{"id":"https://openalex.org/W4401211455","doi":"https://doi.org/10.31857/s0132344x24010063","title":"Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties","display_name":"Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties","publication_year":2024,"publication_date":"2024-08-01","ids":{"openalex":"https://openalex.org/W4401211455","doi":"https://doi.org/10.31857/s0132344x24010063"},"language":"en","primary_location":{"id":"doi:10.31857/s0132344x24010063","doi":"https://doi.org/10.31857/s0132344x24010063","is_oa":true,"landing_page_url":"http://dx.doi.org/10.31857/s0132344x24010063","pdf_url":"https://journals.rcsi.science/0132-344X/article/download/260964/239745","source":{"id":"https://openalex.org/S4210233830","display_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","issn_l":"0132-344X","issn":["0132-344X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319820","host_organization_name":"MAIK Nauka/Interperiodica","host_organization_lineage":["https://openalex.org/P4310319820","https://openalex.org/P4310320267"],"host_organization_lineage_names":["MAIK Nauka/Interperiodica","Pleiades Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://journals.rcsi.science/0132-344X/article/download/260964/239745","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5012687487","display_name":"Andrey Kuzovlev","orcid":"https://orcid.org/0000-0002-4952-3561","observed_orcids":["https://orcid.org/0000-0002-4952-3561"]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]},{"id":"https://openalex.org/I3020440027","display_name":"University of Tyumen","ror":"https://ror.org/05vehv290","country_code":"RU","type":"education","lineage":["https://openalex.org/I3020440027"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"A. S. Kuzovlev","raw_affiliation_strings":["Moscow State University","Tyumen State University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Moscow State University","institution_ids":["https://openalex.org/I19880235"]},{"raw_affiliation_string":"Tyumen State University","institution_ids":["https://openalex.org/I3020440027"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042350290","display_name":"N. A. Gordeeva","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210135186","display_name":"MIREA - Russian Technological University","ror":"https://ror.org/04qrtgy16","country_code":"RU","type":"education","lineage":["https://openalex.org/I4210135186"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"N. A. Gordeeva","raw_affiliation_strings":["Russian Technological University (MIREA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Russian Technological University (MIREA)","institution_ids":["https://openalex.org/I4210135186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062035852","display_name":"Zh. Yu. Pastukhova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210135186","display_name":"MIREA - Russian Technological University","ror":"https://ror.org/04qrtgy16","country_code":"RU","type":"education","lineage":["https://openalex.org/I4210135186"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Zh. Yu. Pastukhova","raw_affiliation_strings":["Russian Technological University (MIREA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Russian Technological University (MIREA)","institution_ids":["https://openalex.org/I4210135186"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038619446","display_name":"Vladimir V. Chernyshev","orcid":"https://orcid.org/0000-0001-8514-7471","observed_orcids":["https://orcid.org/0000-0001-8514-7471"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]},{"id":"https://openalex.org/I4210085913","display_name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences","ror":"https://ror.org/004dzkd51","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210085913","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"V. V. Chernyshev","raw_affiliation_strings":["Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences","Moscow State University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210085913"]},{"raw_affiliation_string":"Moscow State University","institution_ids":["https://openalex.org/I19880235"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058226606","display_name":"Grigorii A. Buzanov","orcid":"https://orcid.org/0000-0003-2676-8774","observed_orcids":["https://orcid.org/0000-0003-2676-8774"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"G. A. Buzanov","raw_affiliation_strings":["Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210108652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110255840","display_name":"Sergei F. Dunaev","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I19880235","display_name":"Lomonosov Moscow State University","ror":"https://ror.org/010pmpe69","country_code":"RU","type":"education","lineage":["https://openalex.org/I19880235"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"S. F. Dunaev","raw_affiliation_strings":["Moscow State University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Moscow State University","institution_ids":["https://openalex.org/I19880235"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5028875605","display_name":"\u041b. \u0413. \u0411\u0440\u0443\u043a","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210135186","display_name":"MIREA - Russian Technological University","ror":"https://ror.org/04qrtgy16","country_code":"RU","type":"education","lineage":["https://openalex.org/I4210135186"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"L. G. Bruk","raw_affiliation_strings":["Russian Technological University (MIREA)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Russian Technological University (MIREA)","institution_ids":["https://openalex.org/I4210135186"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5012687487"],"corresponding_institution_ids":["https://openalex.org/I19880235","https://openalex.org/I3020440027"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"50","issue":"1","first_page":"53","last_page":"61"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.31619998812675476,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.31619998812675476,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.27469998598098755,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.20829999446868896,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/palladium-ii-complexes","display_name":"palladium(II) complexes","score":0.9769999980926514},{"id":"https://openalex.org/keywords/pyrimidine-2-thione","display_name":"pyrimidine-2-thione","score":0.9539999961853027},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6809999942779541},{"id":"https://openalex.org/keywords/square-planar-geometry","display_name":"square-planar coordination","score":0.8019999861717224},{"id":"https://openalex.org/keywords/catalytic-activity","display_name":"catalytic activity","score":0.6549999713897705}],"concepts":[{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.9205677509307861},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.7398009300231934},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.727403998374939},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7040871977806091},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5165073275566101},{"id":"https://openalex.org/C518881349","wikidata":"https://www.wikidata.org/wiki/Q682","display_name":"Sulfur","level":2,"score":0.46255436539649963},{"id":"https://openalex.org/C506065880","wikidata":"https://www.wikidata.org/wiki/Q716","display_name":"Titanium","level":2,"score":0.4497591257095337},{"id":"https://openalex.org/C2779321679","wikidata":"https://www.wikidata.org/wiki/Q207722","display_name":"Pyrimidine","level":2,"score":0.43493375182151794},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.4320676028728485},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.41133278608322144},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.36038464307785034},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3346089720726013},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.27570199966430664},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2234450876712799}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.31857/s0132344x24010063","doi":"https://doi.org/10.31857/s0132344x24010063","is_oa":true,"landing_page_url":"http://dx.doi.org/10.31857/s0132344x24010063","pdf_url":"https://journals.rcsi.science/0132-344X/article/download/260964/239745","source":{"id":"https://openalex.org/S4210233830","display_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","issn_l":"0132-344X","issn":["0132-344X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319820","host_organization_name":"MAIK Nauka/Interperiodica","host_organization_lineage":["https://openalex.org/P4310319820","https://openalex.org/P4310320267"],"host_organization_lineage_names":["MAIK Nauka/Interperiodica","Pleiades Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.31857/s0132344x24010063","doi":"https://doi.org/10.31857/s0132344x24010063","is_oa":true,"landing_page_url":"http://dx.doi.org/10.31857/s0132344x24010063","pdf_url":"https://journals.rcsi.science/0132-344X/article/download/260964/239745","source":{"id":"https://openalex.org/S4210233830","display_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","issn_l":"0132-344X","issn":["0132-344X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319820","host_organization_name":"MAIK Nauka/Interperiodica","host_organization_lineage":["https://openalex.org/P4310319820","https://openalex.org/P4310320267"],"host_organization_lineage_names":["MAIK Nauka/Interperiodica","Pleiades Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u041a\u043e\u043e\u0440\u0434\u0438\u043d\u0430\u0446\u0438\u043e\u043d\u043d\u0430\u044f \u0445\u0438\u043c\u0438\u044f","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4401211455.pdf","grobid_xml":"https://content.openalex.org/works/W4401211455.grobid-xml"},"referenced_works_count":43,"referenced_works":["https://openalex.org/W1462578902","https://openalex.org/W1972334364","https://openalex.org/W1976783116","https://openalex.org/W1993187261","https://openalex.org/W2005351388","https://openalex.org/W2005877813","https://openalex.org/W2014966556","https://openalex.org/W2018894845","https://openalex.org/W2024480558","https://openalex.org/W2025511610","https://openalex.org/W2027184678","https://openalex.org/W2032258894","https://openalex.org/W2034924082","https://openalex.org/W2036895498","https://openalex.org/W2046348943","https://openalex.org/W2047946709","https://openalex.org/W2050569993","https://openalex.org/W2052410273","https://openalex.org/W2075540003","https://openalex.org/W2102512629","https://openalex.org/W2106442422","https://openalex.org/W2107790922","https://openalex.org/W2117631891","https://openalex.org/W2145538332","https://openalex.org/W2154708754","https://openalex.org/W2163041591","https://openalex.org/W2471195113","https://openalex.org/W2566989546","https://openalex.org/W2596460477","https://openalex.org/W2614598335","https://openalex.org/W2736174670","https://openalex.org/W2748760010","https://openalex.org/W2753450037","https://openalex.org/W2761892148","https://openalex.org/W2897154327","https://openalex.org/W2910488153","https://openalex.org/W2918105292","https://openalex.org/W2935402618","https://openalex.org/W2949084244","https://openalex.org/W3015330778","https://openalex.org/W3185637748","https://openalex.org/W3203271059","https://openalex.org/W3206727289"],"related_works":["https://openalex.org/W2066977311","https://openalex.org/W244190868","https://openalex.org/W2513719710","https://openalex.org/W2039707037","https://openalex.org/W2012648118","https://openalex.org/W1979769767","https://openalex.org/W2237756197","https://openalex.org/W1998660008","https://openalex.org/W2041757243","https://openalex.org/W2727979924"],"abstract_inverted_index":{"Complexes":[0],"[PdL2Cl2]":[1],"(I)":[2],"and":[3,11,19,46,88],"[PdL2\u0412r2]":[4],"(II)":[5],"(L":[6],"is":[7,28,40,75],"5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione)":[8],"are":[9],"synthesized":[10,65],"characterized":[12],"by":[13,42],"spectral":[14],"methods":[15],"(1\u041d,":[16],"13\u0421":[17],"NMR":[18],"IR":[20],"spectroscopy).":[21],"The":[22,60],"crystal":[23],"structure":[24],"of":[25,50,63,72,83],"complex":[26],"I":[27],"determined":[29],"(CIF":[30],"file":[31],"\u0421\u0421D\u0421":[32],"no.":[33],"2233053)":[34],"in":[35,54,68,77],"which":[36],"the":[37,64,69,80,84],"palladium":[38,86],"atom":[39],"coordinated":[41],"two":[43,47,51],"halide":[44],"ions":[45],"sulfur":[48],"atoms":[49],"ligands":[52],"L":[53],"a":[55],"distorted":[56],"square":[57],"planar":[58],"geometry.":[59],"catalytic":[61,81],"activity":[62,82],"palladium(II)":[66],"complexes":[67],"model":[70],"epoxidation":[71],"allyl":[73],"alcohol":[74],"estimated":[76],"comparison":[78],"with":[79],"corresponding":[85],"halides":[87],"titanium-containing":[89],"zeolite":[90],"TS-1.":[91]},"counts_by_year":[],"updated_date":"2026-10-08T09:06:37.294493","created_date":"2024-08-02T00:00:00"}