{"id":"https://openalex.org/W4410077258","doi":"https://doi.org/10.26434/chemrxiv-2025-2k47h","title":"Side-Chain Dipolar Character Controls Threshold Voltage in So-lution-Processed Organic Single-Crystal Transistors","display_name":"Side-Chain Dipolar Character Controls Threshold Voltage in So-lution-Processed Organic Single-Crystal Transistors","publication_year":2025,"publication_date":"2025-05-05","ids":{"openalex":"https://openalex.org/W4410077258","doi":"https://doi.org/10.26434/chemrxiv-2025-2k47h"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv-2025-2k47h","doi":"https://doi.org/10.26434/chemrxiv-2025-2k47h","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2025-2k47h","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67fe395672da395cef47c594/original/side-chain-dipolar-character-controls-threshold-voltage-in-so-lution-processed-organic-single-crystal-transistors.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67fe395672da395cef47c594/original/side-chain-dipolar-character-controls-threshold-voltage-in-so-lution-processed-organic-single-crystal-transistors.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057673683","display_name":"Shohei Kumagai","orcid":"https://orcid.org/0000-0002-1554-054X","observed_orcids":["https://orcid.org/0000-0002-1554-054X"]},"institutions":[{"id":"https://openalex.org/I4400009020","display_name":"Institute of Science Tokyo","ror":"https://ror.org/05dqf9946","country_code":"JP","type":"education","lineage":["https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Shohei Kumagai","raw_affiliation_strings":["Institute of Science Tokyo"],"raw_orcid":"https://orcid.org/0000-0002-1554-054X","affiliations":[{"raw_affiliation_string":"Institute of Science Tokyo","institution_ids":["https://openalex.org/I4400009020"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002425142","display_name":"Takeru Koguma","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74801974","display_name":"The University of Tokyo","ror":"https://ror.org/057zh3y96","country_code":"JP","type":"education","lineage":["https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takeru Koguma","raw_affiliation_strings":["The University of Tokyo"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The University of Tokyo","institution_ids":["https://openalex.org/I74801974"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Takuya Seki","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I64189623","display_name":"Kitasato University","ror":"https://ror.org/00f2txz25","country_code":"JP","type":"education","lineage":["https://openalex.org/I64189623"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takuya Seki","raw_affiliation_strings":["Kitasato University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kitasato University","institution_ids":["https://openalex.org/I64189623"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072294943","display_name":"Go Watanabe","orcid":"https://orcid.org/0000-0001-6713-1249","observed_orcids":["https://orcid.org/0000-0001-6713-1249"]},"institutions":[{"id":"https://openalex.org/I64189623","display_name":"Kitasato University","ror":"https://ror.org/00f2txz25","country_code":"JP","type":"education","lineage":["https://openalex.org/I64189623"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Go Watanabe","raw_affiliation_strings":["Kitasato University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kitasato University","institution_ids":["https://openalex.org/I64189623"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065301619","display_name":"Ryoya Kimura","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I56624758","display_name":"Kansai University","ror":"https://ror.org/03xg1f311","country_code":"JP","type":"education","lineage":["https://openalex.org/I56624758"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Ryoya Kimura","raw_affiliation_strings":["Kansai University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kansai University","institution_ids":["https://openalex.org/I56624758"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088823219","display_name":"Masafumi Yano","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I56624758","display_name":"Kansai University","ror":"https://ror.org/03xg1f311","country_code":"JP","type":"education","lineage":["https://openalex.org/I56624758"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masafumi Yano","raw_affiliation_strings":["Kansai University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kansai University","institution_ids":["https://openalex.org/I56624758"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007916551","display_name":"Hiroyuki Ishii","orcid":"https://orcid.org/0000-0003-0644-1424","observed_orcids":["https://orcid.org/0000-0003-0644-1424"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hiroyuki Ishii","raw_affiliation_strings":["University of Tsukuba"],"raw_orcid":"https://orcid.org/0000-0003-0644-1424","affiliations":[{"raw_affiliation_string":"University of Tsukuba","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5107903330","display_name":"Jun Takeya","orcid":"https://orcid.org/0000-0001-7377-6043","observed_orcids":["https://orcid.org/0000-0001-7377-6043"]},"institutions":[{"id":"https://openalex.org/I74801974","display_name":"The University of Tokyo","ror":"https://ror.org/057zh3y96","country_code":"JP","type":"education","lineage":["https://openalex.org/I74801974"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Jun Takeya","raw_affiliation_strings":["The University of Tokyo"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The University of Tokyo","institution_ids":["https://openalex.org/I74801974"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5043708637","display_name":"Toshihiro Okamoto","orcid":"https://orcid.org/0000-0002-4783-0621","observed_orcids":["https://orcid.org/0000-0002-4783-0621"]},"institutions":[{"id":"https://openalex.org/I4400009020","display_name":"Institute of Science Tokyo","ror":"https://ror.org/05dqf9946","country_code":"JP","type":"education","lineage":["https://openalex.org/I4400009020"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Toshihiro Okamoto","raw_affiliation_strings":["Institute of Science Tokyo"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Science Tokyo","institution_ids":["https://openalex.org/I4400009020"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10623","display_name":"Thin-Film Transistor Technologies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/threshold-voltage-tuning","display_name":"threshold voltage control","score":0.777999997138977},{"id":"https://openalex.org/keywords/single-crystal-organic-semiconductors","display_name":"single-crystal organic semiconductors","score":0.8820000290870667},{"id":"https://openalex.org/keywords/organic-thin-film-transistors","display_name":"organic thin-film transistors","score":0.9509999752044678},{"id":"https://openalex.org/keywords/charge-carrier-mobility","display_name":"carrier mobility","score":0.6800000071525574},{"id":"https://openalex.org/keywords/printed-electronics","display_name":"printed electronics","score":0.5799999833106995}],"concepts":[{"id":"https://openalex.org/C2780861071","wikidata":"https://www.wikidata.org/wiki/Q1062934","display_name":"Character (mathematics)","level":2,"score":0.802824854850769},{"id":"https://openalex.org/C173523689","wikidata":"https://www.wikidata.org/wiki/Q215589","display_name":"Dipole","level":2,"score":0.5695987343788147},{"id":"https://openalex.org/C172385210","wikidata":"https://www.wikidata.org/wiki/Q5339","display_name":"Transistor","level":3,"score":0.5554164052009583},{"id":"https://openalex.org/C199185054","wikidata":"https://www.wikidata.org/wiki/Q552299","display_name":"Chain (unit)","level":2,"score":0.5091957449913025},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.500952959060669},{"id":"https://openalex.org/C195370968","wikidata":"https://www.wikidata.org/wiki/Q1754002","display_name":"Threshold voltage","level":4,"score":0.4989013671875},{"id":"https://openalex.org/C165801399","wikidata":"https://www.wikidata.org/wiki/Q25428","display_name":"Voltage","level":2,"score":0.45875266194343567},{"id":"https://openalex.org/C87359718","wikidata":"https://www.wikidata.org/wiki/Q1271916","display_name":"Thin-film transistor","level":3,"score":0.45396149158477783},{"id":"https://openalex.org/C73922627","wikidata":"https://www.wikidata.org/wiki/Q754943","display_name":"Single crystal","level":2,"score":0.4521005153656006},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.44153380393981934},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.25413060188293457},{"id":"https://openalex.org/C119599485","wikidata":"https://www.wikidata.org/wiki/Q43035","display_name":"Electrical engineering","level":1,"score":0.2494085133075714},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.21972328424453735},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.17381921410560608},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.17135104537010193},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.09505295753479004},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09372302889823914},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.07050955295562744},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0703628659248352},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.0},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv-2025-2k47h","doi":"https://doi.org/10.26434/chemrxiv-2025-2k47h","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2025-2k47h","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67fe395672da395cef47c594/original/side-chain-dipolar-character-controls-threshold-voltage-in-so-lution-processed-organic-single-crystal-transistors.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2025-2k47h","doi":"https://doi.org/10.26434/chemrxiv-2025-2k47h","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2025-2k47h","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67fe395672da395cef47c594/original/side-chain-dipolar-character-controls-threshold-voltage-in-so-lution-processed-organic-single-crystal-transistors.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1169371108","display_name":"\u96fb\u5b50\u9589\u3058\u8fbc\u3081\u5206\u5b50\u306e\u4e8c\u6b21\u5143\u7d50\u6676\u3068\u6c4e\u7528\u91cf\u5b50\u30c7\u30d0\u30a4\u30b9\u306e\u958b\u767a","funder_award_id":"JPMJCR21O3","funder_id":"https://openalex.org/F4320334789","funder_display_name":"Japan Science and Technology Agency"},{"id":"https://openalex.org/G1584165024","display_name":"Development of thermoelectric simulation methodology based on density functional theory and application to organic materials","funder_award_id":"18H01856","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G1676224060","display_name":null,"funder_award_id":"JP19H05719","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G2345776453","display_name":null,"funder_award_id":"JPMJCR21Q1","funder_id":"https://openalex.org/F4320338075","funder_display_name":"Core Research for Evolutional Science and Technology"},{"id":"https://openalex.org/G4052460982","display_name":"\u7269\u8cea\u5faa\u74b0\u578b\u534a\u5c0e\u4f53\u96c6\u7a4d\u56de\u8def\u306e\u5275\u88fd","funder_award_id":"JPMJCR24S1","funder_id":"https://openalex.org/F4320334789","funder_display_name":"Japan Science and Technology Agency"},{"id":"https://openalex.org/G4446715812","display_name":null,"funder_award_id":"JPMJPR17R2","funder_id":"https://openalex.org/F4320338111","funder_display_name":"Precursory Research for Embryonic Science and Technology"},{"id":"https://openalex.org/G5398386091","display_name":null,"funder_award_id":"JPMJCR21O3","funder_id":"https://openalex.org/F4320338075","funder_display_name":"Core Research for Evolutional Science and Technology"},{"id":"https://openalex.org/G6360407","display_name":"Scientific development of organic semiconductors through the fusion of materials, theory, and physical properties research","funder_award_id":"24H00472","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G6718509927","display_name":null,"funder_award_id":"CREST","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G6863678541","display_name":"Giant strain effect of charge transport in organic single-crystal semiconductors and flexible mechano-electronics","funder_award_id":"17H06123","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G6911654392","display_name":"Creation of two-dimensional single crystals of n-type organic semiconductors driven by flustration","funder_award_id":"25K00074","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G7536010986","display_name":"\u6709\u6a5f\u534a\u5c0e\u4f53\u306e\u69cb\u9020\u5236\u5fa1\u6280\u8853\u306b\u3088\u308b\u9769\u65b0\u7684\u71b1\u96fb\u6750\u6599\u306e\u5275\u88fd","funder_award_id":"JPMJPR17R2","funder_id":"https://openalex.org/F4320334789","funder_display_name":"Japan Science and Technology Agency"},{"id":"https://openalex.org/G7620332108","display_name":"Creation of next-generation organic semiconductors based on the suppression of molecular vibrations","funder_award_id":"17H03104","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G7672975729","display_name":"Crystal engineering and single-crystal transistors of n-type organic semiconductors beaing alicyclic side chains","funder_award_id":"22K14743","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G780210857","display_name":"Realization of spin transistor using organic single crystal semiconductor","funder_award_id":"17H06200","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G7823778210","display_name":"\u30d0\u30f3\u30c9\u4f1d\u5c0e\u6027\u6709\u6a5f\u534a\u5c0e\u4f53\u3092\u7528\u3044\u305f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u578b\u74b0\u5883\u767a\u96fb\u7d20\u5b50\u306e\u958b\u767a","funder_award_id":"JPMJCR21Q1","funder_id":"https://openalex.org/F4320334789","funder_display_name":"Japan Science and Technology Agency"},{"id":"https://openalex.org/G7829875104","display_name":null,"funder_award_id":"JPMJCR24S1","funder_id":"https://openalex.org/F4320338075","funder_display_name":"Core Research for Evolutional Science and Technology"}],"funders":[{"id":"https://openalex.org/F4320317683","display_name":"AGC","ror":null},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"},{"id":"https://openalex.org/F4320334789","display_name":"Japan Science and Technology Agency","ror":"https://ror.org/00097mb19"},{"id":"https://openalex.org/F4320338075","display_name":"Core Research for Evolutional Science and Technology","ror":"https://ror.org/00097mb19"},{"id":"https://openalex.org/F4320338111","display_name":"Precursory Research for Embryonic Science and Technology","ror":null}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4410077258.pdf","grobid_xml":"https://content.openalex.org/works/W4410077258.grobid-xml"},"referenced_works_count":1,"referenced_works":["https://openalex.org/W2067174909"],"related_works":["https://openalex.org/W7161252638","https://openalex.org/W2013574517","https://openalex.org/W2082673353","https://openalex.org/W2329915244","https://openalex.org/W2153304188","https://openalex.org/W2325934212","https://openalex.org/W1994553437","https://openalex.org/W2907113304","https://openalex.org/W2788466751","https://openalex.org/W2087990372"],"abstract_inverted_index":{"Single-crystal":[0],"organic":[1],"semiconductors":[2],"(OSCs)":[3],"hold":[4],"immense":[5],"potential":[6],"for":[7,249,259],"high-performance":[8,261],"thin-film":[9,265],"transistors":[10],"(TFTs)":[11],"due":[12],"to":[13,188],"their":[14],"high":[15],"charge-carrier":[16],"mobilities":[17],"(\u00b5)":[18],"stemming":[19],"from":[20,159],"defect-free":[21],"and":[22,34,50,56,220,263],"long-range-order":[23],"structure.":[24],"While":[25],"\u00b5":[26],"is":[27,57,85,102,245],"a":[28],"key":[29],"factor":[30],"of":[31,41,71,103,122,154,178,198,232],"TFT":[32],"performance":[33],"can":[35,113],"be":[36,114],"tackled":[37],"by":[38,60,74,117],"molecular":[39],"design":[40,101],"OSCs,":[42],"threshold":[43],"voltage":[44,49],"(Vth)":[45],"significantly":[46],"impacts":[47],"operational":[48],"power":[51],"consumption":[52],"in":[53,110,129,252],"integrated":[54],"circuits":[55],"typically":[58],"controlled":[59],"device":[61],"engineering.":[62],"A":[63],"traditional":[64],"Vth":[65,97,109,207,224,250],"tuning":[66],"method":[67],"involves":[68],"interfacial":[69,269],"modifications":[70],"gate-dielectric":[72],"surface":[73],"self-assembled":[75],"monolayers":[76],"(SAMs)":[77],"with":[78,88,169,228,267],"different":[79],"dipolar":[80,120,196,230,243],"characters.":[81],"Yet,":[82],"the":[83,119,155,160,172,179,195,199,211,223,229,233,237],"SAM":[84],"less":[86],"compatible":[87],"printed":[89],"electronics":[90],"using":[91],"polymeric":[92],"gate":[93],"dielectrics.":[94],"Therefore,":[95],"controlling":[96],"through":[98],"OSC":[99],"material":[100],"interest.":[104],"This":[105,241],"work":[106],"demonstrates":[107],"that":[108],"sin-gle-crystal":[111],"OSCs":[112,262],"effectively":[115],"modulated":[116],"engineering":[118],"character":[121,197,231],"side-chain":[123,156],"substituents":[124],"which":[125],"are":[126],"widely":[127],"employed":[128],"solution-processable":[130],"OSCs.":[131],"To":[132],"validate":[133],"this":[134],"concept,":[135],"we":[136],"focused":[137],"on":[138,210],"3,4,9,10-benzo[de]isoquinolino[1,8-gh]quinolinetetracarboxylic":[139],"diimide":[140],"(BQQDI)":[141],"derivatives":[142],"because":[143],"they":[144],"have":[145],"formed":[146],"compara-ble":[147],"layered":[148],"brickwork":[149],"packing":[150,192],"structures":[151],"mostly":[152],"irrespective":[153],"structures.":[157],"Stemming":[158],"bench-marked,":[161],"phenethyl-substituted":[162],"BQQDI":[163],"(PhC2\u2212BQQDI),":[164],"here,":[165],"three":[166],"PhC2\u2212BQQDI":[167],"analogues":[168],"mono-fluorination":[170],"at":[171,236],"ortho,":[173],"meta":[174],"or":[175],"para":[176],"position":[177,214],"phenyl":[180],"ring":[181],"were":[182,186,215],"synthesized.":[183],"These":[184],"compounds":[185],"designed":[187],"maintain":[189],"isostruc-tural":[190],"crystal":[191,218],"while":[193],"varying":[194],"side":[200,234],"chains.":[201],"In":[202],"solution-processed":[203],"single-crystal":[204],"TFTs,":[205],"obvious":[206],"shifts":[208],"depending":[209],"fluorine":[212],"substitution":[213],"found.":[216],"By":[217],"structure":[219],"computational":[221],"analyses,":[222],"shift":[225],"was":[226],"correlated":[227],"chains":[235],"OSC\u2212gate":[238],"dielectric":[239],"interface.":[240],"side-chain-engineered":[242],"effect":[244],"not":[246],"only":[247],"useful":[248],"control":[251],"TFTs":[253],"but":[254],"also":[255],"proposes":[256],"new":[257],"avenues":[258],"de-signing":[260],"various":[264],"devices":[266],"tailored":[268],"properties.":[270]},"counts_by_year":[],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2025-05-05T00:00:00"}