{"id":"https://openalex.org/W4401433671","doi":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","title":"Strategies and Tactics for Site Specific Deuterium Incorporation at Each Available Carbon Atom of a-Pinene","display_name":"Strategies and Tactics for Site Specific Deuterium Incorporation at Each Available Carbon Atom of a-Pinene","publication_year":2024,"publication_date":"2024-08-07","ids":{"openalex":"https://openalex.org/W4401433671","doi":"https://doi.org/10.26434/chemrxiv-2024-q0ng5"},"language":"en","primary_location":{"id":"doi:10.26434/chemrxiv-2024-q0ng5","doi":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"volume":null,"type":"preprint","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5063010516","display_name":"Regan J. Thomson","orcid":"https://orcid.org/0000-0001-5546-4038","observed_orcids":["https://orcid.org/0000-0001-5546-4038"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Regan Thomson","raw_affiliation_strings":["Northwestern University"],"raw_orcid":"https://orcid.org/0000-0001-5546-4038","affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074202608","display_name":"Jingyi Luo","orcid":"https://orcid.org/0000-0003-2988-1465","observed_orcids":["https://orcid.org/0000-0003-2988-1465"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jingyi Luo","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080314026","display_name":"Mary Alice Upshur","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mary Alice Upshur","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039239372","display_name":"Marvin Vega","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Marvin Vega","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020365608","display_name":"Nicolle A. Doering","orcid":"https://orcid.org/0000-0001-5191-2120","observed_orcids":["https://orcid.org/0000-0001-5191-2120"]},"institutions":[{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nicolle Doering","raw_affiliation_strings":["University of California, Berkeley"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of California, Berkeley","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085132379","display_name":"Jonathan G. Varelas","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jonathan Varelas","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028605058","display_name":"Zhouyang Ren","orcid":"https://orcid.org/0009-0002-5335-1034","observed_orcids":["https://orcid.org/0009-0002-5335-1034"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhouyang Ren","raw_affiliation_strings":["Northwestern University"],"raw_orcid":"https://orcid.org/0009-0002-5335-1034","affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5054512446","display_name":"Franz M. Geiger","orcid":"https://orcid.org/0000-0001-8569-4045","observed_orcids":["https://orcid.org/0000-0001-8569-4045"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Franz Geiger","raw_affiliation_strings":["Northwestern University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Northwestern University","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5043576784","display_name":"Richmond Sarpong","orcid":"https://orcid.org/0000-0002-0028-6323","observed_orcids":["https://orcid.org/0000-0002-0028-6323"]},"institutions":[{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Richmond Sarpong","raw_affiliation_strings":["University of California, Berkeley"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of California, Berkeley","institution_ids":["https://openalex.org/I95457486"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13561","display_name":"Chemical Reactions and Isotopes","score":0.9463000297546387,"subfield":{"id":"https://openalex.org/subfields/3003","display_name":"Pharmaceutical Science"},"field":{"id":"https://openalex.org/fields/30","display_name":"Pharmacology, Toxicology and Pharmaceutics"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T13561","display_name":"Chemical Reactions and Isotopes","score":0.9463000297546387,"subfield":{"id":"https://openalex.org/subfields/3003","display_name":"Pharmaceutical Science"},"field":{"id":"https://openalex.org/fields/30","display_name":"Pharmacology, Toxicology and Pharmaceutics"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.00800000037997961,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.007600000128149986,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alpha-pinene","display_name":"\u03b1-pinene","score":0.824999988079071},{"id":"https://openalex.org/keywords/deuterium-incorporation","display_name":"deuterium incorporation","score":0.8619999885559082},{"id":"https://openalex.org/keywords/isotopologues","display_name":"isotopologues","score":0.9210000038146973},{"id":"https://openalex.org/keywords/secondary-organic-aerosol","display_name":"secondary organic aerosol","score":0.9750000238418579},{"id":"https://openalex.org/keywords/monoterpene-oxidation","display_name":"monoterpene oxidation","score":0.7620000243186951},{"id":"https://openalex.org/keywords/isotopic-labeling","display_name":"isotopic labeling","score":0.3959999978542328}],"concepts":[{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.6203822493553162},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.6167088150978088},{"id":"https://openalex.org/C2993252241","wikidata":"https://www.wikidata.org/wiki/Q623","display_name":"Carbon atom","level":3,"score":0.6128969788551331},{"id":"https://openalex.org/C2779906576","wikidata":"https://www.wikidata.org/wiki/Q2095629","display_name":"Pinene","level":2,"score":0.5830405950546265},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.5082454085350037},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.49839258193969727},{"id":"https://openalex.org/C39432304","wikidata":"https://www.wikidata.org/wiki/Q188847","display_name":"Environmental science","level":0,"score":0.3430495858192444},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.1828802525997162},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.1722451150417328},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14205408096313477},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.13892808556556702},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.13128268718719482},{"id":"https://openalex.org/C11413529","wikidata":"https://www.wikidata.org/wiki/Q8366","display_name":"Algorithm","level":1,"score":0.058450907468795776},{"id":"https://openalex.org/C173608175","wikidata":"https://www.wikidata.org/wiki/Q232661","display_name":"Parallel computing","level":1,"score":0.05196020007133484},{"id":"https://openalex.org/C104779481","wikidata":"https://www.wikidata.org/wiki/Q50707","display_name":"Composite number","level":2,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.26434/chemrxiv-2024-q0ng5","doi":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv-2024-q0ng5","doi":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2024-q0ng5","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":29,"referenced_works":["https://openalex.org/W1990558110","https://openalex.org/W1999134339","https://openalex.org/W2037075678","https://openalex.org/W2045617521","https://openalex.org/W2046143876","https://openalex.org/W2059003011","https://openalex.org/W2077425974","https://openalex.org/W2102032244","https://openalex.org/W2110235526","https://openalex.org/W2126190595","https://openalex.org/W2130338957","https://openalex.org/W2140415329","https://openalex.org/W2223437988","https://openalex.org/W2313190384","https://openalex.org/W2346072123","https://openalex.org/W2402503711","https://openalex.org/W2402991992","https://openalex.org/W2784227084","https://openalex.org/W2904566237","https://openalex.org/W2917630884","https://openalex.org/W3005142660","https://openalex.org/W3216771788","https://openalex.org/W4223931376","https://openalex.org/W4236127859","https://openalex.org/W4296286719","https://openalex.org/W4309691978","https://openalex.org/W4327901993","https://openalex.org/W4361278761","https://openalex.org/W4401433671"],"related_works":["https://openalex.org/W4402720813","https://openalex.org/W4376491169","https://openalex.org/W4409448260","https://openalex.org/W7197863768","https://openalex.org/W4392582663","https://openalex.org/W7097120902","https://openalex.org/W2966370403","https://openalex.org/W2012017516","https://openalex.org/W7034282977","https://openalex.org/W2055302085"],"abstract_inverted_index":{"The":[0],"development":[1],"of":[2,11,39,51,64],"several":[3],"unique":[4],"strategies":[5],"and":[6],"tactics":[7],"for":[8],"the":[9,48,62,70],"synthesis":[10],"a-pinene":[12],"isotopologues":[13,40],"that":[14,56],"has":[15],"culminated":[16],"in":[17,61,69],"access":[18],"to":[19,36,44],"all":[20],"eight":[21],"possible":[22],"isomers":[23],"with":[24],"deuterium":[25],"incorporated":[26],"selectively":[27],"at":[28],"each":[29],"available":[30],"carbon":[31],"atom":[32],"is":[33],"described.":[34],"Access":[35],"this":[37],"library":[38],"provides":[41],"new":[42],"tools":[43],"more":[45],"fully":[46],"investigate":[47],"atmospheric":[49],"autoxidation":[50],"a-pinene,":[52],"a":[53,58],"complex":[54],"process":[55],"plays":[57],"major":[59],"role":[60],"formation":[63],"secondary":[65],"organic":[66],"aerosol":[67],"(SOA)":[68],"Earth\u2019s":[71],"atmosphere.":[72]},"counts_by_year":[{"year":2024,"cited_by_count":2}],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2024-08-09T00:00:00"}