{"id":"https://openalex.org/W4389946511","doi":"https://doi.org/10.1039/d3tb02472e","title":"Solvent-free synthesis of biostable segmented polyurethane shape memory polymers for biomedical applications","display_name":"Solvent-free synthesis of biostable segmented polyurethane shape memory polymers for biomedical applications","publication_year":2023,"publication_date":"2023-12-19","ids":{"openalex":"https://openalex.org/W4389946511","doi":"https://doi.org/10.1039/d3tb02472e","pmid":"https://pubmed.ncbi.nlm.nih.gov/38168979"},"language":"en","primary_location":{"id":"doi:10.1039/d3tb02472e","doi":"https://doi.org/10.1039/d3tb02472e","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3tb02472e","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2024/tb/d3tb02472e","source":{"id":"https://openalex.org/S2479884170","display_name":"Journal of Materials Chemistry B","issn_l":"2050-750X","issn":["2050-750X","2050-7518"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://pubs.rsc.org/en/content/articlepdf/2024/tb/d3tb02472e","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5061911090","display_name":"Maryam Ramezani","orcid":"https://orcid.org/0000-0002-5870-3097","observed_orcids":["https://orcid.org/0000-0002-5870-3097"]},"institutions":[{"id":"https://openalex.org/I70983195","display_name":"Syracuse University","ror":"https://ror.org/025r5qe02","country_code":"US","type":"education","lineage":["https://openalex.org/I70983195"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Maryam Ramezani","raw_affiliation_strings":["Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA","institution_ids":["https://openalex.org/I70983195"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005179560","display_name":"Dariya Getya","orcid":"https://orcid.org/0000-0003-0291-5944","observed_orcids":["https://orcid.org/0000-0003-0291-5944"]},"institutions":[{"id":"https://openalex.org/I1327163397","display_name":"State University of New York","ror":"https://ror.org/01q1z8k08","country_code":"US","type":"education","lineage":["https://openalex.org/I1327163397"]},{"id":"https://openalex.org/I157349981","display_name":"SUNY College of Environmental Science and Forestry","ror":"https://ror.org/00qv0tw17","country_code":"US","type":"education","lineage":["https://openalex.org/I157349981"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Dariya Getya","raw_affiliation_strings":["Department of Chemistry, State University of New York ESF, Syracuse, NY, USA","The Michael M. Szwarc Polymer Research Institute, Syracuse, NY, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, State University of New York ESF, Syracuse, NY, USA","institution_ids":["https://openalex.org/I1327163397","https://openalex.org/I157349981"]},{"raw_affiliation_string":"The Michael M. Szwarc Polymer Research Institute, Syracuse, NY, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079666177","display_name":"Ivan Gitsov","orcid":"https://orcid.org/0000-0001-7433-8571","observed_orcids":["https://orcid.org/0000-0001-7433-8571"]},"institutions":[{"id":"https://openalex.org/I1327163397","display_name":"State University of New York","ror":"https://ror.org/01q1z8k08","country_code":"US","type":"education","lineage":["https://openalex.org/I1327163397"]},{"id":"https://openalex.org/I157349981","display_name":"SUNY College of Environmental Science and Forestry","ror":"https://ror.org/00qv0tw17","country_code":"US","type":"education","lineage":["https://openalex.org/I157349981"]},{"id":"https://openalex.org/I70983195","display_name":"Syracuse University","ror":"https://ror.org/025r5qe02","country_code":"US","type":"education","lineage":["https://openalex.org/I70983195"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ivan Gitsov","raw_affiliation_strings":["Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA","Department of Chemistry, State University of New York ESF, Syracuse, NY, USA","The Michael M. Szwarc Polymer Research Institute, Syracuse, NY, USA"],"raw_orcid":"https://orcid.org/0000-0001-7433-8571","affiliations":[{"raw_affiliation_string":"Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA","institution_ids":["https://openalex.org/I70983195"]},{"raw_affiliation_string":"Department of Chemistry, State University of New York ESF, Syracuse, NY, USA","institution_ids":["https://openalex.org/I1327163397","https://openalex.org/I157349981"]},{"raw_affiliation_string":"The Michael M. Szwarc Polymer Research Institute, Syracuse, NY, USA","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5018219022","display_name":"Mary Beth Browning Monroe","orcid":"https://orcid.org/0000-0003-4540-5303","observed_orcids":["https://orcid.org/0000-0003-4540-5303"]},"institutions":[{"id":"https://openalex.org/I70983195","display_name":"Syracuse University","ror":"https://ror.org/025r5qe02","country_code":"US","type":"education","lineage":["https://openalex.org/I70983195"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Mary Beth Browning Monroe","raw_affiliation_strings":["Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA"],"raw_orcid":"https://orcid.org/0000-0003-4540-5303","affiliations":[{"raw_affiliation_string":"Department of Biomedical and Chemical Engineering, BioInspired Syracuse, Syracuse University, Syracuse, NY, USA","institution_ids":["https://openalex.org/I70983195"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5018219022"],"corresponding_institution_ids":["https://openalex.org/I70983195"],"apc_list":null,"apc_paid":null,"fwci":1.8419,"has_fulltext":true,"cited_by_count":25,"citation_normalized_percentile":{"value":0.84982691,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":98,"max":99},"biblio":{"volume":"12","issue":"5","first_page":"1217","last_page":"1231"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10810","display_name":"Polymer composites and self-healing","score":0.6996999979019165,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10810","display_name":"Polymer composites and self-healing","score":0.6996999979019165,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11737","display_name":"Advanced Materials and Mechanics","score":0.26510000228881836,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10343","display_name":"Hydrogels: synthesis, properties, applications","score":0.016599999740719795,"subfield":{"id":"https://openalex.org/subfields/1313","display_name":"Molecular Medicine"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/segmented-polyurethanes","display_name":"segmented polyurethanes","score":0.8600000143051147},{"id":"https://openalex.org/keywords/shape-memory-polymers","display_name":"shape memory polymers","score":0.9940000176429749},{"id":"https://openalex.org/keywords/solvent-free-synthesis","display_name":"solvent-free synthesis","score":0.9810000061988831},{"id":"https://openalex.org/keywords/biostability","display_name":"biostability","score":0.7599999904632568},{"id":"https://openalex.org/keywords/hydrolytic-degradation","display_name":"hydrolytic degradation","score":0.7720000147819519},{"id":"https://openalex.org/keywords/shape-reconstruction","display_name":"shape recovery","score":0.6209999918937683},{"id":"https://openalex.org/keywords/hard-segment-content","display_name":"hard segment content","score":0.8080000281333923},{"id":"https://openalex.org/keywords/annealing","display_name":"annealing","score":0.7310000061988831},{"id":"https://openalex.org/keywords/solvent-casting","display_name":"solvent casting","score":0.9779999852180481},{"id":"https://openalex.org/keywords/fiber-formation","display_name":"fiber formation","score":0.5809999704360962},{"id":"https://openalex.org/keywords/biomaterial-scaffolds","display_name":"biomaterial scaffolds","score":0.968999981880188},{"id":"https://openalex.org/keywords/stimuli-responsive-materials","display_name":"stimuli-responsive materials","score":0.6200000047683716},{"id":"https://openalex.org/keywords/drug-delivery","display_name":"drug delivery","score":0.9380000233650208}],"concepts":[{"id":"https://openalex.org/C2779578285","wikidata":"https://www.wikidata.org/wiki/Q146322","display_name":"Polyurethane","level":2,"score":0.850387454032898},{"id":"https://openalex.org/C185698529","wikidata":"https://www.wikidata.org/wiki/Q906777","display_name":"Shape-memory polymer","level":3,"score":0.679080605506897},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5873353481292725},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.569058358669281},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.49895215034484863},{"id":"https://openalex.org/C126348684","wikidata":"https://www.wikidata.org/wiki/Q3456979","display_name":"Polymer science","level":1,"score":0.44318076968193054},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.35608425736427307},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.31445419788360596},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.23762118816375732},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1549949049949646}],"mesh":[{"descriptor_ui":"D000080745","descriptor_name":"Smart Materials","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D001672","descriptor_name":"Biocompatible Materials","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D006861","descriptor_name":"Hydrogen Peroxide","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008422","descriptor_name":"Materials Testing","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D011140","descriptor_name":"Polyurethanes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D012997","descriptor_name":"Solvents","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1039/d3tb02472e","doi":"https://doi.org/10.1039/d3tb02472e","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3tb02472e","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2024/tb/d3tb02472e","source":{"id":"https://openalex.org/S2479884170","display_name":"Journal of Materials Chemistry B","issn_l":"2050-750X","issn":["2050-750X","2050-7518"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry B","raw_type":"journal-article"},{"id":"pmid:38168979","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/38168979","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of materials chemistry. B","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1039/d3tb02472e","doi":"https://doi.org/10.1039/d3tb02472e","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3tb02472e","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2024/tb/d3tb02472e","source":{"id":"https://openalex.org/S2479884170","display_name":"Journal of Materials Chemistry B","issn_l":"2050-750X","issn":["2050-750X","2050-7518"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Materials Chemistry B","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320309532","display_name":"Syracuse University","ror":"https://ror.org/025r5qe02"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4389946511.pdf","grobid_xml":"https://content.openalex.org/works/W4389946511.grobid-xml"},"referenced_works_count":57,"referenced_works":["https://openalex.org/W272581626","https://openalex.org/W1965697156","https://openalex.org/W1965904596","https://openalex.org/W1972968005","https://openalex.org/W1977582300","https://openalex.org/W1979099516","https://openalex.org/W1985774368","https://openalex.org/W2000479440","https://openalex.org/W2006079919","https://openalex.org/W2024106178","https://openalex.org/W2027269140","https://openalex.org/W2028133927","https://openalex.org/W2029259783","https://openalex.org/W2043226014","https://openalex.org/W2047078954","https://openalex.org/W2052426110","https://openalex.org/W2067319156","https://openalex.org/W2067492397","https://openalex.org/W2071597558","https://openalex.org/W2081983778","https://openalex.org/W2103924242","https://openalex.org/W2121648403","https://openalex.org/W2145388143","https://openalex.org/W2149711659","https://openalex.org/W2149986572","https://openalex.org/W2157976579","https://openalex.org/W2179753871","https://openalex.org/W2220643393","https://openalex.org/W2314218184","https://openalex.org/W2316626163","https://openalex.org/W2605365714","https://openalex.org/W2745279536","https://openalex.org/W2756955591","https://openalex.org/W2779509510","https://openalex.org/W2793017688","https://openalex.org/W2809900101","https://openalex.org/W2846683368","https://openalex.org/W2900539009","https://openalex.org/W2905930064","https://openalex.org/W3019358254","https://openalex.org/W3089258517","https://openalex.org/W3111648813","https://openalex.org/W3129953111","https://openalex.org/W3189880928","https://openalex.org/W3206652881","https://openalex.org/W3215353627","https://openalex.org/W3216745305","https://openalex.org/W4207048176","https://openalex.org/W4214584736","https://openalex.org/W4221005572","https://openalex.org/W4226394843","https://openalex.org/W4280595843","https://openalex.org/W4285284420","https://openalex.org/W4296847386","https://openalex.org/W4306750329","https://openalex.org/W4306766926","https://openalex.org/W4323066955"],"related_works":["https://openalex.org/W3007122358","https://openalex.org/W4214584736","https://openalex.org/W2618840895","https://openalex.org/W3097353165","https://openalex.org/W2383413553","https://openalex.org/W2135031303","https://openalex.org/W2950934719","https://openalex.org/W856418595","https://openalex.org/W2082503353","https://openalex.org/W2366329083"],"abstract_inverted_index":{")":[0],"and":[1,55,63,105,117],"hydrolytic":[2],"(0.1":[3],"M":[4],"NaOH)":[5],"media.":[6,26],"Additionally,":[7],"minimal":[8],"shape":[9,61,106,157],"recovery":[10],"(\u223c0%)":[11],"occurred":[12],"in":[13,24,32,170],"programmed":[14,34],"samples":[15,35,84],"with":[16,81,102,135,164],"higher":[17,114],"hard":[18],"segment":[19],"content":[20,119],"that":[21,97,140],"were":[22],"stored":[23],"degradation":[25],"After":[27],"40":[28],"days":[29],"of":[30,58,76,83,120,138],"storage":[31],"media,":[33],"recovered":[36],"their":[37,45,68],"primary":[38],"shapes":[39],"upon":[40],"heating":[41],"to":[42,49,112,142,153],"temperatures":[43],"above":[44,50],"transition":[46],"temperature.":[47],"Annealing":[48],"the":[51,113,124],"polymer":[52],"melting":[53],"point":[54],"solvent":[56],"casting":[57],"polymers":[59,96,121],"improved":[60,103],"memory":[62,107],"thermal":[64],"properties.":[65],"To":[66],"enable":[67,154],"potential":[69],"use":[70],"as":[71,146],"biomaterial":[72],"scaffolds,":[73],"fiber":[74],"formation":[75],"synthesized":[77,85,122],"polyurethanes":[78,131],"was":[79],"compared":[80],"those":[82],"using":[86,123],"a":[87,136,155],"previously":[88],"reported":[89],"solvent-based":[90],"method.":[91],"The":[92],"new":[93],"method":[94],"provided":[95],"can":[98],"form":[99],"fibrous":[100],"scaffolds":[101],"mechanical":[104],"properties,":[108],"which":[109,160],"is":[110],"attributed":[111],"molecular":[115],"weight":[116],"crystalline":[118],"new,":[125],"solvent-free":[126],"approach.":[127],"These":[128],"biostable":[129],"segmented":[130],"could":[132,161],"be":[133,162],"coupled":[134,163],"range":[137],"components":[139],"respond":[141],"specific":[143,156],"stimuli,":[144],"such":[145],"enzymes,":[147],"magnetic":[148],"field,":[149],"pH,":[150],"or":[151],"light,":[152],"change":[158],"response,":[159],"drug":[165],"and/or":[166],"bioactive":[167],"material":[168],"delivery":[169],"future":[171],"work.":[172]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":8},{"year":2024,"cited_by_count":8}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2023-12-20T00:00:00"}