{"id":"https://openalex.org/W4387272091","doi":"https://doi.org/10.1039/d3cc01757e","title":"Employing a chiroptical sensor for the absolute stereochemical determination of \u03b1-amino and \u03b1-hydroxyphosphonates","display_name":"Employing a chiroptical sensor for the absolute stereochemical determination of \u03b1-amino and \u03b1-hydroxyphosphonates","publication_year":2023,"publication_date":"2023-01-01","ids":{"openalex":"https://openalex.org/W4387272091","doi":"https://doi.org/10.1039/d3cc01757e","pmid":"https://pubmed.ncbi.nlm.nih.gov/37791684"},"language":"en","primary_location":{"id":"doi:10.1039/d3cc01757e","doi":"https://doi.org/10.1039/d3cc01757e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d3cc01757e","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Communications","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5055067719","display_name":"Debarshi Chakraborty","orcid":"https://orcid.org/0000-0003-0136-0481","observed_orcids":["https://orcid.org/0000-0003-0136-0481"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Debarshi Chakraborty","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100415047","display_name":"Zheng Li","orcid":"https://orcid.org/0000-0003-1944-8270","observed_orcids":["https://orcid.org/0000-0003-1944-8270"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Li Zheng","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009013331","display_name":"Yijing Dai","orcid":"https://orcid.org/0000-0002-9608-8806","observed_orcids":["https://orcid.org/0000-0002-9608-8806"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yijing Dai","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5092990067","display_name":"Jeff Gwasdacus","orcid":"https://orcid.org/0000-0003-1378-6316","observed_orcids":["https://orcid.org/0000-0003-1378-6316"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jeff Gwasdacus","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":"https://orcid.org/0000-0003-1378-6316","affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5092990068","display_name":"James E. McTighe","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James E. McTighe","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068068080","display_name":"William Dean Wulff","orcid":"https://orcid.org/0000-0002-5668-4312","observed_orcids":["https://orcid.org/0000-0002-5668-4312"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"William D. Wulff","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":"https://orcid.org/0000-0002-5668-4312","affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052952898","display_name":"Babak Borhan","orcid":"https://orcid.org/0000-0002-3193-0732","observed_orcids":["https://orcid.org/0000-0002-3193-0732"]},"institutions":[{"id":"https://openalex.org/I87216513","display_name":"Michigan State University","ror":"https://ror.org/05hs6h993","country_code":"US","type":"education","lineage":["https://openalex.org/I87216513"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Babak Borhan","raw_affiliation_strings":["Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA"],"raw_orcid":"https://orcid.org/0000-0002-3193-0732","affiliations":[{"raw_affiliation_string":"Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA","institution_ids":["https://openalex.org/I87216513"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5052952898","https://openalex.org/A5068068080"],"corresponding_institution_ids":["https://openalex.org/I87216513"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.10176261,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"59","issue":"84","first_page":"12629","last_page":"12632"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.5698000192642212,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12748","display_name":"Molecular spectroscopy and chirality","score":0.5698000192642212,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.17260000109672546,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.09769999980926514,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/absolute-configuration","display_name":"absolute configuration","score":0.722000002861023},{"id":"https://openalex.org/keywords/alpha-aminophosphonates","display_name":"\u03b1-aminophosphonates","score":0.9750000238418579},{"id":"https://openalex.org/keywords/alpha-hydroxyphosphonates","display_name":"\u03b1-hydroxyphosphonates","score":0.953000009059906},{"id":"https://openalex.org/keywords/circular-dichroism","display_name":"circular dichroism","score":0.9679999947547913},{"id":"https://openalex.org/keywords/binding-model","display_name":"binding model","score":0.6690000295639038},{"id":"https://openalex.org/keywords/chiral-recognition","display_name":"chiral recognition","score":0.5320000052452087}],"concepts":[{"id":"https://openalex.org/C92869835","wikidata":"https://www.wikidata.org/wiki/Q1209450","display_name":"Dichroic glass","level":2,"score":0.8046773672103882},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.7772508263587952},{"id":"https://openalex.org/C2775859700","wikidata":"https://www.wikidata.org/wiki/Q568855","display_name":"Helicity","level":2,"score":0.7299858331680298},{"id":"https://openalex.org/C25170562","wikidata":"https://www.wikidata.org/wiki/Q2052053","display_name":"Absolute configuration","level":2,"score":0.7188190221786499},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6533480882644653},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5667532682418823},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.48116740584373474},{"id":"https://openalex.org/C2908647359","wikidata":"https://www.wikidata.org/wiki/Q2625603","display_name":"Population","level":2,"score":0.45033931732177734},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3421977162361145},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.1412259042263031},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.13585570454597473},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.13018465042114258},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08543971180915833},{"id":"https://openalex.org/C144024400","wikidata":"https://www.wikidata.org/wiki/Q21201","display_name":"Sociology","level":0,"score":0.0},{"id":"https://openalex.org/C149923435","wikidata":"https://www.wikidata.org/wiki/Q37732","display_name":"Demography","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C109214941","wikidata":"https://www.wikidata.org/wiki/Q18334","display_name":"Particle physics","level":1,"score":0.0},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0},{"id":"https://openalex.org/C52703039","wikidata":"https://www.wikidata.org/wiki/Q5101837","display_name":"Chiral symmetry breaking","level":3,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/d3cc01757e","doi":"https://doi.org/10.1039/d3cc01757e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/d3cc01757e","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Communications","raw_type":"journal-article"},{"id":"pmid:37791684","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37791684","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical communications (Cambridge, England)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3827224499","display_name":null,"funder_award_id":"CHE-2247261","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":48,"referenced_works":["https://openalex.org/W652646270","https://openalex.org/W1967574410","https://openalex.org/W1981128942","https://openalex.org/W1981179376","https://openalex.org/W1982567414","https://openalex.org/W1984527206","https://openalex.org/W1986945099","https://openalex.org/W1990266854","https://openalex.org/W2012187517","https://openalex.org/W2019709253","https://openalex.org/W2024899911","https://openalex.org/W2026761188","https://openalex.org/W2032133327","https://openalex.org/W2034182162","https://openalex.org/W2036125344","https://openalex.org/W2047087474","https://openalex.org/W2055816317","https://openalex.org/W2068834501","https://openalex.org/W2070677923","https://openalex.org/W2076239965","https://openalex.org/W2077513254","https://openalex.org/W2087218100","https://openalex.org/W2089031607","https://openalex.org/W2089618088","https://openalex.org/W2089706156","https://openalex.org/W2140927816","https://openalex.org/W2144770641","https://openalex.org/W2153126574","https://openalex.org/W2154296281","https://openalex.org/W2158730144","https://openalex.org/W2299015718","https://openalex.org/W2318015118","https://openalex.org/W2400800461","https://openalex.org/W2471303148","https://openalex.org/W2495346592","https://openalex.org/W2742410801","https://openalex.org/W2885311230","https://openalex.org/W2952069087","https://openalex.org/W2952983605","https://openalex.org/W2952993643","https://openalex.org/W3044852334","https://openalex.org/W3047083928","https://openalex.org/W3119180937","https://openalex.org/W3192213403","https://openalex.org/W3212395004","https://openalex.org/W4220958819","https://openalex.org/W4243763381","https://openalex.org/W4294817119"],"related_works":["https://openalex.org/W2480950555","https://openalex.org/W2099052194","https://openalex.org/W2021777662","https://openalex.org/W2005161825","https://openalex.org/W2744846036","https://openalex.org/W2326633336","https://openalex.org/W7055329546","https://openalex.org/W4232604849","https://openalex.org/W2039910607","https://openalex.org/W4249334233"],"abstract_inverted_index":{"a":[0],"simple":[1],"binding":[2],"model.":[3],"The":[4],"relative":[5],"size":[6],"of":[7],"the":[8,11],"substituents":[9],"dictates":[10],"predominant":[12],"helical":[13],"population,":[14],"leading":[15],"to":[16],"an":[17],"easy":[18],"circular":[19],"dichroic":[20],"readout.":[21]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2023-10-03T00:00:00"}