{"id":"https://openalex.org/W4401979624","doi":"https://doi.org/10.1021/acs.jpcc.4c03166","title":"Photophysics of \u201cPorphyrin Cages\u201d: Absorption and Emission Spectroscopy","display_name":"Photophysics of \u201cPorphyrin Cages\u201d: Absorption and Emission Spectroscopy","publication_year":2024,"publication_date":"2024-08-29","ids":{"openalex":"https://openalex.org/W4401979624","doi":"https://doi.org/10.1021/acs.jpcc.4c03166"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpcc.4c03166","doi":"https://doi.org/10.1021/acs.jpcc.4c03166","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.4c03166","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://figshare.com/articles/journal_contribution/Photophysics_of_Porphyrin_Cages_Absorption_and_Emission_Spectroscopy/27191895","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5075903297","display_name":"Michael Wilms","orcid":"https://orcid.org/0000-0002-1362-9233","observed_orcids":["https://orcid.org/0000-0002-1362-9233"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Michael Wilms","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-1362-9233","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5092049553","display_name":"Daniel J. Tibben","orcid":"https://orcid.org/0000-0002-5388-8010","observed_orcids":["https://orcid.org/0000-0002-5388-8010"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Daniel Tibben","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-5388-8010","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074538917","display_name":"Igor Lyskov","orcid":"https://orcid.org/0000-0002-6111-2060","observed_orcids":["https://orcid.org/0000-0002-6111-2060"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Igor Lyskov","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-6111-2060","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031877516","display_name":"Salvy P. Russo","orcid":"https://orcid.org/0000-0003-3589-3040","observed_orcids":["https://orcid.org/0000-0003-3589-3040"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Salvy P. Russo","raw_affiliation_strings":["ARC Centre of Excellence in Exciton Science, School of Science, RMIT University, Melbourne, VIC 3000, Australia","School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0003-3589-3040","affiliations":[{"raw_affiliation_string":"ARC Centre of Excellence in Exciton Science, School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]},{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072814611","display_name":"Joel van Embden","orcid":"https://orcid.org/0000-0002-4225-9454","observed_orcids":["https://orcid.org/0000-0002-4225-9454"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Joel van Embden","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-4225-9454","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019027963","display_name":"Enrico Della Gaspera","orcid":"https://orcid.org/0000-0001-9948-5893","observed_orcids":["https://orcid.org/0000-0001-9948-5893"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Enrico Della Gaspera","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0001-9948-5893","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089161101","display_name":"Timothy U. Connell","orcid":"https://orcid.org/0000-0002-6142-3854","observed_orcids":["https://orcid.org/0000-0002-6142-3854"]},"institutions":[{"id":"https://openalex.org/I149704539","display_name":"Deakin University","ror":"https://ror.org/02czsnj07","country_code":"AU","type":"education","lineage":["https://openalex.org/I149704539"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Timothy U. Connell","raw_affiliation_strings":["School of Life and Environmental Sciences, Deakin University, Waurn Ponds, VIC 3216, Australia"],"raw_orcid":"https://orcid.org/0000-0002-6142-3854","affiliations":[{"raw_affiliation_string":"School of Life and Environmental Sciences, Deakin University, Waurn Ponds, VIC 3216, Australia","institution_ids":["https://openalex.org/I149704539"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5002937608","display_name":"Daniel E. G\u00f3mez","orcid":"https://orcid.org/0000-0002-7871-4068","observed_orcids":["https://orcid.org/0000-0002-7871-4068"]},"institutions":[{"id":"https://openalex.org/I82951845","display_name":"RMIT University","ror":"https://ror.org/04ttjf776","country_code":"AU","type":"education","lineage":["https://openalex.org/I82951845"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"Daniel E. G\u00f3mez","raw_affiliation_strings":["School of Science, RMIT University, Melbourne, VIC 3000, Australia"],"raw_orcid":"https://orcid.org/0000-0002-7871-4068","affiliations":[{"raw_affiliation_string":"School of Science, RMIT University, Melbourne, VIC 3000, Australia","institution_ids":["https://openalex.org/I82951845"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5002937608"],"corresponding_institution_ids":["https://openalex.org/I82951845"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.3499,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.38816725,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":96},"biblio":{"volume":"128","issue":"36","first_page":"15041","last_page":"15047"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10957","display_name":"Photodynamic Therapy Research Studies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1306","display_name":"Cancer Research"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.5809999704360962},{"id":"https://openalex.org/keywords/absorption-spectra","display_name":"absorption spectra","score":0.8640000224113464},{"id":"https://openalex.org/keywords/soret-band","display_name":"Soret band","score":0.6399999856948853},{"id":"https://openalex.org/keywords/q-band","display_name":"Q-band","score":0.578000009059906},{"id":"https://openalex.org/keywords/fluorescence-quantum-yield","display_name":"fluorescence quantum yield","score":0.7329999804496765},{"id":"https://openalex.org/keywords/conjugation","display_name":"conjugation","score":0.6349999904632568},{"id":"https://openalex.org/keywords/molar-absorptivity","display_name":"molar absorptivity","score":0.7950000166893005},{"id":"https://openalex.org/keywords/fluorescence-lifetime","display_name":"fluorescence lifetime","score":0.5989999771118164},{"id":"https://openalex.org/keywords/exciton-delocalization","display_name":"exciton delocalization","score":0.9739999771118164},{"id":"https://openalex.org/keywords/optoelectronic-devices","display_name":"optoelectronic devices","score":0.8709999918937683},{"id":"https://openalex.org/keywords/photosensitizers","display_name":"photosensitizers","score":0.9660000205039978},{"id":"https://openalex.org/keywords/photocatalysts","display_name":"photocatalysts","score":0.9919999837875366}],"concepts":[{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.7872588634490967},{"id":"https://openalex.org/C112613896","wikidata":"https://www.wikidata.org/wiki/Q898370","display_name":"Conjugated system","level":3,"score":0.7325811982154846},{"id":"https://openalex.org/C76046532","wikidata":"https://www.wikidata.org/wiki/Q900239","display_name":"Molar absorptivity","level":2,"score":0.6612678170204163},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6436301469802856},{"id":"https://openalex.org/C70050531","wikidata":"https://www.wikidata.org/wiki/Q899089","display_name":"Delocalized electron","level":2,"score":0.6295468807220459},{"id":"https://openalex.org/C125287762","wikidata":"https://www.wikidata.org/wiki/Q1758948","display_name":"Absorption (acoustics)","level":2,"score":0.545459508895874},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.5284416675567627},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.5062028765678406},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4810929000377655},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4649236500263214},{"id":"https://openalex.org/C96141758","wikidata":"https://www.wikidata.org/wiki/Q216817","display_name":"Emission spectrum","level":3,"score":0.4594396650791168},{"id":"https://openalex.org/C17729963","wikidata":"https://www.wikidata.org/wiki/Q858289","display_name":"Exciton","level":2,"score":0.45123276114463806},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4214918315410614},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.35142889618873596},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.1712404489517212},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.08130869269371033},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07370641827583313},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.jpcc.4c03166","doi":"https://doi.org/10.1021/acs.jpcc.4c03166","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.4c03166","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},{"id":"pmh:oai:figshare.com:article/27191895","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/journal_contribution/Photophysics_of_Porphyrin_Cages_Absorption_and_Emission_Spectroscopy/27191895","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:figshare.com:article/27191895","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/journal_contribution/Photophysics_of_Porphyrin_Cages_Absorption_and_Emission_Spectroscopy/27191895","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1247235146","display_name":"Shining a light on the mechanism of photochemical hydrogen production","funder_award_id":"DE210101168","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G2667794772","display_name":"Design of 2D Soft Plasmonic Photocatalysts for Artificial Leaves","funder_award_id":"DP230101764","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G7213462718","display_name":"ARC Centre of Excellence in Exciton Science","funder_award_id":"CE170100026","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"}],"funders":[{"id":"https://openalex.org/F4320334704","display_name":"Australian Research Council","ror":"https://ror.org/05mmh0f86"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W119129338","https://openalex.org/W1881568159","https://openalex.org/W1971350904","https://openalex.org/W1982215860","https://openalex.org/W2013236337","https://openalex.org/W2034078366","https://openalex.org/W2067301242","https://openalex.org/W2080146445","https://openalex.org/W2121575516","https://openalex.org/W2143643649","https://openalex.org/W2168843969","https://openalex.org/W2316149515","https://openalex.org/W2323141164","https://openalex.org/W2324293288","https://openalex.org/W2500001324","https://openalex.org/W2590220706","https://openalex.org/W2961089464","https://openalex.org/W3008371522","https://openalex.org/W3037308739","https://openalex.org/W3046691154","https://openalex.org/W3080471149","https://openalex.org/W3097716688","https://openalex.org/W3127385664","https://openalex.org/W3178000859","https://openalex.org/W4225282816","https://openalex.org/W4283072924","https://openalex.org/W4285278788","https://openalex.org/W4367053057"],"related_works":["https://openalex.org/W2969828706","https://openalex.org/W6889168905","https://openalex.org/W3158651023","https://openalex.org/W7136845424","https://openalex.org/W1972348464","https://openalex.org/W4285278788","https://openalex.org/W4403466017","https://openalex.org/W7217126833","https://openalex.org/W4401369559","https://openalex.org/W2029135922"],"abstract_inverted_index":{"This":[0],"study":[1],"explores":[2],"the":[3,11,45,53,65,83,89,102,123,128,131,149],"optical":[4],"properties":[5],"of":[6,13,38,50,67,82,88,125,151],"porous":[7],"porphyrin":[8],"cages":[9,20,54,84,129,154],"through":[10],"use":[12],"spectroscopic":[14],"techniques.":[15],"The":[16,48,79,95],"findings":[17],"reveal":[18],"that":[19,87,122],"featuring":[21],"electron-donating":[22],"nitrogen":[23],"functional":[24],"groups":[25],"display":[26],"distinct":[27],"alterations":[28],"in":[29,44,115,127,138,155],"their":[30,57,162],"absorption":[31,165],"spectra,":[32],"including":[33],"a":[34,42,61,72,139],"red-shift":[35],"and":[36,41,71,108,159,166],"broadening":[37],"Soret":[39],"bands,":[40],"decrease":[43],"Soret:Q-band":[46],"ratio.":[47],"extent":[49],"conjugation":[51,136],"within":[52],"significantly":[55],"impacts":[56],"molar":[58],"absorptivity,":[59],"demonstrating":[60],"linear":[62],"correlation":[63],"with":[64,104,134],"number":[66,124],"saturated":[68],"cage":[69,116],"linkages":[70],"superlinear":[73],"increase":[74],"for":[75],"highly":[76,152],"conjugated":[77,93,153],"cages.":[78,94],"emission":[80,119,132],"spectra":[81],"largely":[85],"mirror":[86],"monomer,":[90],"barring":[91],"fully":[92],"relative":[96],"fluorescence":[97],"quantum":[98],"yields":[99],"differ":[100],"among":[101],"cages,":[103],"some":[105],"showing":[106],"enhancements":[107],"others":[109],"reductions,":[110],"likely":[111],"due":[112,142],"to":[113,143],"variations":[114],"rigidity.":[117],"Time-resolved":[118],"measurements":[120],"indicate":[121],"porphyrins":[126],"affects":[130],"lifetime,":[133],"increased":[135],"resulting":[137],"shorter":[140],"lifetime":[141],"exciton":[144],"delocalization.":[145],"These":[146],"insights":[147],"underscore":[148],"potential":[150],"optoelectronic":[156],"devices,":[157],"photosensitizers,":[158],"photocatalysts,":[160],"given":[161],"effective":[163],"light":[164],"energy":[167],"distribution":[168],"capabilities.":[169]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2}],"updated_date":"2026-11-05T12:25:35.769452","created_date":"2024-08-29T00:00:00"}