{"id":"https://openalex.org/W4411203996","doi":"https://doi.org/10.1021/jacs.4c18349","title":"Proton-Transfer Kinetics at Liquid\u2013Liquid Interfaces","display_name":"Proton-Transfer Kinetics at Liquid\u2013Liquid Interfaces","publication_year":2025,"publication_date":"2025-06-11","ids":{"openalex":"https://openalex.org/W4411203996","doi":"https://doi.org/10.1021/jacs.4c18349","pmid":"https://pubmed.ncbi.nlm.nih.gov/40498631"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.4c18349","doi":"https://doi.org/10.1021/jacs.4c18349","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.4c18349","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv-2024-sxzbn-v2","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5031615195","display_name":"Nick D\u2019Antona","orcid":"https://orcid.org/0000-0002-7859-7041","observed_orcids":["https://orcid.org/0000-0002-7859-7041"]},"institutions":[{"id":"https://openalex.org/I181233156","display_name":"University of Oregon","ror":"https://ror.org/0293rh119","country_code":"US","type":"education","lineage":["https://openalex.org/I181233156"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nick D\u2019Antona","raw_affiliation_strings":["Department of Chemical & Biomolecular Engineering and Department of Chemistry","Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","University of California, Berkeley","University of Oregon"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical & Biomolecular Engineering and Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","institution_ids":[]},{"raw_affiliation_string":"University of California, Berkeley","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"University of Oregon","institution_ids":["https://openalex.org/I181233156"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101916830","display_name":"Joseph Kelly","orcid":"https://orcid.org/0000-0001-5336-4199","observed_orcids":["https://orcid.org/0000-0001-5336-4199"]},"institutions":[{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joseph Kelly","raw_affiliation_strings":["Department of Chemistry","Stanford University"],"raw_orcid":"https://orcid.org/0000-0001-5336-4199","affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Stanford University","institution_ids":["https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056168783","display_name":"Nadia Barnard","orcid":"https://orcid.org/0000-0003-1655-4182","observed_orcids":["https://orcid.org/0000-0003-1655-4182"]},"institutions":[{"id":"https://openalex.org/I181233156","display_name":"University of Oregon","ror":"https://ror.org/0293rh119","country_code":"US","type":"education","lineage":["https://openalex.org/I181233156"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nadia Barnard","raw_affiliation_strings":["Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","University of Oregon"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","institution_ids":[]},{"raw_affiliation_string":"University of Oregon","institution_ids":["https://openalex.org/I181233156"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020769760","display_name":"Shane Ardo","orcid":"https://orcid.org/0000-0001-7162-6826","observed_orcids":["https://orcid.org/0000-0001-7162-6826"]},"institutions":[{"id":"https://openalex.org/I204250578","display_name":"University of California, Irvine","ror":"https://ror.org/04gyf1771","country_code":"US","type":"education","lineage":["https://openalex.org/I204250578"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shane Ardo","raw_affiliation_strings":["Department of Chemistry","University of California, Irvine"],"raw_orcid":"https://orcid.org/0000-0001-7162-6826","affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"University of California, Irvine","institution_ids":["https://openalex.org/I204250578"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101784898","display_name":"Yixian Wang","orcid":"https://orcid.org/0000-0001-8691-1128","observed_orcids":["https://orcid.org/0000-0001-8691-1128"]},"institutions":[{"id":"https://openalex.org/I27825529","display_name":"California State University Los Angeles","ror":"https://ror.org/0294hxs80","country_code":"US","type":"education","lineage":["https://openalex.org/I27825529"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yixian Wang","raw_affiliation_strings":["California State University, Los Angeles","Department of Chemistry"],"raw_orcid":"https://orcid.org/0000-0001-8691-1128","affiliations":[{"raw_affiliation_string":"California State University, Los Angeles","institution_ids":["https://openalex.org/I27825529"]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021899292","display_name":"Yogesh Surendranath","orcid":"https://orcid.org/0000-0003-1016-3420","observed_orcids":["https://orcid.org/0000-0003-1016-3420"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yogesh Surendranath","raw_affiliation_strings":["Department of Chemistry","Massachusetts Institute of Technology"],"raw_orcid":"https://orcid.org/0000-0003-1016-3420","affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Massachusetts Institute of Technology","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069747836","display_name":"Thomas E. Markland","orcid":"https://orcid.org/0000-0002-2747-0518","observed_orcids":["https://orcid.org/0000-0002-2747-0518"]},"institutions":[{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas E. Markland","raw_affiliation_strings":["Department of Chemistry","Stanford University"],"raw_orcid":"https://orcid.org/0000-0002-2747-0518","affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Stanford University","institution_ids":["https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003067415","display_name":"Paul Andrew Kempler","orcid":"https://orcid.org/0000-0003-3909-1790","observed_orcids":["https://orcid.org/0000-0003-3909-1790"]},"institutions":[{"id":"https://openalex.org/I181233156","display_name":"University of Oregon","ror":"https://ror.org/0293rh119","country_code":"US","type":"education","lineage":["https://openalex.org/I181233156"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Paul A. Kempler","raw_affiliation_strings":["Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","University of Oregon"],"raw_orcid":"https://orcid.org/0000-0003-3909-1790","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","institution_ids":[]},{"raw_affiliation_string":"University of Oregon","institution_ids":["https://openalex.org/I181233156"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032458792","display_name":"Shannon Wachter Boettcher","orcid":"https://orcid.org/0000-0001-8971-9123","observed_orcids":["https://orcid.org/0000-0001-8971-9123"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I181233156","display_name":"University of Oregon","ror":"https://ror.org/0293rh119","country_code":"US","type":"education","lineage":["https://openalex.org/I181233156"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Shannon W. Boettcher","raw_affiliation_strings":["Department of Chemical & Biomolecular Engineering and Department of Chemistry","Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","Energy Storage and Distributed Resources Division","Lawrence Berkeley National Laboratory","University of California, Berkeley","University of Oregon"],"raw_orcid":"https://orcid.org/0000-0001-8971-9123","affiliations":[{"raw_affiliation_string":"Department of Chemical & Biomolecular Engineering and Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry","institution_ids":[]},{"raw_affiliation_string":"Energy Storage and Distributed Resources Division","institution_ids":[]},{"raw_affiliation_string":"Lawrence Berkeley National Laboratory","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"University of California, Berkeley","institution_ids":["https://openalex.org/I95457486"]},{"raw_affiliation_string":"University of Oregon","institution_ids":["https://openalex.org/I181233156"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":7,"corresponding_author_ids":["https://openalex.org/A5003067415","https://openalex.org/A5032458792"],"corresponding_institution_ids":["https://openalex.org/I148283060","https://openalex.org/I181233156","https://openalex.org/I95457486"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.3091,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.88170974,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"147","issue":"25","first_page":"21408","last_page":"21418"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.9818999767303467,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.9818999767303467,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13675","display_name":"Diffusion Coefficients in Liquids","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/proton-transfer-kinetics","display_name":"proton transfer kinetics","score":0.859000027179718},{"id":"https://openalex.org/keywords/liquid-liquid-interface","display_name":"liquid-liquid interface","score":0.9419999718666077},{"id":"https://openalex.org/keywords/immiscible-electrolyte-solutions","display_name":"immiscible electrolyte solutions","score":0.9079999923706055},{"id":"https://openalex.org/keywords/interfacial-energy","display_name":"interfacial energy","score":0.6830000281333923}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9719147682189941},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.786091685295105},{"id":"https://openalex.org/C54516573","wikidata":"https://www.wikidata.org/wiki/Q2294","display_name":"Proton","level":2,"score":0.6784735918045044},{"id":"https://openalex.org/C3017397382","wikidata":"https://www.wikidata.org/wiki/Q3242293","display_name":"Liquid liquid","level":2,"score":0.5686778426170349},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.2507492005825043},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.09785664081573486},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1021/jacs.4c18349","doi":"https://doi.org/10.1021/jacs.4c18349","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.4c18349","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv-2024-sxzbn-v2","doi":"https://doi.org/10.26434/chemrxiv-2024-sxzbn-v2","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-sxzbn-v2","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"doi:10.26434/chemrxiv-2024-sxzbn","doi":"https://doi.org/10.26434/chemrxiv-2024-sxzbn","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-sxzbn","pdf_url":"https://chemrxiv.org/doi/pdf/10.26434/chemrxiv-2024-sxzbn-v2","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:40498631","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/40498631","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:escholarship.org:ark:/13030/qt1b97p9z7","doi":null,"is_oa":true,"landing_page_url":"https://escholarship.org/uc/item/1b97p9z7","pdf_url":null,"source":{"id":"https://openalex.org/S4306400115","display_name":"eScholarship (California Digital Library)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I2801248553","host_organization_name":"California Digital Library","host_organization_lineage":["https://openalex.org/I2801248553"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society, vol 147, iss 25","raw_type":"article"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2024-sxzbn-v2","doi":"https://doi.org/10.26434/chemrxiv-2024-sxzbn-v2","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-sxzbn-v2","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8960384556","display_name":"CCI Phase I: NSF Center for Interfacial Ionics","funder_award_id":"2221599","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4411203996.pdf","grobid_xml":"https://content.openalex.org/works/W4411203996.grobid-xml"},"referenced_works_count":57,"referenced_works":["https://openalex.org/W1514053888","https://openalex.org/W1963632520","https://openalex.org/W1967415474","https://openalex.org/W1972040015","https://openalex.org/W1982935890","https://openalex.org/W1984633709","https://openalex.org/W1987127711","https://openalex.org/W1994201610","https://openalex.org/W1999995334","https://openalex.org/W2002164330","https://openalex.org/W2019692171","https://openalex.org/W2021034885","https://openalex.org/W2022714449","https://openalex.org/W2029186981","https://openalex.org/W2031003787","https://openalex.org/W2041220523","https://openalex.org/W2042438728","https://openalex.org/W2045534769","https://openalex.org/W2055858503","https://openalex.org/W2057806291","https://openalex.org/W2058957311","https://openalex.org/W2060964789","https://openalex.org/W2061414720","https://openalex.org/W2062998281","https://openalex.org/W2077767650","https://openalex.org/W2078752693","https://openalex.org/W2082634114","https://openalex.org/W2102172981","https://openalex.org/W2124129640","https://openalex.org/W2124996496","https://openalex.org/W2126119374","https://openalex.org/W2126276771","https://openalex.org/W2127400370","https://openalex.org/W2144448191","https://openalex.org/W2148228860","https://openalex.org/W2149655632","https://openalex.org/W2168550600","https://openalex.org/W2225958871","https://openalex.org/W2750566476","https://openalex.org/W2809773670","https://openalex.org/W2896751693","https://openalex.org/W2921826364","https://openalex.org/W3024593341","https://openalex.org/W3086303450","https://openalex.org/W3087912915","https://openalex.org/W3099746599","https://openalex.org/W3102774518","https://openalex.org/W3107296503","https://openalex.org/W3118324056","https://openalex.org/W3130914104","https://openalex.org/W3165440785","https://openalex.org/W3207271444","https://openalex.org/W4210832277","https://openalex.org/W4284894915","https://openalex.org/W4308774575","https://openalex.org/W4378907960","https://openalex.org/W4392252290"],"related_works":["https://openalex.org/W4401699010","https://openalex.org/W2082634114","https://openalex.org/W6977821463","https://openalex.org/W4283715859","https://openalex.org/W2048084658","https://openalex.org/W1965358163","https://openalex.org/W2113119676","https://openalex.org/W1605948074","https://openalex.org/W4213170342","https://openalex.org/W2567808299"],"abstract_inverted_index":{"Proton":[0],"transfer":[1,35,54,87,133,169,184],"at":[2,36,62,81,170],"electrochemical":[3,186],"interfaces":[4,83],"is":[5],"fundamentally":[6],"important":[7,175],"for":[8,98,120],"many":[9],"areas":[10],"of":[11,18,59,101,130,167,179,182],"science":[12,187],"and":[13,79,105,115,134,188],"technology,":[14],"yet":[15],"kinetic":[16,102],"measurements":[17],"this":[19],"elementary":[20],"step":[21,157],"are":[22],"often":[23],"convoluted":[24],"by":[25],"inhomogeneous":[26],"electrode":[27],"surface":[28],"structures.":[29],"We":[30],"show":[31],"that":[32,69],"facilitated":[33,72,122],"proton":[34,53,123,132,136],"the":[37,57,76,99,139,154,165,171,177],"interface":[38,78],"between":[39,142],"two":[40,144],"immiscible":[41],"electrolyte":[42],"solutions":[43],"(ITIES)":[44],"can":[45],"serve":[46],"as":[47],"a":[48,93],"model":[49,96],"system":[50],"to":[51,92,110,149,159],"study":[52],"kinetics":[55,166],"in":[56,176,185],"absence":[58],"defects":[60],"found":[61],"solid|electrolyte":[63],"interfaces.":[64],"Diffusion-controlled":[65],"micropipette":[66],"voltammetry":[67,80],"revealed":[68],"2,6-diphenylpyridine":[70],"(DPP)":[71],"interfacial":[73],"proton-transfer":[74],"across":[75],"HCl(aq)|Trifluorotoluene":[77],"nanopipette-supported":[82],"yielded":[84],"activation-controlled":[85],"ion":[86,168,183],"currents.":[88],"Fitting":[89],"quasireversible":[90],"voltammograms":[91],"mixed":[94],"diffusive-kinetic":[95],"allow":[97],"extraction":[100],"parameters":[103],"k0":[104],"\u03b1,":[106],"which":[107],"were":[108],"equal":[109],"3.0":[111],"+/-":[112,117],"1.8":[113],"cm/s":[114],"0.3":[116],"0.2,":[118],"respectively":[119],"DPP":[121],"transfer.":[124],"Finite":[125],"element":[126],"simulations":[127],"highlighted":[128],"regimes":[129],"direct":[131,151],"sequential":[135],"transfer,":[137],"where":[138],"current":[140],"divided":[141],"these":[143],"possible":[145],"pathways":[146],"was":[147,161],"shown":[148],"favor":[150],"PT":[152],"when":[153],"neutral":[155],"partitioning":[156],"DPP(org)":[158],"DPP(aq)":[160],"rate":[162],"determining.":[163],"Understanding":[164],"ITIES":[172],"will":[173],"be":[174],"development":[178],"general":[180],"theories":[181],"technology.":[189]},"counts_by_year":[{"year":2026,"cited_by_count":8},{"year":2025,"cited_by_count":1}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2025-06-12T00:00:00"}
