{"id":"https://openalex.org/W2951731543","doi":"https://doi.org/10.3987/com-12-s(n)35","title":"Advances in Siloxane-Based Coupling Reactions: Application of Palladium-Mediated Allyl-Aryl Coupling to the Synthesis of Pancratistatin Derivatives. The Formal Total Synthesis of (\u00b1)-7-Deoxypancratistatin","display_name":"Advances in Siloxane-Based Coupling Reactions: Application of Palladium-Mediated Allyl-Aryl Coupling to the Synthesis of Pancratistatin Derivatives. The Formal Total Synthesis of (\u00b1)-7-Deoxypancratistatin","publication_year":2012,"publication_date":"2012-01-01","ids":{"openalex":"https://openalex.org/W2951731543","doi":"https://doi.org/10.3987/com-12-s(n)35","mag":"2951731543"},"language":"en","primary_location":{"id":"doi:10.3987/com-12-s(n)35","doi":"https://doi.org/10.3987/com-12-s(n)35","is_oa":true,"landing_page_url":"https://doi.org/10.3987/com-12-s(n)35","pdf_url":null,"source":{"id":"https://openalex.org/S27298842","display_name":"Heterocycles","issn_l":"0385-5414","issn":["0385-5414","1881-0942"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1","poland-40","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"HETEROCYCLES","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://doi.org/10.3987/com-12-s(n)35","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5029649266","display_name":"Philip R. DeShong","orcid":"https://orcid.org/0000-0003-1787-2158","observed_orcids":["https://orcid.org/0000-0003-1787-2158"]},"institutions":[{"id":"https://openalex.org/I66946132","display_name":"University of Maryland, College Park","ror":"https://ror.org/047s2c258","country_code":"US","type":"education","lineage":["https://openalex.org/I66946132"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Philip DeShong","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742","institution_ids":["https://openalex.org/I66946132"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5022503903","display_name":"Krupa H. Shukla","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I66946132","display_name":"University of Maryland, College Park","ror":"https://ror.org/047s2c258","country_code":"US","type":"education","lineage":["https://openalex.org/I66946132"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Krupa H. Shukla","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742","institution_ids":["https://openalex.org/I66946132"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5029649266"],"corresponding_institution_ids":["https://openalex.org/I66946132"],"apc_list":null,"apc_paid":null,"fwci":0.4207,"has_fulltext":false,"cited_by_count":15,"citation_normalized_percentile":{"value":0.59216957,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"86","issue":"2","first_page":"1055","last_page":"1055"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.3953000009059906,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.3953000009059906,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13124","display_name":"Chemical synthesis and alkaloids","score":0.2281000018119812,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13649","display_name":"Advanced Synthetic Organic Chemistry","score":0.14810000360012054,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/pancratistatin","display_name":"pancratistatin","score":0.8230000138282776},{"id":"https://openalex.org/keywords/total-synthesis","display_name":"total synthesis","score":0.7360000014305115},{"id":"https://openalex.org/keywords/hydroxamate","display_name":"hydroxamate","score":0.578000009059906},{"id":"https://openalex.org/keywords/carbamates","display_name":"carbamates","score":0.4620000123977661},{"id":"https://openalex.org/keywords/natural-product-synthesis","display_name":"natural product synthesis","score":0.5040000081062317}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8908442258834839},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.7055714726448059},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.6806821227073669},{"id":"https://openalex.org/C2776139660","wikidata":"https://www.wikidata.org/wiki/Q426680","display_name":"Siloxane","level":3,"score":0.5224812626838684},{"id":"https://openalex.org/C163111631","wikidata":"https://www.wikidata.org/wiki/Q1952454","display_name":"Carbon-13 NMR","level":2,"score":0.49639350175857544},{"id":"https://openalex.org/C103319777","wikidata":"https://www.wikidata.org/wiki/Q1979695","display_name":"Proton NMR","level":2,"score":0.49498504400253296},{"id":"https://openalex.org/C116447816","wikidata":"https://www.wikidata.org/wiki/Q3415253","display_name":"Fluorine-19 NMR","level":3,"score":0.49036550521850586},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.4781304895877838},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.41624757647514343},{"id":"https://openalex.org/C48242016","wikidata":"https://www.wikidata.org/wiki/Q16965936","display_name":"Deuterium NMR","level":3,"score":0.41146278381347656},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.40560874342918396},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.39009323716163635},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2636721730232239},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.13683855533599854},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.10152995586395264},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.3987/com-12-s(n)35","doi":"https://doi.org/10.3987/com-12-s(n)35","is_oa":true,"landing_page_url":"https://doi.org/10.3987/com-12-s(n)35","pdf_url":null,"source":{"id":"https://openalex.org/S27298842","display_name":"Heterocycles","issn_l":"0385-5414","issn":["0385-5414","1881-0942"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1","poland-40","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"HETEROCYCLES","raw_type":"journal-article"},{"id":"mag:575351196","doi":null,"is_oa":true,"landing_page_url":"http://ci.nii.ac.jp/naid/40019533894","pdf_url":null,"source":{"id":"https://openalex.org/S27298842","display_name":"Heterocycles","issn_l":"0385-5414","issn":["0385-5414","1881-0942"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1","poland-40","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"Heterocycles : an international journal for reviews and communications in heterocyclic chemistry","raw_type":null}],"best_oa_location":{"id":"doi:10.3987/com-12-s(n)35","doi":"https://doi.org/10.3987/com-12-s(n)35","is_oa":true,"landing_page_url":"https://doi.org/10.3987/com-12-s(n)35","pdf_url":null,"source":{"id":"https://openalex.org/S27298842","display_name":"Heterocycles","issn_l":"0385-5414","issn":["0385-5414","1881-0942"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1","poland-40","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"HETEROCYCLES","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":58,"referenced_works":["https://openalex.org/W1964518283","https://openalex.org/W1965784874","https://openalex.org/W1970812803","https://openalex.org/W1971232440","https://openalex.org/W1974003841","https://openalex.org/W1982334432","https://openalex.org/W1984567994","https://openalex.org/W1988547696","https://openalex.org/W1988795476","https://openalex.org/W1990290519","https://openalex.org/W1990330481","https://openalex.org/W1991235171","https://openalex.org/W1991471340","https://openalex.org/W1998821601","https://openalex.org/W2005234239","https://openalex.org/W2005389622","https://openalex.org/W2005926704","https://openalex.org/W2009859467","https://openalex.org/W2013586137","https://openalex.org/W2026753043","https://openalex.org/W2027856143","https://openalex.org/W2030236016","https://openalex.org/W2030378668","https://openalex.org/W2036707802","https://openalex.org/W2043557910","https://openalex.org/W2045273625","https://openalex.org/W2050601994","https://openalex.org/W2054918825","https://openalex.org/W2054970825","https://openalex.org/W2055535417","https://openalex.org/W2059972427","https://openalex.org/W2064233724","https://openalex.org/W2067225214","https://openalex.org/W2071638342","https://openalex.org/W2079410294","https://openalex.org/W2079720724","https://openalex.org/W2083759043","https://openalex.org/W2096332128","https://openalex.org/W2099284213","https://openalex.org/W2102554551","https://openalex.org/W2114383393","https://openalex.org/W2125361312","https://openalex.org/W2147418973","https://openalex.org/W2165663583","https://openalex.org/W2175674386","https://openalex.org/W2949193827","https://openalex.org/W2949454940","https://openalex.org/W2949969487","https://openalex.org/W2950361136","https://openalex.org/W2950371367","https://openalex.org/W2950430689","https://openalex.org/W2950733362","https://openalex.org/W2951751929","https://openalex.org/W2952172732","https://openalex.org/W2952652440","https://openalex.org/W2952720862","https://openalex.org/W2952940090","https://openalex.org/W3178641485"],"related_works":["https://openalex.org/W2017310498","https://openalex.org/W575351196","https://openalex.org/W1965784874","https://openalex.org/W21182778","https://openalex.org/W2952646101","https://openalex.org/W2164823162","https://openalex.org/W2088067609","https://openalex.org/W1996252269","https://openalex.org/W2129821810","https://openalex.org/W2950733362"],"abstract_inverted_index":{"1":[0,23],"H":[1,11,24],"NMR,":[2,5,12,15,25,28],"13":[3,13,26],"C":[4,14,27],"IR":[6,16,29],"of":[7,17,30],"hydroxamate":[8],"10":[9],"S2-S41":[10],"Methyl":[18,31],"7-hydroxy-2,2-dimethyl-3a,4,7,7a-tetrahydrobenzo":[19],"2-dimethyl-5-p-tolyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-4-ylcarbamate":[20],"24":[21],"S24-S26":[22],"5-(4-chlorophenyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-4ylcarbamate":[32],"26":[33],"S27-S29":[34]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2013,"cited_by_count":3}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2019-06-27T00:00:00"}