{"id":"https://openalex.org/W4387430320","doi":"https://doi.org/10.1039/d3sc03771a","title":"Photocatalytic redox-neutral selective single C(sp 3 )\u2013F bond activation of perfluoroalkyl iminosulfides with alkenes and water","display_name":"Photocatalytic redox-neutral selective single C(sp 3 )\u2013F bond activation of perfluoroalkyl iminosulfides with alkenes and water","publication_year":2023,"publication_date":"2023-01-01","ids":{"openalex":"https://openalex.org/W4387430320","doi":"https://doi.org/10.1039/d3sc03771a","pmid":"https://pubmed.ncbi.nlm.nih.gov/37886085","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/10599478"},"language":"en","primary_location":{"id":"doi:10.1039/d3sc03771a","doi":"https://doi.org/10.1039/d3sc03771a","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3sc03771a","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/sc/d3sc03771a","source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://pubs.rsc.org/en/content/articlepdf/2023/sc/d3sc03771a","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100453478","display_name":"Tao Wang","orcid":"https://orcid.org/0000-0002-1494-5297","observed_orcids":["https://orcid.org/0000-0002-1494-5297"]},"institutions":[{"id":"https://openalex.org/I4391768068","display_name":"State Key Laboratory of Applied Organic Chemistry","ror":"https://ror.org/050fgfc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]},{"id":"https://openalex.org/I76214153","display_name":"Lanzhou University","ror":"https://ror.org/01mkqqe32","country_code":"CN","type":"education","lineage":["https://openalex.org/I76214153"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tao Wang","raw_affiliation_strings":["State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China","institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108932010","display_name":"Yuan-Yuan Zong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4391768068","display_name":"State Key Laboratory of Applied Organic Chemistry","ror":"https://ror.org/050fgfc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]},{"id":"https://openalex.org/I76214153","display_name":"Lanzhou University","ror":"https://ror.org/01mkqqe32","country_code":"CN","type":"education","lineage":["https://openalex.org/I76214153"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuan-Yuan Zong","raw_affiliation_strings":["State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China","institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032342607","display_name":"Tao Huang","orcid":"https://orcid.org/0000-0002-1888-7389","observed_orcids":["https://orcid.org/0000-0002-1888-7389"]},"institutions":[{"id":"https://openalex.org/I4391768068","display_name":"State Key Laboratory of Applied Organic Chemistry","ror":"https://ror.org/050fgfc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]},{"id":"https://openalex.org/I76214153","display_name":"Lanzhou University","ror":"https://ror.org/01mkqqe32","country_code":"CN","type":"education","lineage":["https://openalex.org/I76214153"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Tao Huang","raw_affiliation_strings":["State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China","institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089855815","display_name":"Xiaoling Jin","orcid":"https://orcid.org/0000-0003-1277-2844","observed_orcids":["https://orcid.org/0000-0003-1277-2844"]},"institutions":[{"id":"https://openalex.org/I4391768068","display_name":"State Key Laboratory of Applied Organic Chemistry","ror":"https://ror.org/050fgfc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]},{"id":"https://openalex.org/I76214153","display_name":"Lanzhou University","ror":"https://ror.org/01mkqqe32","country_code":"CN","type":"education","lineage":["https://openalex.org/I76214153"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiao-Ling Jin","raw_affiliation_strings":["State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China","institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071014155","display_name":"Li\u2010Zhu Wu","orcid":"https://orcid.org/0000-0002-5561-9922","observed_orcids":["https://orcid.org/0000-0002-5561-9922"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I4210140689","display_name":"Technical Institute of Physics and Chemistry","ror":"https://ror.org/04akaak77","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210140689"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Li-Zhu Wu","raw_affiliation_strings":["Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-5561-9922","affiliations":[{"raw_affiliation_string":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, P. R. China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210140689"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100409443","display_name":"Qiang Liu","orcid":"https://orcid.org/0000-0001-8845-1874","observed_orcids":["https://orcid.org/0000-0001-8845-1874"]},"institutions":[{"id":"https://openalex.org/I4391768068","display_name":"State Key Laboratory of Applied Organic Chemistry","ror":"https://ror.org/050fgfc71","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]},{"id":"https://openalex.org/I76214153","display_name":"Lanzhou University","ror":"https://ror.org/01mkqqe32","country_code":"CN","type":"education","lineage":["https://openalex.org/I76214153"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qiang Liu","raw_affiliation_strings":["State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"],"raw_orcid":"https://orcid.org/0000-0001-8845-1874","affiliations":[{"raw_affiliation_string":"State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China","institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5100409443"],"corresponding_institution_ids":["https://openalex.org/I4391768068","https://openalex.org/I76214153"],"apc_list":null,"apc_paid":null,"fwci":1.1845,"has_fulltext":true,"cited_by_count":12,"citation_normalized_percentile":{"value":0.74358114,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"14","issue":"41","first_page":"11566","last_page":"11572"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9526000022888184,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9526000022888184,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.04390000179409981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/c-f-bond-activation","display_name":"C\u2013F bond activation","score":0.9010000228881836},{"id":"https://openalex.org/keywords/defluorination","display_name":"defluorination","score":0.7459999918937683},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.7360000014305115},{"id":"https://openalex.org/keywords/redox-neutral-conditions","display_name":"redox-neutral conditions","score":0.8579999804496765},{"id":"https://openalex.org/keywords/alkenes","display_name":"alkenes","score":0.7379999756813049},{"id":"https://openalex.org/keywords/water","display_name":"water","score":0.7329999804496765},{"id":"https://openalex.org/keywords/chemoselectivity","display_name":"chemoselectivity","score":0.8820000290870667}],"concepts":[{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.7030314207077026},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.6975479125976562},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6640962362289429},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.48378774523735046},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3410070538520813},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2146570086479187},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17971467971801758}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1039/d3sc03771a","doi":"https://doi.org/10.1039/d3sc03771a","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3sc03771a","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/sc/d3sc03771a","source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},{"id":"doi:10.21203/rs.3.rs-2855364/v1","doi":"https://doi.org/10.21203/rs.3.rs-2855364/v1","is_oa":true,"landing_page_url":"http://dx.doi.org/10.21203/rs.3.rs-2855364/v1","pdf_url":"https://www.researchsquare.com/article/rs-2855364/latest.pdf","source":{"id":"https://openalex.org/S4306525896","display_name":"Research Square","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Research Square","raw_type":"posted-content"},{"id":"pmh:oai:pubmedcentral.nih.gov:10599478","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10599478","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10599478/pdf/SC-014-D3SC03771A.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chem Sci","raw_type":"Text"},{"id":"pmid:37886085","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37886085","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical science","raw_type":"Journal Article"}],"best_oa_location":{"id":"doi:10.1039/d3sc03771a","doi":"https://doi.org/10.1039/d3sc03771a","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3sc03771a","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/sc/d3sc03771a","source":{"id":"https://openalex.org/S184645833","display_name":"Chemical Science","issn_l":"2041-6520","issn":["2041-6520","2041-6539"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-b","jufo-3","ki-jl-2","norway-2","oarl","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Science","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2116894412","display_name":null,"funder_award_id":"22171120","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G8914618768","display_name":null,"funder_award_id":"22ZD6FA006","funder_id":"https://openalex.org/F4320325927","funder_display_name":"Science and Technology Department of Gansu Province"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320325927","display_name":"Science and Technology Department of Gansu Province","ror":"https://ror.org/03xz2hx98"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4387430320.pdf","grobid_xml":"https://content.openalex.org/works/W4387430320.grobid-xml"},"referenced_works_count":60,"referenced_works":["https://openalex.org/W862097791","https://openalex.org/W1994685053","https://openalex.org/W2001086298","https://openalex.org/W2008809042","https://openalex.org/W2012404887","https://openalex.org/W2040317364","https://openalex.org/W2042130451","https://openalex.org/W2047077500","https://openalex.org/W2052176548","https://openalex.org/W2070886586","https://openalex.org/W2116087305","https://openalex.org/W2127896256","https://openalex.org/W2141471401","https://openalex.org/W2144869962","https://openalex.org/W2237872262","https://openalex.org/W2264719596","https://openalex.org/W2314650327","https://openalex.org/W2325231891","https://openalex.org/W2333129245","https://openalex.org/W2334721406","https://openalex.org/W2528333019","https://openalex.org/W2768919121","https://openalex.org/W2785609333","https://openalex.org/W2794342785","https://openalex.org/W2888745810","https://openalex.org/W2898324446","https://openalex.org/W2938387481","https://openalex.org/W2949522755","https://openalex.org/W2953293741","https://openalex.org/W2960375316","https://openalex.org/W2965941270","https://openalex.org/W2969326752","https://openalex.org/W2969660692","https://openalex.org/W3022991215","https://openalex.org/W3096471324","https://openalex.org/W3119929546","https://openalex.org/W3133720607","https://openalex.org/W3156479067","https://openalex.org/W3165056805","https://openalex.org/W3169609691","https://openalex.org/W3195707515","https://openalex.org/W3198562969","https://openalex.org/W3213744347","https://openalex.org/W3214281681","https://openalex.org/W3216107856","https://openalex.org/W4200274223","https://openalex.org/W4200597387","https://openalex.org/W4220832787","https://openalex.org/W4225657699","https://openalex.org/W4244488829","https://openalex.org/W4280489397","https://openalex.org/W4284882617","https://openalex.org/W4285390532","https://openalex.org/W4289516333","https://openalex.org/W4293176145","https://openalex.org/W4308545021","https://openalex.org/W4308993981","https://openalex.org/W4310289027","https://openalex.org/W4311672999","https://openalex.org/W4385064406"],"related_works":["https://openalex.org/W4376126694","https://openalex.org/W4404155498","https://openalex.org/W7223157683","https://openalex.org/W4238085576","https://openalex.org/W3019897360","https://openalex.org/W4210652420","https://openalex.org/W4407780772","https://openalex.org/W4392602110","https://openalex.org/W7148638730","https://openalex.org/W3131208231"],"abstract_inverted_index":{"Abstract":[0],"Visible-light-promoted":[1],"site-selective":[2,39],"and":[3,17,47,74,77],"direct":[4],"C":[5],"\u2212":[6,84],"F":[7,85],"bond":[8,86],"functionalization":[9],"of":[10,26,31,60,81],"polyfluorinated":[11],"iminosulfides":[12],"were":[13],"accomplished":[14],"with":[15],"alkenes":[16],"water":[18],"under":[19],"redox-neutral":[20],"conditions,":[21],"affording":[22],"a":[23],"diverse":[24],"array":[25],"mutifluorinated":[27],"\u03b3-lactams.":[28],"A":[29],"variety":[30],"perfluoroalkyl":[32],"units":[33],"included":[34],"C2F5,":[35],"C3F7,":[36],"C4F9and":[37],"C5F11underwent":[38],"defluorofunctionlization.":[40],"This":[41],"protocol":[42],"allows":[43],"high":[44],"chemoselectivity":[45,80],"control":[46],"shows":[48],"excellent":[49],"functional":[50],"group":[51],"tolerance.":[52],"Mechanistic":[53],"studies":[54],"reveal":[55],"that":[56],"the":[57,61,65,68,72,75,79],"remarkable":[58],"changes":[59],"electron":[62],"geometries":[63],"during":[64],"defluorination":[66],"widen":[67],"redox":[69],"window":[70],"between":[71],"substrates":[73],"products":[76],"ensure":[78],"single":[82],"C(sp3)":[83],"cleavage.":[87]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":7}],"updated_date":"2026-11-09T13:22:03.289127","created_date":"2023-10-08T00:00:00"}