oxidation by Diperiodatocuprate(III) in Aqueous Alkaline Medium","publication_year":2015,"publication_date":"2015-01-01","ids":{"openalex":"https://openalex.org/W595584802","doi":"https://doi.org/10.13140/rg.2.1.2985.3604","mag":"595584802"},"language":"en","primary_location":{"id":"doi:10.13140/rg.2.1.2985.3604","doi":"https://doi.org/10.13140/rg.2.1.2985.3604","is_oa":false,"landing_page_url":"https://doi.org/10.13140/rg.2.1.2985.3604","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Other"},"volume":null,"type":"other","is_traditional":false,"indexed_in":["datacite"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5062333169","display_name":"Girish G. Ariga","orcid":"https://orcid.org/0000-0002-6146-9430","observed_orcids":["https://orcid.org/0000-0002-6146-9430"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Girish Ariga","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087235801","display_name":"Laxmi N. Jattinagoudar","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jattinagoudar, Laxmi N.","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015134534","display_name":"Sharanappa T. Nandibewoor","orcid":"https://orcid.org/0000-0003-2340-2275","observed_orcids":["https://orcid.org/0000-0003-2340-2275"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Sharanappa T. Nandibewoor","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":null,"display_name":"Shivmurti A. Chimatadar","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Shivmurti A. Chimatadar","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.7710000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.7710000276565552,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.10209999978542328,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.0763000026345253,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/methylparaben","display_name":"methylparaben","score":0.8769999742507935},{"id":"https://openalex.org/keywords/diperiodatocuprate-iii","display_name":"diperiodatocuprate(III)","score":0.949999988079071},{"id":"https://openalex.org/keywords/ruthenium-iii-catalysis","display_name":"ruthenium(III) catalysis","score":0.9810000061988831},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.6660000085830688},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7110000252723694},{"id":"https://openalex.org/keywords/activation-parameters","display_name":"activation parameters","score":0.9459999799728394},{"id":"https://openalex.org/keywords/alkaline-media","display_name":"alkaline solution","score":0.6919999718666077},{"id":"https://openalex.org/keywords/oxidation-products","display_name":"oxidation products","score":0.7080000042915344},{"id":"https://openalex.org/keywords/ionic-strength-effects","display_name":"ionic strength effects","score":0.5120000243186951},{"id":"https://openalex.org/keywords/dielectric-constant-effect","display_name":"dielectric constant effect","score":0.9599999785423279}],"concepts":[{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.8677511215209961},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8658415079116821},{"id":"https://openalex.org/C2781087243","wikidata":"https://www.wikidata.org/wiki/Q229987","display_name":"Methylparaben","level":3,"score":0.8020117282867432},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.7573172450065613},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6712647676467896},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.6637110710144043},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6625683307647705},{"id":"https://openalex.org/C2776789926","wikidata":"https://www.wikidata.org/wiki/Q417139","display_name":"Periodate","level":2,"score":0.6129535436630249},{"id":"https://openalex.org/C144082473","wikidata":"https://www.wikidata.org/wiki/Q213185","display_name":"Stoichiometry","level":2,"score":0.5664979815483093},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.44776448607444763},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.4330926537513733},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.412195086479187},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.20886045694351196},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.09190607070922852},{"id":"https://openalex.org/C67031304","wikidata":"https://www.wikidata.org/wiki/Q274579","display_name":"Preservative","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.13140/rg.2.1.2985.3604","doi":"https://doi.org/10.13140/rg.2.1.2985.3604","is_oa":false,"landing_page_url":"https://doi.org/10.13140/rg.2.1.2985.3604","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Other"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":22,"referenced_works":["https://openalex.org/W250619416","https://openalex.org/W1523417784","https://openalex.org/W1551651711","https://openalex.org/W1754404028","https://openalex.org/W1825789202","https://openalex.org/W1966841651","https://openalex.org/W1990810216","https://openalex.org/W1993498517","https://openalex.org/W1997696372","https://openalex.org/W2003970635","https://openalex.org/W2016222511","https://openalex.org/W2043959642","https://openalex.org/W2060140380","https://openalex.org/W2069724708","https://openalex.org/W2090002570","https://openalex.org/W2117726740","https://openalex.org/W2181780797","https://openalex.org/W2274204329","https://openalex.org/W2581062903","https://openalex.org/W2908373919","https://openalex.org/W2912309004","https://openalex.org/W3129292152"],"related_works":["https://openalex.org/W2093882628","https://openalex.org/W1995538133","https://openalex.org/W2019964137","https://openalex.org/W2970721368","https://openalex.org/W1993596687","https://openalex.org/W2119467035","https://openalex.org/W2332490050","https://openalex.org/W2017315982","https://openalex.org/W3162329891","https://openalex.org/W2948686971"],"abstract_inverted_index":{"The":[0,55,66,90,98,116,133,157],"kinetics":[1],"of":[2,7,27,39,73,96,100,111,119],"ruthenium(III)":[3,76,122],"catalyzed":[4],"degradative":[5],"oxidation":[6,56],"methylparaben":[8,45,86],"by":[9,60],"the":[10,37,42,94,109,112,139,144,150,163],"copper":[11],"complex,":[12],"diperiodatocuprate(III)":[13,47,74,120],"in":[14,48,71,123,160,170],"alkaline":[15,50,124],"medium":[16,51],"is":[17,166],"studied":[18],"at":[19,23],"298":[20],"K":[21],"and":[22,46,63,75,87,105,121,129,143,155,168],"a":[24],"ionic":[25,103],"strength":[26,104],"8.0":[28],"\u00d7":[29],"10":[30],"\u22122":[31],"mol":[32],"dm":[33],"\u22123":[34],".":[35],"In":[36],"presence":[38],"catalyst":[40],"ruthenium(III),":[41],"reaction":[43,67,113],"between":[44],"aqueous":[49],"exhibits":[52],"1:1":[53],"stoichiometry.":[54],"products":[57],"were":[58,114],"identified":[59],"UV-visible,":[61],"GC-MS":[62],"IR":[64],"spectroscopy.":[65],"exhibited":[68],"unit":[69,81],"order":[70,82],"case":[72],"concentrations,":[77],"while":[78],"less":[79],"than":[80],"with":[83,136,147,162],"respect":[84,137,148],"to":[85,138,149],"alkali":[88],"concentrations.":[89],"added":[91,101],"periodate":[92],"retards":[93],"rate":[95,110,140],"reaction.":[97],"effect":[99],"products,":[102],"dielectric":[106],"constant":[107],"on":[108],"studied.":[115],"active":[117],"species":[118],"media":[125],"are":[126,153],"[Cu(H2IO6)(H3IO6)]":[127],"2\u2212":[128],"[Ru(H2O)5(OH)]":[130],"2+":[131],"respectively.":[132],"activation":[134],"parameters":[135],"determining":[141],"step":[142],"thermodynamic":[145],"quantities":[146],"equilibrium":[151],"steps":[152],"evaluated":[154],"discussed.":[156],"plausible":[158],"mechanism":[159],"consistent":[161],"experimental":[164],"results":[165],"proposed":[167],"discussed":[169],"detail.":[171]},"counts_by_year":[],"updated_date":"2026-10-28T10:33:24.094632","created_date":"2016-06-24T00:00:00"}