{"id":"https://openalex.org/W577378478","doi":null,"title":"Phosphino and amino borates: Stronger field donors for coordination chemistry","display_name":"Phosphino and amino borates: Stronger field donors for coordination chemistry","publication_year":2003,"publication_date":"2003-03-01","ids":{"openalex":"https://openalex.org/W577378478","mag":"577378478"},"language":"en","primary_location":{"id":"pmh:oai:authors.library.caltech.edu:52543","doi":null,"is_oa":false,"landing_page_url":"https://authors.library.caltech.edu/52543/","pdf_url":null,"source":{"id":"https://openalex.org/S4306402161","display_name":"CaltechAUTHORS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"},"volume":null,"type":"article","indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057055428","display_name":"Jonas C. Peters","orcid":"https://orcid.org/0000-0002-6610-4414","observed_orcids":["https://orcid.org/0000-0002-6610-4414"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jonas C. Peters","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-6610-4414","affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022569799","display_name":"Theodore A. Betley","orcid":"https://orcid.org/0000-0001-5946-9629","observed_orcids":["https://orcid.org/0000-0001-5946-9629"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Theodore A. Betley","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0001-5946-9629","affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069264217","display_name":"Jonathan C. Thomas","orcid":"https://orcid.org/0000-0002-1599-9123","observed_orcids":["https://orcid.org/0000-0002-1599-9123"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jonathan C. Thomas","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-1599-9123","affiliations":[]},{"author_position":"middle","author":{"id":null,"display_name":"Steven D. Brown","orcid":"https://orcid.org/0000-0001-7841-3225","observed_orcids":["https://orcid.org/0000-0001-7841-3225"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Steven D. Brown","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0001-7841-3225","affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032112088","display_name":"David M. Jenkins","orcid":"https://orcid.org/0000-0003-2683-9157","observed_orcids":["https://orcid.org/0000-0003-2683-9157"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David M. Jenkins","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0003-2683-9157","affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5009146317","display_name":"Connie C. Lu","orcid":"https://orcid.org/0000-0002-5162-9250","observed_orcids":["https://orcid.org/0000-0002-5162-9250"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Connie C. Lu","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-5162-9250","affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.04448846,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.548799991607666,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.548799991607666,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.26100000739097595,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.09130000323057175,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/spin-crossover","display_name":"spin crossover","score":0.8040000200271606},{"id":"https://openalex.org/keywords/group-transfer","display_name":"group transfer","score":0.5630000233650208},{"id":"https://openalex.org/keywords/isocyanates","display_name":"isocyanates","score":0.7540000081062317}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.775999128818512},{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.7398554682731628},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.7087823748588562},{"id":"https://openalex.org/C38489247","wikidata":"https://www.wikidata.org/wiki/Q413110","display_name":"Nitrene","level":3,"score":0.6992925405502319},{"id":"https://openalex.org/C514695523","wikidata":"https://www.wikidata.org/wiki/Q237200","display_name":"Organometallic chemistry","level":3,"score":0.6591922044754028},{"id":"https://openalex.org/C501308230","wikidata":"https://www.wikidata.org/wiki/Q618","display_name":"Boron","level":2,"score":0.534682035446167},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.5171267986297607},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.4467690587043762},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4042203426361084},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.39755553007125854},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3726407587528229},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.33399689197540283},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.31960171461105347},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.21707239747047424},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19792738556861877},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:authors.library.caltech.edu:52543","doi":null,"is_oa":false,"landing_page_url":"https://authors.library.caltech.edu/52543/","pdf_url":null,"source":{"id":"https://openalex.org/S4306402161","display_name":"CaltechAUTHORS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"},{"id":"mag:577378478","doi":null,"is_oa":false,"landing_page_url":"http://resolver.caltech.edu/CaltechAUTHORS:20141210-095726862","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W623163644","https://openalex.org/W425141129","https://openalex.org/W148630477","https://openalex.org/W1857227173","https://openalex.org/W631500729","https://openalex.org/W1764168498","https://openalex.org/W1629764367","https://openalex.org/W7222788501","https://openalex.org/W1859876276","https://openalex.org/W4406558414"],"abstract_inverted_index":{"Our":[0],"group":[1,137,171],"has":[2],"developed":[3,28],"useful":[4],"protocols":[5],"to":[6,30,54,108,122,142,155,174,199,204,208],"(phosphino)borate":[7],"ligands":[8,36],"\\nfeaturing":[9],"synthetic":[10],"flexibility":[11],"at":[12],"both":[13,183],"the":[14,17,46,84,162,168,194],"borate":[15,77],"and":[16,59,95,185,203,215],"phosphine":[18],"donor":[19],"\\npositions.":[20],"Expanding":[21],"on":[22],"these":[23,66,201],"methods,":[24],"we":[25,38],"have":[26,39,134],"also":[27],"routes":[29],"\\n(amino)borates.":[31],"Representative":[32],"examples":[33,123],"of":[34,62,68,71,98,101,149,164],"some":[35],"that":[37,79,113,140],"prepared":[40],"\\nthus":[41],"far":[42],"are":[43,114],"shown":[44],"in":[45,120,166,193],"figure":[47],"below.":[48],"In":[49,161],"this":[50,206],"talk":[51],"I":[52],"plan":[53],"highlight":[55],"interesting":[56],"\\nstructural,":[57],"electronic,":[58],"reactivity":[60,131],"properties":[61,97],"complexes":[63,105,112],"supported":[64],"by":[65,75],"\\ntypes":[67],"ligands,":[69],"each":[70,148],"which":[72,150],"is":[73,80],"characterized":[74],"a":[76,99,130],"anion":[78],"\\npartially":[81],"insulated":[82],"from":[83],"coordinated":[85],"metal":[86],"center.":[87],"For":[88],"example,":[89],"an":[90,158],"understanding":[91],"\\nof":[92],"subtle":[93],"structural":[94],"electronic":[96],"class":[100],"tris(phosphino)":[102],"\\nborate":[103],"cobalt(II)":[104],"enables":[106],"us":[107],"assign":[109],"pseudo-tetrahedral":[110],"\\ncobalt(II)":[111],"either":[115],"high":[116],"or":[117],"low":[118],"spin,":[119],"addition":[121],"\\nthat":[124],"display":[125],"temperature":[126],"dependent":[127],"spin-crossover.":[128],"From":[129],"standpoint,":[132],"\\nwe":[133],"uncovered":[135],"unusual":[136],"transfer":[138,172],"processes":[139],"lead":[141],"molecular":[143],"iron":[144,165],"\\nand":[145,182],"cobalt":[146],"imides,":[147],"undergoes":[151],"subsequent":[152],"nitrene":[153],"release":[154],"CO":[156,175],"\\nas":[157],"acceptor":[159],"substrate.":[160],"case":[163],"particular,":[167],"Fe(I)/Fe(III)":[169],"\\nnitrene":[170],"cycle":[173],"(liberating":[176],"isocyanate)":[177],"can":[178,188],"be":[179,189,218],"made":[180],"catalytic":[181],"Fe(I)":[184],"Fe(III)":[186],"species":[187],"identified":[190],"as":[191],"intermediates":[192],"cycle.":[195],"\\nOur":[196],"continued":[197],"efforts":[198],"explore":[200],"systems,":[202],"expand":[205],"chemistry":[207],"\\nother":[209],"first":[210],"row":[211],"metals":[212],"including":[213],"nickel":[214],"copper,":[216],"will":[217],"discussed.":[219]},"counts_by_year":[],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}