{"id":"https://openalex.org/W4403887828","doi":"https://doi.org/10.1021/acs.inorgchem.4c03185","title":"In Situ FT-IR Spectroelectrochemistry Reveals Mechanistic Insights into Nitric Oxide Release from Ruthenium(II) Nitrosyl Complexes","display_name":"In Situ FT-IR Spectroelectrochemistry Reveals Mechanistic Insights into Nitric Oxide Release from Ruthenium(II) Nitrosyl Complexes","publication_year":2024,"publication_date":"2024-10-30","ids":{"openalex":"https://openalex.org/W4403887828","doi":"https://doi.org/10.1021/acs.inorgchem.4c03185","pmid":"https://pubmed.ncbi.nlm.nih.gov/39475160","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/11558665"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.4c03185","doi":"https://doi.org/10.1021/acs.inorgchem.4c03185","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.4c03185","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c03185?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c03185?ref=article_openPDF","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5008192679","display_name":"Felipe de Santis Gon\u00e7alves","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Felipe de Santis Gon\u00e7alves","raw_affiliation_strings":["S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057292572","display_name":"Lucyano J. A. Macedo","orcid":"https://orcid.org/0000-0002-7949-5397","observed_orcids":["https://orcid.org/0000-0002-7949-5397"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4210106422","display_name":"Brazilian Synchrotron Light Laboratory","ror":"https://ror.org/01p6gzq21","country_code":"BR","type":"facility","lineage":["https://openalex.org/I4210106422","https://openalex.org/I4210151455","https://openalex.org/I4210152696"]},{"id":"https://openalex.org/I4210152696","display_name":"Brazilian Center for Research in Energy and Materials","ror":"https://ror.org/05m235j20","country_code":"BR","type":"other","lineage":["https://openalex.org/I4210151455","https://openalex.org/I4210152696"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Lucyano J. A. Macedo","raw_affiliation_strings":["Brazilian Synchrotron Light Laboratory, Brazilian Center for Research in Energy and Materials","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","Brazilian Synchrotron Light Laboratory, Brazilian Center for Research in Energy and Materials, Campinas 13084-971, SP, Brazil"],"raw_orcid":"https://orcid.org/0000-0002-7949-5397","affiliations":[{"raw_affiliation_string":"Brazilian Synchrotron Light Laboratory, Brazilian Center for Research in Energy and Materials","institution_ids":["https://openalex.org/I4210106422","https://openalex.org/I4210152696"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"Brazilian Synchrotron Light Laboratory, Brazilian Center for Research in Energy and Materials, Campinas 13084-971, SP, Brazil","institution_ids":["https://openalex.org/I4210106422","https://openalex.org/I4210152696"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037892747","display_name":"Maykon Lima Souza","orcid":"https://orcid.org/0000-0003-0452-6774","observed_orcids":["https://orcid.org/0000-0003-0452-6774"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Maykon L. Souza","raw_affiliation_strings":["S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011061327","display_name":"Nicolai Lehnert","orcid":"https://orcid.org/0000-0002-5221-5498","observed_orcids":["https://orcid.org/0000-0002-5221-5498"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nicolai Lehnert","raw_affiliation_strings":["Department of Chemistry","University of Michigan","Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States"],"raw_orcid":"https://orcid.org/0000-0002-5221-5498","affiliations":[{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"University of Michigan","institution_ids":["https://openalex.org/I27837315"]},{"raw_affiliation_string":"Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069952828","display_name":"Frank N. Crespilho","orcid":"https://orcid.org/0000-0003-4830-652X","observed_orcids":["https://orcid.org/0000-0003-4830-652X"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Frank N. Crespilho","raw_affiliation_strings":["S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006249150","display_name":"Antonio C. Roveda","orcid":"https://orcid.org/0000-0001-9409-8093","observed_orcids":["https://orcid.org/0000-0001-9409-8093"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"Antonio C. Roveda Jr","raw_affiliation_strings":["S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil"],"raw_orcid":"https://orcid.org/0000-0001-9409-8093","affiliations":[{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010832137","display_name":"Daniel R. Cardoso","orcid":"https://orcid.org/0000-0002-3492-3327","observed_orcids":["https://orcid.org/0000-0002-3492-3327"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I4405263178","display_name":"Instituto de Qu\u00edmica de S\u00e3o Carlos","ror":"https://ror.org/03kh8rv18","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"Daniel R. Cardoso","raw_affiliation_strings":["S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil"],"raw_orcid":"https://orcid.org/0000-0002-3492-3327","affiliations":[{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]},{"raw_affiliation_string":"S\u00e3o Carlos Institute of Chemistry, University of S\u00e3o Paulo, S\u00e3o Carlos 13560-970, SP,Brazil","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5006249150","https://openalex.org/A5010832137"],"corresponding_institution_ids":["https://openalex.org/I17974374","https://openalex.org/I4405263178"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":{"value":4500,"currency":"USD","value_usd":4500},"fwci":0.9697,"has_fulltext":true,"cited_by_count":6,"citation_normalized_percentile":{"value":0.75624772,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"63","issue":"45","first_page":"21387","last_page":"21396"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.5708000063896179,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.5708000063896179,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.28439998626708984,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.03350000083446503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-ii-nitrosyl-complexes","display_name":"ruthenium(II) nitrosyl complexes","score":0.9660000205039978},{"id":"https://openalex.org/keywords/nitric-oxide-release","display_name":"nitric oxide release","score":0.9139999747276306},{"id":"https://openalex.org/keywords/nitric-oxide-donors","display_name":"nitric oxide donors","score":0.8560000061988831},{"id":"https://openalex.org/keywords/one-electron-reduction","display_name":"one-electron reduction","score":0.875},{"id":"https://openalex.org/keywords/outer-sphere-electron-transfer","display_name":"outer-sphere electron transfer","score":0.8840000033378601},{"id":"https://openalex.org/keywords/cis-trans-isomers","display_name":"cis-trans isomers","score":0.796999990940094},{"id":"https://openalex.org/keywords/hydroxide-ligand","display_name":"hydroxide ligand","score":0.5550000071525574},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.47200000286102295}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9776750802993774},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.8839514851570129},{"id":"https://openalex.org/C2777822432","wikidata":"https://www.wikidata.org/wiki/Q216681","display_name":"In situ","level":2,"score":0.7745419144630432},{"id":"https://openalex.org/C519581460","wikidata":"https://www.wikidata.org/wiki/Q207843","display_name":"Nitric oxide","level":2,"score":0.7013634443283081},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.39723169803619385},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3406528830528259},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.33137011528015137},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2100699245929718},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1878875195980072}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acs.inorgchem.4c03185","doi":"https://doi.org/10.1021/acs.inorgchem.4c03185","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.4c03185","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c03185?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:pubmedcentral.nih.gov:11558665","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/11558665","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC11558665/pdf/ic4c03185.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorg Chem","raw_type":"Text"},{"id":"pmid:39475160","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/39475160","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1021/acs.inorgchem.4c03185","doi":"https://doi.org/10.1021/acs.inorgchem.4c03185","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.4c03185","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c03185?ref=article_openPDF","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G22113365","display_name":null,"funder_award_id":"00x0ma614","funder_id":"https://openalex.org/F4320322025","funder_display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico"},{"id":"https://openalex.org/G2910959980","display_name":"Novel aging: technologies and solutions to manufacture novel dairy products for healthy aging","funder_award_id":"17/01189-0","funder_id":"https://openalex.org/F4320320997","funder_display_name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo"},{"id":"https://openalex.org/G3690646728","display_name":null,"funder_award_id":"00x0MA614","funder_id":"https://openalex.org/F4320321091","funder_display_name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior"}],"funders":[{"id":"https://openalex.org/F4320320997","display_name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","ror":"https://ror.org/02ddkpn78"},{"id":"https://openalex.org/F4320321091","display_name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","ror":"https://ror.org/00x0ma614"},{"id":"https://openalex.org/F4320322025","display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","ror":"https://ror.org/03swz6y49"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4403887828.pdf","grobid_xml":"https://content.openalex.org/works/W4403887828.grobid-xml"},"referenced_works_count":84,"referenced_works":["https://openalex.org/W136256204","https://openalex.org/W1547749433","https://openalex.org/W1752933235","https://openalex.org/W1828441724","https://openalex.org/W1963960722","https://openalex.org/W1966192524","https://openalex.org/W1969274058","https://openalex.org/W1970175445","https://openalex.org/W1975968104","https://openalex.org/W1981996436","https://openalex.org/W1983014323","https://openalex.org/W1983875831","https://openalex.org/W1985289402","https://openalex.org/W1985691574","https://openalex.org/W1987340301","https://openalex.org/W1988091937","https://openalex.org/W1989786922","https://openalex.org/W1995418515","https://openalex.org/W1996147332","https://openalex.org/W2001636469","https://openalex.org/W2002247106","https://openalex.org/W2003071644","https://openalex.org/W2007534357","https://openalex.org/W2007680267","https://openalex.org/W2011131666","https://openalex.org/W2011805858","https://openalex.org/W2014058296","https://openalex.org/W2014882652","https://openalex.org/W2022003198","https://openalex.org/W2022143873","https://openalex.org/W2022922847","https://openalex.org/W2030687437","https://openalex.org/W2037640551","https://openalex.org/W2038518647","https://openalex.org/W2040763306","https://openalex.org/W2041049135","https://openalex.org/W2042399435","https://openalex.org/W2046215965","https://openalex.org/W2047354298","https://openalex.org/W2048322679","https://openalex.org/W2050827506","https://openalex.org/W2050899522","https://openalex.org/W2056874984","https://openalex.org/W2061778764","https://openalex.org/W2064104942","https://openalex.org/W2065596554","https://openalex.org/W2067658729","https://openalex.org/W2068555097","https://openalex.org/W2073658394","https://openalex.org/W2074190471","https://openalex.org/W2077971026","https://openalex.org/W2078146328","https://openalex.org/W2081398215","https://openalex.org/W2083168623","https://openalex.org/W2084591461","https://openalex.org/W2086309946","https://openalex.org/W2086957099","https://openalex.org/W2092155814","https://openalex.org/W2094407301","https://openalex.org/W2110881939","https://openalex.org/W2113305715","https://openalex.org/W2113895240","https://openalex.org/W2125036705","https://openalex.org/W2143236777","https://openalex.org/W2334679641","https://openalex.org/W2334933433","https://openalex.org/W2342017929","https://openalex.org/W2484066416","https://openalex.org/W2784495890","https://openalex.org/W2786875461","https://openalex.org/W2950681919","https://openalex.org/W2953393594","https://openalex.org/W3000735903","https://openalex.org/W3008477923","https://openalex.org/W3136335459","https://openalex.org/W3136813111","https://openalex.org/W3163426361","https://openalex.org/W3187947295","https://openalex.org/W4200141959","https://openalex.org/W4220746702","https://openalex.org/W4229925216","https://openalex.org/W4246693559","https://openalex.org/W4307406267","https://openalex.org/W4385879615"],"related_works":["https://openalex.org/W7043510558","https://openalex.org/W7120496783","https://openalex.org/W7120737766","https://openalex.org/W3013948453","https://openalex.org/W2069549427","https://openalex.org/W2125036705","https://openalex.org/W1981646879","https://openalex.org/W2548543748","https://openalex.org/W2086309946","https://openalex.org/W4411583054"],"abstract_inverted_index":{"High":[0],"Resolution":[1],"Image":[2],"Download":[3],"MS":[4],"PowerPoint":[5],"Slide":[6],"Ruthenium(II)":[7],"tetraamine":[8],"nitrosyl":[9,94,148,233],"complexes":[10,202],"with":[11],"N-heterocyclic":[12],"ligands":[13],"are":[14,165],"known":[15],"for":[16,54],"their":[17,240],"potential":[18,241],"as":[19,130,190,242],"nitric":[20,186],"oxide":[21,187],"(NO":[22],"\u2022":[23,30,126,244],")":[24,63,153,161,206,214],"donors,":[25],"capable":[26],"of":[27,38,92,124,146,198,231,239],"releasing":[28],"NO":[29,125,243],"through":[31],"either":[32],"direct":[33,122],"photodissociation":[34],"or":[35],"one-electron":[36,51,90],"reduction":[37,52,91,135,168,197,226],"the":[39,50,55,83,93,131,144,147,196,199,225],"Ru(II)NO":[40],"+":[41,156],"center.":[42],"This":[43,219],"study":[44,220],"delivers":[45],"a":[46,96,180],"novel":[47],"insight":[48],"into":[49,224],"mechanism":[53,227],"model":[56],"complex":[57],"trans":[58,158,211],"-[Ru":[59],"II":[60],"(NO)(NH":[61],"3":[62,152,160,205,213],"4":[64,154,162,207,215],"(py)]":[65],"3+":[66],"(RuNOpy,":[67],"py":[68],"=":[69],"pyridine)":[70],"in":[71,119],"phosphate":[72],"buffer":[73],"solution":[74],"(pH":[75],"7.4).":[76],"In":[77],"situ":[78],"FT-IR":[79,140],"spectroelectrochemistry":[80],"reveals":[81],"that":[82,143,178],"pyridine":[84,118,170],"ligand":[85],"is":[86,188],"readily":[87],"released":[88],"upon":[89],"complex,":[95,149],"finding":[97],"supported":[98],"by":[99],"nuclear":[100],"magnetic":[101],"resonance":[102],"spectroscopy":[103],"(":[104],"1":[105],"H":[106],"NMR)":[107],"and":[108,157,169,210,228],"electrochemistry":[109],"coupled":[110],"to":[111,236],"mass":[112],"spectrometry":[113],"(EC-MS),":[114],"which":[115],"detect":[116],"free":[117],"solution.":[120],"However,":[121],"evidence":[123],"release":[127],"from":[128,195],"RuNOpy":[129],"primary":[132],"step":[133],"following":[134,167],"was":[136],"not":[137],"observed.":[138],"Interestingly,":[139],"results":[141],"indicate":[142],"isomers":[145],"cis":[150,203],"-[Ru(NO)(NH":[151,159,204,212],"(OH)]":[155,163,208,216],"+,":[164],"formed":[166],"labilization,":[171],"initiating":[172],"an":[173,191],"outer-sphere":[174],"electron":[175,182],"transfer":[176,183],"process":[177],"triggers":[179],"chain":[181],"reaction.":[184],"Finally,":[185],"liberated":[189],"end":[192],"product,":[193],"arising":[194],"hydroxyl":[200],"isomer":[201],"2+":[209,217],".":[218],"provides":[221],"new":[222],"insights":[223],"transformation":[229],"pathways":[230],"ruthenium":[232],"complexes,":[234],"contributing":[235],"our":[237],"understanding":[238],"donors.":[245]},"counts_by_year":[{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":1}],"updated_date":"2026-10-29T09:56:32.521200","created_date":"2024-10-31T00:00:00"}
