{"id":"https://openalex.org/W4387965547","doi":"https://doi.org/10.1002/anie.202313010","title":"Experimental and Computational Studies on Uranium Diazomethanediide Complexes","display_name":"Experimental and Computational Studies on Uranium Diazomethanediide Complexes","publication_year":2023,"publication_date":"2023-10-26","ids":{"openalex":"https://openalex.org/W4387965547","doi":"https://doi.org/10.1002/anie.202313010","pmid":"https://pubmed.ncbi.nlm.nih.gov/37883663"},"language":"en","primary_location":{"id":"doi:10.1002/anie.202313010","doi":"https://doi.org/10.1002/anie.202313010","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202313010","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202313010","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202313010","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5042036838","display_name":"Tongyu Li","orcid":"https://orcid.org/0000-0002-8745-4587","observed_orcids":["https://orcid.org/0000-0002-8745-4587"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tongyu Li","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100735744","display_name":"Dongwei Wang","orcid":"https://orcid.org/0000-0003-4193-7302","observed_orcids":["https://orcid.org/0000-0003-4193-7302"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Dongwei Wang","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063180331","display_name":"Yi Heng","orcid":"https://orcid.org/0000-0003-4114-1398","observed_orcids":["https://orcid.org/0000-0003-4114-1398"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yi Heng","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053570999","display_name":"Guohua Hou","orcid":"https://orcid.org/0000-0002-3571-456X","observed_orcids":["https://orcid.org/0000-0002-3571-456X"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Guohua Hou","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082812665","display_name":"Guofu Zi","orcid":"https://orcid.org/0000-0002-7455-460X","observed_orcids":["https://orcid.org/0000-0002-7455-460X"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Guofu Zi","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080658249","display_name":"Wanjian Ding","orcid":"https://orcid.org/0000-0002-4970-5816","observed_orcids":["https://orcid.org/0000-0002-4970-5816"]},"institutions":[{"id":"https://openalex.org/I25254941","display_name":"Beijing Normal University","ror":"https://ror.org/022k4wk35","country_code":"CN","type":"education","lineage":["https://openalex.org/I25254941"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Wanjian Ding","raw_affiliation_strings":["Department of Chemistry Beijing Normal University  Beijing 100875 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry Beijing Normal University  Beijing 100875 China","institution_ids":["https://openalex.org/I25254941"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100775902","display_name":"Laurent Maron","orcid":"https://orcid.org/0000-0003-2653-8557","observed_orcids":["https://orcid.org/0000-0003-2653-8557"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I134560555","display_name":"Universit\u00e9 Toulouse III - Paul Sabatier","ror":"https://ror.org/02v6kpv12","country_code":"FR","type":"education","lineage":["https://openalex.org/I134560555","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I196454796","display_name":"Institut National des Sciences Appliqu\u00e9es de Toulouse","ror":"https://ror.org/01h8pf755","country_code":"FR","type":"education","lineage":["https://openalex.org/I196454796"]},{"id":"https://openalex.org/I4210156113","display_name":"Laboratoire de Physique et Chimie des Nano-Objets","ror":"https://ror.org/042xmz674","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I196454796","https://openalex.org/I4210156113","https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Laurent Maron","raw_affiliation_strings":["LPCNO CNRS and INSA Universit\u00e9 Paul Sabatier  31077 Toulouse France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"LPCNO CNRS and INSA Universit\u00e9 Paul Sabatier  31077 Toulouse France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I134560555","https://openalex.org/I196454796","https://openalex.org/I4210156113"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010213141","display_name":"Marc D. Walter","orcid":"https://orcid.org/0000-0002-4682-8749","observed_orcids":["https://orcid.org/0000-0002-4682-8749"]},"institutions":[{"id":"https://openalex.org/I94509681","display_name":"Technische Universit\u00e4t Braunschweig","ror":"https://ror.org/010nsgg66","country_code":"DE","type":"education","lineage":["https://openalex.org/I94509681"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Marc D. Walter","raw_affiliation_strings":["Institut f\u00fcr Anorganische und Analytische Chemie Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig Germany"],"raw_orcid":"https://orcid.org/0000-0002-4682-8749","affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Anorganische und Analytische Chemie Technische Universit\u00e4t Braunschweig  Hagenring 30 38106 Braunschweig Germany","institution_ids":["https://openalex.org/I94509681"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5010213141","https://openalex.org/A5080658249","https://openalex.org/A5082812665"],"corresponding_institution_ids":["https://openalex.org/I25254941","https://openalex.org/I94509681"],"apc_list":{"value":5250,"currency":"USD","value_usd":5250},"apc_paid":{"value":5250,"currency":"USD","value_usd":5250},"fwci":0.7301,"has_fulltext":true,"cited_by_count":10,"citation_normalized_percentile":{"value":0.61004599,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"62","issue":"50","first_page":"e202313010","last_page":"e202313010"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.5360999703407288,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.5360999703407288,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.4311999976634979,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.016499999910593033,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.4050000011920929},{"id":"https://openalex.org/keywords/nucleophilicity","display_name":"nucleophilicity","score":0.593999981880188},{"id":"https://openalex.org/keywords/internal-alkynes","display_name":"internal alkynes","score":0.5730000138282776}],"concepts":[{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.8896223306655884},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7709208726882935},{"id":"https://openalex.org/C555451288","wikidata":"https://www.wikidata.org/wiki/Q1098","display_name":"Uranium","level":2,"score":0.7285457849502563},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6465340852737427},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.634778618812561},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5974056124687195},{"id":"https://openalex.org/C59061564","wikidata":"https://www.wikidata.org/wiki/Q7783071","display_name":"Thermal stability","level":2,"score":0.5131345391273499},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.4778941869735718},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4431113600730896},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4101719856262207},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3614620566368103},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3026166558265686},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14162200689315796},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.12786802649497986},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12102660536766052},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/anie.202313010","doi":"https://doi.org/10.1002/anie.202313010","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202313010","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202313010","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},{"id":"pmid:37883663","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37883663","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie (International ed. in English)","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-04707669v1","doi":null,"is_oa":false,"landing_page_url":"https://hal.science/hal-04707669","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Angewandte Chemie International Edition, 2023, 62 (50), ⟨10.1002/anie.202313010⟩","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.1002/anie.202313010","doi":"https://doi.org/10.1002/anie.202313010","is_oa":true,"landing_page_url":"https://doi.org/10.1002/anie.202313010","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.202313010","source":{"id":"https://openalex.org/S67393510","display_name":"Angewandte Chemie International Edition","issn_l":"1433-7851","issn":["1433-7851","1521-3773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2933745529","display_name":null,"funder_award_id":"22271017","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7009667666","display_name":null,"funder_award_id":"WA 2513/8","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"}],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4387965547.pdf","grobid_xml":"https://content.openalex.org/works/W4387965547.grobid-xml"},"referenced_works_count":48,"referenced_works":["https://openalex.org/W563531732","https://openalex.org/W1148208603","https://openalex.org/W1965986015","https://openalex.org/W1967313553","https://openalex.org/W1967690457","https://openalex.org/W1982574787","https://openalex.org/W1983516146","https://openalex.org/W1984232099","https://openalex.org/W2007747215","https://openalex.org/W2010560917","https://openalex.org/W2021963685","https://openalex.org/W2026203637","https://openalex.org/W2030362646","https://openalex.org/W2033778446","https://openalex.org/W2034115443","https://openalex.org/W2038352494","https://openalex.org/W2072000589","https://openalex.org/W2078006158","https://openalex.org/W2089807649","https://openalex.org/W2103051976","https://openalex.org/W2111581994","https://openalex.org/W2111826641","https://openalex.org/W2134173074","https://openalex.org/W2138447417","https://openalex.org/W2323780549","https://openalex.org/W2503984749","https://openalex.org/W2505779132","https://openalex.org/W2507407341","https://openalex.org/W2569506976","https://openalex.org/W2890121115","https://openalex.org/W2897926338","https://openalex.org/W2949627759","https://openalex.org/W2949633663","https://openalex.org/W2973972149","https://openalex.org/W2990526552","https://openalex.org/W3047192510","https://openalex.org/W4206622432","https://openalex.org/W4223537189","https://openalex.org/W4231081891","https://openalex.org/W4256294841","https://openalex.org/W4281757321","https://openalex.org/W4285087771","https://openalex.org/W4309662538","https://openalex.org/W4366814966","https://openalex.org/W4382011781","https://openalex.org/W4382345244","https://openalex.org/W4386265411","https://openalex.org/W6602046083"],"related_works":["https://openalex.org/W2119260012","https://openalex.org/W1996452907","https://openalex.org/W2028494991","https://openalex.org/W2044956834","https://openalex.org/W2161911826","https://openalex.org/W4390142415","https://openalex.org/W2586181124","https://openalex.org/W2001642257","https://openalex.org/W2341197645","https://openalex.org/W2586475009"],"abstract_inverted_index":{"Abstract":[0],"Uranium":[1],"diazomethanediide":[2],"complexes":[3,71],"can":[4],"be":[5],"prepared":[6],"and":[7,11,103,131,150,185],"their":[8],"synthesis,":[9],"structure":[10],"reactivity":[12,170],"were":[13,132],"explored.":[14],"Reaction":[15],"of":[16,171,202],"the":[17,67,142,145,169,200],"uranium":[18],"imido":[19],"compound":[20],"[":[21,41,72],"\u03b7":[22,42,73,88,105],"5":[23,29,43,49,74,80,89,95,106,112,122,160,177],"\u20101,2,4\u2010(Me":[24,75,90],"3":[25,27,45,51,62,76,78,91,93,108,114],"Si)":[26,77,92],"C":[28,48,79,94,111],"H":[30,50,81,96,113],"2":[31,33,47,53,64,82,84,97,99,101,110,116,147,193],"]":[32,52,83,98,115],"U=N(":[34,54],"p":[35,55],"\u2010tolyl)(dmap)":[36,56],"(":[37,57,100,121],"1":[38],")":[39,59,102],"or":[40],"\u20101,3\u2010(Me":[44,107],"C)":[46,109],"4":[58],"with":[60,157,191],"Me":[61],"SiCHN":[63],"cleanly":[65],"yields":[66],"first":[68],"isocyanoimido":[69],"metal":[70],"U(=NNC)(":[85],"\u03bc":[86,118],"\u2010CNN=)U(dmap)[":[87],"{[":[104],"U[":[117],"\u2010(=NNC)]}":[119],"6":[120],"),":[123],"respectively.":[124],"Both":[125],"compounds":[126],"exhibit":[127],"remarkable":[128],"thermal":[129],"stability":[130],"fully":[133],"characterized.":[134],"According":[135],"to":[136],"density":[137],"functional":[138],"theory":[139],"(DFT)":[140],"studies":[141],"bonding":[143],"between":[144],"Cp":[146],"U":[148],"2+":[149],"[NNC]":[151],"2\u2212":[152],"moieties":[153],"is":[154,165],"strongly":[155],"polarized":[156],"a":[158,180,188],"significant":[159],"f":[161],"orbital":[162],"contribution,":[163],"which":[164],"also":[166],"reflected":[167],"in":[168,187,199],"these":[172],"complexes.":[173],"For":[174],"example,":[175],"complex":[176],"acts":[178],"as":[179],"nucleophile":[181],"toward":[182],"alkylsilyl":[183],"halides":[184],"engages":[186],"[2+2]":[189],"cycloaddition":[190],"CS":[192],",":[194],"but":[195],"no":[196],"reaction":[197],"occurs":[198],"presence":[201],"internal":[203],"alkynes.":[204]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2023-10-28T00:00:00"}