{"id":"https://openalex.org/W4414101329","doi":"https://doi.org/10.1002/ange.202515723","title":"Synthesis and Reactivity of a Crystalline Zinc\u2013cAAC Radical","display_name":"Synthesis and Reactivity of a Crystalline Zinc\u2013cAAC Radical","publication_year":2025,"publication_date":"2025-09-10","ids":{"openalex":"https://openalex.org/W4414101329","doi":"https://doi.org/10.1002/ange.202515723"},"language":"en","primary_location":{"id":"doi:10.1002/ange.202515723","doi":"https://doi.org/10.1002/ange.202515723","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.202515723","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102672193","display_name":"Shuilian Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3923682","display_name":"Soochow University","ror":"https://ror.org/05t8y2r12","country_code":"CN","type":"education","lineage":["https://openalex.org/I3923682"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shuilian Xu","raw_affiliation_strings":["Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China","institution_ids":["https://openalex.org/I3923682"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101728981","display_name":"Yizhen Chen","orcid":"https://orcid.org/0000-0003-1547-7787","observed_orcids":["https://orcid.org/0000-0003-1547-7787"]},"institutions":[{"id":"https://openalex.org/I157773358","display_name":"Sun Yat-sen University","ror":"https://ror.org/0064kty71","country_code":"CN","type":"education","lineage":["https://openalex.org/I157773358"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yizhen Chen","raw_affiliation_strings":["Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry IGCME, Sun Yat\u2010sen University  Guangzhou 510275 P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry IGCME, Sun Yat\u2010sen University  Guangzhou 510275 P.R. China","institution_ids":["https://openalex.org/I157773358"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066969731","display_name":"Shengjie Jiang","orcid":"https://orcid.org/0000-0003-2552-8736","observed_orcids":["https://orcid.org/0000-0003-2552-8736"]},"institutions":[{"id":"https://openalex.org/I3923682","display_name":"Soochow University","ror":"https://ror.org/05t8y2r12","country_code":"CN","type":"education","lineage":["https://openalex.org/I3923682"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shengjie Jiang","raw_affiliation_strings":["Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China","institution_ids":["https://openalex.org/I3923682"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019373896","display_name":"Gengwen Tan","orcid":"https://orcid.org/0000-0002-6972-2197","observed_orcids":["https://orcid.org/0000-0002-6972-2197"]},"institutions":[{"id":"https://openalex.org/I157773358","display_name":"Sun Yat-sen University","ror":"https://ror.org/0064kty71","country_code":"CN","type":"education","lineage":["https://openalex.org/I157773358"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Gengwen Tan","raw_affiliation_strings":["Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry IGCME, Sun Yat\u2010sen University  Guangzhou 510275 P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry IGCME, Sun Yat\u2010sen University  Guangzhou 510275 P.R. China","institution_ids":["https://openalex.org/I157773358"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5085558225","display_name":"Xin Fang Xu","orcid":"https://orcid.org/0000-0003-2426-9816","observed_orcids":["https://orcid.org/0000-0003-2426-9816"]},"institutions":[{"id":"https://openalex.org/I3923682","display_name":"Soochow University","ror":"https://ror.org/05t8y2r12","country_code":"CN","type":"education","lineage":["https://openalex.org/I3923682"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xin Xu","raw_affiliation_strings":["Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China"],"raw_orcid":"https://orcid.org/0000-0003-2426-9816","affiliations":[{"raw_affiliation_string":"Key Laboratory of Organic Synthesis of Jiangsu Province &amp; State Key Laboratory of Bioinspired Interfacial Materials Science, College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou 215123 P.R. China","institution_ids":["https://openalex.org/I3923682"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5019373896","https://openalex.org/A5085558225"],"corresponding_institution_ids":["https://openalex.org/I157773358","https://openalex.org/I3923682"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.1237062,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"137","issue":"43","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.5092999935150146,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.5092999935150146,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.4196999967098236,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.043800000101327896,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cyclic-alkyl-amino-carbenes","display_name":"cyclic (alkyl)(amino)carbenes","score":0.9259999990463257},{"id":"https://openalex.org/keywords/radical-complexes","display_name":"radical complexes","score":0.4259999990463257},{"id":"https://openalex.org/keywords/pi-back-bonding","display_name":"\u03c0-backbonding","score":0.6980000138282776},{"id":"https://openalex.org/keywords/spin-density","display_name":"spin density","score":0.5070000290870667},{"id":"https://openalex.org/keywords/radical-reactivity","display_name":"radical reactivity","score":0.734000027179718},{"id":"https://openalex.org/keywords/zinc-ii-complexes","display_name":"zinc(II) complexes","score":0.7990000247955322},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.5699999928474426},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.8880000114440918},{"id":"https://openalex.org/keywords/single-crystal-structure","display_name":"single crystal structure","score":0.6690000295639038},{"id":"https://openalex.org/keywords/organozinc-chemistry","display_name":"organozinc chemistry","score":0.4650000035762787}],"concepts":[{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.886900007724762},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7694000005722046},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.7519000172615051},{"id":"https://openalex.org/C2777000832","wikidata":"https://www.wikidata.org/wiki/Q419853","display_name":"Trimethylsilyl","level":2,"score":0.663100004196167},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.585099995136261},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5839999914169312},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.5475999712944031},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.49869999289512634},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4422000050544739},{"id":"https://openalex.org/C3018272316","wikidata":"https://www.wikidata.org/wiki/Q905186","display_name":"Spin density","level":2,"score":0.41659998893737793},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4108999967575073},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3822999894618988},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.36000001430511475},{"id":"https://openalex.org/C196099240","wikidata":"https://www.wikidata.org/wiki/Q177033","display_name":"Triple bond","level":3,"score":0.328000009059906},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.3264999985694885},{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.3059999942779541},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.2944999933242798},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.2782999873161316},{"id":"https://openalex.org/C33947775","wikidata":"https://www.wikidata.org/wiki/Q271439","display_name":"Elongation","level":3,"score":0.2777999937534332},{"id":"https://openalex.org/C42704618","wikidata":"https://www.wikidata.org/wiki/Q910917","display_name":"Spin (aerodynamics)","level":2,"score":0.2630999982357025},{"id":"https://openalex.org/C91819851","wikidata":"https://www.wikidata.org/wiki/Q146889","display_name":"Pincer movement","level":3,"score":0.25360000133514404},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.25290000438690186},{"id":"https://openalex.org/C139210041","wikidata":"https://www.wikidata.org/wiki/Q2145840","display_name":"Resonance (particle physics)","level":2,"score":0.2517000138759613},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.2506999969482422}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202515723","doi":"https://doi.org/10.1002/ange.202515723","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.202515723","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G7015076382","display_name":null,"funder_award_id":"22371198","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":47,"referenced_works":["https://openalex.org/W1564238460","https://openalex.org/W1972069831","https://openalex.org/W1987839030","https://openalex.org/W1989405944","https://openalex.org/W2003202497","https://openalex.org/W2007453759","https://openalex.org/W2016295984","https://openalex.org/W2024131932","https://openalex.org/W2025594636","https://openalex.org/W2041405921","https://openalex.org/W2055079701","https://openalex.org/W2060071755","https://openalex.org/W2070596454","https://openalex.org/W2093405519","https://openalex.org/W2103540105","https://openalex.org/W2123469142","https://openalex.org/W2135432101","https://openalex.org/W2151640189","https://openalex.org/W2273230199","https://openalex.org/W2321230304","https://openalex.org/W2325950078","https://openalex.org/W2328627525","https://openalex.org/W2330357558","https://openalex.org/W2462518070","https://openalex.org/W2561795014","https://openalex.org/W2751979898","https://openalex.org/W2910060233","https://openalex.org/W2930599102","https://openalex.org/W3008395880","https://openalex.org/W3046443388","https://openalex.org/W3182951708","https://openalex.org/W3216886561","https://openalex.org/W4210469774","https://openalex.org/W4220961183","https://openalex.org/W4230004918","https://openalex.org/W4281954493","https://openalex.org/W4283758603","https://openalex.org/W4283812491","https://openalex.org/W4292183728","https://openalex.org/W4366819734","https://openalex.org/W4386498777","https://openalex.org/W4386741235","https://openalex.org/W4389738808","https://openalex.org/W4391134765","https://openalex.org/W4392761980","https://openalex.org/W4400297079","https://openalex.org/W4412199100"],"related_works":["https://openalex.org/W4387497383","https://openalex.org/W2948807893","https://openalex.org/W2899084033","https://openalex.org/W2778153218","https://openalex.org/W2748952813","https://openalex.org/W1531601525","https://openalex.org/W4391375266","https://openalex.org/W2078814861","https://openalex.org/W2527526854","https://openalex.org/W1976181487"],"abstract_inverted_index":{"Abstract":[0],"Reaction":[1],"of":[2,15,29,39,101],"LAmZnI":[3],"[LAm":[4],"=":[5,8],"tBuC(N\u2010DIPP)2,":[6],"DIPP":[7],"2,6\u2010iPr2\u2010C6H3]":[9],"with":[10,75,93],"KC8":[11],"in":[12],"the":[13,43,51,54,64,71,80,105,110],"presence":[14],"cyclic":[16],"(alkyl)(amino)carbene":[17],"(cAAC)":[18],"affords":[19],"a":[20,32,47,76],"stable":[21],"radical":[22,87],"complex":[23],"[LAmZn(cAAC)]\u2022":[24],"(3).":[25],"Single\u2010crystal":[26],"structural":[27],"analysis":[28],"3":[30,84],"shows":[31],"short":[33],"Zn\u2500C":[34],"bond":[35,41],"and":[36,59,98,108],"concomitant":[37],"elongation":[38],"C\u2500N":[40],"within":[42],"cAAC":[44,55],"ligand,":[45],"indicating":[46],"significant":[48],"\u03c0\u2010backbonding":[49],"from":[50],"metal":[52],"to":[53],"ligand.":[56],"EPR":[57],"spectroscopy":[58],"DFT":[60],"calculations":[61],"reveal":[62],"that":[63],"spin":[65],"density":[66],"is":[67],"mainly":[68],"localized":[69],"on":[70,79],"carbenic":[72],"carbon":[73],"atom,":[74],"small":[77],"portion":[78],"zinc":[81,106],"center.":[82],"Complex":[83],"exhibits":[85],"zinc\u2010centered":[86],"reactivity":[88],"as":[89],"demonstrated":[90],"by":[91],"reactions":[92],"2,2,6,6\u2010tetramethyl\u20101\u2010piperidinyloxy,":[94],"iodobenzene,":[95],"trimethylsilyl":[96],"azide,":[97],"[FeCp(CO)2]2,":[99],"all":[100],"which":[102],"occur":[103],"at":[104],"center":[107],"yield":[109],"corresponding":[111],"Zn(II)":[112],"complexes.":[113]},"counts_by_year":[],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2025-10-10T00:00:00"}
