{"id":"https://openalex.org/W4412442452","doi":"https://doi.org/10.1103/txdw-nqvn","title":"Coherent Dynamics of Molecular Vibrations in Single Plasmonic Nanogaps","display_name":"Coherent Dynamics of Molecular Vibrations in Single Plasmonic Nanogaps","publication_year":2025,"publication_date":"2025-07-15","ids":{"openalex":"https://openalex.org/W4412442452","doi":"https://doi.org/10.1103/txdw-nqvn","pmid":"https://pubmed.ncbi.nlm.nih.gov/40929208"},"language":"en","primary_location":{"id":"doi:10.1103/txdw-nqvn","doi":"https://doi.org/10.1103/txdw-nqvn","is_oa":true,"landing_page_url":"https://doi.org/10.1103/txdw-nqvn","pdf_url":null,"source":{"id":"https://openalex.org/S24807848","display_name":"Physical Review Letters","issn_l":"0031-9007","issn":["0031-9007","1079-7114","1092-0145"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1103/txdw-nqvn","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5125393059","display_name":"Fiona Bell","orcid":"https://orcid.org/0009-0001-7887-124X","observed_orcids":["https://orcid.org/0009-0001-7887-124X"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Fiona Bell","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":"https://orcid.org/0009-0001-7887-124X","affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029324772","display_name":"Lukas A. Jakob","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Lukas Jakob","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076521822","display_name":"Caleb Todd","orcid":"https://orcid.org/0000-0002-3657-8942","observed_orcids":["https://orcid.org/0000-0002-3657-8942"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Caleb Todd","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":"https://orcid.org/0000-0002-3657-8942","affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5117635080","display_name":"Ishaan Lohia","orcid":"https://orcid.org/0000-0002-3420-0903","observed_orcids":["https://orcid.org/0000-0002-3420-0903"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Ishaan Lohia","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":"https://orcid.org/0000-0002-3420-0903","affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025783214","display_name":"Yeeun Roh","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Yeeun Roh","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065550889","display_name":"Rakesh Arul","orcid":"https://orcid.org/0000-0001-8355-2158","observed_orcids":["https://orcid.org/0000-0001-8355-2158"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Rakesh Arul","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":"https://orcid.org/0000-0001-8355-2158","affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5073844026","display_name":"Jeremy J. Baumberg","orcid":"https://orcid.org/0000-0002-9606-9488","observed_orcids":["https://orcid.org/0000-0002-9606-9488"]},"institutions":[{"id":"https://openalex.org/I241749","display_name":"University of Cambridge","ror":"https://ror.org/013meh722","country_code":"GB","type":"education","lineage":["https://openalex.org/I241749"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Jeremy J. Baumberg","raw_affiliation_strings":["Cavendish Laboratory","NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom"],"raw_orcid":"https://orcid.org/0000-0002-9606-9488","affiliations":[{"raw_affiliation_string":"Cavendish Laboratory","institution_ids":[]},{"raw_affiliation_string":"NanoPhotonics Centre, Cavendish Laboratory, Department of Physics, JJ Thompson Avenue, University of Cambridge, Cambridge CB3 0US, United Kingdom","institution_ids":["https://openalex.org/I241749"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I241749"],"apc_list":{"value":3750,"currency":"USD","value_usd":3750},"apc_paid":{"value":3750,"currency":"USD","value_usd":3750},"fwci":3.0321,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.9189515,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"135","issue":"7","first_page":"076901","last_page":"076901"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10295","display_name":"Plasmonic and Surface Plasmon Research","score":0.4399000108242035,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10295","display_name":"Plasmonic and Surface Plasmon Research","score":0.4399000108242035,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.2671000063419342,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12612","display_name":"Strong Light-Matter Interactions","score":0.14669999480247498,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/plasmonic-nanocavities","display_name":"plasmonic nanocavities","score":0.8980000019073486},{"id":"https://openalex.org/keywords/nanogap","display_name":"nanogap","score":0.6140000224113464},{"id":"https://openalex.org/keywords/vibrational-dephasing","display_name":"vibrational dephasing","score":0.7509999871253967},{"id":"https://openalex.org/keywords/coherence-lifetime","display_name":"coherence lifetime","score":0.8360000252723694},{"id":"https://openalex.org/keywords/sum-frequency-generation","display_name":"sum-frequency generation","score":0.7250000238418579},{"id":"https://openalex.org/keywords/time-resolved-spectroscopy","display_name":"time-resolved spectroscopy","score":0.8949999809265137}],"concepts":[{"id":"https://openalex.org/C110879396","wikidata":"https://www.wikidata.org/wiki/Q58392","display_name":"Plasmon","level":2,"score":0.80216383934021},{"id":"https://openalex.org/C198394728","wikidata":"https://www.wikidata.org/wiki/Q3695508","display_name":"Vibration","level":2,"score":0.5447074770927429},{"id":"https://openalex.org/C145912823","wikidata":"https://www.wikidata.org/wiki/Q113558","display_name":"Dynamics (music)","level":2,"score":0.4430955946445465},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.43523260951042175},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3783218264579773},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.29803329706192017},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.25401386618614197},{"id":"https://openalex.org/C24890656","wikidata":"https://www.wikidata.org/wiki/Q82811","display_name":"Acoustics","level":1,"score":0.13424265384674072}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1103/txdw-nqvn","doi":"https://doi.org/10.1103/txdw-nqvn","is_oa":true,"landing_page_url":"https://doi.org/10.1103/txdw-nqvn","pdf_url":null,"source":{"id":"https://openalex.org/S24807848","display_name":"Physical Review Letters","issn_l":"0031-9007","issn":["0031-9007","1079-7114","1092-0145"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review Letters","raw_type":"journal-article"},{"id":"pmid:40929208","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/40929208","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical review letters","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1103/txdw-nqvn","doi":"https://doi.org/10.1103/txdw-nqvn","is_oa":true,"landing_page_url":"https://doi.org/10.1103/txdw-nqvn","pdf_url":null,"source":{"id":"https://openalex.org/S24807848","display_name":"Physical Review Letters","issn_l":"0031-9007","issn":["0031-9007","1079-7114","1092-0145"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320261","host_organization_name":"American Physical Society","host_organization_lineage":["https://openalex.org/P4310320261"],"host_organization_lineage_names":["American Physical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Review Letters","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1063499797","display_name":null,"funder_award_id":"MIRVALS EP/Y008162/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"},{"id":"https://openalex.org/G2769057724","display_name":"Vibrational pumping of molecules in tightly-confined plasmonic nanocavities","funder_award_id":"2437572","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"},{"id":"https://openalex.org/G50985846","display_name":null,"funder_award_id":"PICOFORCE / 883703","funder_id":"https://openalex.org/F4320338335","funder_display_name":"H2020 European Research Council"},{"id":"https://openalex.org/G7922555838","display_name":null,"funder_award_id":"UbOHT EP/X037770/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"},{"id":"https://openalex.org/G8479444993","display_name":null,"funder_award_id":"MIRVID EP/Y036379/1","funder_id":"https://openalex.org/F4320334627","funder_display_name":"Engineering and Physical Sciences Research Council"}],"funders":[{"id":"https://openalex.org/F4320334627","display_name":"Engineering and Physical Sciences Research Council","ror":"https://ror.org/0439y7842"},{"id":"https://openalex.org/F4320338335","display_name":"H2020 European Research Council","ror":"https://ror.org/0472cxd90"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W1636616099","https://openalex.org/W1969423983","https://openalex.org/W1971800438","https://openalex.org/W1982606807","https://openalex.org/W1993754142","https://openalex.org/W2010154632","https://openalex.org/W2024568801","https://openalex.org/W2031510004","https://openalex.org/W2033014123","https://openalex.org/W2036918727","https://openalex.org/W2046682151","https://openalex.org/W2047688126","https://openalex.org/W2073543819","https://openalex.org/W2079745663","https://openalex.org/W2081157234","https://openalex.org/W2085022104","https://openalex.org/W2085868964","https://openalex.org/W2095419468","https://openalex.org/W2414381099","https://openalex.org/W2788884019","https://openalex.org/W2904724367","https://openalex.org/W2924574971","https://openalex.org/W2933064643","https://openalex.org/W2969875339","https://openalex.org/W2972445116","https://openalex.org/W2980182048","https://openalex.org/W3015304931","https://openalex.org/W3033325601","https://openalex.org/W3093629166","https://openalex.org/W3111741518","https://openalex.org/W3148567701","https://openalex.org/W3173534266","https://openalex.org/W3215172065","https://openalex.org/W3216666478","https://openalex.org/W4283383476","https://openalex.org/W4283744569","https://openalex.org/W4288051576","https://openalex.org/W4293499193","https://openalex.org/W4297002268","https://openalex.org/W4375955676","https://openalex.org/W4379537374","https://openalex.org/W4390545084","https://openalex.org/W4396578839","https://openalex.org/W4396721172","https://openalex.org/W4400008830","https://openalex.org/W4401885306","https://openalex.org/W4402120635","https://openalex.org/W4404096733","https://openalex.org/W4408447260","https://openalex.org/W7093084639"],"related_works":["https://openalex.org/W4304194285","https://openalex.org/W7128376287","https://openalex.org/W6924178390","https://openalex.org/W2323266673","https://openalex.org/W4408447260","https://openalex.org/W2913934323","https://openalex.org/W2615135597","https://openalex.org/W6962822377","https://openalex.org/W7130657830","https://openalex.org/W4379537374"],"abstract_inverted_index":{"Coupling":[0],"with":[1,75],"a":[2,24,41,49,61,80,91],"resonant":[3],"optical":[4],"cavity":[5,113],"is":[6,71],"well":[7],"known":[8],"to":[9,23,65,73,94,112],"modify":[10],"the":[11,18,28,38,86,96],"coherence":[12,33,62],"of":[13,20,31,40,45,85,99],"molecular":[14],"vibrations.":[15],"However,":[16],"in":[17],"case":[19],"molecules":[21,44],"coupled":[22],"plasmonic":[25,51],"nanocavity":[26,52],"mode,":[27],"local":[29],"mechanisms":[30],"vibrational":[32,77,104,110],"decay":[34],"remain":[35],"unclear.":[36],"Here,":[37],"dynamics":[39],"few":[42],"hundred":[43],"nitrothiophenol":[46],"(NTP)":[47],"within":[48,102],"single":[50],"are":[53],"studied":[54],"by":[55],"sum-frequency":[56],"generation.":[57],"Time-resolved":[58],"experiments":[59],"reveal":[60],"lifetime":[63],"sensitive":[64],"intermolecular":[66],"dipole":[67,88],"coupling":[68],"strength,":[69],"and":[70],"found":[72],"compete":[74],"cavity-induced":[76],"dephasing":[78],"above":[79],"threshold":[81],"\u223c10":[82],"cm^{-1}.":[83],"Tuning":[84],"system":[87],"strength":[89],"presents":[90],"quantitative":[92],"means":[93],"explore":[95],"energy":[97],"landscape":[98],"coherent":[100],"interactions":[101],"nanoscale":[103],"platforms,":[105],"relevant":[106],"for":[107],"studies":[108],"from":[109],"chemistry":[111],"quantum":[114],"optomechanics.":[115]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":2}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2025-10-10T00:00:00"}
