{"id":"https://openalex.org/W4402030833","doi":"https://doi.org/10.1021/acsami.4c06949","title":"Post-Modification Approach for Self-Exfoliated Synthesis of Pyridinium Sulfobetaine Covalent Organic Frameworks for Enhanced Lithium-Ion Conductivity","display_name":"Post-Modification Approach for Self-Exfoliated Synthesis of Pyridinium Sulfobetaine Covalent Organic Frameworks for Enhanced Lithium-Ion Conductivity","publication_year":2024,"publication_date":"2024-08-30","ids":{"openalex":"https://openalex.org/W4402030833","doi":"https://doi.org/10.1021/acsami.4c06949","pmid":"https://pubmed.ncbi.nlm.nih.gov/39213657"},"language":"en","primary_location":{"id":"doi:10.1021/acsami.4c06949","doi":"https://doi.org/10.1021/acsami.4c06949","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.4c06949","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5046484668","display_name":"Cong\u2010Xue Liu","orcid":"https://orcid.org/0000-0003-1730-7570","observed_orcids":["https://orcid.org/0000-0003-1730-7570"]},"institutions":[{"id":"https://openalex.org/I123900574","display_name":"Pohang University of Science and Technology","ror":"https://ror.org/04xysgw12","country_code":"KR","type":"education","lineage":["https://openalex.org/I123900574"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Cong-Xue Liu","raw_affiliation_strings":["Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0003-1730-7570","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I123900574"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5086037339","display_name":"Soomin Hwang","orcid":"https://orcid.org/0009-0003-7778-0738","observed_orcids":["https://orcid.org/0009-0003-7778-0738"]},"institutions":[{"id":"https://openalex.org/I123900574","display_name":"Pohang University of Science and Technology","ror":"https://ror.org/04xysgw12","country_code":"KR","type":"education","lineage":["https://openalex.org/I123900574"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Soomin Hwang","raw_affiliation_strings":["Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I123900574"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100746798","display_name":"Yeji Lee","orcid":"https://orcid.org/0009-0009-9655-2961","observed_orcids":["https://orcid.org/0009-0009-9655-2961","https://orcid.org/0000-0003-3688-1199"]},"institutions":[{"id":"https://openalex.org/I123900574","display_name":"Pohang University of Science and Technology","ror":"https://ror.org/04xysgw12","country_code":"KR","type":"education","lineage":["https://openalex.org/I123900574"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Yeji Lee","raw_affiliation_strings":["Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I123900574"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067537735","display_name":"Young Ho Ko","orcid":"https://orcid.org/0000-0001-5379-2820","observed_orcids":["https://orcid.org/0000-0001-5379-2820"]},"institutions":[{"id":"https://openalex.org/I4210104335","display_name":"Institute for Basic Science","ror":"https://ror.org/00y0zf565","country_code":"KR","type":"facility","lineage":["https://openalex.org/I4210104335"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Young Ho Ko","raw_affiliation_strings":["Center for Epitaxial van der Waals Quantum Solids, Institute for Basic Science, Pohang 37673, Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Epitaxial van der Waals Quantum Solids, Institute for Basic Science, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I4210104335"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080164411","display_name":"Sarah S. Park","orcid":"https://orcid.org/0000-0002-8770-6094","observed_orcids":["https://orcid.org/0000-0002-8770-6094"]},"institutions":[{"id":"https://openalex.org/I123900574","display_name":"Pohang University of Science and Technology","ror":"https://ror.org/04xysgw12","country_code":"KR","type":"education","lineage":["https://openalex.org/I123900574"]},{"id":"https://openalex.org/I193775966","display_name":"Yonsei University","ror":"https://ror.org/01wjejq96","country_code":"KR","type":"education","lineage":["https://openalex.org/I193775966"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Sarah S. Park","raw_affiliation_strings":["Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","Institute for Convergence Research and Education in Advanced Technology (I-CREATE), Yonsei University, Seoul 03722, Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0002-8770-6094","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I123900574"]},{"raw_affiliation_string":"Institute for Convergence Research and Education in Advanced Technology (I-CREATE), Yonsei University, Seoul 03722, Republic of Korea","institution_ids":["https://openalex.org/I193775966"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5085521599","display_name":"Eunsung Lee","orcid":"https://orcid.org/0000-0002-1507-098X","observed_orcids":["https://orcid.org/0000-0002-1507-098X"]},"institutions":[{"id":"https://openalex.org/I123900574","display_name":"Pohang University of Science and Technology","ror":"https://ror.org/04xysgw12","country_code":"KR","type":"education","lineage":["https://openalex.org/I123900574"]},{"id":"https://openalex.org/I139264467","display_name":"Seoul National University","ror":"https://ror.org/04h9pn542","country_code":"KR","type":"education","lineage":["https://openalex.org/I139264467"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Eunsung Lee","raw_affiliation_strings":["Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0002-1507-098X","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea","institution_ids":["https://openalex.org/I123900574"]},{"raw_affiliation_string":"Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea","institution_ids":["https://openalex.org/I139264467"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5080164411","https://openalex.org/A5085521599"],"corresponding_institution_ids":["https://openalex.org/I123900574","https://openalex.org/I139264467","https://openalex.org/I193775966"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.547,"has_fulltext":false,"cited_by_count":15,"citation_normalized_percentile":{"value":0.8214835,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":98,"max":99},"biblio":{"volume":"16","issue":"36","first_page":"48203","last_page":"48210"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.9609000086784363,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.9609000086784363,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.03739999979734421,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/covalent-organic-frameworks","display_name":"covalent organic frameworks","score":0.9789999723434448},{"id":"https://openalex.org/keywords/lithium-ion-conductivity","display_name":"lithium ion conductivity","score":0.7009999752044678},{"id":"https://openalex.org/keywords/organic-electrolytes","display_name":"organic electrolytes","score":0.8679999709129333},{"id":"https://openalex.org/keywords/lithium-plating-stripping","display_name":"lithium plating/stripping","score":0.859000027179718},{"id":"https://openalex.org/keywords/electrochemical-stability-window","display_name":"electrochemical stability window","score":0.8769999742507935},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.6710000038146973}],"concepts":[{"id":"https://openalex.org/C2777221202","wikidata":"https://www.wikidata.org/wiki/Q2518436","display_name":"Pyridinium","level":2,"score":0.8804548978805542},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7194725275039673},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.6347512006759644},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.6166788339614868},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.6141230463981628},{"id":"https://openalex.org/C138679309","wikidata":"https://www.wikidata.org/wiki/Q6063658","display_name":"Ionic conductivity","level":4,"score":0.6001355051994324},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5663195252418518},{"id":"https://openalex.org/C131540310","wikidata":"https://www.wikidata.org/wiki/Q907564","display_name":"Conductivity","level":2,"score":0.5635764002799988},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.552794337272644},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4569341540336609},{"id":"https://openalex.org/C2777893391","wikidata":"https://www.wikidata.org/wiki/Q5178887","display_name":"Covalent organic framework","level":3,"score":0.4505015015602112},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.44103625416755676},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4313446283340454},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.39884012937545776},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.38831648230552673},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17685475945472717},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.15939021110534668},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.14973536133766174},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.08684581518173218},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acsami.4c06949","doi":"https://doi.org/10.1021/acsami.4c06949","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsami.4c06949","pdf_url":null,"source":{"id":"https://openalex.org/S164001016","display_name":"ACS Applied Materials & Interfaces","issn_l":"1944-8244","issn":["1944-8244","1944-8252"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Applied Materials & Interfaces","raw_type":"journal-article"},{"id":"pmid:39213657","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/39213657","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS applied materials & interfaces","raw_type":"Journal Article"},{"id":"pmh:oai:s-space.snu.ac.kr:10371/234991","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/10371/234991","pdf_url":null,"source":{"id":"https://openalex.org/S4306401345","display_name":"Seoul National University Open Repository (Seoul National University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139264467","host_organization_name":"Seoul National University","host_organization_lineage":["https://openalex.org/I139264467"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Article"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.878000020980835,"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy"}],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3463859459","display_name":null,"funder_award_id":"RS-2023-00243412","funder_id":"https://openalex.org/F4320322120","funder_display_name":"National Research Foundation of Korea"},{"id":"https://openalex.org/G5162386068","display_name":null,"funder_award_id":"RS-2023-00212896","funder_id":"https://openalex.org/F4320322120","funder_display_name":"National Research Foundation of Korea"},{"id":"https://openalex.org/G6685005352","display_name":null,"funder_award_id":"2021R1A6A1A10042944","funder_id":"https://openalex.org/F4320322120","funder_display_name":"National Research Foundation of Korea"}],"funders":[{"id":"https://openalex.org/F4320322120","display_name":"National Research Foundation of Korea","ror":"https://ror.org/013aysd81"},{"id":"https://openalex.org/F4320322725","display_name":"China Scholarship Council","ror":"https://ror.org/04atp4p48"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":59,"referenced_works":["https://openalex.org/W1971275758","https://openalex.org/W1976740307","https://openalex.org/W1979247345","https://openalex.org/W1989896216","https://openalex.org/W2029667189","https://openalex.org/W2049145344","https://openalex.org/W2062960374","https://openalex.org/W2075271835","https://openalex.org/W2092944857","https://openalex.org/W2100061873","https://openalex.org/W2132525235","https://openalex.org/W2148284063","https://openalex.org/W2266412763","https://openalex.org/W2467088530","https://openalex.org/W2554066920","https://openalex.org/W2594238106","https://openalex.org/W2595476858","https://openalex.org/W2751261040","https://openalex.org/W2781831224","https://openalex.org/W2807350777","https://openalex.org/W2885772221","https://openalex.org/W2896446875","https://openalex.org/W2905801883","https://openalex.org/W2915192591","https://openalex.org/W2924652724","https://openalex.org/W2945345197","https://openalex.org/W2980037270","https://openalex.org/W2980612688","https://openalex.org/W3010767733","https://openalex.org/W3015879182","https://openalex.org/W3023123403","https://openalex.org/W3093602012","https://openalex.org/W3100290071","https://openalex.org/W3133068034","https://openalex.org/W3153212458","https://openalex.org/W3154037338","https://openalex.org/W3169791078","https://openalex.org/W3192545661","https://openalex.org/W3214131680","https://openalex.org/W4205222199","https://openalex.org/W4226376259","https://openalex.org/W4283072405","https://openalex.org/W4285798212","https://openalex.org/W4295752813","https://openalex.org/W4305057744","https://openalex.org/W4307851798","https://openalex.org/W4311272554","https://openalex.org/W4317780839","https://openalex.org/W4320709374","https://openalex.org/W4321612193","https://openalex.org/W4327943796","https://openalex.org/W4360977305","https://openalex.org/W4379209524","https://openalex.org/W4380677074","https://openalex.org/W4384007312","https://openalex.org/W4385556004","https://openalex.org/W4391659395","https://openalex.org/W4392731927","https://openalex.org/W4394903848"],"related_works":["https://openalex.org/W4205302935","https://openalex.org/W2619700507","https://openalex.org/W3165767075","https://openalex.org/W4282935463","https://openalex.org/W4389318482","https://openalex.org/W2998179049","https://openalex.org/W4291567136","https://openalex.org/W4385762170","https://openalex.org/W3112419871","https://openalex.org/W4382055114"],"abstract_inverted_index":{"While":[0],"covalent":[1,49],"organic":[2,13,50,163],"frameworks":[3],"(COFs)":[4],"have":[5],"been":[6],"extensively":[7],"investigated":[8],"in":[9,36,75,84],"the":[10,37,63,72,95,99,104,138,153],"field":[11],"of":[12,22,66,98,113,156],"electrolyte":[14],"materials,":[15],"there":[16],"is":[17],"potential":[18,155],"for":[19,146],"further":[20],"enhancement":[21,83],"their":[23],"room-temperature":[24],"ionic":[25,111],"conductivity.":[26],"This":[27,46],"study":[28],"introduces":[29],"a":[30,43,81,109,122,130],"novel":[31],"methodology":[32],"to":[33,58,62,80],"induce":[34],"self-exfoliation":[35],"parent":[38],"COF":[39],"during":[40],"synthesis":[41],"through":[42],"postmodification":[44],"technique.":[45],"process":[47],"yields":[48],"nanosheets":[51,160],"that":[52],"feature":[53],"pyridinium":[54,67,100],"sulfobetaine":[55,70,101],"groups,":[56,102],"referred":[57],"as":[59,161],"PS-CON.":[60],"Due":[61],"strategic":[64],"arrangement":[65],"cations":[68],"and":[69,121],"anions,":[71],"charge":[73],"distribution":[74],"PS-CON":[76,107],"varies":[77],"substantially,":[78],"leading":[79],"significant":[82],"lithium-ion":[85,105],"dissociation.":[86],"The":[87],"methodically":[88],"organized":[89],"one-dimensional":[90],"pore":[91],"channels,":[92],"along":[93],"with":[94,129],"linear":[96],"structure":[97],"facilitate":[103],"transport.":[106],"demonstrated":[108],"remarkable":[110],"conductivity":[112],"2.19":[114],"\u00d7":[115],"10":[116],"\u20134":[117],"S":[118],"cm":[119],"\u20131":[120],"low":[123],"activation":[124],"energy":[125],"(0.26":[126],"eV)":[127],"coupled":[128],"broad":[131],"electrochemical":[132],"stabilization":[133],"window":[134],"(4.05":[135],"V).":[136],"Furthermore,":[137],"symmetrical":[139],"cell":[140],"(Li|Li@PS-CON|Li)":[141],"demonstrates":[142],"stable":[143],"Li":[144],"plating/stripping":[145],"more":[147],"than":[148],"1200":[149],"h,":[150],"which":[151],"highlights":[152],"vast":[154],"pyridinium-sulfobetaine":[157],"based":[158],"zwitterionic":[159],"high-performance":[162],"electrolytes.":[164]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":6}],"updated_date":"2026-10-13T10:08:12.033832","created_date":"2025-10-10T00:00:00"}