{"id":"https://openalex.org/W4409898253","doi":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","title":"Versatile sulfidation of a metal-organic framework via heterolytic splitting of organo sulfides at distorted Zr-nodes","display_name":"Versatile sulfidation of a metal-organic framework via heterolytic splitting of organo sulfides at distorted Zr-nodes","publication_year":2025,"publication_date":"2025-04-28","ids":{"openalex":"https://openalex.org/W4409898253","doi":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv-2023-z007q-v3","doi":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/680c14b150018ac7c53637cb/original/versatile-sulfidation-of-a-metal-organic-framework-via-heterolytic-splitting-of-organo-sulfides-at-distorted-zr-nodes.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/680c14b150018ac7c53637cb/original/versatile-sulfidation-of-a-metal-organic-framework-via-heterolytic-splitting-of-organo-sulfides-at-distorted-zr-nodes.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101573475","display_name":"Qining Wang","orcid":"https://orcid.org/0000-0001-5199-7849","observed_orcids":["https://orcid.org/0000-0001-5199-7849"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Qining Wang","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089971271","display_name":"Simon M. Vornholt","orcid":"https://orcid.org/0000-0001-9490-3785","observed_orcids":["https://orcid.org/0000-0001-9490-3785"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Simon M. Vornholt","raw_affiliation_strings":["Stony Brook University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stony Brook University","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036205956","display_name":"Patrick Melix","orcid":"https://orcid.org/0000-0002-1027-1272","observed_orcids":["https://orcid.org/0000-0002-1027-1272"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]},{"id":"https://openalex.org/I926574661","display_name":"Leipzig University","ror":"https://ror.org/03s7gtk40","country_code":"DE","type":"education","lineage":["https://openalex.org/I926574661"]}],"countries":["DE","US"],"is_corresponding":false,"raw_author_name":"Patrick Melix","raw_affiliation_strings":["Leipzig University","Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Leipzig University","institution_ids":["https://openalex.org/I926574661"]},{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028024581","display_name":"Filip Formalik","orcid":"https://orcid.org/0000-0003-3981-3298","observed_orcids":["https://orcid.org/0000-0003-3981-3298"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Filip Formalik","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005468708","display_name":"Zhihengyu Chen","orcid":"https://orcid.org/0000-0001-5882-7076","observed_orcids":["https://orcid.org/0000-0001-5882-7076"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhihengyu Chen","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5093474251","display_name":"Luke M. Tufaro","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Luke M. Tufaro","raw_affiliation_strings":["Stony Brook University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stony Brook University","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025142988","display_name":"Jian Liu","orcid":"https://orcid.org/0000-0002-5024-1879","observed_orcids":["https://orcid.org/0000-0002-5024-1879"]},"institutions":[{"id":"https://openalex.org/I155173764","display_name":"Rochester Institute of Technology","ror":"https://ror.org/00v4yb702","country_code":"US","type":"education","lineage":["https://openalex.org/I155173764"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jian Liu","raw_affiliation_strings":["Rochester Institute of Technology"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Rochester Institute of Technology","institution_ids":["https://openalex.org/I155173764"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5041734257","display_name":"Boris V. Kramar","orcid":"https://orcid.org/0000-0001-8731-7542","observed_orcids":["https://orcid.org/0000-0001-8731-7542"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Boris V. Kramar","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048618786","display_name":"Zhiwei Wang","orcid":"https://orcid.org/0000-0002-2003-9231","observed_orcids":["https://orcid.org/0000-0002-2003-9231"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhiwei Wang","raw_affiliation_strings":["Northwestern University"],"raw_orcid":"https://orcid.org/0000-0002-2003-9231","affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014620636","display_name":"Lin X. Chen","orcid":"https://orcid.org/0000-0002-8450-6687","observed_orcids":["https://orcid.org/0000-0002-8450-6687"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]},{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lin X. Chen","raw_affiliation_strings":["Argonne National Laboratory","Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Argonne National Laboratory","institution_ids":["https://openalex.org/I1282105669"]},{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019016673","display_name":"Randall Q. Snurr","orcid":"https://orcid.org/0000-0003-2925-9246","observed_orcids":["https://orcid.org/0000-0003-2925-9246"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Randall Q. Snurr","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022805732","display_name":"Karena W. Chapman","orcid":"https://orcid.org/0000-0002-8725-5633","observed_orcids":["https://orcid.org/0000-0002-8725-5633"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Karena W. Chapman","raw_affiliation_strings":["Stony Brook University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Stony Brook University","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030553728","display_name":"Justin M. Notestein","orcid":"https://orcid.org/0000-0003-1780-7356","observed_orcids":["https://orcid.org/0000-0003-1780-7356"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Justin M. Notestein","raw_affiliation_strings":["Northwestern University"],"raw_orcid":"https://orcid.org/0000-0003-1780-7356","affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5074510664","display_name":"Joseph T. Hupp","orcid":"https://orcid.org/0000-0003-3982-9812","observed_orcids":["https://orcid.org/0000-0003-3982-9812"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joseph T. Hupp","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10353","display_name":"Zeolite Catalysis and Synthesis","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11351","display_name":"Catalysis and Hydrodesulfurization Studies","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/sulfurization","display_name":"sulfidation","score":0.8220000267028809},{"id":"https://openalex.org/keywords/metal-organic-frameworks","display_name":"metal-organic frameworks","score":0.9599999785423279},{"id":"https://openalex.org/keywords/nu-1000","display_name":"NU-1000","score":0.9900000095367432},{"id":"https://openalex.org/keywords/zr6-clusters","display_name":"Zr6 clusters","score":0.8259999752044678},{"id":"https://openalex.org/keywords/thermal-distortion","display_name":"thermal distortion","score":0.5879999995231628},{"id":"https://openalex.org/keywords/organosulfides","display_name":"organosulfides","score":0.652999997138977},{"id":"https://openalex.org/keywords/alkanethiols","display_name":"alkanethiols","score":0.8960000276565552},{"id":"https://openalex.org/keywords/hydrogen-sulfide","display_name":"hydrogen sulfide","score":0.7419999837875366},{"id":"https://openalex.org/keywords/zirconia","display_name":"zirconia","score":0.6899999976158142},{"id":"https://openalex.org/keywords/catalytic-site","display_name":"catalytic site","score":0.5960000157356262}],"concepts":[{"id":"https://openalex.org/C44578547","wikidata":"https://www.wikidata.org/wiki/Q907567","display_name":"Heterolysis","level":3,"score":0.9592099785804749},{"id":"https://openalex.org/C2778480967","wikidata":"https://www.wikidata.org/wiki/Q17083717","display_name":"Sulfidation","level":3,"score":0.9532508850097656},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5206160545349121},{"id":"https://openalex.org/C179366358","wikidata":"https://www.wikidata.org/wiki/Q909212","display_name":"Metal-organic framework","level":3,"score":0.5038866400718689},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.399713933467865},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3735155761241913},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.36118102073669434},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.24513989686965942},{"id":"https://openalex.org/C518881349","wikidata":"https://www.wikidata.org/wiki/Q682","display_name":"Sulfur","level":2,"score":0.15314191579818726},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.052673906087875366},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv-2023-z007q-v3","doi":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/680c14b150018ac7c53637cb/original/versatile-sulfidation-of-a-metal-organic-framework-via-heterolytic-splitting-of-organo-sulfides-at-distorted-zr-nodes.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2023-z007q-v3","doi":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2023-z007q-v3","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/680c14b150018ac7c53637cb/original/versatile-sulfidation-of-a-metal-organic-framework-via-heterolytic-splitting-of-organo-sulfides-at-distorted-zr-nodes.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2077991651","display_name":null,"funder_award_id":"NSF DMR-1121262","funder_id":"https://openalex.org/F4320334183","funder_display_name":"Materials Research Science and Engineering Center, Northwestern University"},{"id":"https://openalex.org/G303010891","display_name":null,"funder_award_id":"DE-FG02-03-ER15457","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5815712311","display_name":"NNCI: Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource","funder_award_id":"1542205","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G7139330677","display_name":null,"funder_award_id":"DE SC0023383","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G809240154","display_name":"CEMRI: Multifunctional Nanoscale Material Structures","funder_award_id":"1121262","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320306159","display_name":"W. M. Keck Foundation","ror":"https://ror.org/000dswa46"},{"id":"https://openalex.org/F4320308269","display_name":"Alexander von Humboldt-Stiftung","ror":"https://ror.org/012kf4317"},{"id":"https://openalex.org/F4320309475","display_name":"Northwestern University","ror":"https://ror.org/000e0be47"},{"id":"https://openalex.org/F4320317220","display_name":"National Energy Research Scientific Computing Center","ror":"https://ror.org/05v3mvq14"},{"id":"https://openalex.org/F4320328499","display_name":"Narodowa Agencja Wymiany Akademickiej","ror":"https://ror.org/02jf81j23"},{"id":"https://openalex.org/F4320332359","display_name":"Office of Science","ror":"https://ror.org/00mmn6b08"},{"id":"https://openalex.org/F4320334021","display_name":"International Institute for Nanotechnology, Northwestern University","ror":"https://ror.org/00rncr820"},{"id":"https://openalex.org/F4320334183","display_name":"Materials Research Science and Engineering Center, Northwestern University","ror":null},{"id":"https://openalex.org/F4320337345","display_name":"Office of Naval Research","ror":"https://ror.org/00rk2pe57"},{"id":"https://openalex.org/F4320337367","display_name":"Division of Materials Research","ror":"https://ror.org/01pc7k308"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4409898253.pdf","grobid_xml":"https://content.openalex.org/works/W4409898253.grobid-xml"},"referenced_works_count":47,"referenced_works":["https://openalex.org/W1930417496","https://openalex.org/W1963977085","https://openalex.org/W1966701921","https://openalex.org/W1967485833","https://openalex.org/W1973993234","https://openalex.org/W1987530225","https://openalex.org/W1988096759","https://openalex.org/W1996557854","https://openalex.org/W2009778234","https://openalex.org/W2033506740","https://openalex.org/W2039228925","https://openalex.org/W2056090465","https://openalex.org/W2059289509","https://openalex.org/W2069771769","https://openalex.org/W2070227796","https://openalex.org/W2088732846","https://openalex.org/W2092265729","https://openalex.org/W2094608275","https://openalex.org/W2168597295","https://openalex.org/W2274719868","https://openalex.org/W2302255876","https://openalex.org/W2506894030","https://openalex.org/W2594109941","https://openalex.org/W2800276454","https://openalex.org/W2883953810","https://openalex.org/W2889789069","https://openalex.org/W2933117144","https://openalex.org/W2973153050","https://openalex.org/W2989095227","https://openalex.org/W2996850687","https://openalex.org/W3034995587","https://openalex.org/W3080647540","https://openalex.org/W3082215798","https://openalex.org/W3082553951","https://openalex.org/W3092831439","https://openalex.org/W3107960248","https://openalex.org/W3108817208","https://openalex.org/W3129018228","https://openalex.org/W3156201081","https://openalex.org/W3176461145","https://openalex.org/W3201005404","https://openalex.org/W3207849752","https://openalex.org/W4283770514","https://openalex.org/W4284959632","https://openalex.org/W4312012207","https://openalex.org/W4389609416","https://openalex.org/W4399673979"],"related_works":["https://openalex.org/W4295682544","https://openalex.org/W2889261514","https://openalex.org/W4313320513","https://openalex.org/W3016516995","https://openalex.org/W2552722662","https://openalex.org/W3107960248","https://openalex.org/W3108866045","https://openalex.org/W2970051412","https://openalex.org/W4412494046","https://openalex.org/W2056919219"],"abstract_inverted_index":{"The":[0,63],"sulfidation":[1,30,64,133],"of":[2,10,31,57,78,134],"metal":[3,136],"oxides":[4,24,137],"is":[5],"critical":[6],"to":[7,112,148],"the":[8,32,58,76,89,127,132],"creation":[9],"catalyst":[11],"active":[12],"sites":[13,81],"for":[14,22,131,144],"industrially-relevant":[15],"reactions,":[16],"but":[17],"occurs":[18],"at":[19,51],"high":[20],"temperatures":[21],"refractory":[23],"like":[25],"zirconia.":[26],"Here,":[27],"we":[28],"investigate":[29],"structurally-well-defined,":[33],"Zr-based":[34],"metal-organic":[35],"framework":[36],"(MOF)":[37],"NU-1000":[38],"as":[39],"a":[40,83,119,141],"model":[41],"system.":[42],"Sulfidation":[43],"with":[44,108],"H2S":[45],"and":[46,82,100,118,138],"alkane":[47],"thiols":[48,106],"occurred":[49,65],"readily":[50],"room":[52],"temperature":[53],"after":[54],"thermal":[55,90],"distortion":[56],"Zr6":[59,110],"clusters":[60],"in":[61,75],"NU-1000.":[62],"via":[66],"heterolytic":[67],"S-H":[68],"bond":[69],"cleavage":[70],"over":[71],"frustrated":[72],"Lewis-acid/Lewis-base":[73],"pairs":[74],"form":[77,113],"under-coordinated":[79],"Zr(IV)":[80],"terminal":[84,120],"O(-II)":[85],"site":[86],"formed":[87],"during":[88],"distortion.":[91],"In":[92],"situ":[93],"synchrotron":[94],"based":[95],"structural":[96],"analysis,":[97],"spectroscopic":[98],"characterization,":[99],"computational":[101],"studies":[102],"provide":[103],"evidence":[104],"that":[105],"react":[107],"distorted":[109],"nodes":[111],"stable":[114],"bridging":[115],"Zr-S-Zr":[116],"bonds":[117],"hydroxo.":[121],"This":[122],"study":[123],"provides":[124],"insight":[125],"into":[126],"surface":[128],"structures":[129],"responsible":[130],"high-valent":[135],"also":[139],"suggests":[140],"promising":[142],"strategy":[143],"introducing":[145],"S-bearing":[146],"moieties":[147],"otherwise":[149],"sulfur-resistant":[150],"MOF":[151],"nodes.":[152]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2025-04-29T00:00:00"}
