{"id":"https://openalex.org/W4412372504","doi":"https://doi.org/10.1021/acs.inorgchem.5c02310","title":"Mechanistic Insights into Molecular Oxygen Reactivity with Late Transition Metal\u2013Hydride Bonds","display_name":"Mechanistic Insights into Molecular Oxygen Reactivity with Late Transition Metal\u2013Hydride Bonds","publication_year":2025,"publication_date":"2025-07-13","ids":{"openalex":"https://openalex.org/W4412372504","doi":"https://doi.org/10.1021/acs.inorgchem.5c02310","pmid":"https://pubmed.ncbi.nlm.nih.gov/40652390"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.5c02310","doi":"https://doi.org/10.1021/acs.inorgchem.5c02310","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.5c02310","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c02310?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","datacite","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c02310?ref=article_openPDF","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082611443","display_name":"Diego Sorbelli","orcid":"https://orcid.org/0000-0002-1348-1371","observed_orcids":["https://orcid.org/0000-0002-1348-1371"]},"institutions":[{"id":"https://openalex.org/I40347166","display_name":"University of Chicago","ror":"https://ror.org/024mw5h28","country_code":"US","type":"education","lineage":["https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Diego Sorbelli","raw_affiliation_strings":["Pritzker School of Molecular Engineering, University of Chicago, 5640 South Ellis Avenue, Chicago, Illinois 60615, United States"],"raw_orcid":"https://orcid.org/0000-0002-1348-1371","affiliations":[{"raw_affiliation_string":"Pritzker School of Molecular Engineering, University of Chicago, 5640 South Ellis Avenue, Chicago, Illinois 60615, United States","institution_ids":["https://openalex.org/I40347166"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058779678","display_name":"Leonardo Belpassi","orcid":"https://orcid.org/0000-0002-2888-4990","observed_orcids":["https://orcid.org/0000-0002-2888-4990"]},"institutions":[{"id":"https://openalex.org/I4403928382","display_name":"Istituto di Scienze e Tecnologie Chimiche \"Giulio Natta\"","ror":"https://ror.org/04r43k021","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210155236","https://openalex.org/I4403928382"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Leonardo Belpassi","raw_affiliation_strings":["CNR Institute of Chemical Science and Technologies \u201cGiulio Natta\u201d (CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy"],"raw_orcid":"https://orcid.org/0000-0002-2888-4990","affiliations":[{"raw_affiliation_string":"CNR Institute of Chemical Science and Technologies \u201cGiulio Natta\u201d (CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy","institution_ids":["https://openalex.org/I4403928382"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052163219","display_name":"Paola Belanzoni","orcid":"https://orcid.org/0000-0002-1286-9294","observed_orcids":["https://orcid.org/0000-0002-1286-9294"]},"institutions":[{"id":"https://openalex.org/I27483092","display_name":"University of Perugia","ror":"https://ror.org/00x27da85","country_code":"IT","type":"education","lineage":["https://openalex.org/I27483092"]},{"id":"https://openalex.org/I4403928382","display_name":"Istituto di Scienze e Tecnologie Chimiche \"Giulio Natta\"","ror":"https://ror.org/04r43k021","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210155236","https://openalex.org/I4403928382"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Paola Belanzoni","raw_affiliation_strings":["CNR Institute of Chemical Science and Technologies \u201cGiulio Natta\u201d (CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy","Department of Chemistry, Biology and Biotechnology,University of Perugia, Via Elce di Sotto 8, 06123Perugia, Italy"],"raw_orcid":"https://orcid.org/0000-0002-1286-9294","affiliations":[{"raw_affiliation_string":"CNR Institute of Chemical Science and Technologies \u201cGiulio Natta\u201d (CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy","institution_ids":["https://openalex.org/I4403928382"]},{"raw_affiliation_string":"Department of Chemistry, Biology and Biotechnology,University of Perugia, Via Elce di Sotto 8, 06123Perugia, Italy","institution_ids":["https://openalex.org/I27483092"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5052163219","https://openalex.org/A5082611443"],"corresponding_institution_ids":["https://openalex.org/I27483092","https://openalex.org/I40347166","https://openalex.org/I4403928382"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":{"value":4500,"currency":"USD","value_usd":4500},"fwci":0.298,"has_fulltext":true,"cited_by_count":1,"citation_normalized_percentile":{"value":0.42927114,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":90,"max":94},"biblio":{"volume":"64","issue":"29","first_page":"15193","last_page":"15205"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.5479000210762024,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.5479000210762024,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.41429999470710754,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.01209999993443489,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/spin-orbit-coupling","display_name":"spin-orbit coupling","score":0.7440000176429749},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.6240000128746033},{"id":"https://openalex.org/keywords/radical-chain-mechanism","display_name":"radical chain mechanism","score":0.6620000004768372},{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.6510000228881836},{"id":"https://openalex.org/keywords/imidazolylidene-ligands","display_name":"imidazolylidene ligands","score":0.7919999957084656},{"id":"https://openalex.org/keywords/gold-complexes","display_name":"gold complexes","score":0.35499998927116394},{"id":"https://openalex.org/keywords/palladium-complexes","display_name":"palladium complexes","score":0.9649999737739563}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.949588418006897},{"id":"https://openalex.org/C205188671","wikidata":"https://www.wikidata.org/wiki/Q3803316","display_name":"Isostructural","level":3,"score":0.805667519569397},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.7641878128051758},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5400370955467224},{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.5382112860679626},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5019128322601318},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.49339404702186584},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.4535733461380005},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4454199969768524},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.37130093574523926},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.36933422088623047},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.2997083067893982},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.17252513766288757},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12684422731399536},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08214312791824341},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0}],"mesh":[],"locations_count":6,"locations":[{"id":"doi:10.1021/acs.inorgchem.5c02310","doi":"https://doi.org/10.1021/acs.inorgchem.5c02310","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.5c02310","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c02310?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:40652390","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/40652390","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:12308812","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/12308812","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorg Chem","raw_type":"Text"},{"id":"pmh:oai:uchicago.tind.io:16211","doi":null,"is_oa":false,"landing_page_url":"http://knowledge.uchicago.edu/record/16211","pdf_url":null,"source":{"id":"https://openalex.org/S4306402460","display_name":"Knowledge@UChicago (University of Chicago)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I40347166","host_organization_name":"University of Chicago","host_organization_lineage":["https://openalex.org/I40347166"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://knowledge.uchicago.edu/record/16211","raw_type":"Text"},{"id":"doi:10.6082/17ewh-v4m65","doi":"https://doi.org/10.6082/17ewh-v4m65","is_oa":true,"landing_page_url":"https://doi.org/10.6082/17ewh-v4m65","pdf_url":null,"source":{"id":"https://openalex.org/S7407053018","display_name":"University of Chicago","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":null,"raw_source_name":null,"raw_type":"JournalArticle"},{"id":"doi:10.6082/r5r00-14284","doi":"https://doi.org/10.6082/r5r00-14284","is_oa":true,"landing_page_url":"https://doi.org/10.6082/r5r00-14284","pdf_url":null,"source":{"id":"https://openalex.org/S7407053018","display_name":"University of Chicago","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":null,"raw_source_name":null,"raw_type":"JournalArticle"}],"best_oa_location":{"id":"doi:10.1021/acs.inorgchem.5c02310","doi":"https://doi.org/10.1021/acs.inorgchem.5c02310","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.5c02310","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c02310?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","ki-jl-2","medline","norway-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1459111861","display_name":null,"funder_award_id":"CUP B43C22000470005","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"},{"id":"https://openalex.org/G2109022620","display_name":null,"funder_award_id":"CUP J97G22000170005","funder_id":"https://openalex.org/F4320321873","funder_display_name":"Ministero dell\u2019Istruzione, dell\u2019Universit\u00e0 e della Ricerca"},{"id":"https://openalex.org/G3315389780","display_name":null,"funder_award_id":"CUP J97G22000170005","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"},{"id":"https://openalex.org/G539632367","display_name":null,"funder_award_id":"ECS_00000041","funder_id":"https://openalex.org/F7311471023","funder_display_name":"NextGenerationEU"},{"id":"https://openalex.org/G6151417066","display_name":null,"funder_award_id":"CUP B43C22000470005","funder_id":"https://openalex.org/F4320321873","funder_display_name":"Ministero dell\u2019Istruzione, dell\u2019Universit\u00e0 e della Ricerca"},{"id":"https://openalex.org/G7285817237","display_name":null,"funder_award_id":"ECS00000041","funder_id":"https://openalex.org/F4320321873","funder_display_name":"Ministero dell\u2019Istruzione, dell\u2019Universit\u00e0 e della Ricerca"},{"id":"https://openalex.org/G903117326","display_name":null,"funder_award_id":"ECS00000041","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"}],"funders":[{"id":"https://openalex.org/F4320320300","display_name":"European Commission","ror":"https://ror.org/00k4n6c32"},{"id":"https://openalex.org/F4320321873","display_name":"Ministero dell\u2019Istruzione, dell\u2019Universit\u00e0 e della Ricerca","ror":"https://ror.org/0166hxq48"},{"id":"https://openalex.org/F4320322651","display_name":"Consiglio Nazionale delle Ricerche","ror":"https://ror.org/04zaypm56"},{"id":"https://openalex.org/F4320326523","display_name":"Universit\u00e0 degli Studi di Perugia","ror":"https://ror.org/00x27da85"},{"id":"https://openalex.org/F7311471023","display_name":"NextGenerationEU","ror":null}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4412372504.pdf","grobid_xml":"https://content.openalex.org/works/W4412372504.grobid-xml"},"referenced_works_count":67,"referenced_works":["https://openalex.org/W1637643788","https://openalex.org/W1971347878","https://openalex.org/W1974931722","https://openalex.org/W1976952687","https://openalex.org/W1985264891","https://openalex.org/W1990442032","https://openalex.org/W1998809987","https://openalex.org/W2011372081","https://openalex.org/W2019066397","https://openalex.org/W2029064676","https://openalex.org/W2030687437","https://openalex.org/W2042267313","https://openalex.org/W2048088234","https://openalex.org/W2052113323","https://openalex.org/W2060157763","https://openalex.org/W2062927193","https://openalex.org/W2084261072","https://openalex.org/W2084897153","https://openalex.org/W2085831526","https://openalex.org/W2086957099","https://openalex.org/W2091208014","https://openalex.org/W2092157292","https://openalex.org/W2093962008","https://openalex.org/W2095374362","https://openalex.org/W2096747776","https://openalex.org/W2099911759","https://openalex.org/W2101376122","https://openalex.org/W2103595236","https://openalex.org/W2108446403","https://openalex.org/W2121265498","https://openalex.org/W2127058321","https://openalex.org/W2127520810","https://openalex.org/W2139664529","https://openalex.org/W2139926613","https://openalex.org/W2150345533","https://openalex.org/W2166198169","https://openalex.org/W2170923445","https://openalex.org/W2171492520","https://openalex.org/W2316461462","https://openalex.org/W2316730697","https://openalex.org/W2495996386","https://openalex.org/W2601224882","https://openalex.org/W2741935384","https://openalex.org/W2766913260","https://openalex.org/W2806646938","https://openalex.org/W2891753512","https://openalex.org/W2898434977","https://openalex.org/W2948008879","https://openalex.org/W2954397451","https://openalex.org/W2996575422","https://openalex.org/W3157094166","https://openalex.org/W3168365116","https://openalex.org/W3197477767","https://openalex.org/W4211231377","https://openalex.org/W4213342450","https://openalex.org/W4226434051","https://openalex.org/W4229036682","https://openalex.org/W4229864351","https://openalex.org/W4287455453","https://openalex.org/W4309921752","https://openalex.org/W4311026805","https://openalex.org/W4311617466","https://openalex.org/W4317532292","https://openalex.org/W4389800989","https://openalex.org/W4391338281","https://openalex.org/W4395068565","https://openalex.org/W4396677026"],"related_works":["https://openalex.org/W4284676956","https://openalex.org/W2321960439","https://openalex.org/W2045828317","https://openalex.org/W2142358554","https://openalex.org/W3191062931","https://openalex.org/W2594337696","https://openalex.org/W4406084117","https://openalex.org/W1983924825","https://openalex.org/W2080615720","https://openalex.org/W2004604901"],"abstract_inverted_index":{"High":[0],"Resolution":[1],"Image":[2],"Download":[3],"MS":[4],"PowerPoint":[5],"Slide":[6],"A":[7],"gold":[8],"complex,":[9],"[(":[10,146,151],"t":[11,16,104,147,152,181,190],"Bu":[12,17,105,148,153,182,191],"PCP)Au\u2013H]":[13,154,183],"+":[14,155,184],"(":[15],"PCP":[18],"=":[19,114,120],"2,6-bis(di-":[20],"tert":[21],"-butylphosphinomethyl)benzene),":[22],"has":[23],"been":[24],"recently":[25],"reported":[26,52],"to":[27,36,129,161,164,233],"insert":[28],"O":[29,62],"2":[30,63],"into":[31],"the":[32,79,89,144,170,199,205,210,214,217,221,224],"Au(III)\u2013H":[33,90,111],"bond,":[34],"leading":[35],"a":[37,137,177,187],"stable":[38],"Au(III)\u2013OOH":[39],"complex":[40],"with":[41,48,61,88,96,167,169],"an":[42],"observed":[43],"kinetic":[44],"behavior":[45],"sharing":[46],"similarities":[47],"those":[49],"of":[50,73,132,140,212,223,227],"previously":[51],"Pd(II)\u2013H":[53,102],"(nonradical)":[54],"and":[55,93,186,216],"Pt(IV)\u2013H":[56],"(autoaccelerated":[57],"radical":[58,178],"chain)":[59],"reactions":[60],".":[64],"In":[65],"this":[66,82],"work,":[67],"we":[68,159],"computationally":[69],"investigate,":[70],"by":[71],"inclusion":[72],"spin\u2013orbit":[74],"coupling":[75],"(SOC)":[76],"effects,":[77],"along":[78],"adiabatic":[80],"PES,":[81],"elusive":[83],"reaction":[84],"mechanism":[85],"in":[86,94,124,143,197,209],"connection":[87],"bond":[91,172,201],"nature":[92,211],"comparison":[95],"recent":[97],"case":[98],"studies":[99],"involving":[100],"isostructural":[101],"([(":[103,180,189],"PCP)Pd\u2013H])":[106,192],"or":[107],"different":[108],"ligand":[109,215],"supported":[110],"([(CNC)Au\u2013H],":[112],"CNC":[113],"2,6-bis(alkylimidazol-2-ylidene)-pyridine)":[115],"bonds.":[116],"The":[117,194],"M\u2013H":[118,171,200],"(M":[119],"Au,":[121],"Pd)":[122],"bonds":[123],"these":[125,228],"complexes":[126,229],"are":[127],"shown":[128],"be":[130,162],"mainly":[131],"electron-sharing":[133],"nature,":[134],"featuring,":[135],"however,":[136],"decreasing":[138],"degree":[139],"M(\u03b4+)\u2013H(\u03b4\u2212)":[141],"polarization":[142],"order":[145],"PCP)Pd\u2013H]":[149],">":[150,156],"[(CNC)Au\u2013H],":[157],"which":[158],"propose":[160],"related":[163],"their":[165],"reactivity":[166,175],"dioxygen,":[168],"displaying":[173],"no":[174],"([(CNC)Au\u2013H]),":[176],"chain":[179],"),":[185],"nonradical":[188],"reactivity.":[193],"decisive":[195],"factors":[196],"dictating":[198],"polarity":[202],"and,":[203],"consequently,":[204],"preferred":[206],"pathway":[207],"lie":[208],"both":[213],"metal,":[218],"demonstrating":[219],"how":[220],"fine-tuning":[222],"electronic":[225],"structure":[226],"causes":[230],"mechanistic":[231],"pathways":[232],"diverge.":[234]},"counts_by_year":[{"year":2025,"cited_by_count":1}],"updated_date":"2026-09-23T05:00:35.095934","created_date":"2025-10-10T00:00:00"}