{"id":"https://openalex.org/W4403005259","doi":"https://doi.org/10.2174/0122115447334739240903072058","title":"Hydroxylation of Phenol by an Azomethine Quinoxaline Schiff Base Copper (II) Complex","display_name":"Hydroxylation of Phenol by an Azomethine Quinoxaline Schiff Base Copper (II) Complex","publication_year":2024,"publication_date":"2024-10-01","ids":{"openalex":"https://openalex.org/W4403005259","doi":"https://doi.org/10.2174/0122115447334739240903072058"},"language":"en","primary_location":{"id":"doi:10.2174/0122115447334739240903072058","doi":"https://doi.org/10.2174/0122115447334739240903072058","is_oa":false,"landing_page_url":"https://doi.org/10.2174/0122115447334739240903072058","pdf_url":null,"source":{"id":"https://openalex.org/S4210184777","display_name":"Current Catalysis","issn_l":"2211-5447","issn":["2211-5447","2211-5455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Current Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5079957656","display_name":"Vasudevan Arun","orcid":"https://orcid.org/0000-0003-2519-975X","observed_orcids":["https://orcid.org/0000-0003-2519-975X"]},"institutions":[{"id":"https://openalex.org/I4405254405","display_name":"Sree Narayana College, Punalur","ror":"https://ror.org/01s3q7074","country_code":"IN","type":"education","lineage":["https://openalex.org/I4405254405"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Vasudevan Arun","raw_affiliation_strings":["Department of Chemistry, Sree Narayana College, Punalur, 691305, Kerala, India & Research Department of Chemistry, Sree Narayana College, Kollam, Kerala, 691001, India","Department of Chemistry, Sree Narayana College, Punalur-690305, Kerala, India & Research Department of Chemistry, Sree Narayana College, Kollam, Kerala, 691001, India"],"raw_orcid":"https://orcid.org/0000-0003-2519-975X","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Sree Narayana College, Punalur, 691305, Kerala, India & Research Department of Chemistry, Sree Narayana College, Kollam, Kerala, 691001, India","institution_ids":["https://openalex.org/I4405254405"]},{"raw_affiliation_string":"Department of Chemistry, Sree Narayana College, Punalur-690305, Kerala, India & Research Department of Chemistry, Sree Narayana College, Kollam, Kerala, 691001, India","institution_ids":["https://openalex.org/I4405254405"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5079957656"],"corresponding_institution_ids":["https://openalex.org/I4405254405"],"apc_list":null,"apc_paid":null,"fwci":0.1024,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.20653595,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":91,"max":95},"biblio":{"volume":"13","issue":"2","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9253000020980835,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9253000020980835,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.033900000154972076,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.011500000022351742,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/phenol-hydroxylation","display_name":"phenol hydroxylation","score":0.9950000047683716},{"id":"https://openalex.org/keywords/schiff-base","display_name":"Schiff base","score":0.7820000052452087},{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.9769999980926514},{"id":"https://openalex.org/keywords/dinuclear-copper-ii-complex","display_name":"dinuclear copper(II) complex","score":0.9200000166893005},{"id":"https://openalex.org/keywords/square-planar-geometry","display_name":"square-planar coordination","score":0.7459999918937683},{"id":"https://openalex.org/keywords/hydrogen-peroxide-oxidation","display_name":"hydrogen peroxide oxidation","score":0.6840000152587891},{"id":"https://openalex.org/keywords/green-oxidant","display_name":"green oxidant","score":0.8510000109672546},{"id":"https://openalex.org/keywords/heterogeneous-catalysis","display_name":"heterogeneous catalysis","score":0.8100000023841858},{"id":"https://openalex.org/keywords/phenol-conversion","display_name":"phenol conversion","score":0.5580000281333923}],"concepts":[{"id":"https://openalex.org/C2780362310","wikidata":"https://www.wikidata.org/wiki/Q419930","display_name":"Quinoxaline","level":2,"score":0.8858263492584229},{"id":"https://openalex.org/C2781109383","wikidata":"https://www.wikidata.org/wiki/Q898497","display_name":"Hydroxylation","level":3,"score":0.8557014465332031},{"id":"https://openalex.org/C2776428424","wikidata":"https://www.wikidata.org/wiki/Q2602701","display_name":"Schiff base","level":2,"score":0.8317338228225708},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7301878929138184},{"id":"https://openalex.org/C2777702071","wikidata":"https://www.wikidata.org/wiki/Q130336","display_name":"Phenol","level":2,"score":0.6439493894577026},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.5846890211105347},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.35830920934677124},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3474588394165039},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3329991102218628},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2830492854118347},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.06453162431716919}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.2174/0122115447334739240903072058","doi":"https://doi.org/10.2174/0122115447334739240903072058","is_oa":false,"landing_page_url":"https://doi.org/10.2174/0122115447334739240903072058","pdf_url":null,"source":{"id":"https://openalex.org/S4210184777","display_name":"Current Catalysis","issn_l":"2211-5447","issn":["2211-5447","2211-5455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Current Catalysis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W158423966","https://openalex.org/W229320091","https://openalex.org/W1980478926","https://openalex.org/W1985779038","https://openalex.org/W1989807773","https://openalex.org/W1998664206","https://openalex.org/W2007193317","https://openalex.org/W2013573700","https://openalex.org/W2015864415","https://openalex.org/W2016942187","https://openalex.org/W2018216323","https://openalex.org/W2032783402","https://openalex.org/W2034239878","https://openalex.org/W2044005623","https://openalex.org/W2045270647","https://openalex.org/W2048645097","https://openalex.org/W2049083506","https://openalex.org/W2061458542","https://openalex.org/W2073084067","https://openalex.org/W2087243939","https://openalex.org/W2111046360","https://openalex.org/W2117026646","https://openalex.org/W2124440245","https://openalex.org/W2139093165","https://openalex.org/W2145494421","https://openalex.org/W2150829534","https://openalex.org/W2462436506","https://openalex.org/W2767082708","https://openalex.org/W2949625153","https://openalex.org/W3005038279","https://openalex.org/W3022602249","https://openalex.org/W3131817938","https://openalex.org/W3133047276","https://openalex.org/W3136626870","https://openalex.org/W4365449302","https://openalex.org/W4385174030","https://openalex.org/W4399093772"],"related_works":["https://openalex.org/W6948047998","https://openalex.org/W2041472290","https://openalex.org/W4312928382","https://openalex.org/W3003923038","https://openalex.org/W1994177267","https://openalex.org/W2259618307","https://openalex.org/W3131222033","https://openalex.org/W2085292841","https://openalex.org/W4408095161","https://openalex.org/W2058896765"],"abstract_inverted_index":{"Introduction:":[0],"A":[1],"binuclear":[2],"azomethine":[3,26],"quinoxaline":[4,27],"Schiff":[5,28],"base":[6,29],"copper":[7,16,31],"(II)":[8,32],"complex,":[9],"[Cu2LCl2],":[10],"having":[11],"square-planar":[12],"environment":[13],"around":[14],"each":[15],"(II),":[17],"has":[18,54,78],"been":[19,55,79],"synthesized.":[20],"Method:":[21],"The":[22],"coordination":[23],"of":[24,47,76],"the":[25],"with":[30],"and":[33,41,69],"its":[34],"structure":[35],"was":[36],"studied":[37],"by":[38],"various":[39],"physicochemical":[40],"spectroscopic":[42],"measurements.":[43],"Results:":[44],"Catalytic":[45,64],"activity":[46],"this":[48,82],"complex":[49],"in":[50],"phenol":[51,77],"hydroxylation":[52],"reaction":[53,65],"examined":[56],"using":[57],"H2O2":[58],"as":[59],"a":[60],"green":[61],"oxidant.":[62],"Conclusion:":[63],"conditions":[66],"were":[67],"optimized":[68],"under":[70],"these":[71],"conditions,":[72],"18.32":[73],"%":[74],"conversion":[75],"obtained":[80],"for":[81],"catalyst":[83]},"counts_by_year":[{"year":2026,"cited_by_count":1}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2024-10-01T00:00:00"}
