{"id":"https://openalex.org/W4406283452","doi":"https://doi.org/10.1002/chem.202404555","title":"Light\u2010Dependent Amide or Thioamide Formation of Acylsilanes with Amines using Elemental Sulfur","display_name":"Light\u2010Dependent Amide or Thioamide Formation of Acylsilanes with Amines using Elemental Sulfur","publication_year":2025,"publication_date":"2025-01-11","ids":{"openalex":"https://openalex.org/W4406283452","doi":"https://doi.org/10.1002/chem.202404555","pmid":"https://pubmed.ncbi.nlm.nih.gov/39797904"},"language":"en","primary_location":{"id":"doi:10.1002/chem.202404555","doi":"https://doi.org/10.1002/chem.202404555","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.202404555","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5080764611","display_name":"Yuanhang Li","orcid":"https://orcid.org/0000-0001-5819-3456","observed_orcids":["https://orcid.org/0000-0001-5819-3456"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuanhang Li","raw_affiliation_strings":["School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005877184","display_name":"Haiting Ye","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Haiting Ye","raw_affiliation_strings":["School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000808868","display_name":"Shaohong Wang","orcid":"https://orcid.org/0000-0001-5421-2971","observed_orcids":["https://orcid.org/0000-0001-5421-2971"]},"institutions":[{"id":"https://openalex.org/I4210126203","display_name":"Hubei University of Automotive Technology","ror":"https://ror.org/039m95m06","country_code":"CN","type":"education","lineage":["https://openalex.org/I4210126203"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shaohong Wang","raw_affiliation_strings":["School of Mathematics, Physics and Optoelectronic Engineering Hubei University of Automotive Technology  Shiyan 442002 P.\u2005R. China","Hubei University of Automotive Technology, School of Mathematics, Physics and Optoelectronic Engineering, 442002 Shiyan, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Mathematics, Physics and Optoelectronic Engineering Hubei University of Automotive Technology  Shiyan 442002 P.\u2005R. China","institution_ids":["https://openalex.org/I4210126203"]},{"raw_affiliation_string":"Hubei University of Automotive Technology, School of Mathematics, Physics and Optoelectronic Engineering, 442002 Shiyan, CHINA","institution_ids":["https://openalex.org/I4210126203"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035150048","display_name":"Silong Xu","orcid":"https://orcid.org/0000-0003-3279-9331","observed_orcids":["https://orcid.org/0000-0003-3279-9331"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Silong Xu","raw_affiliation_strings":["School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5012538333","display_name":"Martin James Lear","orcid":"https://orcid.org/0000-0003-2556-2029","observed_orcids":["https://orcid.org/0000-0003-2556-2029"]},"institutions":[{"id":"https://openalex.org/I51532219","display_name":"University of Lincoln","ror":"https://ror.org/03yeq9x20","country_code":"GB","type":"education","lineage":["https://openalex.org/I51532219"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Martin J. Lear","raw_affiliation_strings":["Department of Chemistry, School of Natural Sciences University of Lincoln Brayford Pool  Lincoln LN6 7TS United Kingdom","University of Lincoln, School of chemistry, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, School of Natural Sciences University of Lincoln Brayford Pool  Lincoln LN6 7TS United Kingdom","institution_ids":["https://openalex.org/I51532219"]},{"raw_affiliation_string":"University of Lincoln, School of chemistry, CHINA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042178740","display_name":"Kendall N. Houk","orcid":"https://orcid.org/0000-0002-8387-5261","observed_orcids":["https://orcid.org/0000-0002-8387-5261"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kendall N. Houk","raw_affiliation_strings":["School of Chemistry Department of Chemistry and Biochemistry University of California, Los Angeles  California 90095-1569 USA","University of California Los Angeles, School of chemistry, 90095-1569 California, UNITED STATES OF AMERICA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry Department of Chemistry and Biochemistry University of California, Los Angeles  California 90095-1569 USA","institution_ids":["https://openalex.org/I161318765"]},{"raw_affiliation_string":"University of California Los Angeles, School of chemistry, 90095-1569 California, UNITED STATES OF AMERICA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028087447","display_name":"Pengchen Ma","orcid":"https://orcid.org/0000-0002-4110-4696","observed_orcids":["https://orcid.org/0000-0002-4110-4696"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Pengchen Ma","raw_affiliation_strings":["School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"Xi'an Jiaotong University, School of chemistry, No.28, Xianning West Road, 710049 Xi'an, CHINA","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"last","author":{"id":null,"display_name":"Jing Li","orcid":"https://orcid.org/0000-0002-8401-253X","observed_orcids":["https://orcid.org/0000-0002-8401-253X"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jing Li","raw_affiliation_strings":["School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","Xi'an Jiaotong University, School of Chemistry, No.28, West Xianning Road, 710049 Xi'an, CHINA"],"raw_orcid":"https://orcid.org/0000-0002-8401-253X","affiliations":[{"raw_affiliation_string":"School of Chemistry Xi'an Jiaotong University  Xi'an 710049 P.\u2005R. China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"Xi'an Jiaotong University, School of Chemistry, No.28, West Xianning Road, 710049 Xi'an, CHINA","institution_ids":["https://openalex.org/I87445476"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5028087447"],"corresponding_institution_ids":["https://openalex.org/I87445476"],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":0.836,"has_fulltext":false,"cited_by_count":3,"citation_normalized_percentile":{"value":0.60610582,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":95,"max":97},"biblio":{"volume":"31","issue":"12","first_page":"e202404555","last_page":"e202404555"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13304","display_name":"Synthesis and Reactivity of Sulfur-Containing Compounds","score":0.2969000041484833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13304","display_name":"Synthesis and Reactivity of Sulfur-Containing Compounds","score":0.2969000041484833,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10911","display_name":"Chemical Synthesis and Analysis","score":0.2667999863624573,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.2046000063419342,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/acylsilanes","display_name":"acylsilanes","score":0.8939999938011169},{"id":"https://openalex.org/keywords/amide-synthesis","display_name":"amide synthesis","score":0.7760000228881836},{"id":"https://openalex.org/keywords/elemental-sulfur","display_name":"elemental sulfur","score":0.8159999847412109},{"id":"https://openalex.org/keywords/umpolung","display_name":"umpolung","score":0.7419999837875366},{"id":"https://openalex.org/keywords/amine-coupling","display_name":"amine coupling","score":0.5820000171661377},{"id":"https://openalex.org/keywords/postsynthetic-modification","display_name":"post-synthetic modification","score":0.8119999766349792},{"id":"https://openalex.org/keywords/drug-modification","display_name":"drug modification","score":0.5080000162124634},{"id":"https://openalex.org/keywords/peptide-modification","display_name":"peptide modification","score":0.6859999895095825},{"id":"https://openalex.org/keywords/natural-product-modification","display_name":"natural product modification","score":0.640999972820282}],"concepts":[{"id":"https://openalex.org/C2778183973","wikidata":"https://www.wikidata.org/wiki/Q2476769","display_name":"Silanes","level":3,"score":0.8754695057868958},{"id":"https://openalex.org/C5304478","wikidata":"https://www.wikidata.org/wiki/Q502457","display_name":"Silylation","level":3,"score":0.8559432625770569},{"id":"https://openalex.org/C2777332933","wikidata":"https://www.wikidata.org/wiki/Q170409","display_name":"Functional group","level":3,"score":0.7033063173294067},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7021783590316772},{"id":"https://openalex.org/C2778439535","wikidata":"https://www.wikidata.org/wiki/Q188777","display_name":"Amide","level":2,"score":0.6670534014701843},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.6458666920661926},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.6294630169868469},{"id":"https://openalex.org/C2777650178","wikidata":"https://www.wikidata.org/wiki/Q419481","display_name":"Thioamide","level":2,"score":0.5724153518676758},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.49709656834602356},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4376160204410553},{"id":"https://openalex.org/C76164948","wikidata":"https://www.wikidata.org/wiki/Q904718","display_name":"Umpolung","level":4,"score":0.41902074217796326},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2169400453567505},{"id":"https://openalex.org/C2778024649","wikidata":"https://www.wikidata.org/wiki/Q410572","display_name":"Silane","level":2,"score":0.08561164140701294},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/chem.202404555","doi":"https://doi.org/10.1002/chem.202404555","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.202404555","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},{"id":"pmid:39797904","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/39797904","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry (Weinheim an der Bergstrasse, Germany)","raw_type":"Journal Article"},{"id":"pmh:oai:figshare.com:article/28171547","doi":null,"is_oa":false,"landing_page_url":"https://figshare.com/articles/journal_contribution/Light-Dependent_Amide_or_Thioamide_Formation_of_Acylsilanes_with_Amines_using_Elemental_Sulfur/28171547","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2666085608","display_name":null,"funder_award_id":"GYKP024","funder_id":"https://openalex.org/F4320336656","funder_display_name":"Thousand Young Talents Program of China"},{"id":"https://openalex.org/G5351077397","display_name":null,"funder_award_id":"2021QCYRC4-41","funder_id":"https://openalex.org/F4320322666","funder_display_name":"Natural Science Foundation of Shanxi Province"},{"id":"https://openalex.org/G6889850522","display_name":null,"funder_award_id":"22471206","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G785696877","display_name":null,"funder_award_id":"22101223","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320322666","display_name":"Natural Science Foundation of Shanxi Province","ror":null},{"id":"https://openalex.org/F4320336656","display_name":"Thousand Young Talents Program of China","ror":null}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":46,"referenced_works":["https://openalex.org/W1549362810","https://openalex.org/W1975947882","https://openalex.org/W1990415043","https://openalex.org/W2001379731","https://openalex.org/W2026669180","https://openalex.org/W2031734182","https://openalex.org/W2033660432","https://openalex.org/W2041513075","https://openalex.org/W2054117177","https://openalex.org/W2078731146","https://openalex.org/W2106246551","https://openalex.org/W2139411610","https://openalex.org/W2141617805","https://openalex.org/W2313091617","https://openalex.org/W2317490008","https://openalex.org/W2344331085","https://openalex.org/W2561403503","https://openalex.org/W2604210161","https://openalex.org/W2767246150","https://openalex.org/W2784541983","https://openalex.org/W2801416352","https://openalex.org/W2950702187","https://openalex.org/W2963807856","https://openalex.org/W2976193227","https://openalex.org/W3017318101","https://openalex.org/W3042595256","https://openalex.org/W3044388665","https://openalex.org/W3096199608","https://openalex.org/W3127297964","https://openalex.org/W3167288305","https://openalex.org/W3211267820","https://openalex.org/W3211593650","https://openalex.org/W4210784162","https://openalex.org/W4213262935","https://openalex.org/W4280561831","https://openalex.org/W4385379238","https://openalex.org/W4385493700","https://openalex.org/W4387003900","https://openalex.org/W4388730991","https://openalex.org/W4389685483","https://openalex.org/W4391177757","https://openalex.org/W4392245312","https://openalex.org/W4400237195","https://openalex.org/W4400432996","https://openalex.org/W4402477086","https://openalex.org/W6602434089"],"related_works":["https://openalex.org/W4212834413","https://openalex.org/W4385379238","https://openalex.org/W4205542265","https://openalex.org/W4392245312","https://openalex.org/W4416721684","https://openalex.org/W4400415943","https://openalex.org/W2029214747","https://openalex.org/W2037037697","https://openalex.org/W1992076512","https://openalex.org/W2979142215"],"abstract_inverted_index":{"Abstract":[0],"Due":[1],"to":[2,20,41,101,135,143,167,171,179],"the":[3,48,55,65,125,160,181],"diverse":[4,29],"chemical":[5,66],"and":[6,13,24,57,86,114,121,147],"physical":[7],"properties":[8],"of":[9,31,60,68,93,108,128,130,183],"functional":[10,25],"groups,":[11],"mild":[12],"controllable":[14],"ligation":[15,44,67],"methods":[16,45],"are":[17,177],"often":[18],"required":[19],"construct":[21],"complex":[22],"drugs":[23],"materials.":[26,51],"To":[27],"make":[28],"sets":[30],"products":[32],"with":[33,70,116,141,156,162,169],"tunable":[34],"physicochemical":[35],"properties,":[36],"it":[37],"is":[38,82,96],"also":[39],"useful":[40],"employ":[42],"complimentary":[43],"that":[46,139],"adopt":[47],"same":[49],"starting":[50],"Here,":[52],"we":[53],"disclose":[54],"efficient":[56],"modular":[58],"synthesis":[59],"amides":[61],"or":[62,78],"thioamides":[63],"through":[64],"acylsilanes":[69,152],"amines,":[71],"simply":[72],"by":[73,98],"turning":[74],"a":[75,106],"light":[76],"on":[77,105],"off.":[79],"This":[80],"method":[81],"fast,":[83],"mild,":[84],"high\u2010yielding":[85],"displays":[87],"excellent":[88],"functional\u2010group":[89],"tolerance.":[90],"The":[91],"versatility":[92],"these":[94],"reactions":[95],"highlighted":[97],"their":[99],"ability":[100],"perform":[102],"post\u2010synthetic":[103],"modifications":[104],"variety":[107],"marketed":[109],"medications,":[110],"peptides,":[111],"natural":[112],"substances,":[113],"compounds":[115],"biological":[117],"activity.":[118],"In\u2010depth":[119],"computational":[120],"experimental":[122],"studies":[123],"clarified":[124],"photo\u2010dependent":[126],"umpolung":[127],"reactivity":[129],"acylsilanes,":[131],"namely:":[132],"photoexcitation":[133],"leads":[134],"nucleophilic":[136],"O\u2010silyl":[137,145],"carbenes":[138],"react":[140,153],"S8":[142,170],"form":[144,172],"thionoesters":[146],"eventually":[148],"amides.":[149],"In":[150],"contrast,":[151],"as":[154],"electrophiles":[155],"amines":[157],"thermally":[158],"in":[159],"dark,":[161],"C\u2192O":[163],"silyl":[164],"transfer,":[165],"prior":[166],"reacting":[168],"thioamides.":[173],"These":[174],"mechanistic":[175],"details":[176],"expected":[178],"guide":[180],"development":[182],"similar":[184],"coupling":[185],"reactions.":[186]},"counts_by_year":[{"year":2025,"cited_by_count":3}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2025-01-12T00:00:00"}
