{"id":"https://openalex.org/W4386818324","doi":"https://doi.org/10.1021/jacs.3c08216","title":"Photoredox Catalysis-Enabled Sulfination of Alcohols and Bromides","display_name":"Photoredox Catalysis-Enabled Sulfination of Alcohols and Bromides","publication_year":2023,"publication_date":"2023-09-18","ids":{"openalex":"https://openalex.org/W4386818324","doi":"https://doi.org/10.1021/jacs.3c08216","pmid":"https://pubmed.ncbi.nlm.nih.gov/37721547","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/10680125"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.3c08216","doi":"https://doi.org/10.1021/jacs.3c08216","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.3c08216","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10680125/pdf/nihms-1945418.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021926549","display_name":"William Carson","orcid":"https://orcid.org/0000-0002-0321-5096","observed_orcids":["https://orcid.org/0000-0002-0321-5096"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"William P. Carson II","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010220817","display_name":"Patrick Sarver","orcid":"https://orcid.org/0000-0001-7227-8966","observed_orcids":["https://orcid.org/0000-0001-7227-8966"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Patrick J. Sarver","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States"],"raw_orcid":"https://orcid.org/0000-0001-7227-8966","affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011769436","display_name":"Goudy Noelle","orcid":"https://orcid.org/0000-0003-0374-6847","observed_orcids":["https://orcid.org/0000-0003-0374-6847"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Noelle S. Goudy","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States"],"raw_orcid":"https://orcid.org/0000-0003-0374-6847","affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5025805979","display_name":"David W. C. MacMillan","orcid":"https://orcid.org/0000-0001-6447-0587","observed_orcids":["https://orcid.org/0000-0001-6447-0587"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"David W. C. MacMillan","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States"],"raw_orcid":"https://orcid.org/0000-0001-6447-0587","affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5025805979"],"corresponding_institution_ids":["https://openalex.org/I20089843"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":6.8422,"has_fulltext":true,"cited_by_count":67,"citation_normalized_percentile":{"value":0.98785966,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":97,"max":100},"biblio":{"volume":"145","issue":"38","first_page":"20767","last_page":"20774"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.010099999606609344,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12251","display_name":"Synthesis and Catalytic Reactions","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photoredox-catalysis","display_name":"photoredox catalysis","score":0.9710000157356262},{"id":"https://openalex.org/keywords/alcohol-chemistry","display_name":"alcohol chemistry","score":0.8889999985694885},{"id":"https://openalex.org/keywords/alkyl-bromides","display_name":"alkyl bromides","score":0.9959999918937683},{"id":"https://openalex.org/keywords/radical-precursors","display_name":"radical precursors","score":0.8759999871253967},{"id":"https://openalex.org/keywords/sulfonamides","display_name":"sulfonamides","score":0.9089999794960022},{"id":"https://openalex.org/keywords/sulfonyl-fluorides","display_name":"sulfonyl fluorides","score":0.9240000247955322},{"id":"https://openalex.org/keywords/late-stage-functionalization","display_name":"late-stage functionalization","score":0.7250000238418579},{"id":"https://openalex.org/keywords/natural-products","display_name":"natural products","score":0.5519999861717224}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9519931077957153},{"id":"https://openalex.org/C45849291","wikidata":"https://www.wikidata.org/wiki/Q17166058","display_name":"Photoredox catalysis","level":4,"score":0.8362790942192078},{"id":"https://openalex.org/C87906975","wikidata":"https://www.wikidata.org/wiki/Q899114","display_name":"Sulfonyl","level":3,"score":0.7677580714225769},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.6452628970146179},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5337594151496887},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.529945969581604},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.4928000271320343},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4768023192882538},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.42617207765579224},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.35281801223754883}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jacs.3c08216","doi":"https://doi.org/10.1021/jacs.3c08216","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.3c08216","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:37721547","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/37721547","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:10680125","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10680125","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10680125/pdf/nihms-1945418.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Am Chem Soc","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:10680125","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/10680125","pdf_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC10680125/pdf/nihms-1945418.pdf","source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Am Chem Soc","raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3368294025","display_name":"Graduate Research Fellowship Program (GRFP)","funder_award_id":"2039656","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G5406835506","display_name":null,"funder_award_id":"DGE-2039656","funder_id":"https://openalex.org/F4320337368","funder_display_name":"Division of Graduate Education"},{"id":"https://openalex.org/G9000912975","display_name":"Photoredox Catalysis Applications in Organometallics and Chemical Biology","funder_award_id":"R35GM134897","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320307115","display_name":"Bristol-Myers Squibb","ror":"https://ror.org/00gtmwv55"},{"id":"https://openalex.org/F4320307765","display_name":"Pfizer","ror":"https://ror.org/01xdqrp08"},{"id":"https://openalex.org/F4320309086","display_name":"Celgene","ror":"https://ror.org/0527yg379"},{"id":"https://openalex.org/F4320309292","display_name":"Princeton University","ror":"https://ror.org/00hx57361"},{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320332193","display_name":"Genentech","ror":"https://ror.org/04gndp242"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337368","display_name":"Division of Graduate Education","ror":"https://ror.org/00whkrf32"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W4386818324.pdf","grobid_xml":"https://content.openalex.org/works/W4386818324.grobid-xml"},"referenced_works_count":46,"referenced_works":["https://openalex.org/W1453281523","https://openalex.org/W1975947882","https://openalex.org/W1984145201","https://openalex.org/W1994253906","https://openalex.org/W2013368754","https://openalex.org/W2035183023","https://openalex.org/W2094129737","https://openalex.org/W2107226240","https://openalex.org/W2118737630","https://openalex.org/W2119039945","https://openalex.org/W2130841503","https://openalex.org/W2239806434","https://openalex.org/W2295278142","https://openalex.org/W2334417220","https://openalex.org/W2348529374","https://openalex.org/W2472000160","https://openalex.org/W2760997335","https://openalex.org/W2770108186","https://openalex.org/W2784913318","https://openalex.org/W2786943411","https://openalex.org/W2792299721","https://openalex.org/W2806697979","https://openalex.org/W2807247089","https://openalex.org/W2901960265","https://openalex.org/W2933530798","https://openalex.org/W2946651253","https://openalex.org/W2954109746","https://openalex.org/W2964588072","https://openalex.org/W2971850243","https://openalex.org/W3010571866","https://openalex.org/W3035896776","https://openalex.org/W3044388665","https://openalex.org/W3083979914","https://openalex.org/W3102918969","https://openalex.org/W3124392357","https://openalex.org/W3135024637","https://openalex.org/W3159000749","https://openalex.org/W3164266664","https://openalex.org/W3175870912","https://openalex.org/W3198900623","https://openalex.org/W3201682397","https://openalex.org/W3205125179","https://openalex.org/W3217590202","https://openalex.org/W4206253369","https://openalex.org/W4221121422","https://openalex.org/W4236662555"],"related_works":["https://openalex.org/W4407340947","https://openalex.org/W7162640293","https://openalex.org/W4389986434","https://openalex.org/W4414495436","https://openalex.org/W2913816214","https://openalex.org/W4310421924","https://openalex.org/W4365442739","https://openalex.org/W3210096688","https://openalex.org/W4416688206","https://openalex.org/W2999525161"],"abstract_inverted_index":{"Sulfinates":[0],"are":[1,41,75],"important":[2],"lynchpin":[3],"intermediates":[4],"in":[5],"pharmaceutical":[6],"production;":[7],"however,":[8],"their":[9,18],"synthesis":[10,62],"via":[11,100],"photoredox":[12,133],"catalysis":[13],"is":[14,97],"challenging":[15],"because":[16],"of":[17,31,46,63,72,94,104,124,132],"facile":[19],"oxidation.":[20],"We":[21],"herein":[22],"disclose":[23],"a":[24],"photocatalytic":[25],"strategy":[26],"for":[27],"the":[28,44,64,78,101,122,130],"direct":[29],"conversion":[30],"alcohols":[32],"and":[33,56,89,107,113],"alkyl":[34,37],"bromides":[35],"into":[36,109],"sulfinates.":[38],"These":[39],"transformations":[40],"enabled":[42],"by":[43],"utilization":[45],"easily":[47],"oxidized":[48],"radical":[49,126],"precursors\u2500namely,":[50],"alcohol":[51],"N":[52,57],"-heterocyclic":[53],"carbene":[54],"adducts":[55],"-adamantyl":[58],"aminosupersilane\u2500that":[59],"facilitate":[60],"efficient":[61],"oxidatively":[65],"labile":[66],"sulfinate":[67],"products.":[68],"A":[69],"broad":[70],"range":[71],"functional":[73],"groups":[74],"amenable":[76],"to":[77,84,128],"reported":[79],"transformations,":[80],"providing":[81],"rapid":[82],"access":[83],"sulfonamides,":[85],"sulfonyl":[86,115],"halides,":[87],"sulfones,":[88],"sulfonic":[90],"acids.":[91],"The":[92],"utility":[93],"these":[95],"methods":[96],"further":[98],"demonstrated":[99],"late-stage":[102],"diversification":[103],"natural":[105],"products":[106],"drugs":[108],"pharmaceutically":[110],"relevant":[111],"sulfonamides":[112],"\u201cclickable\u201d":[114],"fluorides.":[116],"In":[117],"summary,":[118],"this":[119],"work":[120],"illustrates":[121],"potential":[123],"novel":[125],"precursors":[127],"expand":[129],"breadth":[131],"transformations.":[134]},"counts_by_year":[{"year":2026,"cited_by_count":21},{"year":2025,"cited_by_count":20},{"year":2024,"cited_by_count":22},{"year":2023,"cited_by_count":4}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2023-09-19T00:00:00"}
