{"id":"https://openalex.org/W4388564120","doi":"https://doi.org/10.1002/anie.202312546","title":"Rapid Polyolefin Hydrogenolysis by a Single\u2010Site Organo\u2010Tantalum Catalyst on a Super\u2010Acidic Support: Structure and Mechanism","display_name":"Rapid Polyolefin Hydrogenolysis by a Single\u2010Site Organo\u2010Tantalum Catalyst on a Super\u2010Acidic Support: Structure and Mechanism","publication_year":2023,"publication_date":"2023-11-10","ids":{"openalex":"https://openalex.org/W4388564120","doi":"https://doi.org/10.1002/anie.202312546","pmid":"https://pubmed.ncbi.nlm.nih.gov/37948306"},"language":"en","primary_location":{"id":"doi:10.1002/anie.202312546","doi":"https://doi.org/10.1002/anie.202312546","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202312546","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202312546","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W4388564120"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202312546","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021073015","display_name":"Qingheng Lai","orcid":"https://orcid.org/0000-0002-2739-2337","observed_orcids":["https://orcid.org/0000-0002-2739-2337"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Qingheng Lai","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073454968","display_name":"Alexander H. Mason","orcid":"https://orcid.org/0000-0001-7652-364X","observed_orcids":["https://orcid.org/0000-0001-7652-364X"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alexander H. Mason","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Amol Agarwal","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Amol Agarwal","raw_affiliation_strings":["Department of Materials Science & Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL-60208-3113 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science & Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008137182","display_name":"Wilson C. Edenfield","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wilson C. Edenfield","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100708913","display_name":"Xinrui Zhang","orcid":"https://orcid.org/0000-0003-3803-4372","observed_orcids":["https://orcid.org/0000-0003-3803-4372","https://orcid.org/0009-0000-2705-4605"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xinrui Zhang","raw_affiliation_strings":["Department of Materials Science & Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL-60208-3113 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science & Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042306628","display_name":"Takeshi Kobayashi","orcid":"https://orcid.org/0000-0002-6366-0925","observed_orcids":["https://orcid.org/0000-0002-6366-0925"]},"institutions":[{"id":"https://openalex.org/I173911158","display_name":"Iowa State University","ror":"https://ror.org/04rswrd78","country_code":"US","type":"education","lineage":["https://openalex.org/I173911158"]},{"id":"https://openalex.org/I2802789608","display_name":"Ames National Laboratory","ror":"https://ror.org/041m9xr71","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I173911158","https://openalex.org/I2802789608","https://openalex.org/I39565521"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Takeshi Kobayashi","raw_affiliation_strings":["U.S. DOE Ames National Laboratory, IOWA State University, Ames, IA50011-3020 USA"],"raw_orcid":"https://orcid.org/0000-0002-6366-0925","affiliations":[{"raw_affiliation_string":"U.S. DOE Ames National Laboratory, IOWA State University, Ames, IA50011-3020 USA","institution_ids":["https://openalex.org/I173911158","https://openalex.org/I2802789608"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057402828","display_name":"Yosi Kratish","orcid":"https://orcid.org/0000-0001-5279-0268","observed_orcids":["https://orcid.org/0000-0001-5279-0268"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Yosi Kratish","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA"],"raw_orcid":"https://orcid.org/0000-0001-5279-0268","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5000731301","display_name":"Tobin Jay Marks","orcid":"https://orcid.org/0000-0001-8771-0141","observed_orcids":["https://orcid.org/0000-0001-8771-0141"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Tobin J. Marks","raw_affiliation_strings":["Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA"],"raw_orcid":"https://orcid.org/0000-0001-8771-0141","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL-60208-3113 USA","institution_ids":["https://openalex.org/I111979921"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5000731301","https://openalex.org/A5042306628","https://openalex.org/A5057402828"],"corresponding_institution_ids":["https://openalex.org/I111979921","https://openalex.org/I173911158","https://openalex.org/I2802789608"],"apc_list":{"value":5250,"currency":"USD","value_usd":5250},"apc_paid":null,"fwci":1.4596,"has_fulltext":true,"cited_by_count":15,"citation_normalized_percentile":{"value":0.78463087,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":96,"max":98},"biblio":{"volume":"62","issue":"50","first_page":"e202312546","last_page":"e202312546"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8833000063896179,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.8833000063896179,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11351","display_name":"Catalysis and Hydrodesulfurization Studies","score":0.014100000262260437,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.01209999993443489,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/single-site-catalysts","display_name":"single-site catalysts","score":0.8740000128746033},{"id":"https://openalex.org/keywords/c-c-bond-cleavage","display_name":"C\u2013C bond cleavage","score":0.6840000152587891},{"id":"https://openalex.org/keywords/catalyst-thermal-stability","display_name":"catalyst thermal stability","score":0.6800000071525574},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.5099999904632568}],"concepts":[{"id":"https://openalex.org/C181886296","wikidata":"https://www.wikidata.org/wiki/Q903188","display_name":"Hydrogenolysis","level":3,"score":0.9760887622833252},{"id":"https://openalex.org/C2777686893","wikidata":"https://www.wikidata.org/wiki/Q424370","display_name":"Polyolefin","level":3,"score":0.974724292755127},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7901623249053955},{"id":"https://openalex.org/C514619126","wikidata":"https://www.wikidata.org/wiki/Q1123","display_name":"Tantalum","level":2,"score":0.6773420572280884},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5824550986289978},{"id":"https://openalex.org/C107861141","wikidata":"https://www.wikidata.org/wiki/Q908783","display_name":"Extended X-ray absorption fine structure","level":3,"score":0.46483325958251953},{"id":"https://openalex.org/C33790079","wikidata":"https://www.wikidata.org/wiki/Q899417","display_name":"Chemisorption","level":3,"score":0.4429186284542084},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.43346548080444336},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4065520167350769},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.40301722288131714},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.0652448832988739},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1002/anie.202312546","doi":"https://doi.org/10.1002/anie.202312546","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202312546","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202312546","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv-2023-24gfx","doi":"https://doi.org/10.26434/chemrxiv-2023-24gfx","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv-2023-24gfx","pdf_url":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/6410d986b5d5dbe9e84245bf/original/highly-efficient-polyolefin-hydrogenolysis-enabled-by-a-single-site-organo-tantalum-catalyst-on-a-super-acidic-support.pdf","source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:37948306","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37948306","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"pmh:oai:osti.gov:2228999","doi":null,"is_oa":false,"landing_page_url":"https://www.osti.gov/biblio/2228999","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"doi:10.1002/anie.202312546","doi":"https://doi.org/10.1002/anie.202312546","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202312546","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202312546","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G102163711","display_name":null,"funder_award_id":"DE\u2010 AC02\u201006CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G107546177","display_name":null,"funder_award_id":"DE- AC02-06-CH11357","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G1166121473","display_name":null,"funder_award_id":"DE-AC-02-07CH11358","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G1235551788","display_name":"NNCI: Soft Hybrid Nanotechnology Experimental (SHyNE) Resource","funder_award_id":"2025633","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G1286251239","display_name":null,"funder_award_id":"DE-AC02","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G1313983767","display_name":null,"funder_award_id":"DE-AC02","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G1338583345","display_name":null,"funder_award_id":"DOE DE-FG02-03-ER15457","funder_id":"https://openalex.org/F4320309475","funder_display_name":"Northwestern University"},{"id":"https://openalex.org/G1418315740","display_name":null,"funder_award_id":"AC02-07CH11358","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G1505794299","display_name":null,"funder_award_id":"Contract No. DE-AC02-06CH11357.","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G1519358529","display_name":null,"funder_award_id":"07CH11358","funder_id":"https://openalex.org/F4320311090","funder_display_name":"Iowa State University"},{"id":"https://openalex.org/G1664757510","display_name":null,"funder_award_id":"AC02\u201306CH11357","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G1866217153","display_name":null,"funder_award_id":"AC02-07CH11358","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G1879923082","display_name":"INSTITUTE FOR ENVIRONMENTAL CATALYSIS","funder_award_id":"FG02-03ER15457","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G2001921306","display_name":null,"funder_award_id":"DOE DE-FG02-03ER15457","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G2065229796","display_name":"NEW AWARD; TITLE: NORTHWESTERN UNIVERSITY FACILITY FOR CLEAN CATALYTIC PROCESS RESEARCH; PI: TOBIN J. MARKS","funder_award_id":"DESC0001329","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G20786169","display_name":"FOR CONSTRUCTION OF THE INSTITUTE FOR PROTEOMICS A ND NANOBIOTECHNOLOGY","funder_award_id":"NNA04CC36G","funder_id":"https://openalex.org/F4320306101","funder_display_name":"National Aeronautics and Space Administration"},{"id":"https://openalex.org/G2101401529","display_name":null,"funder_award_id":"Contract No. DE-AC02-06CH11357","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G222768804","display_name":null,"funder_award_id":"DE\u2010FG02\u2010","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G2287611682","display_name":null,"funder_award_id":"AC02\u201006CH11357","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G2316606464","display_name":null,"funder_award_id":"AC02-07CH11358","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G2327333655","display_name":null,"funder_award_id":"07CH11358","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G2357880494","display_name":null,"funder_award_id":"DE-SC0001329","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G249831736","display_name":null,"funder_award_id":"DEAC02- 07CH11358","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G262962599","display_name":null,"funder_award_id":"AC02\u201006CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G285533474","display_name":null,"funder_award_id":"DE-AC02-07CH11358","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G2887060908","display_name":null,"funder_award_id":"No. DE-AC02-06CH11357","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G2917895714","display_name":null,"funder_award_id":"DESC0014664","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G2980159964","display_name":null,"funder_award_id":"DE-AC02-06CH11357","funder_id":"https://openalex.org/F4320307783","funder_display_name":"Dow Chemical Company"},{"id":"https://openalex.org/G3010471893","display_name":null,"funder_award_id":"ECCS-2025633","funder_id":"https://openalex.org/F4320337392","funder_display_name":"Division of Electrical, Communications and Cyber Systems"},{"id":"https://openalex.org/G303010891","display_name":null,"funder_award_id":"DE-FG02-03-ER15457","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G3075337988","display_name":null,"funder_award_id":"06CH11357","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G316399430","display_name":null,"funder_award_id":"NSF ECCS-2025633","funder_id":"https://openalex.org/F4320337392","funder_display_name":"Division of Electrical, Communications and Cyber Systems"},{"id":"https://openalex.org/G340565428","display_name":null,"funder_award_id":"Contract No. DE-AC02-06CH11357.","funder_id":"https://openalex.org/F4320338284","funder_display_name":"Argonne National Laboratory"},{"id":"https://openalex.org/G353356689","display_name":"NEW AWARD; TITLE: NORTHWESTERN UNIVERSITY FACILITY FOR CLEAN CATALYTIC PROCESS RESEARCH; PI: TOBIN J. MARKS","funder_award_id":"DESC0001329","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G4120964173","display_name":null,"funder_award_id":"NSF ECCS\u20102025633","funder_id":"https://openalex.org/F4320309475","funder_display_name":"Northwestern University"},{"id":"https://openalex.org/G426311843","display_name":null,"funder_award_id":"DE-AC- 02-06CH11357","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G473123490","display_name":null,"funder_award_id":"DE-SC 0014664","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G473396326","display_name":null,"funder_award_id":"DESC0014664","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G4958141111","display_name":null,"funder_award_id":"2025633","funder_id":"https://openalex.org/F4320337392","funder_display_name":"Division of Electrical, Communications and Cyber Systems"},{"id":"https://openalex.org/G498139845","display_name":null,"funder_award_id":"DE-AC02","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G5106849484","display_name":null,"funder_award_id":"No. DE-AC02-06CH11357.","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G524707868","display_name":null,"funder_award_id":"DE-AC02-07CH11358","funder_id":"https://openalex.org/F4320311090","funder_display_name":"Iowa State University"},{"id":"https://openalex.org/G5387317844","display_name":null,"funder_award_id":"AC02\u201006CH11357","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5425137327","display_name":null,"funder_award_id":"FG02-03ER15457","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5542764779","display_name":"INSTITUTE FOR CATALYSIS IN ENERGY PROCESS","funder_award_id":"DEFG0203ER15457","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G5648016710","display_name":null,"funder_award_id":"DE-FG02","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5910536577","display_name":null,"funder_award_id":"Contract No. DE-AC02-06CH11357","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G5955693984","display_name":null,"funder_award_id":"NNA04CC36G","funder_id":"https://openalex.org/F4320332374","funder_display_name":"Ames Research Center"},{"id":"https://openalex.org/G5959670421","display_name":null,"funder_award_id":"DE-AC-02-07CH11358","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G601061201","display_name":null,"funder_award_id":"DE\u2013SC0014664","funder_id":"https://openalex.org/F4320332382","funder_display_name":"Oak Ridge Institute for Science and Education"},{"id":"https://openalex.org/G6017181652","display_name":null,"funder_award_id":"SC0014664","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G665223801","display_name":null,"funder_award_id":"DE-AC-0206CH11357","funder_id":"https://openalex.org/F4320337744","funder_display_name":"Chemical Sciences, Geosciences, and Biosciences Division"},{"id":"https://openalex.org/G6848031779","display_name":null,"funder_award_id":"06CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G6918803902","display_name":null,"funder_award_id":"06CH11357","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G7368700025","display_name":null,"funder_award_id":"No. DE-AC02-06CH11357","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G7583137537","display_name":null,"funder_award_id":"06CH11357","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G7619220232","display_name":null,"funder_award_id":"SC0014664","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G8570346810","display_name":null,"funder_award_id":"SC0014664","funder_id":"https://openalex.org/F4320332382","funder_display_name":"Oak Ridge Institute for Science and Education"},{"id":"https://openalex.org/G8726365431","display_name":"INSTITUTE FOR CATALYSIS IN ENERGY PROCESS","funder_award_id":"DEFG0203ER15457","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"},{"id":"https://openalex.org/G9000239236","display_name":null,"funder_award_id":"DOE DE-FG02-03-ER15457","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G969889393","display_name":null,"funder_award_id":"DE-AC02-","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G993149817","display_name":null,"funder_award_id":"DE-AC02-06CH11357 ","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320306101","display_name":"National Aeronautics and Space Administration","ror":"https://ror.org/027ka1x80"},{"id":"https://openalex.org/F4320307783","display_name":"Dow Chemical Company","ror":"https://ror.org/032hx4q18"},{"id":"https://openalex.org/F4320307794","display_name":"DuPont","ror":"https://ror.org/03g3m1w62"},{"id":"https://openalex.org/F4320309475","display_name":"Northwestern University","ror":"https://ror.org/000e0be47"},{"id":"https://openalex.org/F4320311090","display_name":"Iowa State University","ror":"https://ror.org/04rswrd78"},{"id":"https://openalex.org/F4320332359","display_name":"Office of Science","ror":"https://ror.org/00mmn6b08"},{"id":"https://openalex.org/F4320332374","display_name":"Ames Research Center","ror":"https://ror.org/02acart68"},{"id":"https://openalex.org/F4320332382","display_name":"Oak Ridge Institute for Science and Education","ror":"https://ror.org/0526p1y61"},{"id":"https://openalex.org/F4320333986","display_name":"Quest High Performance Computing","ror":null},{"id":"https://openalex.org/F4320337392","display_name":"Division of Electrical, Communications and Cyber Systems","ror":"https://ror.org/01krpsy48"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320337744","display_name":"Chemical Sciences, Geosciences, and Biosciences Division","ror":null},{"id":"https://openalex.org/F4320338284","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4388564120.pdf","grobid_xml":"https://content.openalex.org/works/W4388564120.grobid-xml"},"referenced_works_count":63,"referenced_works":["https://openalex.org/W1530845907","https://openalex.org/W1965877659","https://openalex.org/W1966335238","https://openalex.org/W1972388036","https://openalex.org/W1976572760","https://openalex.org/W1977168693","https://openalex.org/W1985763212","https://openalex.org/W1993978324","https://openalex.org/W1995430025","https://openalex.org/W2007767017","https://openalex.org/W2008507947","https://openalex.org/W2010137021","https://openalex.org/W2011099889","https://openalex.org/W2020381390","https://openalex.org/W2037496050","https://openalex.org/W2054973957","https://openalex.org/W2060176306","https://openalex.org/W2063726108","https://openalex.org/W2078856430","https://openalex.org/W2091943837","https://openalex.org/W2093299928","https://openalex.org/W2135745744","https://openalex.org/W2325017833","https://openalex.org/W2334348473","https://openalex.org/W2588550257","https://openalex.org/W2621679044","https://openalex.org/W2653069682","https://openalex.org/W2737217596","https://openalex.org/W2746112255","https://openalex.org/W2749550903","https://openalex.org/W2770941005","https://openalex.org/W2802243083","https://openalex.org/W2896016908","https://openalex.org/W2901406413","https://openalex.org/W2963754836","https://openalex.org/W2981503372","https://openalex.org/W3005879126","https://openalex.org/W3012481340","https://openalex.org/W3094505816","https://openalex.org/W3097559636","https://openalex.org/W3116533171","https://openalex.org/W3126538505","https://openalex.org/W3129319549","https://openalex.org/W3134717135","https://openalex.org/W3146681163","https://openalex.org/W3173250669","https://openalex.org/W3185866389","https://openalex.org/W3209755814","https://openalex.org/W4200562917","https://openalex.org/W4220686573","https://openalex.org/W4223498063","https://openalex.org/W4280588776","https://openalex.org/W4298006419","https://openalex.org/W4301599872","https://openalex.org/W4307897540","https://openalex.org/W4309883025","https://openalex.org/W4321766460","https://openalex.org/W6600007113","https://openalex.org/W6600120041","https://openalex.org/W6600592474","https://openalex.org/W6601575777","https://openalex.org/W6601616801","https://openalex.org/W6816708214"],"related_works":["https://openalex.org/W4390227395","https://openalex.org/W4385443228","https://openalex.org/W4309883025","https://openalex.org/W4389955380","https://openalex.org/W2115932903","https://openalex.org/W7223623539","https://openalex.org/W4321766460","https://openalex.org/W4392095801","https://openalex.org/W6888697271"],"abstract_inverted_index":{"Abstract":[0],"The":[1,24],"novel":[2],"electrophilic":[3],"organo\u2010tantalum":[4],"catalyst":[5,26,107],"AlS/TaNpx":[6,122],"(1)":[7],"(Np=neopentyl)":[8],"is":[9,28,41,50,108,123,136],"prepared":[10],"by":[11,30,140],"chemisorption":[12],"of":[13,56,70,76,129],"the":[14,54,68,77,98,102,105],"alkylidene":[15],"Np3Ta=CHtBu":[16],"onto":[17],"highly":[18,51],"Br\u00f8nsted":[19],"acidic":[20],"sulfated":[21],"alumina":[22],"(AlS).":[23],"proposed":[25],"structure":[27],"supported":[29],"EXAFS,":[31],"XANES,":[32],"ICP,":[33],"DRIFTS,":[34],"elemental":[35],"analysis,":[36],"and":[37,40,59,112,131,135],"SSNMR":[38],"measurements":[39],"in":[42,97],"good":[43],"agreement":[44],"with":[45],"DFT":[46],"analysis.":[47],"Catalyst":[48],"1":[49,73],"effective":[52,124],"for":[53,125],"hydrogenolysis":[55,80],"diverse":[57],"linear":[58],"branched":[60],"hydrocarbons,":[61],"ranging":[62],"from":[63],"C2":[64],"to":[65,95],"polyolefins.":[66],"To":[67],"best":[69],"our":[71],"knowledge,":[72],"exhibits":[74],"one":[75],"highest":[78],"polyolefin":[79,133,142],"activities":[81],"(9,800":[82],"(CH2":[83],"units)":[84],"\u22c5":[85,87],"mol(Ta)\u22121":[86],"h\u22121":[88],"at":[89,144],"200":[90],"\u00b0C/17":[91],"atm":[92],"H2)":[93],"reported":[94],"date":[96],"peer\u2010reviewed":[99],"literature.":[100],"Unlike":[101],"AlS/ZrNp2":[103],"analog,":[104],"Ta":[106],"more":[109],"thermally":[110],"stable":[111],"offers":[113],"multiple":[114],"potential":[115],"C\u2212C":[116],"bond":[117],"activation":[118],"pathways.":[119],"For":[120],"hydrogenolysis,":[121],"a":[126],"wide":[127],"variety":[128],"pre\u2010":[130],"post\u2010consumer":[132],"plastics":[134],"not":[137],"significantly":[138],"deactivated":[139],"standard":[141],"additives":[143],"typical":[145],"industrial":[146],"concentrations.":[147]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":6}],"updated_date":"2026-11-14T11:04:58.165337","created_date":"2023-11-11T00:00:00"}