{"id":"https://openalex.org/W4412499342","doi":"https://doi.org/10.1016/j.tet.2025.134849","title":"Magnesium-catalyzed hydrophosphination of alkenes and alkynes","display_name":"Magnesium-catalyzed hydrophosphination of alkenes and alkynes","publication_year":2025,"publication_date":"2025-07-19","ids":{"openalex":"https://openalex.org/W4412499342","doi":"https://doi.org/10.1016/j.tet.2025.134849"},"language":"en","primary_location":{"id":"doi:10.1016/j.tet.2025.134849","doi":"https://doi.org/10.1016/j.tet.2025.134849","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tet.2025.134849","pdf_url":null,"source":{"id":"https://openalex.org/S205754296","display_name":"Tetrahedron","issn_l":"0040-4020","issn":["0040-4020","1464-5416"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1016/j.tet.2025.134849","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072132077","display_name":"Yongxin Feng","orcid":"https://orcid.org/0000-0002-8632-7834","observed_orcids":["https://orcid.org/0000-0002-8632-7834","https://orcid.org/0009-0007-0748-0042"]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yongxin Feng","raw_affiliation_strings":["Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China","institution_ids":["https://openalex.org/I167027274"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111223459","display_name":"Xiaofei Rong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiaofei Rong","raw_affiliation_strings":["Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China","institution_ids":["https://openalex.org/I167027274"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5107522397","display_name":"Xuguang Zhang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xuguang Zhang","raw_affiliation_strings":["Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China","institution_ids":["https://openalex.org/I167027274"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102875720","display_name":"Yuqian He","orcid":"https://orcid.org/0000-0001-9233-358X","observed_orcids":["https://orcid.org/0000-0001-9233-358X","https://orcid.org/0009-0006-1512-0592"]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yukang He","raw_affiliation_strings":["Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China","institution_ids":["https://openalex.org/I167027274"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089491169","display_name":"Mengtao Ma","orcid":"https://orcid.org/0000-0001-9629-6464","observed_orcids":["https://orcid.org/0000-0001-9629-6464"]},"institutions":[{"id":"https://openalex.org/I167027274","display_name":"Nanjing Forestry University","ror":"https://ror.org/03m96p165","country_code":"CN","type":"education","lineage":["https://openalex.org/I167027274"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Mengtao Ma","raw_affiliation_strings":["Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China"],"raw_orcid":"https://orcid.org/0000-0001-9629-6464","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, College of Science, Nanjing Forestry University, Nanjing, 210037, China","institution_ids":["https://openalex.org/I167027274"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5089491169"],"corresponding_institution_ids":["https://openalex.org/I167027274"],"apc_list":{"value":3680,"currency":"USD","value_usd":3680},"apc_paid":{"value":3680,"currency":"USD","value_usd":3680},"fwci":1.1918,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.7480453,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":90,"max":98},"biblio":{"volume":"185","issue":null,"first_page":"134849","last_page":"134849"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9589999914169312,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.9589999914169312,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.03240000084042549,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrophosphination","display_name":"hydrophosphination","score":0.9660000205039978},{"id":"https://openalex.org/keywords/magnesium-catalysis","display_name":"magnesium catalysis","score":0.9639999866485596},{"id":"https://openalex.org/keywords/grignard-reagents","display_name":"Grignard reagents","score":0.878000020980835},{"id":"https://openalex.org/keywords/alkylphosphines","display_name":"alkylphosphines","score":0.765999972820282},{"id":"https://openalex.org/keywords/anti-markovnikov-regioselectivity","display_name":"anti-Markovnikov regioselectivity","score":0.8880000114440918},{"id":"https://openalex.org/keywords/alkene-functionalization","display_name":"alkene functionalization","score":0.796999990940094},{"id":"https://openalex.org/keywords/alkyne-functionalization","display_name":"alkyne functionalization","score":0.9750000238418579}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9787793159484863},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7944220304489136},{"id":"https://openalex.org/C543218039","wikidata":"https://www.wikidata.org/wiki/Q660","display_name":"Magnesium","level":2,"score":0.7228671908378601},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.5239848494529724},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.34278011322021484}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1016/j.tet.2025.134849","doi":"https://doi.org/10.1016/j.tet.2025.134849","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tet.2025.134849","pdf_url":null,"source":{"id":"https://openalex.org/S205754296","display_name":"Tetrahedron","issn_l":"0040-4020","issn":["0040-4020","1464-5416"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1016/j.tet.2025.134849","doi":"https://doi.org/10.1016/j.tet.2025.134849","is_oa":true,"landing_page_url":"https://doi.org/10.1016/j.tet.2025.134849","pdf_url":null,"source":{"id":"https://openalex.org/S205754296","display_name":"Tetrahedron","issn_l":"0040-4020","issn":["0040-4020","1464-5416"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"score":0.4399999976158142,"display_name":"Clean water and sanitation","id":"https://metadata.un.org/sdg/6"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G263157848","display_name":"\u4e0d\u5bf9\u79f0\u4e00\u4ef7\u9541\u91d1\u5c5e\u5316\u5408\u7269\u7684\u5408\u6210\u53ca\u5176\u50ac\u5316\u6027\u80fd\u7684\u7814\u7a76","funder_award_id":"21772093","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G5114055651","display_name":null,"funder_award_id":"22171137","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":48,"referenced_works":["https://openalex.org/W2012433173","https://openalex.org/W2077833716","https://openalex.org/W2091778649","https://openalex.org/W2160799704","https://openalex.org/W2265665099","https://openalex.org/W2306108856","https://openalex.org/W2333115663","https://openalex.org/W2395064857","https://openalex.org/W2411663135","https://openalex.org/W2527566935","https://openalex.org/W2542480340","https://openalex.org/W2545331787","https://openalex.org/W2555332681","https://openalex.org/W2601335836","https://openalex.org/W2620342026","https://openalex.org/W2775784408","https://openalex.org/W2788463981","https://openalex.org/W2790592853","https://openalex.org/W2805322838","https://openalex.org/W2900324102","https://openalex.org/W2901884444","https://openalex.org/W2946429541","https://openalex.org/W2954233763","https://openalex.org/W2965657410","https://openalex.org/W2978347535","https://openalex.org/W3008653361","https://openalex.org/W3011023668","https://openalex.org/W3020966112","https://openalex.org/W3030511695","https://openalex.org/W3091747304","https://openalex.org/W3091902475","https://openalex.org/W3094373349","https://openalex.org/W3115478721","https://openalex.org/W3152430324","https://openalex.org/W3210325009","https://openalex.org/W4200249903","https://openalex.org/W4214912301","https://openalex.org/W4220865894","https://openalex.org/W4224079605","https://openalex.org/W4246798197","https://openalex.org/W4284974535","https://openalex.org/W4285612330","https://openalex.org/W4308638390","https://openalex.org/W4312193095","https://openalex.org/W4391262298","https://openalex.org/W4392797699","https://openalex.org/W4399500287","https://openalex.org/W4401502113"],"related_works":["https://openalex.org/W4387497383","https://openalex.org/W2948807893","https://openalex.org/W2899084033","https://openalex.org/W2778153218","https://openalex.org/W2748952813","https://openalex.org/W1531601525","https://openalex.org/W4391375266","https://openalex.org/W2078814861","https://openalex.org/W2527526854","https://openalex.org/W1976181487"],"abstract_inverted_index":{"The":[0],"hydrophosphination":[1,48],"of":[2,17,37,49],"alkenes":[3,18],"and":[4,31,72],"alkynes":[5,51],"catalyzed":[6,53],"by":[7,54],"simple":[8],"commercially":[9],"available":[10],"magnesium":[11],"reagent":[12,41],"was":[13,52],"reported.":[14],"A":[15],"range":[16],"were":[19],"converted":[20],"to":[21,61],"the":[22,35,47,63],"corresponding":[23,64],"anti":[24,65],"-Markovnikov":[25,66],"alkylphosphine":[26],"products":[27],"in":[28,80],"high":[29,32,70],"yields":[30,71],"regioselectivity":[33],"under":[34],"presence":[36],"10":[38,55],"mol%":[39,56],"Grignard":[40],"MeMgI":[42],"at":[43],"room":[44],"temperature.":[45],"Meanwhile,":[46],"various":[50],"n":[57],"Bu":[58],"2":[59],"Mg":[60],"afford":[62],"Z":[67],"-alkenylphosphines":[68],"with":[69],"excellent":[73],"regioselectivity.":[74],"Scale-up":[75],"reaction":[76],"show":[77],"great":[78],"potential":[79],"practical":[81],"applications.":[82]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":1}],"updated_date":"2026-09-24T07:57:37.273135","created_date":"2025-10-10T00:00:00"}