{"id":"https://openalex.org/W4390054856","doi":"https://doi.org/10.1002/app.55076","title":"Cationic polymerization of isobutylene by AlCl3 in n\u2010hexane and toluene at mild temperatures","display_name":"Cationic polymerization of isobutylene by AlCl3 in n\u2010hexane and toluene at mild temperatures","publication_year":2023,"publication_date":"2023-12-20","ids":{"openalex":"https://openalex.org/W4390054856","doi":"https://doi.org/10.1002/app.55076"},"language":"en","primary_location":{"id":"doi:10.1002/app.55076","doi":"https://doi.org/10.1002/app.55076","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.55076","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5089803689","display_name":"J\u00e9ssica Bentes Alves","orcid":"https://orcid.org/0000-0003-4324-2475","observed_orcids":["https://orcid.org/0000-0003-4324-2475"]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"J\u00e9ssica Bentes","raw_affiliation_strings":["Programa de Engenharia de Nanotecnologia/COPPE Universidade Federal do Rio de Janeiro Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":"https://orcid.org/0000-0003-4324-2475","affiliations":[{"raw_affiliation_string":"Programa de Engenharia de Nanotecnologia/COPPE Universidade Federal do Rio de Janeiro Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005143698","display_name":"Lys H. R. Mangia","orcid":"https://orcid.org/0000-0001-5614-2823","observed_orcids":["https://orcid.org/0000-0001-5614-2823"]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Lys H. R. Mangia","raw_affiliation_strings":["Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046164455","display_name":"Mateus K. Vasconcelos","orcid":"https://orcid.org/0000-0003-3716-9806","observed_orcids":["https://orcid.org/0000-0003-3716-9806"]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Mateus K. Vasconcelos","raw_affiliation_strings":["Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043625551","display_name":"Maxmiliano Tatagiba","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Maxmiliano Tatagiba","raw_affiliation_strings":["Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066408580","display_name":"Juliana Fidalgo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Juliana Fidalgo","raw_affiliation_strings":["Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082118136","display_name":"Daniela Campos","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Daniela Campos","raw_affiliation_strings":["Escola de Qu\u00edmica, Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Escola de Qu\u00edmica, Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016482828","display_name":"M\u00e1rcio V. Rebou\u00e7as","orcid":"https://orcid.org/0000-0002-8094-9587","observed_orcids":["https://orcid.org/0000-0002-8094-9587"]},"institutions":[{"id":"https://openalex.org/I4210159212","display_name":"Braskem (Brazil)","ror":"https://ror.org/05wetj454","country_code":"BR","type":"company","lineage":["https://openalex.org/I4210159212"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Marcio das V. Rebou\u00e7as","raw_affiliation_strings":["Braskem S. A  Cama\u00e7ari Bahia Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Braskem S. A  Cama\u00e7ari Bahia Brazil","institution_ids":["https://openalex.org/I4210159212"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005553729","display_name":"Marcio Henrique dos S. Andrade","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159212","display_name":"Braskem (Brazil)","ror":"https://ror.org/05wetj454","country_code":"BR","type":"company","lineage":["https://openalex.org/I4210159212"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Marcio Henrique dos S. Andrade","raw_affiliation_strings":["Braskem S. A  Cama\u00e7ari Bahia Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Braskem S. A  Cama\u00e7ari Bahia Brazil","institution_ids":["https://openalex.org/I4210159212"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5101767121","display_name":"Jos\u00e9 Carlos Pinto","orcid":"https://orcid.org/0000-0003-2631-1811","observed_orcids":["https://orcid.org/0000-0003-2631-1811"]},"institutions":[{"id":"https://openalex.org/I122140584","display_name":"Universidade Federal do Rio de Janeiro","ror":"https://ror.org/03490as77","country_code":"BR","type":"education","lineage":["https://openalex.org/I122140584"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"Jos\u00e9 Carlos Pinto","raw_affiliation_strings":["Escola de Qu\u00edmica, Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Escola de Qu\u00edmica, Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]},{"raw_affiliation_string":"Programa de Engenharia Qu\u00edmica/COPPE Universidade Federal do Rio de Janeiro  Rio de Janeiro Rio de Janeiro Brazil","institution_ids":["https://openalex.org/I122140584"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5101767121"],"corresponding_institution_ids":["https://openalex.org/I122140584"],"apc_list":{"value":4430,"currency":"USD","value_usd":4430},"apc_paid":null,"fwci":0.3892,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.39781468,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":96},"biblio":{"volume":"141","issue":"11","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8184000253677368,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8184000253677368,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.11599999666213989,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.02759999968111515,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cationic-polymerization","display_name":"cationic polymerization","score":0.9100000262260437},{"id":"https://openalex.org/keywords/isobutene","display_name":"isobutene","score":0.9660000205039978},{"id":"https://openalex.org/keywords/polyisobutylene","display_name":"polyisobutylene","score":0.9629999995231628},{"id":"https://openalex.org/keywords/vinyl-content","display_name":"vinyl content","score":0.6010000109672546},{"id":"https://openalex.org/keywords/toluene-solvent","display_name":"toluene solvent","score":0.6779999732971191},{"id":"https://openalex.org/keywords/hexane-solvent","display_name":"hexane solvent","score":0.9750000238418579},{"id":"https://openalex.org/keywords/low-temperature-polymerization","display_name":"low-temperature polymerization","score":0.6990000009536743},{"id":"https://openalex.org/keywords/polymerization-kinetics","display_name":"polymerization kinetics","score":0.4000000059604645}],"concepts":[{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.9035850763320923},{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.7462737560272217},{"id":"https://openalex.org/C2777077568","wikidata":"https://www.wikidata.org/wiki/Q150440","display_name":"Hexane","level":2,"score":0.7338545322418213},{"id":"https://openalex.org/C2776906966","wikidata":"https://www.wikidata.org/wiki/Q776976","display_name":"Isobutylene","level":4,"score":0.7132030725479126},{"id":"https://openalex.org/C2780493264","wikidata":"https://www.wikidata.org/wiki/Q63126578","display_name":"Vinyl ether","level":4,"score":0.644080638885498},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.5855617523193359},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5765568614006042},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5530070066452026},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5431879758834839},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5003340244293213},{"id":"https://openalex.org/C159937420","wikidata":"https://www.wikidata.org/wiki/Q17151990","display_name":"Living cationic polymerization","level":5,"score":0.4841516613960266},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3639771342277527},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.20124831795692444},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.11432620882987976}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/app.55076","doi":"https://doi.org/10.1002/app.55076","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.55076","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321091","display_name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","ror":"https://ror.org/00x0ma614"},{"id":"https://openalex.org/F4320322025","display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","ror":"https://ror.org/03swz6y49"},{"id":"https://openalex.org/F4320322749","display_name":"Funda\u00e7\u00e3o Carlos Chagas Filho de Amparo \u00e0 Pesquisa do Estado do Rio de Janeiro","ror":"https://ror.org/03kk0s825"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1498235692","https://openalex.org/W1969080424","https://openalex.org/W1991797713","https://openalex.org/W2000200384","https://openalex.org/W2002644370","https://openalex.org/W2008578017","https://openalex.org/W2021364841","https://openalex.org/W2027749384","https://openalex.org/W2033639715","https://openalex.org/W2063454710","https://openalex.org/W2071223190","https://openalex.org/W2085920104","https://openalex.org/W2090619601","https://openalex.org/W2111532539","https://openalex.org/W2119813990","https://openalex.org/W2120550894","https://openalex.org/W2166821034","https://openalex.org/W2320888537","https://openalex.org/W2322790920","https://openalex.org/W2473899602","https://openalex.org/W2509338071","https://openalex.org/W2523839660","https://openalex.org/W2581706370","https://openalex.org/W2607268225","https://openalex.org/W2767040144","https://openalex.org/W2789109550","https://openalex.org/W2794382346","https://openalex.org/W2796245484","https://openalex.org/W2886492486","https://openalex.org/W2955961875","https://openalex.org/W2969889497","https://openalex.org/W2970803844","https://openalex.org/W2981217290","https://openalex.org/W3186243008","https://openalex.org/W4296222957"],"related_works":["https://openalex.org/W2098784626","https://openalex.org/W4414298436","https://openalex.org/W4414575572","https://openalex.org/W2119813990","https://openalex.org/W2007621666","https://openalex.org/W2356825784","https://openalex.org/W2094791548","https://openalex.org/W2120550894","https://openalex.org/W3005279400","https://openalex.org/W1998645961"],"abstract_inverted_index":{"Abstract":[0],"This":[1],"study":[2,34],"aims":[3],"to":[4,9,118,163],"find":[5],"more":[6],"efficient":[7],"ways":[8],"manufacture":[10,164],"highly":[11],"reactive":[12],"polyisobutylene":[13],"(HRPIB)":[14],"and":[15,49,54,56,59,82,126,182,184,191],"modified":[16],"conventional":[17],"PIB":[18],"materials":[19],"(MCPIB)":[20],"industrially":[21],"with":[22,44,167,193],"high":[23,145,194],"vinyl":[24,68,91,103,169],"exo\u2010group":[25],"contents":[26,69,92,170],"through":[27],"cationic":[28],"polymerization":[29],"at":[30,174],"mild":[31,175],"temperatures.":[32],"The":[33,153],"performed":[35,98],"polymerizations":[36],"using":[37],"aluminum":[38],"trichloride":[39],"(AlCl3)":[40],"as":[41,84],"a":[42],"catalyst":[43],"different":[45],"nonpolar":[46,179],"solvents":[47,180],"(hexane":[48],"toluene),":[50],"reaction":[51,140],"temperatures":[52,176],"(10":[53],"30\u00b0C),":[55],"co\u2010catalysts":[57,189],"(water":[58,190],"dibutyl":[60],"ether":[61,134,146],"[DBE]).":[62],"At":[63],"30\u00b0C,":[64],"toluene":[65,81],"can":[66,159],"provide":[67],"above":[70,93,171],"30":[71],"mol%.":[72,107],"Particularly,":[73],"an":[74],"important":[75],"synergetic":[76],"effect":[77],"was":[78],"observed":[79],"between":[80],"ether,":[83],"corroborated":[85],"by":[86],"statistical":[87],"analyses,":[88],"resulting":[89],"in":[90,99,142,177,185],"50":[94,172],"mol%,":[95],"while":[96],"reactions":[97],"n\u2010hexane":[100],"provided":[101],"maximum":[102],"content":[104],"of":[105,124,131,133,139,144,187,196],"20":[106],"In":[108],"all":[109],"cases,":[110],"number":[111],"average":[112],"molar":[113],"masses":[114],"ranged":[115],"from":[116],"200":[117],"1000":[119],"Da,":[120],"which":[121],"are":[122],"typical":[123],"CPIB":[125],"MCPIB":[127,165],"materials.":[128],"Moreover,":[129],"addition":[130],"excess":[132],"indicated":[135,156],"the":[136],"likely":[137],"inhibition":[138],"rates":[141,195],"presence":[143,186],"concentrations":[147],"(\u22651.18":[148],"\u00d7":[149],"10":[150],"\u22121":[151],"mol/L).":[152],"obtained":[154],"results":[155],"that":[157],"AlCl3":[158],"be":[160],"used":[161],"successfully":[162],"products":[166],"terminal":[168],"mol%":[173],"common":[178,188],"(n\u2010hexane":[181],"toluene)":[183],"DBE)":[192],"reactions.":[197]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2023-12-22T00:00:00"}