{"id":"https://openalex.org/W4390618591","doi":"https://doi.org/10.1021/acs.iecr.3c02619","title":"Applying the Bayesian Technique, Statistical Analysis, and the Maximum Adsorption Capacity in a Deterministic Way for Caffeine Removal by Adsorption: Kinetic and Isotherm Modeling","display_name":"Applying the Bayesian Technique, Statistical Analysis, and the Maximum Adsorption Capacity in a Deterministic Way for Caffeine Removal by Adsorption: Kinetic and Isotherm Modeling","publication_year":2024,"publication_date":"2024-01-05","ids":{"openalex":"https://openalex.org/W4390618591","doi":"https://doi.org/10.1021/acs.iecr.3c02619"},"language":"en","primary_location":{"id":"doi:10.1021/acs.iecr.3c02619","doi":"https://doi.org/10.1021/acs.iecr.3c02619","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.iecr.3c02619","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial & Engineering Chemistry Research","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5068813589","display_name":"J\u00falia Toffoli de Oliveira","orcid":"https://orcid.org/0000-0002-5741-8454","observed_orcids":["https://orcid.org/0000-0002-5741-8454"]},"institutions":[{"id":"https://openalex.org/I130442723","display_name":"Universidade Federal do Rio Grande do Sul","ror":"https://ror.org/041yk2d64","country_code":"BR","type":"education","lineage":["https://openalex.org/I130442723"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"J\u00falia Toffoli de Oliveira","raw_affiliation_strings":["Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil"],"raw_orcid":"https://orcid.org/0000-0002-5741-8454","affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil","institution_ids":["https://openalex.org/I130442723"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020515001","display_name":"Keila Guerra Pacheco Nunes","orcid":"https://orcid.org/0000-0001-7332-096X","observed_orcids":["https://orcid.org/0000-0001-7332-096X"]},"institutions":[{"id":"https://openalex.org/I130442723","display_name":"Universidade Federal do Rio Grande do Sul","ror":"https://ror.org/041yk2d64","country_code":"BR","type":"education","lineage":["https://openalex.org/I130442723"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Keila Guerra Pacheco Nunes","raw_affiliation_strings":["Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil","institution_ids":["https://openalex.org/I130442723"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003259907","display_name":"Diego Cardoso Estumano","orcid":"https://orcid.org/0000-0003-4318-4455","observed_orcids":["https://orcid.org/0000-0003-4318-4455"]},"institutions":[{"id":"https://openalex.org/I59606676","display_name":"Universidade Federal do Par\u00e1","ror":"https://ror.org/03q9sr818","country_code":"BR","type":"education","lineage":["https://openalex.org/I59606676"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Diego Cardoso Estumano","raw_affiliation_strings":["Faculty of Biotechnology, Federal University of Par\u00e1, Augusto Corr\u00eaa Street 01, Bel\u00e9m, Par\u00e1 66075-110, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Biotechnology, Federal University of Par\u00e1, Augusto Corr\u00eaa Street 01, Bel\u00e9m, Par\u00e1 66075-110, Brazil","institution_ids":["https://openalex.org/I59606676"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089835585","display_name":"Liliana Amaral F\u00e9ris","orcid":"https://orcid.org/0000-0002-5900-4474","observed_orcids":["https://orcid.org/0000-0002-5900-4474"]},"institutions":[{"id":"https://openalex.org/I130442723","display_name":"Universidade Federal do Rio Grande do Sul","ror":"https://ror.org/041yk2d64","country_code":"BR","type":"education","lineage":["https://openalex.org/I130442723"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Liliana Amaral F\u00e9ris","raw_affiliation_strings":["Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street 2777, Porto Alegre, Rio Grande do Sul90035-007, Brazil","institution_ids":["https://openalex.org/I130442723"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5068813589"],"corresponding_institution_ids":["https://openalex.org/I130442723"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.558,"has_fulltext":false,"cited_by_count":32,"citation_normalized_percentile":{"value":0.93753507,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"63","issue":"3","first_page":"1530","last_page":"1545"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10016","display_name":"Adsorption and biosorption for pollutant removal","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10016","display_name":"Adsorption and biosorption for pollutant removal","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13604","display_name":"Adsorption, diffusion, and thermodynamic properties of materials","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11188","display_name":"Coagulation and Flocculation Studies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/caffeine-removal","display_name":"caffeine removal","score":0.8679999709129333},{"id":"https://openalex.org/keywords/adsorption","display_name":"adsorption","score":0.8500000238418579},{"id":"https://openalex.org/keywords/granular-activated-carbon","display_name":"granular activated carbon","score":0.9919999837875366},{"id":"https://openalex.org/keywords/bayesian-model-selection","display_name":"Bayesian model selection","score":0.7110000252723694},{"id":"https://openalex.org/keywords/adsorption-kinetics","display_name":"adsorption kinetics","score":0.8299999833106995},{"id":"https://openalex.org/keywords/adsorption-isotherms","display_name":"adsorption isotherms","score":0.9539999961853027},{"id":"https://openalex.org/keywords/maximum-adsorption-capacity","display_name":"maximum adsorption capacity","score":0.9390000104904175},{"id":"https://openalex.org/keywords/pseudo-first-order-kinetics","display_name":"pseudo-first-order kinetics","score":0.7319999933242798},{"id":"https://openalex.org/keywords/pseudo-second-order-kinetics","display_name":"pseudo-second-order kinetics","score":0.9919999837875366},{"id":"https://openalex.org/keywords/elovich-model","display_name":"Elovich model","score":0.9959999918937683},{"id":"https://openalex.org/keywords/langmuir-isotherm","display_name":"Langmuir isotherm","score":0.9660000205039978},{"id":"https://openalex.org/keywords/freundlich-isotherm","display_name":"Freundlich isotherm","score":0.9300000071525574},{"id":"https://openalex.org/keywords/redlich-peterson-model","display_name":"Redlich-Peterson isotherm","score":0.968999981880188},{"id":"https://openalex.org/keywords/sips-isotherm","display_name":"Sips isotherm","score":0.9990000128746033},{"id":"https://openalex.org/keywords/temperature-effects","display_name":"temperature effects","score":0.7760000228881836},{"id":"https://openalex.org/keywords/ph-effect","display_name":"pH effect","score":0.7009999752044678}],"concepts":[{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.8093376159667969},{"id":"https://openalex.org/C112825004","wikidata":"https://www.wikidata.org/wiki/Q1924292","display_name":"Freundlich equation","level":3,"score":0.7970893383026123},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.6535390019416809},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.5822277665138245},{"id":"https://openalex.org/C2779647737","wikidata":"https://www.wikidata.org/wiki/Q190878","display_name":"Activated carbon","level":3,"score":0.5464616417884827},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5339065790176392},{"id":"https://openalex.org/C12143843","wikidata":"https://www.wikidata.org/wiki/Q6486358","display_name":"Langmuir adsorption model","level":3,"score":0.49016842246055603},{"id":"https://openalex.org/C115958267","wikidata":"https://www.wikidata.org/wiki/Q464196","display_name":"Langmuir","level":3,"score":0.48259246349334717},{"id":"https://openalex.org/C18762648","wikidata":"https://www.wikidata.org/wiki/Q42213","display_name":"Work (physics)","level":2,"score":0.43693289160728455},{"id":"https://openalex.org/C186060115","wikidata":"https://www.wikidata.org/wiki/Q30336093","display_name":"Biological system","level":1,"score":0.37668582797050476},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.3701495826244354},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.34454014897346497},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3222622275352478},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.16213375329971313},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.1580738127231598},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.iecr.3c02619","doi":"https://doi.org/10.1021/acs.iecr.3c02619","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.iecr.3c02619","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial & Engineering Chemistry Research","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321091","display_name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","ror":"https://ror.org/00x0ma614"},{"id":"https://openalex.org/F4320322025","display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","ror":"https://ror.org/03swz6y49"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":73,"referenced_works":["https://openalex.org/W303053514","https://openalex.org/W1964077077","https://openalex.org/W1970235305","https://openalex.org/W1972322214","https://openalex.org/W1975993854","https://openalex.org/W1979275879","https://openalex.org/W1981903823","https://openalex.org/W2001629563","https://openalex.org/W2002899984","https://openalex.org/W2005995298","https://openalex.org/W2027086787","https://openalex.org/W2040153588","https://openalex.org/W2055552433","https://openalex.org/W2056760934","https://openalex.org/W2064521815","https://openalex.org/W2067705099","https://openalex.org/W2073239074","https://openalex.org/W2085504117","https://openalex.org/W2089798714","https://openalex.org/W2114383891","https://openalex.org/W2138309709","https://openalex.org/W2141837911","https://openalex.org/W2142635246","https://openalex.org/W2146855196","https://openalex.org/W2253162998","https://openalex.org/W2260817582","https://openalex.org/W2279936274","https://openalex.org/W2326993032","https://openalex.org/W2339764516","https://openalex.org/W2343883968","https://openalex.org/W2477330071","https://openalex.org/W2530721703","https://openalex.org/W2557727477","https://openalex.org/W2603965622","https://openalex.org/W2737029506","https://openalex.org/W2744407388","https://openalex.org/W2752561115","https://openalex.org/W2754661875","https://openalex.org/W2775070756","https://openalex.org/W2778195071","https://openalex.org/W2886973280","https://openalex.org/W2903569031","https://openalex.org/W2949408804","https://openalex.org/W2951724169","https://openalex.org/W2981043521","https://openalex.org/W2997725604","https://openalex.org/W3008601735","https://openalex.org/W3009577078","https://openalex.org/W3011872589","https://openalex.org/W3020909596","https://openalex.org/W3044079492","https://openalex.org/W3044528194","https://openalex.org/W3048329703","https://openalex.org/W3090241008","https://openalex.org/W3091769338","https://openalex.org/W3095481630","https://openalex.org/W3095961857","https://openalex.org/W3116361517","https://openalex.org/W3127070647","https://openalex.org/W3152107981","https://openalex.org/W3155283510","https://openalex.org/W3171593217","https://openalex.org/W3186577911","https://openalex.org/W3189200869","https://openalex.org/W4225139324","https://openalex.org/W4280525585","https://openalex.org/W4283661342","https://openalex.org/W4309090455","https://openalex.org/W4309179935","https://openalex.org/W4366977544","https://openalex.org/W4367309523","https://openalex.org/W4376648919","https://openalex.org/W4378364421"],"related_works":["https://openalex.org/W4367309523","https://openalex.org/W7037485252","https://openalex.org/W4292314405","https://openalex.org/W3171593217","https://openalex.org/W4391316910","https://openalex.org/W4394819691","https://openalex.org/W4406183038","https://openalex.org/W3116361517","https://openalex.org/W7120879444","https://openalex.org/W2530721703"],"abstract_inverted_index":{"The":[0,79,109,141,182,256],"present":[1],"work":[2],"evaluates":[3],"the":[4,17,21,25,31,34,60,86,88,92,124,186,211,230,233,241,246,249,261,265,271,281,287,290,295,301,308,319,322,335,357,364,367],"Bayesian":[5,242],"statistical":[6,136,194],"method":[7],"in":[8,48,85,91,223,227,339,355],"adsorption,":[9],"kinetic,":[10,102],"and":[11,56,59,73,94,120,122,129,139,174,192,200,207,216,237,277,280,314,324],"isotherm":[12,208],"studies":[13,209],"for":[14,123,204,252,270,283],"estimation":[15],"of":[16,24,36,153,157,213,232,248,273,326,359,366],"parameters":[18],"along":[19],"with":[20,185],"experimental":[22,32,99,266,345],"data":[23,267],"solid\u2019s":[26],"maximum":[27,80,187],"adsorption":[28,81,188,328],"capacity.":[29],"For":[30,286],"data,":[33],"removal":[35,152],"caffeine":[37,360],"(CAF)":[38],"on":[39,363],"granular":[40],"activated":[41],"carbon":[42],"(GAC),":[43],"previously":[44],"characterized,":[45],"was":[46,83,146,235,304],"evaluated":[47,226],"five":[49,135,193],"different":[50],"temperatures":[51,225,272,310],"(288,":[52],"298,":[53,275],"308,":[54],"313,":[55,313],"323":[57,284,315,353],"K),":[58,316],"following":[61],"operational":[62],"conditions":[63],"were":[64,113,132,219],"investigated:":[65],"pH;":[66],"adsorbent":[67],"concentration":[68,156],"(":[69,76],"C":[70,175],"GAC":[71,176,330],"),":[72],"contact":[74],"time":[75],"t":[77,170],").":[78,108],"capacity":[82,189],"estimated":[84],"models,":[87],"usual":[89],"approach":[90,203],"literature,":[93],"not":[95],"by":[96,165,334],"applying":[97,166],"its":[98],"value":[100],"(deterministic:":[101],"q":[103,106,214,217,346],"e;":[104],"isotherm,":[105],"max":[107,218,347],"kinetic":[110,206,257],"models":[111,234],"applied":[112],"pseudo-first":[114],"order":[115,118],"(PFO),":[116],"pseudo-second":[117],"(PSO),":[119],"Elovich,":[121],"isotherms,":[125,289],"Langmuir,":[126],"Freundlich,":[127],"Redlich\u2013Peterson,":[128],"Sips,":[130],"which":[131,342],"selected":[133],"through":[134,240],"metrics":[137,243],"(classical":[138],"Bayesian).":[140],"results":[142],"showed":[143,259],"that":[144,260,321],"it":[145],"possible":[147,239],"to":[148,245,318],"obtain":[149],"a":[150,197],"CAF":[151,327],"90%":[154],"(residual":[155],"0.978":[158],"mg\u00b7L":[159],"\u20131":[160,180,351],")":[161],"at":[162,297,307,352],"room":[163],"temperature":[164],"pH":[167],"=":[168,171,177,348],"6,":[169],"120":[172],"min,":[173],"10":[178],"g\u00b7L":[179],".":[181,255],"proposed":[183],"method,":[184],"used":[190],"deterministically":[191],"metrics,":[195],"is":[196,331],"more":[198,268,305],"reliable":[199],"accurate":[201],"resolution":[202],"both":[205],"because":[210],"values":[212,250],"e":[215],"over-":[220],"or":[221],"underestimated":[222],"all":[224],"this":[228],"work;":[229],"selection":[231],"altered":[236],"only":[238],"due":[244],"proximity":[247],"obtained":[251,343],"R":[253],"2":[254],"study":[258],"Elovich":[262],"model":[263,292,303],"fitted":[264,294],"adequately":[269],"288,":[274],"303,":[276,312],"313":[278],"K":[279],"PFO":[282],"K.":[285],"equilibrium":[288,325],"Langmuir":[291],"best":[293],"system":[296],"288":[298],"K,":[299],"while":[300],"Redlich\u2013Peterson":[302],"adequate":[306],"remaining":[309],"(298,":[311],"leading":[317],"conclusion":[320],"kinetics":[323],"onto":[329],"directly":[332],"affected":[333],"temperature,":[336],"being":[337],"enhanced":[338],"higher":[340],"temperatures,":[341],"an":[344],"24.85":[349],"mg\u00b7g":[350],"K;":[354],"addition,":[356],"incorporation":[358],"occurs,":[361],"mainly,":[362],"surface":[365],"solid.":[368]},"counts_by_year":[{"year":2026,"cited_by_count":12},{"year":2025,"cited_by_count":17},{"year":2024,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2024-01-07T00:00:00"}