{"id":"https://openalex.org/W4411249538","doi":"https://doi.org/10.1021/acssuschemeng.5c00933","title":"High-Voltage Fluoride-Free Electrolytes for Ni-Rich Cathodes Offering Superior Water Resistance","display_name":"High-Voltage Fluoride-Free Electrolytes for Ni-Rich Cathodes Offering Superior Water Resistance","publication_year":2025,"publication_date":"2025-06-12","ids":{"openalex":"https://openalex.org/W4411249538","doi":"https://doi.org/10.1021/acssuschemeng.5c00933"},"language":"en","primary_location":{"id":"doi:10.1021/acssuschemeng.5c00933","doi":"https://doi.org/10.1021/acssuschemeng.5c00933","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acssuschemeng.5c00933","pdf_url":null,"source":{"id":"https://openalex.org/S2502047864","display_name":"ACS Sustainable Chemistry & Engineering","issn_l":"2168-0485","issn":["2168-0485"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Sustainable Chemistry &amp; Engineering","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101857347","display_name":"Chengkun Liu","orcid":"https://orcid.org/0000-0002-4733-3705","observed_orcids":["https://orcid.org/0000-0002-4733-3705"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chengkun Liu","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100719205","display_name":"Tao Yang","orcid":"https://orcid.org/0000-0002-0043-5501","observed_orcids":["https://orcid.org/0000-0002-0043-5501"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tao Yang","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100781757","display_name":"Qi Yu","orcid":"https://orcid.org/0000-0002-7786-7441","observed_orcids":["https://orcid.org/0000-0002-7786-7441","https://orcid.org/0009-0003-3645-571X","https://orcid.org/0009-0004-4364-1585","https://orcid.org/0009-0009-9899-523X"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qi Yu","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101819081","display_name":"Shuilin Wu","orcid":"https://orcid.org/0000-0001-6957-7498","observed_orcids":["https://orcid.org/0000-0001-6957-7498"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shilin Wu","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091626025","display_name":"Haiwen Li","orcid":"https://orcid.org/0000-0001-7223-1754","observed_orcids":["https://orcid.org/0000-0001-7223-1754"]},"institutions":[{"id":"https://openalex.org/I157773358","display_name":"Sun Yat-sen University","ror":"https://ror.org/0064kty71","country_code":"CN","type":"education","lineage":["https://openalex.org/I157773358"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hai-Wen Li","raw_affiliation_strings":["School of Advanced Energy","Sun Yat-sen University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Advanced Energy","institution_ids":[]},{"raw_affiliation_string":"Sun Yat-sen University","institution_ids":["https://openalex.org/I157773358"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074835551","display_name":"Zhipeng Jiang","orcid":"https://orcid.org/0000-0001-6394-5552","observed_orcids":["https://orcid.org/0000-0001-6394-5552"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Zhipeng Jiang","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering","School of Materials Science and Engineering, Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen & Electricity of Anhui Province"],"raw_orcid":"https://orcid.org/0000-0001-6394-5552","affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]},{"raw_affiliation_string":"School of Materials Science and Engineering, Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen & Electricity of Anhui Province","institution_ids":["https://openalex.org/I92178344"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100753077","display_name":"Yongtao Li","orcid":"https://orcid.org/0000-0003-1745-4466","observed_orcids":["https://orcid.org/0000-0003-1745-4466","https://orcid.org/0000-0002-7478-8975"]},"institutions":[{"id":"https://openalex.org/I92178344","display_name":"Anhui University of Technology","ror":"https://ror.org/02qdtrq21","country_code":"CN","type":"education","lineage":["https://openalex.org/I92178344"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yongtao Li","raw_affiliation_strings":["Anhui University of Technology","School of Materials Science and Engineering","School of Materials Science and Engineering, Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen & Electricity of Anhui Province"],"raw_orcid":"https://orcid.org/0000-0003-1745-4466","affiliations":[{"raw_affiliation_string":"Anhui University of Technology","institution_ids":["https://openalex.org/I92178344"]},{"raw_affiliation_string":"School of Materials Science and Engineering","institution_ids":[]},{"raw_affiliation_string":"School of Materials Science and Engineering, Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen & Electricity of Anhui Province","institution_ids":["https://openalex.org/I92178344"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5074835551","https://openalex.org/A5100753077"],"corresponding_institution_ids":["https://openalex.org/I92178344"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.7713,"has_fulltext":false,"cited_by_count":12,"citation_normalized_percentile":{"value":0.91138276,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":96,"max":100},"biblio":{"volume":"13","issue":"24","first_page":"8951","last_page":"8958"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.5648999810218811,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.5648999810218811,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.4196999967098236,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10663","display_name":"Advanced Battery Technologies Research","score":0.005900000222027302,"subfield":{"id":"https://openalex.org/subfields/2203","display_name":"Automotive Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/high-voltage-electrolytes","display_name":"high-voltage electrolytes","score":0.9279999732971191},{"id":"https://openalex.org/keywords/ni-rich-cathodes","display_name":"Ni-rich cathodes","score":0.8029999732971191},{"id":"https://openalex.org/keywords/ncm811","display_name":"NCM811","score":0.9649999737739563},{"id":"https://openalex.org/keywords/water-resistance","display_name":"water resistance","score":0.7630000114440918},{"id":"https://openalex.org/keywords/hydrofluoric-acid","display_name":"hydrofluoric acid","score":0.8539999723434448},{"id":"https://openalex.org/keywords/cathode-electrolyte-interphase","display_name":"cathode electrolyte interphase","score":0.9789999723434448},{"id":"https://openalex.org/keywords/cycling-stability","display_name":"cycling stability","score":0.6430000066757202},{"id":"https://openalex.org/keywords/humid-conditions","display_name":"humid conditions","score":0.5680000185966492},{"id":"https://openalex.org/keywords/lithium-ion-batteries","display_name":"lithium-ion batteries","score":0.6859999895095825},{"id":"https://openalex.org/keywords/electric-vehicle-batteries","display_name":"electric vehicle batteries","score":0.7369999885559082},{"id":"https://openalex.org/keywords/full-cell-cycling","display_name":"full cell cycling","score":0.4440000057220459}],"concepts":[{"id":"https://openalex.org/C2780828025","wikidata":"https://www.wikidata.org/wiki/Q44793182","display_name":"Fluoride","level":2,"score":0.6785578727722168},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.6118912100791931},{"id":"https://openalex.org/C49110097","wikidata":"https://www.wikidata.org/wiki/Q175233","display_name":"Cathode","level":2,"score":0.5903777480125427},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.48335641622543335},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4021531641483307},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.34760332107543945},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.34747031331062317},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.18498927354812622},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0709056556224823},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acssuschemeng.5c00933","doi":"https://doi.org/10.1021/acssuschemeng.5c00933","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acssuschemeng.5c00933","pdf_url":null,"source":{"id":"https://openalex.org/S2502047864","display_name":"ACS Sustainable Chemistry & Engineering","issn_l":"2168-0485","issn":["2168-0485"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Sustainable Chemistry &amp; Engineering","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.9090999960899353}],"sustainable_development_goals_aurora":[{"id":"https://metadata.un.org/sdg/6","display_name":"Clean water and sanitation","score":0.6899999976158142}],"study_designs":[],"awards":[{"id":"https://openalex.org/G1993080861","display_name":null,"funder_award_id":"2022AH010025","funder_id":"https://openalex.org/F4320326664","funder_display_name":"Anhui Provincial Department of Education"},{"id":"https://openalex.org/G3936213801","display_name":null,"funder_award_id":"2308085QB50","funder_id":"https://openalex.org/F4320334897","funder_display_name":"Natural Science Foundation of Anhui Province"},{"id":"https://openalex.org/G5156378303","display_name":null,"funder_award_id":"2022AH020033","funder_id":"https://openalex.org/F4320326664","funder_display_name":"Anhui Provincial Department of Education"},{"id":"https://openalex.org/G7347563520","display_name":null,"funder_award_id":"52471027","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G8193049289","display_name":null,"funder_award_id":"22308003","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320326664","display_name":"Anhui Provincial Department of Education","ror":null},{"id":"https://openalex.org/F4320334897","display_name":"Natural Science Foundation of Anhui Province","ror":null}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":43,"referenced_works":["https://openalex.org/W2026133746","https://openalex.org/W2041340092","https://openalex.org/W2089111927","https://openalex.org/W2098382293","https://openalex.org/W2202401119","https://openalex.org/W2473123944","https://openalex.org/W2767761113","https://openalex.org/W2796510664","https://openalex.org/W2800200865","https://openalex.org/W2954940783","https://openalex.org/W2968782665","https://openalex.org/W2979895419","https://openalex.org/W3037454756","https://openalex.org/W3082730245","https://openalex.org/W3085708853","https://openalex.org/W3120709975","https://openalex.org/W3171967663","https://openalex.org/W3210206434","https://openalex.org/W3213328656","https://openalex.org/W4200396283","https://openalex.org/W4281697669","https://openalex.org/W4283359282","https://openalex.org/W4296697742","https://openalex.org/W4367845112","https://openalex.org/W4380434497","https://openalex.org/W4386701075","https://openalex.org/W4388280731","https://openalex.org/W4388367941","https://openalex.org/W4390268727","https://openalex.org/W4390521246","https://openalex.org/W4392458039","https://openalex.org/W4392940066","https://openalex.org/W4394725351","https://openalex.org/W4394819692","https://openalex.org/W4395008792","https://openalex.org/W4396805599","https://openalex.org/W4399726814","https://openalex.org/W4399808527","https://openalex.org/W4401368476","https://openalex.org/W4401734141","https://openalex.org/W4403284491","https://openalex.org/W4403615249","https://openalex.org/W4403699647"],"related_works":["https://openalex.org/W2748952813","https://openalex.org/W2969851177","https://openalex.org/W189299056","https://openalex.org/W2019442459","https://openalex.org/W2185683615","https://openalex.org/W968773416","https://openalex.org/W1897436063","https://openalex.org/W2473684735","https://openalex.org/W787063493","https://openalex.org/W2028117211"],"abstract_inverted_index":{"To":[0],"enhance":[1],"the":[2,82,100,118,132],"range":[3],"of":[4,67,78,84,102,134,137,148,188,202],"electric":[5],"vehicles":[6],"(EVs),":[7],"high-nickel":[8],"(Ni)":[9],"layered":[10],"oxide":[11],"cathode":[12,119],"materials":[13],"are":[14],"increasingly":[15],"favored":[16],"in":[17,31],"power":[18],"battery":[19],"design.":[20],"However,":[21],"Ni-rich":[22,95],"cathodes":[23,61],"face":[24],"significant":[25],"challenges":[26],"regarding":[27],"cycling":[28,163],"stability,":[29],"particularly":[30],"humid":[32],"conditions,":[33],"where":[34],"their":[35],"lifespan":[36],"deteriorates":[37],"rapidly.":[38],"Herein,":[39],"we":[40],"present":[41],"a":[42,64,103,146,155,178],"sustainable":[43],"high-voltage":[44],"fluoride-free":[45,76],"electrolyte":[46,80,140],"(HVFFE)":[47],"that":[48,129],"is":[49],"compatible":[50],"with":[51,109,131,172,185],"LiNi":[52],"0.8":[53],"Co":[54],"0.1":[55,57],"Mn":[56],"O":[58,191],"2":[59,170,190],"(NCM811)":[60],"operating":[62],"at":[63,154,169],"cutoff":[65],"voltage":[66],"4.4":[68],"V":[69],"and":[70,113,121,160],"exhibiting":[71],"superior":[72],"water":[73],"resistance.":[74],"The":[75,97],"nature":[77],"this":[79,139],"prevents":[81],"formation":[83,101],"hydrofluoric":[85],"acid":[86],"(HF)":[87],"upon":[88],"exposure":[89],"to":[90,144],"moisture,":[91],"which":[92],"commonly":[93],"degrades":[94],"cathodes.":[96],"HVFFE":[98,184],"facilitates":[99],"robust":[104],"cathode-electrolyte":[105],"interphase":[106],"(CEI)":[107],"enriched":[108],"sulfur,":[110],"boron,":[111],"oxygen,":[112],"nitrogen":[114],"(S/B/O/N),":[115],"effectively":[116],"stabilizing":[117],"structure":[120],"minimizing":[122],"active":[123],"material":[124],"degradation.":[125],"Electrochemical":[126],"testing":[127],"reveals":[128],"even":[130],"addition":[133],"1000":[135,186],"ppm":[136,187],"water,":[138],"enables":[141],"Li-NCM811":[142,180],"cells":[143],"maintain":[145],"capacity":[147,174],"over":[149,194],"100":[150],"mAh":[151],"g":[152],"\u20131":[153],"10":[156],"C":[157],"discharge":[158],"rate":[159],"supports":[161],"stable":[162],"for":[164],"more":[165],"than":[166],"500":[167],"cycles":[168],"C,":[171],"94.7%":[173],"retention.":[175],"More":[176],"importantly,":[177],"high-loading":[179],"full":[181],"cell":[182],"using":[183],"H":[189],"maintained":[192],"stability":[193],"200":[195],"cycles,":[196],"achieving":[197],"an":[198],"average":[199],"Coulombic":[200],"efficiency":[201],"99.61%.":[203]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":3}],"updated_date":"2026-09-24T07:57:37.273135","created_date":"2025-10-10T00:00:00"}
