{"id":"https://openalex.org/W4389045907","doi":"https://doi.org/10.1021/acs.inorgchem.3c01908","title":"Strategy for an Effective Eco-Optimized Design of Heteroleptic Cu(I) Coordination Polymers Exhibiting Thermally Activated Delayed Fluorescence","display_name":"Strategy for an Effective Eco-Optimized Design of Heteroleptic Cu(I) Coordination Polymers Exhibiting Thermally Activated Delayed Fluorescence","publication_year":2023,"publication_date":"2023-11-27","ids":{"openalex":"https://openalex.org/W4389045907","doi":"https://doi.org/10.1021/acs.inorgchem.3c01908","pmid":"https://pubmed.ncbi.nlm.nih.gov/38010323","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/10716906"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.3c01908","doi":"https://doi.org/10.1021/acs.inorgchem.3c01908","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.3c01908","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c01908","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c01908","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5076631292","display_name":"Sabina W. Jaros","orcid":"https://orcid.org/0000-0002-5648-8629","observed_orcids":["https://orcid.org/0000-0002-5648-8629"]},"institutions":[{"id":"https://openalex.org/I219388962","display_name":"University of Wroc\u0142aw","ror":"https://ror.org/00yae6e25","country_code":"PL","type":"education","lineage":["https://openalex.org/I219388962"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Sabina W. Jaros","raw_affiliation_strings":["Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland"],"raw_orcid":"https://orcid.org/0000-0002-5648-8629","affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland","institution_ids":["https://openalex.org/I219388962"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042240182","display_name":"Jerzy Sokolnicki","orcid":"https://orcid.org/0000-0003-0929-1492","observed_orcids":["https://orcid.org/0000-0003-0929-1492"]},"institutions":[{"id":"https://openalex.org/I219388962","display_name":"University of Wroc\u0142aw","ror":"https://ror.org/00yae6e25","country_code":"PL","type":"education","lineage":["https://openalex.org/I219388962"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Jerzy Sokolnicki","raw_affiliation_strings":["Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland","institution_ids":["https://openalex.org/I219388962"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019278540","display_name":"Mi\u0142osz Siczek","orcid":"https://orcid.org/0000-0002-4214-6492","observed_orcids":["https://orcid.org/0000-0002-4214-6492"]},"institutions":[{"id":"https://openalex.org/I219388962","display_name":"University of Wroc\u0142aw","ror":"https://ror.org/00yae6e25","country_code":"PL","type":"education","lineage":["https://openalex.org/I219388962"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Mi\u0142osz Siczek","raw_affiliation_strings":["Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland","institution_ids":["https://openalex.org/I219388962"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5002592621","display_name":"Piotr Smole\u0144ski","orcid":"https://orcid.org/0000-0001-5969-6012","observed_orcids":["https://orcid.org/0000-0001-5969-6012"]},"institutions":[{"id":"https://openalex.org/I219388962","display_name":"University of Wroc\u0142aw","ror":"https://ror.org/00yae6e25","country_code":"PL","type":"education","lineage":["https://openalex.org/I219388962"]}],"countries":["PL"],"is_corresponding":true,"raw_author_name":"Piotr Smole\u0144ski","raw_affiliation_strings":["Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland"],"raw_orcid":"https://orcid.org/0000-0001-5969-6012","affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, University of Wroc\u0142aw, F. Joliot-Curie 14, 50-383 Wroc\u0142aw, Poland","institution_ids":["https://openalex.org/I219388962"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5002592621"],"corresponding_institution_ids":["https://openalex.org/I219388962"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":{"value":5000,"currency":"USD","value_usd":5000},"fwci":0.8552,"has_fulltext":true,"cited_by_count":12,"citation_normalized_percentile":{"value":0.67149024,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":97,"max":98},"biblio":{"volume":"62","issue":"49","first_page":"19898","last_page":"19907"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.6898999810218811,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.6898999810218811,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.21089999377727509,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.06790000200271606,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/copper-i-coordination-polymers","display_name":"copper(I) coordination polymers","score":0.9070000052452087},{"id":"https://openalex.org/keywords/thermally-activated-delayed-fluorescence","display_name":"thermally activated delayed fluorescence","score":0.9610000252723694},{"id":"https://openalex.org/keywords/1-3-5-triaza-7-phosphaadamantane","display_name":"1,3,5-triaza-7-phosphaadamantane","score":0.9380000233650208},{"id":"https://openalex.org/keywords/polypyridyl-ligands","display_name":"polypyridyl ligands","score":0.953000009059906},{"id":"https://openalex.org/keywords/molecular-rigidity","display_name":"molecular rigidity","score":0.7170000076293945},{"id":"https://openalex.org/keywords/s1-t1-energy-gap","display_name":"S1-T1 energy gap","score":0.7649999856948853},{"id":"https://openalex.org/keywords/fluorescence-quantum-yield","display_name":"fluorescence quantum yield","score":0.6880000233650208},{"id":"https://openalex.org/keywords/mechanochemical-synthesis","display_name":"mechanochemical synthesis","score":0.6610000133514404},{"id":"https://openalex.org/keywords/singlet-excited-state","display_name":"singlet excited state","score":0.5210000276565552},{"id":"https://openalex.org/keywords/ambient-stability","display_name":"air stability","score":0.37400001287460327},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.3449999988079071}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9630805253982544},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.6995962262153625},{"id":"https://openalex.org/C2781432337","wikidata":"https://www.wikidata.org/wiki/Q5168035","display_name":"Coordination polymer","level":3,"score":0.5507829189300537},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5265529155731201},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.46066370606422424},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3860514163970947},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.37349215149879456},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3516477942466736},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23164120316505432},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.048484474420547485},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acs.inorgchem.3c01908","doi":"https://doi.org/10.1021/acs.inorgchem.3c01908","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.3c01908","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c01908","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:pubmedcentral.nih.gov:10716906","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10716906","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10716906/pdf/ic3c01908.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorg Chem","raw_type":"Text"},{"id":"pmid:38010323","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/38010323","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1021/acs.inorgchem.3c01908","doi":"https://doi.org/10.1021/acs.inorgchem.3c01908","is_oa":true,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.3c01908","pdf_url":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c01908","source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2164275334","display_name":null,"funder_award_id":"PL-TW/VII/3/2020","funder_id":"https://openalex.org/F4320335039","funder_display_name":"Narodowe Centrum Bada\u0144 i Rozwoju"},{"id":"https://openalex.org/G2834613324","display_name":null,"funder_award_id":"2018/29/B/ST5/01418","funder_id":"https://openalex.org/F4320322511","funder_display_name":"Narodowe Centrum Nauki"}],"funders":[{"id":"https://openalex.org/F4320322511","display_name":"Narodowe Centrum Nauki","ror":"https://ror.org/03ha2q922"},{"id":"https://openalex.org/F4320335039","display_name":"Narodowe Centrum Bada\u0144 i Rozwoju","ror":"https://ror.org/05pwfyy15"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4389045907.pdf","grobid_xml":"https://content.openalex.org/works/W4389045907.grobid-xml"},"referenced_works_count":61,"referenced_works":["https://openalex.org/W1496689888","https://openalex.org/W1967577920","https://openalex.org/W1968682289","https://openalex.org/W1969189690","https://openalex.org/W1969360633","https://openalex.org/W1969870202","https://openalex.org/W1977898858","https://openalex.org/W1980642168","https://openalex.org/W1988479638","https://openalex.org/W1996889617","https://openalex.org/W2000958543","https://openalex.org/W2001004738","https://openalex.org/W2001205412","https://openalex.org/W2007784512","https://openalex.org/W2014438322","https://openalex.org/W2020111108","https://openalex.org/W2025154088","https://openalex.org/W2025325691","https://openalex.org/W2025705315","https://openalex.org/W2032529816","https://openalex.org/W2045200945","https://openalex.org/W2049810297","https://openalex.org/W2051293602","https://openalex.org/W2056202398","https://openalex.org/W2067322609","https://openalex.org/W2126627414","https://openalex.org/W2132454074","https://openalex.org/W2137787276","https://openalex.org/W2155819396","https://openalex.org/W2313458881","https://openalex.org/W2321183885","https://openalex.org/W2345313355","https://openalex.org/W2464723524","https://openalex.org/W2487770617","https://openalex.org/W2556788732","https://openalex.org/W2766196840","https://openalex.org/W2766862539","https://openalex.org/W2767796649","https://openalex.org/W2769804799","https://openalex.org/W2774131734","https://openalex.org/W2805008491","https://openalex.org/W2900166041","https://openalex.org/W2900268400","https://openalex.org/W2944451481","https://openalex.org/W2948058629","https://openalex.org/W2952207708","https://openalex.org/W2955873512","https://openalex.org/W2982312779","https://openalex.org/W2987631152","https://openalex.org/W2990345807","https://openalex.org/W3034389579","https://openalex.org/W3034975118","https://openalex.org/W3038259691","https://openalex.org/W3048984963","https://openalex.org/W3049173975","https://openalex.org/W3082661994","https://openalex.org/W3088149705","https://openalex.org/W3134874059","https://openalex.org/W3149507045","https://openalex.org/W3171583567","https://openalex.org/W4388396013"],"related_works":["https://openalex.org/W4302759414","https://openalex.org/W3038259691","https://openalex.org/W2966928231","https://openalex.org/W2883045660","https://openalex.org/W4214848929","https://openalex.org/W3135825245","https://openalex.org/W2888783037","https://openalex.org/W4410383152","https://openalex.org/W4392235795","https://openalex.org/W3137449721"],"abstract_inverted_index":{"High":[0],"Resolution":[1],"Image":[2],"Download":[3],"MS":[4],"PowerPoint":[5],"Slide":[6],"The":[7,74,91,285],"new":[8],"series":[9],"of":[10,51,138,141,156,166,182,199],"copper(I)":[11],"coordination":[12],"polymers":[13],"[Cu(N\u2013N)(\u03bc-PTA)]":[14],"n":[15,19],"[PF":[16],"6":[17,55],"]":[18,56],"{N\u2013N":[20],"=":[21,279,300],"dmbpy":[22],"(":[23,27,31,36],"1":[24,157,168,222,224,248,250,255],"),":[25,29,33,106],"bpy":[26],"2":[28,159],"ncup":[30],"3":[32,163,170,212,257],"and":[34,60,71,81,88,104,158,164,169,230,256,268,272,281,302],"phen":[35],"4":[37,53,105],")}":[38],"were":[39,76,94],"generated":[40],"by":[41,84,96,114,175],"straightforward":[42],"reaction":[43],"in":[44,146,210,263],"solution":[45],"or":[46],"through":[47],"a":[48,172,177,216],"mechanochemical":[49],"route,":[50],"[Cu(MeCN)":[52],"][PF":[54],"with":[57],"1,3,5-triaza-7-phosphaadamantane":[58],"(PTA)":[59],"the":[61,139,142,147,153,183,200,203,207,211,218,231,239,244,260,264,273],"corresponding":[62],"polypyridines,":[63],"namely,":[64],"5,5\u2032-dimethyl-2,2\u2032-bipyridine":[65],"(dmbpy),":[66],"2,2\u2032-bipyridine":[67],"(bpy),":[68],"2,9-dimethyl-1,10-phenanthroline":[69],"(ncup),":[70],"1,10-phenanthroline":[72],"(phen).":[73],"compounds":[75,122],"obtained":[77],"as":[78,160,162],"air-stable":[79],"solids":[80],"fully":[82],"characterized":[83],"IR,":[85],"NMR":[86],"spectroscopy,":[87],"elemental":[89],"analyses.":[90],"molecular":[92,192],"structures":[93],"confirmed":[95],"single-crystal":[97],"X-ray":[98],"diffraction":[99],"analysis":[100],"(for":[101],"1,":[102],"2,":[103],"revealing":[107],"infinite":[108],"one-dimensional":[109],"(1D)":[110],"linear":[111],"chains":[112],"driven":[113],"\u03bc-PTA":[115],"N,P":[116],"-linkers.":[117],"All":[118],"tested":[119],"Cu(I)":[120,208],"polymeric":[121],"show":[123],"emission":[124,148,240],"at":[125],"room":[126],"temperature,":[127],"which":[128,167],"was":[129],"attributed":[130],"to":[131,180,294],"thermally":[132],"activated":[133],"delayed":[134],"fluorescence":[135,232,286],"(TADF).":[136],"Evidence":[137],"involvement":[140],"excited":[143],"singlet":[144],"state":[145],"process":[149],"is":[150,195],"presented.":[151],"Comparing":[152],"photophysical":[154],"properties":[155,189],"well":[161],"4,":[165],"have":[171],"stiffened":[173],"structure,":[174],"introducing":[176],"methyl":[178],"group":[179],"one":[181],"ligands,":[184],"we":[185],"demonstrate":[186],"how":[187],"TADF":[188,274],"depend":[190],"on":[191],"rigidity.":[193],"It":[194],"shown":[196],"that":[197],"stiffening":[198],"structure":[201],"reduces":[202],"flattening":[204],"distortion":[205],"around":[206],"center":[209],"MLCT":[213],"state.":[214],"As":[215],"result,":[217],"\u0394":[219,245],"E":[220,246],"(S":[221,247],"\u2013T":[223,249],")":[225,251],"energy":[226],"gap":[227],"becomes":[228],"smaller":[229],"quantum":[233,287],"yield":[234],"increases":[235],"without":[236],"significantly":[237],"extending":[238],"lifetime.":[241],"In":[242],"particular,":[243],"values":[252],"for":[253,289],"complexes":[254,291],"are":[258,276,292],"among":[259],"shortest":[261],"reported":[262],"scientific":[265],"literature,":[266],"253":[267],"337":[269],"cm":[270],"\u20131,":[271],"lifetimes":[275],"\u03c4(300":[277],"K)":[278,299],"5.7":[280],"4.2":[282],"\u03bcs,":[283],"respectively.":[284],"yields":[288],"these":[290],"measured":[293],"be":[295],"\u03a6":[296],"PL":[297],"(300":[298],"70":[301],"80%.":[303]},"counts_by_year":[{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":6}],"updated_date":"2026-10-29T09:56:32.521200","created_date":"2023-11-28T00:00:00"}