{"id":"https://openalex.org/W4387048189","doi":"https://doi.org/10.1039/d3qi01541f","title":"Reactivity variance between stereoisomers of saturated N-heterocyclic carbenes on gold surfaces","display_name":"Reactivity variance between stereoisomers of saturated N-heterocyclic carbenes on gold surfaces","publication_year":2023,"publication_date":"2023-01-01","ids":{"openalex":"https://openalex.org/W4387048189","doi":"https://doi.org/10.1039/d3qi01541f"},"language":"en","primary_location":{"id":"doi:10.1039/d3qi01541f","doi":"https://doi.org/10.1039/d3qi01541f","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3qi01541f","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/qi/d3qi01541f","source":{"id":"https://openalex.org/S2764402489","display_name":"Inorganic Chemistry Frontiers","issn_l":"2052-1545","issn":["2052-1545","2052-1553"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry Frontiers","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://pubs.rsc.org/en/content/articlepdf/2023/qi/d3qi01541f","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072726828","display_name":"Gurkiran Kaur","orcid":"https://orcid.org/0000-0001-8757-5605","observed_orcids":["https://orcid.org/0000-0001-8757-5605"]},"institutions":[{"id":"https://openalex.org/I75027704","display_name":"University of Tennessee at Knoxville","ror":"https://ror.org/020f3ap87","country_code":"US","type":"education","lineage":["https://openalex.org/I75027704"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gurkiran Kaur","raw_affiliation_strings":["Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA"],"raw_orcid":"https://orcid.org/0000-0001-8757-5605","affiliations":[{"raw_affiliation_string":"Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA","institution_ids":["https://openalex.org/I75027704"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033007555","display_name":"Nathaniel L. Dominique","orcid":"https://orcid.org/0000-0002-0439-9982","observed_orcids":["https://orcid.org/0000-0002-0439-9982"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nathaniel L. Dominique","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA"],"raw_orcid":"https://orcid.org/0000-0002-0439-9982","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100593033","display_name":"Gaohe Hu","orcid":"https://orcid.org/0009-0009-6625-906X","observed_orcids":["https://orcid.org/0009-0009-6625-906X"]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gaohe Hu","raw_affiliation_strings":["Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA","institution_ids":["https://openalex.org/I130769515"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047044280","display_name":"Phattananawee Nalaoh","orcid":"https://orcid.org/0000-0002-8470-3322","observed_orcids":["https://orcid.org/0000-0002-8470-3322"]},"institutions":[{"id":"https://openalex.org/I75027704","display_name":"University of Tennessee at Knoxville","ror":"https://ror.org/020f3ap87","country_code":"US","type":"education","lineage":["https://openalex.org/I75027704"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Phattananawee Nalaoh","raw_affiliation_strings":["Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA"],"raw_orcid":"https://orcid.org/0000-0002-8470-3322","affiliations":[{"raw_affiliation_string":"Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA","institution_ids":["https://openalex.org/I75027704"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022235828","display_name":"Rebekah L. Thimes","orcid":"https://orcid.org/0000-0001-6333-126X","observed_orcids":["https://orcid.org/0000-0001-6333-126X"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Rebekah L. Thimes","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069048531","display_name":"Shelby L. Strausser","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I75027704","display_name":"University of Tennessee at Knoxville","ror":"https://ror.org/020f3ap87","country_code":"US","type":"education","lineage":["https://openalex.org/I75027704"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shelby L. Strausser","raw_affiliation_strings":["Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA","institution_ids":["https://openalex.org/I75027704"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5053090797","display_name":"Lasse Jensen","orcid":"https://orcid.org/0000-0003-1237-5021","observed_orcids":["https://orcid.org/0000-0003-1237-5021"]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Lasse Jensen","raw_affiliation_strings":["Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA"],"raw_orcid":"https://orcid.org/0000-0003-1237-5021","affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA","institution_ids":["https://openalex.org/I130769515"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077658490","display_name":"Jon P. Camden","orcid":"https://orcid.org/0000-0002-6179-2692","observed_orcids":["https://orcid.org/0000-0002-6179-2692"]},"institutions":[{"id":"https://openalex.org/I107639228","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43","country_code":"US","type":"education","lineage":["https://openalex.org/I107639228"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jon P. Camden","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA"],"raw_orcid":"https://orcid.org/0000-0002-6179-2692","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA","institution_ids":["https://openalex.org/I107639228"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032112088","display_name":"David M. Jenkins","orcid":"https://orcid.org/0000-0003-2683-9157","observed_orcids":["https://orcid.org/0000-0003-2683-9157"]},"institutions":[{"id":"https://openalex.org/I75027704","display_name":"University of Tennessee at Knoxville","ror":"https://ror.org/020f3ap87","country_code":"US","type":"education","lineage":["https://openalex.org/I75027704"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"David M. Jenkins","raw_affiliation_strings":["Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA"],"raw_orcid":"https://orcid.org/0000-0003-2683-9157","affiliations":[{"raw_affiliation_string":"Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996, USA","institution_ids":["https://openalex.org/I75027704"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5032112088","https://openalex.org/A5053090797","https://openalex.org/A5077658490"],"corresponding_institution_ids":["https://openalex.org/I107639228","https://openalex.org/I130769515","https://openalex.org/I75027704"],"apc_list":null,"apc_paid":null,"fwci":0.9222,"has_fulltext":true,"cited_by_count":9,"citation_normalized_percentile":{"value":0.67282872,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"10","issue":"21","first_page":"6282","last_page":"6293"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.6509000062942505,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.6509000062942505,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.33180001378059387,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.002400000113993883,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.9330000281333923},{"id":"https://openalex.org/keywords/stereoisomers","display_name":"stereoisomers","score":0.8700000047683716},{"id":"https://openalex.org/keywords/gold-surfaces","display_name":"gold surfaces","score":0.6439999938011169},{"id":"https://openalex.org/keywords/c2-symmetry","display_name":"C2 symmetry","score":0.722000002861023},{"id":"https://openalex.org/keywords/cs-symmetry","display_name":"Cs symmetry","score":0.9729999899864197},{"id":"https://openalex.org/keywords/gold-films","display_name":"gold films","score":0.5189999938011169},{"id":"https://openalex.org/keywords/surface-adsorption","display_name":"surface adsorption","score":0.4399999976158142}],"concepts":[{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.8746267557144165},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5641134977340698},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3547619879245758},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/d3qi01541f","doi":"https://doi.org/10.1039/d3qi01541f","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3qi01541f","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/qi/d3qi01541f","source":{"id":"https://openalex.org/S2764402489","display_name":"Inorganic Chemistry Frontiers","issn_l":"2052-1545","issn":["2052-1545","2052-1553"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry Frontiers","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1039/d3qi01541f","doi":"https://doi.org/10.1039/d3qi01541f","is_oa":true,"landing_page_url":"https://doi.org/10.1039/d3qi01541f","pdf_url":"https://pubs.rsc.org/en/content/articlepdf/2023/qi/d3qi01541f","source":{"id":"https://openalex.org/S2764402489","display_name":"Inorganic Chemistry Frontiers","issn_l":"2052-1545","issn":["2052-1545","2052-1553"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-2","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry Frontiers","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1785054185","display_name":"Collaborative Research: Characterization and Optimization of N-Heterocyclic Carbene Functionalized Nanoparticle Systems","funder_award_id":"2108330","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G2351931133","display_name":null,"funder_award_id":"CHE2108330","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G3503173706","display_name":null,"funder_award_id":"CHE-2312222","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G4607515710","display_name":"Collaborative Research: Characterization and Optimization of N-Heterocyclic Carbene Functionalized Nanoparticle Systems","funder_award_id":"2108328","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G476511176","display_name":null,"funder_award_id":"2108328","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G5031477582","display_name":"Computational Methods for Ensemble Averaged Surface-Enhanced Raman Scattering","funder_award_id":"2312222","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G5404812216","display_name":"New methods for linear and nonlinear Spectroscopy in inhomogeneous electromagnetic fields","funder_award_id":"1856419","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G6493617547","display_name":null,"funder_award_id":"CHE-1856419","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G8657272577","display_name":null,"funder_award_id":"2108330","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G938035178","display_name":null,"funder_award_id":"CHE-2108328","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320310260","display_name":"University of Notre Dame","ror":"https://ror.org/00mkhxb43"},{"id":"https://openalex.org/F4320333901","display_name":"Notre Dame Integrated Imaging Facility, University of Notre Dame","ror":null},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4387048189.pdf","grobid_xml":"https://content.openalex.org/works/W4387048189.grobid-xml"},"referenced_works_count":68,"referenced_works":["https://openalex.org/W1969335186","https://openalex.org/W1969605747","https://openalex.org/W1974713831","https://openalex.org/W1983838740","https://openalex.org/W1984020896","https://openalex.org/W1991868992","https://openalex.org/W1996784448","https://openalex.org/W2009836106","https://openalex.org/W2011705292","https://openalex.org/W2030634530","https://openalex.org/W2030687437","https://openalex.org/W2031691942","https://openalex.org/W2035536419","https://openalex.org/W2044318715","https://openalex.org/W2044441303","https://openalex.org/W2046890061","https://openalex.org/W2055770627","https://openalex.org/W2061738127","https://openalex.org/W2066635731","https://openalex.org/W2071371510","https://openalex.org/W2081946270","https://openalex.org/W2084151021","https://openalex.org/W2086957099","https://openalex.org/W2091265465","https://openalex.org/W2092049851","https://openalex.org/W2095374362","https://openalex.org/W2096747776","https://openalex.org/W2116373706","https://openalex.org/W2119423701","https://openalex.org/W2119628039","https://openalex.org/W2129321824","https://openalex.org/W2132331298","https://openalex.org/W2173775091","https://openalex.org/W2261815319","https://openalex.org/W2293237240","https://openalex.org/W2301697910","https://openalex.org/W2319044135","https://openalex.org/W2469746628","https://openalex.org/W2562451752","https://openalex.org/W2591864733","https://openalex.org/W2729172579","https://openalex.org/W2784537151","https://openalex.org/W2800782731","https://openalex.org/W2896399839","https://openalex.org/W2899669545","https://openalex.org/W2921531998","https://openalex.org/W2922509303","https://openalex.org/W2926036315","https://openalex.org/W2972859682","https://openalex.org/W2977435517","https://openalex.org/W2982145787","https://openalex.org/W2999197386","https://openalex.org/W3008183976","https://openalex.org/W3033006646","https://openalex.org/W3044983021","https://openalex.org/W3045491018","https://openalex.org/W3119140696","https://openalex.org/W3131735448","https://openalex.org/W3158142694","https://openalex.org/W3158822905","https://openalex.org/W3184328247","https://openalex.org/W3202746504","https://openalex.org/W4282561666","https://openalex.org/W4308119591","https://openalex.org/W4308369204","https://openalex.org/W4312391984","https://openalex.org/W4322617482","https://openalex.org/W4367601560"],"related_works":["https://openalex.org/W4312391984","https://openalex.org/W4308369204","https://openalex.org/W2028389264","https://openalex.org/W4408363279","https://openalex.org/W2078790658","https://openalex.org/W2025849277","https://openalex.org/W2949806588","https://openalex.org/W1998564512","https://openalex.org/W2952060124","https://openalex.org/W2758731220"],"abstract_inverted_index":{"Two":[0],"stereoisomers,":[1],"one":[2,7],"C":[3,8],"2":[4],"symmetric":[5],"and":[6,21],"s":[9],"symmetric,":[10],"of":[11],"saturated":[12],"N-heterocyclic":[13],"carbenes":[14],"(NHCs)":[15],"were":[16],"placed":[17],"on":[18],"gold":[19],"films":[20],"they":[22],"demonstrate":[23],"different":[24],"reactivity.":[25]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1}],"updated_date":"2026-09-21T07:43:02.447757","created_date":"2023-09-27T00:00:00"}
