{"id":"https://openalex.org/W4391054652","doi":"https://doi.org/10.18596/jotcsa.1325480","title":"Photo-Induced Tautomerism of Isocytosine in Aqueous Solution when Irradiated with UVC Light","display_name":"Photo-Induced Tautomerism of Isocytosine in Aqueous Solution when Irradiated with UVC Light","publication_year":2024,"publication_date":"2024-01-20","ids":{"openalex":"https://openalex.org/W4391054652","doi":"https://doi.org/10.18596/jotcsa.1325480"},"language":"en","primary_location":{"id":"doi:10.18596/jotcsa.1325480","doi":"https://doi.org/10.18596/jotcsa.1325480","is_oa":true,"landing_page_url":"https://doi.org/10.18596/jotcsa.1325480","pdf_url":null,"source":{"id":"https://openalex.org/S2739349281","display_name":"Journal of the Turkish Chemical Society Section A Chemistry","issn_l":"2149-0120","issn":["2149-0120"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["doaj","poland-20","russia-white-list-3","tr-dizin"],"host_organization":"https://openalex.org/P4310318398","host_organization_name":"Turkish Chemical Society","host_organization_lineage":["https://openalex.org/P4310318398"],"host_organization_lineage_names":["Turkish Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Turkish Chemical Society Section A: Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://dergipark.org.tr/tr/pub/jotcsa/issue/80874/1325480","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5032115005","display_name":"Tsvetina D. Cherneva","orcid":"https://orcid.org/0000-0003-2500-0667","observed_orcids":["https://orcid.org/0000-0003-2500-0667"]},"institutions":[{"id":"https://openalex.org/I192878625","display_name":"Plovdiv University","ror":"https://ror.org/0545p3742","country_code":"BG","type":"education","lineage":["https://openalex.org/I192878625"]}],"countries":["BG"],"is_corresponding":false,"raw_author_name":"Tsvetina CHERNEVA","raw_affiliation_strings":["University of Plovdiv"],"raw_orcid":"https://orcid.org/0000-0003-2500-0667","affiliations":[{"raw_affiliation_string":"University of Plovdiv","institution_ids":["https://openalex.org/I192878625"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073617517","display_name":"Mina Mihaylova Todorova","orcid":"https://orcid.org/0000-0002-0850-0902","observed_orcids":["https://orcid.org/0000-0002-0850-0902"]},"institutions":[{"id":"https://openalex.org/I192878625","display_name":"Plovdiv University","ror":"https://ror.org/0545p3742","country_code":"BG","type":"education","lineage":["https://openalex.org/I192878625"]}],"countries":["BG"],"is_corresponding":false,"raw_author_name":"Mina TODOROVA","raw_affiliation_strings":["University of Plovdiv"],"raw_orcid":"https://orcid.org/0000-0002-0850-0902","affiliations":[{"raw_affiliation_string":"University of Plovdiv","institution_ids":["https://openalex.org/I192878625"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063226623","display_name":"Rumyana Bakalska","orcid":"https://orcid.org/0000-0001-8638-8111","observed_orcids":["https://orcid.org/0000-0001-8638-8111"]},"institutions":[{"id":"https://openalex.org/I192878625","display_name":"Plovdiv University","ror":"https://ror.org/0545p3742","country_code":"BG","type":"education","lineage":["https://openalex.org/I192878625"]}],"countries":["BG"],"is_corresponding":false,"raw_author_name":"Rumyana BAKALSKA","raw_affiliation_strings":["University of Plovdiv"],"raw_orcid":"https://orcid.org/0000-0001-8638-8111","affiliations":[{"raw_affiliation_string":"University of Plovdiv","institution_ids":["https://openalex.org/I192878625"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067630672","display_name":"Vassil Borisov Delchev","orcid":"https://orcid.org/0000-0002-8305-413X","observed_orcids":["https://orcid.org/0000-0002-8305-413X"]},"institutions":[{"id":"https://openalex.org/I192878625","display_name":"Plovdiv University","ror":"https://ror.org/0545p3742","country_code":"BG","type":"education","lineage":["https://openalex.org/I192878625"]}],"countries":["BG"],"is_corresponding":true,"raw_author_name":"Vassil DELCHEV","raw_affiliation_strings":["University of Plovdiv"],"raw_orcid":"https://orcid.org/0000-0002-8305-413X","affiliations":[{"raw_affiliation_string":"University of Plovdiv","institution_ids":["https://openalex.org/I192878625"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5067630672"],"corresponding_institution_ids":["https://openalex.org/I192878625"],"apc_list":null,"apc_paid":null,"fwci":0.273,"has_fulltext":true,"cited_by_count":2,"citation_normalized_percentile":{"value":0.29838399,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":95},"biblio":{"volume":"11","issue":"1","first_page":"321","last_page":"330"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9854000210762024,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9854000210762024,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.005100000184029341,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.004999999888241291,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/isocytosine","display_name":"isocytosine","score":0.9909999966621399},{"id":"https://openalex.org/keywords/phototautomerism","display_name":"phototautomerism","score":0.8619999885559082},{"id":"https://openalex.org/keywords/uv-c-irradiation","display_name":"UV-C irradiation","score":0.9769999980926514},{"id":"https://openalex.org/keywords/aqueous-solutions","display_name":"aqueous solutions","score":0.9649999737739563},{"id":"https://openalex.org/keywords/excited-state-proton-transfer","display_name":"excited-state proton transfer","score":0.6859999895095825},{"id":"https://openalex.org/keywords/conical-intersections","display_name":"conical intersections","score":0.8019999861717224},{"id":"https://openalex.org/keywords/water-catalysis","display_name":"water catalysis","score":0.7829999923706055},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7580000162124634}],"concepts":[{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.8321431875228882},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.720020592212677},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.7096762657165527},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6701128482818604},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.6659167408943176},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.5881614089012146},{"id":"https://openalex.org/C111233374","wikidata":"https://www.wikidata.org/wiki/Q334640","display_name":"Tautomer","level":2,"score":0.5280143618583679},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5092769861221313},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.5070898532867432},{"id":"https://openalex.org/C111337013","wikidata":"https://www.wikidata.org/wiki/Q2737837","display_name":"Irradiation","level":2,"score":0.4891856014728546},{"id":"https://openalex.org/C84551667","wikidata":"https://www.wikidata.org/wiki/Q155640","display_name":"Potential energy","level":2,"score":0.4707014560699463},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.30473488569259644},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.2996706962585449},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.15116456151008606},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.1004757285118103},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.09972512722015381},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08947935700416565},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.18596/jotcsa.1325480","doi":"https://doi.org/10.18596/jotcsa.1325480","is_oa":true,"landing_page_url":"https://doi.org/10.18596/jotcsa.1325480","pdf_url":null,"source":{"id":"https://openalex.org/S2739349281","display_name":"Journal of the Turkish Chemical Society Section A Chemistry","issn_l":"2149-0120","issn":["2149-0120"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["doaj","poland-20","russia-white-list-3","tr-dizin"],"host_organization":"https://openalex.org/P4310318398","host_organization_name":"Turkish Chemical Society","host_organization_lineage":["https://openalex.org/P4310318398"],"host_organization_lineage_names":["Turkish Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Turkish Chemical Society Section A: Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:dergipark.org.tr:article/1325480","doi":null,"is_oa":true,"landing_page_url":"https://dergipark.org.tr/tr/pub/jotcsa/issue/80874/1325480","pdf_url":"https://dergipark.org.tr/tr/pub/jotcsa/issue/80874/1325480","source":{"id":"https://openalex.org/S2739349281","display_name":"Journal of the Turkish Chemical Society Section A Chemistry","issn_l":"2149-0120","issn":["2149-0120"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["doaj","poland-20","russia-white-list-3","tr-dizin"],"host_organization":"https://openalex.org/P4310318398","host_organization_name":"Turkish Chemical Society","host_organization_lineage":["https://openalex.org/P4310318398"],"host_organization_lineage_names":["Turkish Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Turkish Chemical Society Section A: Chemistry","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:doaj.org/article:4e6cc5cce4484b169e81d1ef97dcccf2","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/4e6cc5cce4484b169e81d1ef97dcccf2","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 11, Iss 1, Pp 321-330 (2024)","raw_type":"article"}],"best_oa_location":{"id":"pmh:oai:dergipark.org.tr:article/1325480","doi":null,"is_oa":true,"landing_page_url":"https://dergipark.org.tr/tr/pub/jotcsa/issue/80874/1325480","pdf_url":"https://dergipark.org.tr/tr/pub/jotcsa/issue/80874/1325480","source":{"id":"https://openalex.org/S2739349281","display_name":"Journal of the Turkish Chemical Society Section A Chemistry","issn_l":"2149-0120","issn":["2149-0120"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["doaj","poland-20","russia-white-list-3","tr-dizin"],"host_organization":"https://openalex.org/P4310318398","host_organization_name":"Turkish Chemical Society","host_organization_lineage":["https://openalex.org/P4310318398"],"host_organization_lineage_names":["Turkish Chemical Society"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Turkish Chemical Society Section A: Chemistry","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5889412503","display_name":null,"funder_award_id":"D01-168","funder_id":"https://openalex.org/F4320321843","funder_display_name":"Bulgarian National Science Fund"},{"id":"https://openalex.org/G7139850194","display_name":null,"funder_award_id":"D01-168/28.07.2022","funder_id":"https://openalex.org/F4320321843","funder_display_name":"Bulgarian National Science Fund"},{"id":"https://openalex.org/G7184182950","display_name":null,"funder_award_id":"\u041aP-06-N59/7","funder_id":"https://openalex.org/F4320321843","funder_display_name":"Bulgarian National Science Fund"}],"funders":[{"id":"https://openalex.org/F4320321843","display_name":"Bulgarian National Science Fund","ror":"https://ror.org/05eg49r29"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4391054652.pdf","grobid_xml":"https://content.openalex.org/works/W4391054652.grobid-xml"},"referenced_works_count":34,"referenced_works":["https://openalex.org/W65588820","https://openalex.org/W1967203418","https://openalex.org/W1967556854","https://openalex.org/W1975155744","https://openalex.org/W1990734020","https://openalex.org/W1993449464","https://openalex.org/W2001054421","https://openalex.org/W2008916603","https://openalex.org/W2010868305","https://openalex.org/W2012277121","https://openalex.org/W2023271753","https://openalex.org/W2025650018","https://openalex.org/W2035411416","https://openalex.org/W2040449723","https://openalex.org/W2041611333","https://openalex.org/W2043395118","https://openalex.org/W2045508665","https://openalex.org/W2045547630","https://openalex.org/W2053242843","https://openalex.org/W2063663126","https://openalex.org/W2068228867","https://openalex.org/W2085769008","https://openalex.org/W2088430073","https://openalex.org/W2095474273","https://openalex.org/W2136243875","https://openalex.org/W2142861346","https://openalex.org/W2143981217","https://openalex.org/W2144783661","https://openalex.org/W2171083607","https://openalex.org/W2178006639","https://openalex.org/W2324915806","https://openalex.org/W2954306074","https://openalex.org/W3017260797","https://openalex.org/W4318205565"],"related_works":["https://openalex.org/W4387904206","https://openalex.org/W2954306074","https://openalex.org/W4386407493","https://openalex.org/W2883700538","https://openalex.org/W2554235816","https://openalex.org/W2329586548","https://openalex.org/W2150796172","https://openalex.org/W961302006","https://openalex.org/W2334670843","https://openalex.org/W2035411416"],"abstract_inverted_index":{"It":[0,29,93,117],"was":[1,30],"found":[2,127],"that":[3],"the":[4,19,37,51,56,85,90,96,120,129,139,143,149],"irradiation":[5],"of":[6,9,18,25,45,50,73],"aqueous":[7],"solution":[8],"isocytosine":[10],"with":[11,21,41],"UVC":[12],"light":[13,39],"provokes":[14],"an":[15,106],"oxo-hydroxy":[16],"phototautomerism":[17,52],"compound":[20],"a":[22,32,42,68,74,111,115],"rate":[23,43],"constant":[24,44],"5.29\u00d7":[26],"10-3":[27],"min-1.":[28,47],"observed":[31],"backward":[33],"reaction,":[34],"after":[35],"removing":[36],"UV":[38],"source,":[40],"0.12\u00d710-3":[46],"Two":[48],"mechanisms":[49],"were":[53,82],"investigated":[54],"at":[55,84],"B3LYP/aug-cc-pVDZ":[57],"theoretical":[58,87],"level":[59,88],"in":[60,89,142,148],"water":[61,112,135],"surroundings":[62],"(PCM).":[63],"The":[64,101,134],"first":[65],"one":[66],"showed":[67],"consecutive":[69],"dissociation":[70],"and":[71],"association":[72],"proton":[75],"through":[76],"conical":[77],"intersections":[78],"S0/S1":[79],"whose":[80],"structures":[81],"located":[83],"same":[86],"gas":[91],"phase.":[92],"occurs":[94,118],"along":[95,119],"1\u03c0\u03c3*":[97],"excited-state":[98,107,122],"reaction":[99,123],"pathway.":[100],"more":[102],"probable":[103],"mechanism":[104],"includes":[105],"H-transfer":[108],"supported":[109],"by":[110],"molecule":[113,136],"as":[114,146],"catalyst.":[116],"1\u03c0\u03c0*":[121],"pathway":[124],"which":[125],"we":[126],"over":[128],"IRC":[130],"ground-state":[131],"energy":[132,140],"curve.":[133],"drastically":[137],"reduces":[138],"barrier":[141],"ground":[144],"state":[145],"well":[147],"excited":[150],"state.":[151]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1}],"updated_date":"2026-11-13T13:42:25.865203","created_date":"2024-01-21T00:00:00"}
