{"id":"https://openalex.org/W4389119639","doi":"https://doi.org/10.1088/2053-1583/ad10ba","title":"The role of solvent interfacial structural ordering in maintaining stable graphene dispersions","display_name":"The role of solvent interfacial structural ordering in maintaining stable graphene dispersions","publication_year":2023,"publication_date":"2023-11-29","ids":{"openalex":"https://openalex.org/W4389119639","doi":"https://doi.org/10.1088/2053-1583/ad10ba"},"language":"en","primary_location":{"id":"doi:10.1088/2053-1583/ad10ba","doi":"https://doi.org/10.1088/2053-1583/ad10ba","is_oa":true,"landing_page_url":"https://doi.org/10.1088/2053-1583/ad10ba","pdf_url":null,"source":{"id":"https://openalex.org/S4210229423","display_name":"2D Materials","issn_l":"2053-1583","issn":["2053-1583"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320083","host_organization_name":"IOP Publishing","host_organization_lineage":["https://openalex.org/P4310320083","https://openalex.org/P4310311669"],"host_organization_lineage_names":["IOP Publishing","Institute of Physics"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"2D Materials","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["arxiv","crossref","datacite"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1088/2053-1583/ad10ba","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037319767","display_name":"Urvesh Patil","orcid":"https://orcid.org/0000-0002-3924-653X","observed_orcids":["https://orcid.org/0000-0002-3924-653X"]},"institutions":[{"id":"https://openalex.org/I205274468","display_name":"Trinity College Dublin","ror":"https://ror.org/02tyrky19","country_code":"IE","type":"education","lineage":["https://openalex.org/I205274468"]}],"countries":["IE"],"is_corresponding":false,"raw_author_name":"Urvesh Patil","raw_affiliation_strings":["School of Physics and CRANN, Trinity College Dublin, College Green, Dublin, 2, IRELAND"],"raw_orcid":"https://orcid.org/0000-0002-3924-653X","affiliations":[{"raw_affiliation_string":"School of Physics and CRANN, Trinity College Dublin, College Green, Dublin, 2, IRELAND","institution_ids":["https://openalex.org/I205274468"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5012935227","display_name":"Nuala Mai Caffrey","orcid":"https://orcid.org/0000-0002-5330-9074","observed_orcids":["https://orcid.org/0000-0002-5330-9074"]},"institutions":[{"id":"https://openalex.org/I100930933","display_name":"University College Dublin","ror":"https://ror.org/05m7pjf47","country_code":"IE","type":"education","lineage":["https://openalex.org/I100930933"]}],"countries":["IE"],"is_corresponding":true,"raw_author_name":"Nuala M Caffrey","raw_affiliation_strings":["School of Physics, University College Dublin College of Science, University College Dublin, Belfield, Dublin 4, Dublin, 4, IRELAND"],"raw_orcid":"https://orcid.org/0000-0002-5330-9074","affiliations":[{"raw_affiliation_string":"School of Physics, University College Dublin College of Science, University College Dublin, Belfield, Dublin 4, Dublin, 4, IRELAND","institution_ids":["https://openalex.org/I100930933"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5012935227"],"corresponding_institution_ids":["https://openalex.org/I100930933"],"apc_list":{"value":3690,"currency":"USD","value_usd":3690},"apc_paid":{"value":3690,"currency":"USD","value_usd":3690},"fwci":0.5392,"has_fulltext":true,"cited_by_count":8,"citation_normalized_percentile":{"value":0.50901069,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":96,"max":98},"biblio":{"volume":"11","issue":"1","first_page":"015017","last_page":"015017"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10083","display_name":"Graphene research and applications","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10083","display_name":"Graphene research and applications","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10074","display_name":"Carbon Nanotubes in Composites","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/graphene-dispersion","display_name":"graphene dispersion","score":0.8009999990463257},{"id":"https://openalex.org/keywords/liquid-phase-exfoliation","display_name":"liquid-phase exfoliation","score":0.9879999756813049},{"id":"https://openalex.org/keywords/solvation-layer","display_name":"solvation layer","score":0.8849999904632568},{"id":"https://openalex.org/keywords/dispersion-stability","display_name":"dispersion stability","score":0.7409999966621399},{"id":"https://openalex.org/keywords/reaggregation","display_name":"reaggregation","score":0.9079999923706055},{"id":"https://openalex.org/keywords/molecular-diffusion-coefficient","display_name":"molecular diffusion coefficient","score":0.4690000116825104},{"id":"https://openalex.org/keywords/sonication","display_name":"sonication","score":0.5440000295639038},{"id":"https://openalex.org/keywords/benzaldehyde","display_name":"benzaldehyde","score":0.6769999861717224},{"id":"https://openalex.org/keywords/quinoline","display_name":"quinoline","score":1.0},{"id":"https://openalex.org/keywords/nanosheets","display_name":"nanosheets","score":0.7910000085830688},{"id":"https://openalex.org/keywords/separation-efficiency","display_name":"separation efficiency","score":0.4359999895095825}],"concepts":[{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.8584798574447632},{"id":"https://openalex.org/C129162502","wikidata":"https://www.wikidata.org/wiki/Q1200889","display_name":"Exfoliation joint","level":3,"score":0.8351487517356873},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.7171722650527954},{"id":"https://openalex.org/C177562468","wikidata":"https://www.wikidata.org/wiki/Q182893","display_name":"Dispersion (optics)","level":2,"score":0.6751271486282349},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6638869047164917},{"id":"https://openalex.org/C148093993","wikidata":"https://www.wikidata.org/wiki/Q739398","display_name":"Solvation","level":3,"score":0.6347980499267578},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.591234028339386},{"id":"https://openalex.org/C104628117","wikidata":"https://www.wikidata.org/wiki/Q3964828","display_name":"Sonication","level":2,"score":0.5617696642875671},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.4412415027618408},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.43510180711746216},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.42063260078430176},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4085044264793396},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.2525080442428589},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.21157968044281006},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.2109278440475464},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.20861974358558655},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1896582543849945},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1088/2053-1583/ad10ba","doi":"https://doi.org/10.1088/2053-1583/ad10ba","is_oa":true,"landing_page_url":"https://doi.org/10.1088/2053-1583/ad10ba","pdf_url":null,"source":{"id":"https://openalex.org/S4210229423","display_name":"2D Materials","issn_l":"2053-1583","issn":["2053-1583"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320083","host_organization_name":"IOP Publishing","host_organization_lineage":["https://openalex.org/P4310320083","https://openalex.org/P4310311669"],"host_organization_lineage_names":["IOP Publishing","Institute of Physics"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"2D Materials","raw_type":"journal-article"},{"id":"pmh:oai:arXiv.org:2310.17283","doi":null,"is_oa":true,"landing_page_url":"http://arxiv.org/abs/2310.17283","pdf_url":"https://arxiv.org/pdf/2310.17283","source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"text"},{"id":"doi:10.48550/arxiv.2310.17283","doi":"https://doi.org/10.48550/arxiv.2310.17283","is_oa":true,"landing_page_url":"https://doi.org/10.48550/arxiv.2310.17283","pdf_url":null,"source":{"id":"https://openalex.org/S4306400194","display_name":"arXiv (Cornell University)","issn_l":"2331-8422","issn":["2331-8422"],"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I205783295","host_organization_name":"Cornell University","host_organization_lineage":["https://openalex.org/I205783295"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Preprint"}],"best_oa_location":{"id":"doi:10.1088/2053-1583/ad10ba","doi":"https://doi.org/10.1088/2053-1583/ad10ba","is_oa":true,"landing_page_url":"https://doi.org/10.1088/2053-1583/ad10ba","pdf_url":null,"source":{"id":"https://openalex.org/S4210229423","display_name":"2D Materials","issn_l":"2053-1583","issn":["2053-1583"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320083","host_organization_name":"IOP Publishing","host_organization_lineage":["https://openalex.org/P4310320083","https://openalex.org/P4310311669"],"host_organization_lineage_names":["IOP Publishing","Institute of Physics"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"2D Materials","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8191741620","display_name":null,"funder_award_id":"15/SIRG/3314","funder_id":"https://openalex.org/F4320320847","funder_display_name":"Science Foundation Ireland"}],"funders":[{"id":"https://openalex.org/F4320320847","display_name":"Science Foundation Ireland","ror":"https://ror.org/0271asj38"},{"id":"https://openalex.org/F4320330055","display_name":"Irish Centre for High-End Computing","ror":"https://ror.org/04te6a418"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4389119639.pdf","grobid_xml":"https://content.openalex.org/works/W4389119639.grobid-xml"},"referenced_works_count":63,"referenced_works":["https://openalex.org/W1970973025","https://openalex.org/W1975192769","https://openalex.org/W1976980577","https://openalex.org/W1977967893","https://openalex.org/W1984104023","https://openalex.org/W1996613059","https://openalex.org/W2003949305","https://openalex.org/W2015197254","https://openalex.org/W2016969237","https://openalex.org/W2018437741","https://openalex.org/W2019465613","https://openalex.org/W2034388492","https://openalex.org/W2038335742","https://openalex.org/W2043668344","https://openalex.org/W2063437649","https://openalex.org/W2074309598","https://openalex.org/W2074708624","https://openalex.org/W2078315409","https://openalex.org/W2085537249","https://openalex.org/W2087686135","https://openalex.org/W2092956715","https://openalex.org/W2105829142","https://openalex.org/W2125612486","https://openalex.org/W2142092459","https://openalex.org/W2150371565","https://openalex.org/W2252401283","https://openalex.org/W2314776595","https://openalex.org/W2328619383","https://openalex.org/W2330407276","https://openalex.org/W2414108464","https://openalex.org/W2468866888","https://openalex.org/W2538065224","https://openalex.org/W2549976854","https://openalex.org/W2554047040","https://openalex.org/W2560030413","https://openalex.org/W2561730398","https://openalex.org/W2588133600","https://openalex.org/W2589236205","https://openalex.org/W2589948472","https://openalex.org/W2592719236","https://openalex.org/W2604381375","https://openalex.org/W2606142660","https://openalex.org/W2608035706","https://openalex.org/W2735472168","https://openalex.org/W2781407557","https://openalex.org/W2783923657","https://openalex.org/W2784673717","https://openalex.org/W2809452534","https://openalex.org/W2899070097","https://openalex.org/W2901457479","https://openalex.org/W2948545629","https://openalex.org/W2967623047","https://openalex.org/W2976224320","https://openalex.org/W3013624163","https://openalex.org/W3037363938","https://openalex.org/W3110967607","https://openalex.org/W3119104182","https://openalex.org/W3174111621","https://openalex.org/W4287447130","https://openalex.org/W4297206862","https://openalex.org/W4313231746","https://openalex.org/W4313490667","https://openalex.org/W4376654062"],"related_works":["https://openalex.org/W2150071745","https://openalex.org/W1996510060","https://openalex.org/W1968691608","https://openalex.org/W2781407557","https://openalex.org/W2995748582","https://openalex.org/W2989893961","https://openalex.org/W2317806057","https://openalex.org/W1996613059","https://openalex.org/W4400837385","https://openalex.org/W2100809023"],"abstract_inverted_index":{"Abstract":[0],"Liquid":[1],"phase":[2],"exfoliation":[3,22,214],"is":[4,44,64,91,110,183],"the":[5,10,29,41,56,72,103,126,130,144,149,162,186,199,208,212,222,247],"most":[6,25],"promising":[7],"method":[8],"for":[9,59,113],"low-cost,":[11],"scalable":[12],"production":[13],"of":[14,32,71,102,105,129,153,165,201,211,224,246],"two-dimensional":[15],"nanosheets":[16],"from":[17],"their":[18,108],"bulk":[19],"counterparts.":[20],"Extensive":[21],"occurs":[23],"in":[24,52,75,93,148,155,167,176,203,227],"solvents":[26,137,228],"due":[27],"to":[28,86,143],"huge":[30],"amount":[31],"energy":[33],"introduced":[34],"by":[35,161,243],"sonication":[36,249],"or":[37],"shear":[38],"mixing.":[39],"However,":[40,117],"subsequent":[42],"dispersion":[43,131],"not":[45,124],"always":[46],"stable,":[47],"with":[48,138,171],"extensive":[49],"reaggregation":[50,166,182],"occurring":[51],"some":[53],"solvents.":[54,116,169],"Identifying":[55],"optimal":[57],"solvent":[58,106],"a":[60,68,77,94],"particular":[61],"layered":[62],"material":[63],"difficult":[65],"and":[66,107,232],"requires":[67],"fundamental":[69],"understanding":[70],"mechanism":[73],"involved":[74],"maintaining":[76],"stable":[78],"dispersion.":[79],"Here,":[80],"we":[81,134,219],"use":[82],"molecular":[83],"dynamics":[84],"calculations":[85],"show":[87],"that":[88,136,197,221],"when":[89],"graphene":[90,145,154,179,202,226],"immersed":[92],"solvent,":[95],"distinct":[96],"solvation":[97],"layers":[98],"are":[99],"formed":[100],"irrespective":[101],"choice":[104],"formation":[109],"energetically":[111],"favourable":[112],"all":[114],"considered":[115],"energetic":[118],"considerations":[119],"such":[120,229],"as":[121,181,230],"these":[122,168],"do":[123],"explain":[125],"experimental":[127,151,178,248],"solvent-dependence":[128],"concentration.":[132],"Instead,":[133],"find":[135],"high":[139],"diffusion":[140,173,188,237],"coefficients":[141,174],"parallel":[142],"layer":[146],"result":[147,175],"lowest":[150],"concentration":[152,200,223],"solution.":[156],"This":[157],"can":[158,239],"be":[159,240],"explained":[160],"enhanced":[163],"ease":[164],"Solvents":[170],"smaller":[172],"higher":[177],"concentrations":[180],"prevented.":[184],"In":[185],"low":[187,236],"limit,":[189],"however,":[190],"this":[191],"relationship":[192],"breaks":[193],"down.":[194],"We":[195],"suggest":[196],"here":[198],"solution":[204],"depends":[205],"primarily":[206],"on":[207,217],"separation":[209],"efficiency":[210],"initial":[213],"step.":[215],"Based":[216],"this,":[218],"predict":[220],"exfoliated":[225],"benzaldehyde":[231],"quinoline,":[233],"which":[234],"have":[235],"constants,":[238],"increased":[241],"dramatically":[242],"careful":[244],"tuning":[245],"parameters.":[250]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2024,"cited_by_count":5}],"updated_date":"2026-11-10T11:39:43.021295","created_date":"2023-11-30T00:00:00"}