{"id":"https://openalex.org/W4403983751","doi":"https://doi.org/10.1080/00958972.2024.2423034","title":"Benzo[1,2-b:4,5-b\u2019]dithiophene diethynyl bridged bimetallic ruthenium complexes: syntheses and characterization, (spectro)electrochemistry combined with theoretical calculations","display_name":"Benzo[1,2-b:4,5-b\u2019]dithiophene diethynyl bridged bimetallic ruthenium complexes: syntheses and characterization, (spectro)electrochemistry combined with theoretical calculations","publication_year":2024,"publication_date":"2024-11-01","ids":{"openalex":"https://openalex.org/W4403983751","doi":"https://doi.org/10.1080/00958972.2024.2423034"},"language":"en","primary_location":{"id":"doi:10.1080/00958972.2024.2423034","doi":"https://doi.org/10.1080/00958972.2024.2423034","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00958972.2024.2423034","pdf_url":null,"source":{"id":"https://openalex.org/S161439912","display_name":"Journal of Coordination Chemistry","issn_l":"0095-8972","issn":["0095-8972","1026-7441","1029-0389"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Coordination Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5078367110","display_name":"Yonglin Xia","orcid":"https://orcid.org/0009-0007-6504-2577","observed_orcids":["https://orcid.org/0009-0007-6504-2577"]},"institutions":[{"id":"https://openalex.org/I149735164","display_name":"Hengyang Normal University","ror":"https://ror.org/006bvjm48","country_code":"CN","type":"education","lineage":["https://openalex.org/I149735164"]},{"id":"https://openalex.org/I4405279429","display_name":"Hengyang Normal University Nanyue College","ror":"https://ror.org/01f4tsm71","country_code":"CN","type":"education","lineage":["https://openalex.org/I4405279429"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yonglin Xia","raw_affiliation_strings":["Department of Chemistry and Material Science, Hengyang Normal University Nanyue College, Hengyang, Hunan, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Material Science, Hengyang Normal University Nanyue College, Hengyang, Hunan, P.R. China","institution_ids":["https://openalex.org/I149735164","https://openalex.org/I4405279429"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Zhengji Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149735164","display_name":"Hengyang Normal University","ror":"https://ror.org/006bvjm48","country_code":"CN","type":"education","lineage":["https://openalex.org/I149735164"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhengji Liu","raw_affiliation_strings":["Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China","institution_ids":["https://openalex.org/I149735164"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Chengshuo Gao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149735164","display_name":"Hengyang Normal University","ror":"https://ror.org/006bvjm48","country_code":"CN","type":"education","lineage":["https://openalex.org/I149735164"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chengshuo Gao","raw_affiliation_strings":["Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China","institution_ids":["https://openalex.org/I149735164"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100729387","display_name":"Qian Zhang","orcid":"https://orcid.org/0000-0001-8606-2808","observed_orcids":["https://orcid.org/0000-0001-8606-2808"]},"institutions":[{"id":"https://openalex.org/I149735164","display_name":"Hengyang Normal University","ror":"https://ror.org/006bvjm48","country_code":"CN","type":"education","lineage":["https://openalex.org/I149735164"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qian Zhang","raw_affiliation_strings":["Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China","institution_ids":["https://openalex.org/I149735164"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5090046474","display_name":"Ya\u2010Ping Ou","orcid":"https://orcid.org/0000-0001-9285-1643","observed_orcids":["https://orcid.org/0000-0001-9285-1643"]},"institutions":[{"id":"https://openalex.org/I149735164","display_name":"Hengyang Normal University","ror":"https://ror.org/006bvjm48","country_code":"CN","type":"education","lineage":["https://openalex.org/I149735164"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Ya-Ping Ou","raw_affiliation_strings":["Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional\u00a0Organometallic Materials of Hunan Province College, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan, P.R. China","institution_ids":["https://openalex.org/I149735164"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5090046474","https://openalex.org/A5100729387"],"corresponding_institution_ids":["https://openalex.org/I149735164"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"77","issue":"20-21","first_page":"2363","last_page":"2375"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.15049999952316284,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.15049999952316284,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.13089999556541443,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.11840000003576279,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/benzo-1-2-b-4-5-b-dithiophene","display_name":"benzo[1,2-b:4,5-b']dithiophene","score":0.9480000138282776},{"id":"https://openalex.org/keywords/ruthenium-complexes","display_name":"ruthenium complexes","score":0.7319999933242798},{"id":"https://openalex.org/keywords/triruthenium-complexes","display_name":"triruthenium complexes","score":0.9369999766349792},{"id":"https://openalex.org/keywords/bimetallic-complexes","display_name":"bimetallic complexes","score":0.7310000061988831},{"id":"https://openalex.org/keywords/redox-properties","display_name":"redox properties","score":0.5809999704360962},{"id":"https://openalex.org/keywords/one-electron-oxidation","display_name":"one-electron oxidation","score":0.6549999713897705},{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.8769999742507935},{"id":"https://openalex.org/keywords/charge-delocalization","display_name":"charge delocalization","score":0.7710000276565552},{"id":"https://openalex.org/keywords/ir-spectroelectrochemistry","display_name":"IR spectroelectrochemistry","score":0.7279999852180481},{"id":"https://openalex.org/keywords/td-dft-calculations","display_name":"TD-DFT calculations","score":0.5860000252723694},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.5239999890327454}],"concepts":[{"id":"https://openalex.org/C43411465","wikidata":"https://www.wikidata.org/wiki/Q2997621","display_name":"Bimetallic strip","level":3,"score":0.9502854347229004},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9330873489379883},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.7631337642669678},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.6866448521614075},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.6281546354293823},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.38290688395500183},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.2491230070590973},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2431907057762146},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.16884008049964905},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.11596119403839111},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.058034747838974},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.02738937735557556}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/00958972.2024.2423034","doi":"https://doi.org/10.1080/00958972.2024.2423034","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00958972.2024.2423034","pdf_url":null,"source":{"id":"https://openalex.org/S161439912","display_name":"Journal of Coordination Chemistry","issn_l":"0095-8972","issn":["0095-8972","1026-7441","1029-0389"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Coordination Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1368973419","display_name":null,"funder_award_id":"2017JJ3004","funder_id":"https://openalex.org/F4320322866","funder_display_name":"Natural Science Foundation of Hainan Province"},{"id":"https://openalex.org/G4404022294","display_name":null,"funder_award_id":"21602049","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7336962521","display_name":null,"funder_award_id":"2021JJ30058","funder_id":"https://openalex.org/F4320322866","funder_display_name":"Natural Science Foundation of Hainan Province"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320322866","display_name":"Natural Science Foundation of Hainan Province","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W213791877","https://openalex.org/W1966220862","https://openalex.org/W1975002766","https://openalex.org/W1986176923","https://openalex.org/W1988786940","https://openalex.org/W2011352044","https://openalex.org/W2016661813","https://openalex.org/W2023128337","https://openalex.org/W2023971512","https://openalex.org/W2039559098","https://openalex.org/W2063151161","https://openalex.org/W2076339719","https://openalex.org/W2088481620","https://openalex.org/W2096282320","https://openalex.org/W2107897709","https://openalex.org/W2165289729","https://openalex.org/W2166624456","https://openalex.org/W2169474890","https://openalex.org/W2197662972","https://openalex.org/W2202098509","https://openalex.org/W2230361973","https://openalex.org/W2276507077","https://openalex.org/W2321889473","https://openalex.org/W2325239528","https://openalex.org/W2510718413","https://openalex.org/W2753069591","https://openalex.org/W2766487524","https://openalex.org/W2795498572","https://openalex.org/W2805113451","https://openalex.org/W2898344833","https://openalex.org/W2922156260","https://openalex.org/W2957136527","https://openalex.org/W3012731129","https://openalex.org/W3093342421","https://openalex.org/W4211094321","https://openalex.org/W4293764479","https://openalex.org/W4381199315","https://openalex.org/W4397034486"],"related_works":["https://openalex.org/W2615862076","https://openalex.org/W2729750568","https://openalex.org/W4293764479","https://openalex.org/W7162458577","https://openalex.org/W2514308302","https://openalex.org/W1933698922","https://openalex.org/W2753069591","https://openalex.org/W2009757381","https://openalex.org/W1989472047","https://openalex.org/W2276507077"],"abstract_inverted_index":{"We":[0],"have":[1],"constructed":[2],"isomeric":[3],"triruthenium":[4],"ethynyl":[5],"complexes":[6,76],"1":[7,17,33,92,115],"and":[8,18,24,34,65,93,101,148],"2":[9,19,35,94,106],"linked":[10],"by":[11,22,150],"benzo[1,2-b:4,5-b\u2019]dithiophene.":[12],"The":[13,88,118,155,168],"electronic":[14],"properties":[15],"of":[16,54,62,69,91,105,114,122,134,171,199],"were":[20],"compared":[21],"(spectro)electrochemical":[23],"theoretical":[25],"calculations.":[26,154],"DFT":[27],"(density":[28],"functional":[29],"theory)":[30],"fully-optimized":[31],"structures":[32],"showed":[36,188,194],"that":[37,74,113,133,158],"the":[38,51,59,66,75,102,159,165,185],"ruthenium":[39],"terminal":[40],"groups":[41],"both":[42],"exhibit":[43],"a":[44,78,128,177],"similar":[45],"pseudo-octahedral":[46],"configuration":[47],"as":[48],"reported":[49],"for":[50],"crystal":[52],"structure":[53],"1.":[55],"With":[56],"step-by-step":[57],"oxidation,":[58],"bond":[60,67],"length":[61,68],"Ru-C":[63],"decreases":[64],"C\u2261C":[70],"increases,":[71],"which":[72,136],"indicated":[73],"undergo":[77],"transition":[79],"from":[80,124,173],"Ru-C\u2261C":[81],"to":[82,132,140,143],"Ru":[83],"=":[84,86],"C":[85],"C.":[87],"electrochemical":[89],"results":[90,156,193],"featured":[95],"two":[96],"consecutive":[97],"single-electron":[98],"redox":[99,166],"processes,":[100],"\u0394E":[103],"value":[104],"(329":[107],"mV)":[108],"was":[109],"significantly":[110],"higher":[111],"than":[112],"(140":[116],"mV).":[117],"near-IR":[119],"broad":[120],"absorptions":[121,147],"2+":[123,172],"UV-Vis-NIR":[125],"spectroelectrochemistry":[126,175],"exhibited":[127,176],"blue":[129],"shift":[130],"relative":[131],"1+,":[135],"could":[137],"be":[138],"attributed":[139],"MLCT":[141],"(metal":[142],"ligand":[144],"charge":[145,196],"transfer)":[146],"confirmed":[149],"TDDFT":[151],"(time":[152],"dependent)":[153],"suggested":[157],"bridge":[160],"ligands":[161],"are":[162],"involved":[163],"in":[164],"process.":[167],"\u03bd(C\u2261C)":[169],"stretch":[170],"IR":[174],"strong":[178],"single":[179],"peak":[180],"at":[181],"1969":[182],"cm-1,":[183],"while":[184],"isomer":[186],"1+":[187],"three":[189],"asymmetric":[190],"peaks.":[191],"These":[192],"excellent":[195],"delocalization":[197],"ability":[198],"2.":[200]},"counts_by_year":[],"updated_date":"2026-09-27T08:07:27.782135","created_date":"2024-11-02T00:00:00"}
