{"id":"https://openalex.org/W4415328497","doi":"https://doi.org/10.1007/s11581-025-06775-3","title":"Spatially confined Ni3Se4/C architecture via continuous selenization: dual-role carbon matrix enables ultrahigh-rate lithium storage and reveals sodium-ion transport limitations","display_name":"Spatially confined Ni3Se4/C architecture via continuous selenization: dual-role carbon matrix enables ultrahigh-rate lithium storage and reveals sodium-ion transport limitations","publication_year":2025,"publication_date":"2025-10-18","ids":{"openalex":"https://openalex.org/W4415328497","doi":"https://doi.org/10.1007/s11581-025-06775-3"},"language":"en","primary_location":{"id":"doi:10.1007/s11581-025-06775-3","doi":"https://doi.org/10.1007/s11581-025-06775-3","is_oa":false,"landing_page_url":"https://doi.org/10.1007/s11581-025-06775-3","pdf_url":null,"source":{"id":"https://openalex.org/S137979523","display_name":"Ionics","issn_l":"0947-7047","issn":["0947-7047","1862-0760"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Ionics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.researchsquare.com/article/rs-7261910/latest.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5091002771","display_name":"Chenhao Zhao","orcid":"https://orcid.org/0000-0001-7256-6714","observed_orcids":["https://orcid.org/0000-0001-7256-6714","https://orcid.org/0009-0006-9772-1550","https://orcid.org/0009-0009-5718-8378"]},"institutions":[{"id":"https://openalex.org/I181361081","display_name":"Longyan University","ror":"https://ror.org/0483s5p06","country_code":"CN","type":"education","lineage":["https://openalex.org/I181361081"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Chenhao Zhao","raw_affiliation_strings":["Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China"],"raw_orcid":"https://orcid.org/0000-0001-7256-6714","affiliations":[{"raw_affiliation_string":"Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China","institution_ids":["https://openalex.org/I181361081"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113267724","display_name":"Jianming Fan","orcid":"https://orcid.org/0009-0008-5485-3304","observed_orcids":["https://orcid.org/0009-0008-5485-3304"]},"institutions":[{"id":"https://openalex.org/I181361081","display_name":"Longyan University","ror":"https://ror.org/0483s5p06","country_code":"CN","type":"education","lineage":["https://openalex.org/I181361081"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jianming Fan","raw_affiliation_strings":["Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China","institution_ids":["https://openalex.org/I181361081"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113215505","display_name":"Zhibiao Hu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181361081","display_name":"Longyan University","ror":"https://ror.org/0483s5p06","country_code":"CN","type":"education","lineage":["https://openalex.org/I181361081"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhibiao Hu","raw_affiliation_strings":["Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China","institution_ids":["https://openalex.org/I181361081"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5018152342","display_name":"Fengzhang Tu","orcid":"https://orcid.org/0000-0001-7663-8906","observed_orcids":["https://orcid.org/0000-0001-7663-8906"]},"institutions":[{"id":"https://openalex.org/I181361081","display_name":"Longyan University","ror":"https://ror.org/0483s5p06","country_code":"CN","type":"education","lineage":["https://openalex.org/I181361081"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Fengzhang Tu","raw_affiliation_strings":["Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China"],"raw_orcid":"https://orcid.org/0000-0001-7663-8906","affiliations":[{"raw_affiliation_string":"Fujian Provincial Key Laboratory of Clean Energy Materials, College of Chemistry & Materials, Longyan University, Fujian Longyan, 364000, China","institution_ids":["https://openalex.org/I181361081"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5018152342","https://openalex.org/A5091002771"],"corresponding_institution_ids":["https://openalex.org/I181361081"],"apc_list":{"value":3590,"currency":"USD","value_usd":3590},"apc_paid":null,"fwci":0.1957,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.33139497,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":91,"max":95},"biblio":{"volume":"31","issue":"12","first_page":"12757","last_page":"12768"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Battery Modeling and Management","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nickel-selenide","display_name":"nickel selenide","score":0.9120000004768372},{"id":"https://openalex.org/keywords/lithium-ion-battery-anodes","display_name":"lithium-ion battery anodes","score":0.8809999823570251},{"id":"https://openalex.org/keywords/conversion-type-anodes","display_name":"conversion-type anodes","score":0.8579999804496765},{"id":"https://openalex.org/keywords/volume-expansion-buffering","display_name":"volume expansion buffering","score":0.7080000042915344},{"id":"https://openalex.org/keywords/charge-transfer-resistance","display_name":"charge transfer resistance","score":0.8069999814033508},{"id":"https://openalex.org/keywords/phase-evolution","display_name":"phase evolution","score":0.6669999957084656}],"concepts":[{"id":"https://openalex.org/C89395315","wikidata":"https://www.wikidata.org/wiki/Q181232","display_name":"Anode","level":3,"score":0.782800018787384},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7688000202178955},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.6312000155448914},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.6183000206947327},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.608299970626831},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.5996999740600586},{"id":"https://openalex.org/C104779481","wikidata":"https://www.wikidata.org/wiki/Q50707","display_name":"Composite number","level":2,"score":0.566100001335144},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.5503000020980835},{"id":"https://openalex.org/C2993969710","wikidata":"https://www.wikidata.org/wiki/Q837718","display_name":"Electrochemical energy storage","level":5,"score":0.5220000147819519},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.5023000240325928},{"id":"https://openalex.org/C156622251","wikidata":"https://www.wikidata.org/wiki/Q1036221","display_name":"Hydrothermal circulation","level":2,"score":0.4790000021457672},{"id":"https://openalex.org/C555008776","wikidata":"https://www.wikidata.org/wiki/Q267298","display_name":"Battery (electricity)","level":3,"score":0.47530001401901245},{"id":"https://openalex.org/C73916439","wikidata":"https://www.wikidata.org/wiki/Q837718","display_name":"Energy storage","level":3,"score":0.4401000142097473},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.37619999051094055},{"id":"https://openalex.org/C2779004117","wikidata":"https://www.wikidata.org/wiki/Q899079","display_name":"Lithium battery","level":4,"score":0.366100013256073},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.3643999993801117},{"id":"https://openalex.org/C202374169","wikidata":"https://www.wikidata.org/wiki/Q124291","display_name":"Electrical conductor","level":2,"score":0.3643999993801117},{"id":"https://openalex.org/C513720949","wikidata":"https://www.wikidata.org/wiki/Q1778729","display_name":"Carbon nanotube","level":2,"score":0.35519999265670776},{"id":"https://openalex.org/C45206210","wikidata":"https://www.wikidata.org/wiki/Q2415817","display_name":"Nanoscopic scale","level":2,"score":0.35440000891685486},{"id":"https://openalex.org/C2779197387","wikidata":"https://www.wikidata.org/wiki/Q2822895","display_name":"Lithium-ion battery","level":4,"score":0.3052999973297119},{"id":"https://openalex.org/C2776301907","wikidata":"https://www.wikidata.org/wiki/Q391088","display_name":"Sodium-ion battery","level":5,"score":0.30390000343322754},{"id":"https://openalex.org/C44038986","wikidata":"https://www.wikidata.org/wiki/Q764245","display_name":"Carbon black","level":3,"score":0.2775999903678894},{"id":"https://openalex.org/C92880739","wikidata":"https://www.wikidata.org/wiki/Q2639556","display_name":"Nanocomposite","level":2,"score":0.26820001006126404},{"id":"https://openalex.org/C138631740","wikidata":"https://www.wikidata.org/wiki/Q967847","display_name":"Nanomaterials","level":2,"score":0.2655999958515167},{"id":"https://openalex.org/C177367955","wikidata":"https://www.wikidata.org/wiki/Q4468924","display_name":"Carbon nanofiber","level":3,"score":0.25459998846054077},{"id":"https://openalex.org/C194739806","wikidata":"https://www.wikidata.org/wiki/Q66221","display_name":"Computer data storage","level":2,"score":0.2522999942302704}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1007/s11581-025-06775-3","doi":"https://doi.org/10.1007/s11581-025-06775-3","is_oa":false,"landing_page_url":"https://doi.org/10.1007/s11581-025-06775-3","pdf_url":null,"source":{"id":"https://openalex.org/S137979523","display_name":"Ionics","issn_l":"0947-7047","issn":["0947-7047","1862-0760"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Ionics","raw_type":"journal-article"},{"id":"doi:10.21203/rs.3.rs-7261910/v1","doi":"https://doi.org/10.21203/rs.3.rs-7261910/v1","is_oa":true,"landing_page_url":"https://doi.org/10.21203/rs.3.rs-7261910/v1","pdf_url":"https://www.researchsquare.com/article/rs-7261910/latest.pdf","source":{"id":"https://openalex.org/S4306525896","display_name":"Research Square","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Research Square","raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.21203/rs.3.rs-7261910/v1","doi":"https://doi.org/10.21203/rs.3.rs-7261910/v1","is_oa":true,"landing_page_url":"https://doi.org/10.21203/rs.3.rs-7261910/v1","pdf_url":"https://www.researchsquare.com/article/rs-7261910/latest.pdf","source":{"id":"https://openalex.org/S4306525896","display_name":"Research Square","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Research Square","raw_type":"posted-content"},"sustainable_development_goals":[{"score":0.878000020980835,"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G6377438313","display_name":"\u78b3\u8fbe\u5cf0\u89c6\u57df\u4e0b\u9ad8\u6027\u80fd\u94be\u7852\u7535\u6c60\u6b63\u6781\u6750\u6599\u4eff\u751f\u7ed3\u6784\u7684\u7cbe\u51c6\u8bbe\u8ba1\u3001\u53ef\u63a7\u6784\u7b51\u53ca\u5173\u952e\u673a\u7406\u7814\u7a76","funder_award_id":"2021J011094","funder_id":"https://openalex.org/F4320321878","funder_display_name":"Natural Science Foundation of Fujian Province"},{"id":"https://openalex.org/G8702638076","display_name":null,"funder_award_id":"2021J011094, 2023J01983, and 2023J01984","funder_id":"https://openalex.org/F4320321878","funder_display_name":"Natural Science Foundation of Fujian Province"}],"funders":[{"id":"https://openalex.org/F4320321878","display_name":"Natural Science Foundation of Fujian Province","ror":null}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4415328497.pdf","grobid_xml":"https://content.openalex.org/works/W4415328497.grobid-xml"},"referenced_works_count":41,"referenced_works":["https://openalex.org/W2334338652","https://openalex.org/W2345988629","https://openalex.org/W2580453798","https://openalex.org/W2681411897","https://openalex.org/W2777365267","https://openalex.org/W2790549514","https://openalex.org/W2792770588","https://openalex.org/W2796004428","https://openalex.org/W2796603243","https://openalex.org/W2796968200","https://openalex.org/W2799835441","https://openalex.org/W2806061995","https://openalex.org/W2809155330","https://openalex.org/W2809706983","https://openalex.org/W2831661154","https://openalex.org/W2883071941","https://openalex.org/W2889568117","https://openalex.org/W2890441144","https://openalex.org/W2891133238","https://openalex.org/W2917256040","https://openalex.org/W2944029930","https://openalex.org/W2969662859","https://openalex.org/W2987030858","https://openalex.org/W3217189796","https://openalex.org/W4285029851","https://openalex.org/W4307425431","https://openalex.org/W4313480187","https://openalex.org/W4319595181","https://openalex.org/W4321782595","https://openalex.org/W4385414951","https://openalex.org/W4388037266","https://openalex.org/W4389503234","https://openalex.org/W4390542053","https://openalex.org/W4393008467","https://openalex.org/W4398252929","https://openalex.org/W4399957072","https://openalex.org/W4404339932","https://openalex.org/W4405526804","https://openalex.org/W4409152187","https://openalex.org/W4409247359","https://openalex.org/W4409541419"],"related_works":["https://openalex.org/W4295107399","https://openalex.org/W4205618650","https://openalex.org/W4415316498","https://openalex.org/W3197310617","https://openalex.org/W2979535829","https://openalex.org/W2998597273","https://openalex.org/W3095843313","https://openalex.org/W4411234906","https://openalex.org/W4401212496","https://openalex.org/W4405443009"],"abstract_inverted_index":{"Abstract":[0],"Nickel":[1],"selenides'":[2],"structural":[3,20],"diversity":[4],"offers":[5],"promising":[6],"avenues":[7],"for":[8,130],"advanced":[9],"battery":[10],"anodes,":[11,133],"yet":[12],"their":[13],"practical":[14],"implementation":[15],"faces":[16],"persistent":[17],"challenges":[18],"of":[19],"instability":[21],"and":[22,67,81],"sluggish":[23],"kinetics.":[24],"Addressing":[25],"these":[26],"limitations,":[27],"we":[28],"pioneer":[29],"a":[30],"spatially":[31],"confined":[32],"architecture":[33],"through":[34],"template-directed":[35],"hydrothermal":[36],"synthesis:":[37],"~48":[38],"nm":[39],"Ni3Se4":[40],"nanoparticles":[41],"uniformly":[42],"encapsulated":[43],"within":[44],"conductive":[45],"carbon":[46,75,113],"nanoplates.":[47],"Time-dependent":[48],"XRD":[49],"analysis":[50,111],"confirms":[51],"continuous":[52],"selenization-driven":[53],"phase":[54],"evolution,":[55],"while":[56],"XPS/TGA":[57],"verify":[58],"the":[59],"composite":[60],"(30.6":[61],"wt%":[62],"carbon)":[63],"comprises":[64],"Ni2+,":[65],"Se22-":[66],"Se2-":[68],"species.":[69],"This":[70],"dual-role":[71],"design":[72],"-":[73,84],"where":[74],"simultaneously":[76],"serves":[77],"as":[78],"electron":[79],"highway":[80],"volume-change":[82],"buffer":[83],"enables":[85],"breakthrough":[86],"lithium":[87],"storage":[88,136,150],"performance:":[89],"586.2":[90],"mAh":[91,102,140],"g-1":[92,103,141],"after":[93,142],"100":[94,143],"cycles":[95],"(0.2":[96],"A":[97,108],"g-1)":[98],"with":[99],"exceptional":[100],"375.5":[101],"retention":[104],"at":[105],"ultrahigh":[106],"5":[107],"g-1.":[109],"Electrochemical":[110],"demonstrates":[112],"spacers":[114],"reduce":[115],"charge-transfer":[116],"resistance":[117],"by":[118],">40%":[119],"versus":[120],"bare":[121],"counterparts.":[122],"The":[123],"strategically":[124],"engineered":[125],"interface":[126],"provides":[127],"critical":[128],"insights":[129],"stabilizing":[131],"conversion-type":[132],"though":[134],"sodium":[135],"remains":[137],"challenging":[138],"(167.9":[139],"cycles),":[144],"highlighting":[145],"fundamental":[146],"differences":[147],"in":[148],"ion":[149],"mechanisms":[151],"that":[152],"guide":[153],"future":[154],"material":[155],"design.":[156]},"counts_by_year":[{"year":2026,"cited_by_count":1}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2025-10-19T00:00:00"}