{"id":"https://openalex.org/W4385874792","doi":"https://doi.org/10.1021/acs.jpcc.3c01984","title":"Potential Effects on the Catalytic Mechanisms of OER and ORR","display_name":"Potential Effects on the Catalytic Mechanisms of OER and ORR","publication_year":2023,"publication_date":"2023-08-16","ids":{"openalex":"https://openalex.org/W4385874792","doi":"https://doi.org/10.1021/acs.jpcc.3c01984"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpcc.3c01984","doi":"https://doi.org/10.1021/acs.jpcc.3c01984","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.3c01984","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100406668","display_name":"Quan Zhang","orcid":"https://orcid.org/0000-0001-8925-2906","observed_orcids":["https://orcid.org/0000-0001-8925-2906"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Quan Zhang","raw_affiliation_strings":["MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China"],"raw_orcid":"https://orcid.org/0000-0001-8925-2906","affiliations":[{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100786185","display_name":"Yang Zhang","orcid":"https://orcid.org/0000-0002-2132-0148","observed_orcids":["https://orcid.org/0000-0002-2132-0148","https://orcid.org/0000-0003-3949-1823"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yang Zhang","raw_affiliation_strings":["MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China"],"raw_orcid":"https://orcid.org/0000-0002-2132-0148","affiliations":[{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100413416","display_name":"Shengli Zhang","orcid":"https://orcid.org/0000-0002-5866-7591","observed_orcids":["https://orcid.org/0000-0002-5866-7591"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Shengli Zhang","raw_affiliation_strings":["MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China"],"raw_orcid":"https://orcid.org/0000-0002-5866-7591","affiliations":[{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5005055697","display_name":"Guoping Gao","orcid":"https://orcid.org/0000-0002-6106-7423","observed_orcids":["https://orcid.org/0000-0002-6106-7423"]},"institutions":[{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Guoping Gao","raw_affiliation_strings":["MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi\u2019an Jiaotong University, Xi\u2019an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]},{"raw_affiliation_string":"MOE Key Lab for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China","institution_ids":["https://openalex.org/I87445476"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5005055697","https://openalex.org/A5100413416"],"corresponding_institution_ids":["https://openalex.org/I87445476"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.8663,"has_fulltext":false,"cited_by_count":39,"citation_normalized_percentile":{"value":0.85522647,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":100},"biblio":{"volume":"127","issue":"33","first_page":"16346","last_page":"16356"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/oxygen-evolution-reaction","display_name":"oxygen evolution reaction","score":0.9990000128746033},{"id":"https://openalex.org/keywords/oxygen-reduction-reaction","display_name":"oxygen reduction reaction","score":1.0},{"id":"https://openalex.org/keywords/single-atom-catalysts","display_name":"single-atom catalysts","score":0.9900000095367432},{"id":"https://openalex.org/keywords/work-function","display_name":"work function","score":0.625},{"id":"https://openalex.org/keywords/surface-dipole","display_name":"surface dipole","score":0.9950000047683716},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.8960000276565552},{"id":"https://openalex.org/keywords/overpotential","display_name":"overpotential","score":0.6669999957084656},{"id":"https://openalex.org/keywords/universal-scaling-relations","display_name":"universal scaling relations","score":0.7990000247955322},{"id":"https://openalex.org/keywords/bifunctional-electrocatalysts","display_name":"bifunctional electrocatalysts","score":0.9300000071525574}],"concepts":[{"id":"https://openalex.org/C186460083","wikidata":"https://www.wikidata.org/wiki/Q333853","display_name":"Overpotential","level":4,"score":0.8667657375335693},{"id":"https://openalex.org/C135473242","wikidata":"https://www.wikidata.org/wiki/Q4147614","display_name":"Oxygen evolution","level":4,"score":0.7030963897705078},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6709083914756775},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.645315945148468},{"id":"https://openalex.org/C2780443040","wikidata":"https://www.wikidata.org/wiki/Q3737863","display_name":"Bifunctional","level":3,"score":0.6191067695617676},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5384893417358398},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.5220111012458801},{"id":"https://openalex.org/C18787249","wikidata":"https://www.wikidata.org/wiki/Q11025104","display_name":"Electrode potential","level":4,"score":0.4755820035934448},{"id":"https://openalex.org/C33989665","wikidata":"https://www.wikidata.org/wiki/Q5357962","display_name":"Electrocatalyst","level":4,"score":0.43621838092803955},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.30573782324790955},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.21910947561264038},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.1252320110797882},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.jpcc.3c01984","doi":"https://doi.org/10.1021/acs.jpcc.3c01984","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpcc.3c01984","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":40,"referenced_works":["https://openalex.org/W1981368803","https://openalex.org/W2015871216","https://openalex.org/W2017841378","https://openalex.org/W2020119851","https://openalex.org/W2029347502","https://openalex.org/W2034291571","https://openalex.org/W2040182267","https://openalex.org/W2075219690","https://openalex.org/W2092157292","https://openalex.org/W2146546128","https://openalex.org/W2153882824","https://openalex.org/W2159987122","https://openalex.org/W2167035995","https://openalex.org/W2276671738","https://openalex.org/W2322429591","https://openalex.org/W2581493313","https://openalex.org/W2586065917","https://openalex.org/W2617194355","https://openalex.org/W2785307491","https://openalex.org/W2803427589","https://openalex.org/W2811283851","https://openalex.org/W2908916379","https://openalex.org/W2942910260","https://openalex.org/W2999079946","https://openalex.org/W3009385115","https://openalex.org/W3033005886","https://openalex.org/W3084562712","https://openalex.org/W3089261827","https://openalex.org/W3094777310","https://openalex.org/W3100475594","https://openalex.org/W3158016175","https://openalex.org/W3169129413","https://openalex.org/W3209027308","https://openalex.org/W4225287835","https://openalex.org/W4229454204","https://openalex.org/W4254154065","https://openalex.org/W4288430346","https://openalex.org/W4289784883","https://openalex.org/W4308919952","https://openalex.org/W4372335604"],"related_works":["https://openalex.org/W2329576799","https://openalex.org/W3010715276","https://openalex.org/W2530140974","https://openalex.org/W4415447716","https://openalex.org/W7082356426","https://openalex.org/W4387642948","https://openalex.org/W7148468451","https://openalex.org/W4404868130","https://openalex.org/W3153802102","https://openalex.org/W4409238190"],"abstract_inverted_index":{"A":[0],"fundamental":[1],"understanding":[2,183],"of":[3,7,54,112,139,147,173,184],"the":[4,8,14,32,42,51,61,64,77,83,87,96,113,119,129,137,145,163,170,174,178,182,185],"catalytic":[5,142,186,189],"mechanisms":[6,187],"oxygen":[9,15],"evolution":[10],"reaction":[11,17,55],"(OER)":[12],"and":[13,34,66,69,90,141,165,180,188],"reduction":[16],"(ORR)":[18],"at":[19],"applied":[20],"electrode":[21,133,155],"potentials":[22],"is":[23,48,104],"crucial":[24],"for":[25,162],"designing":[26],"bifunctional":[27],"catalysts.":[28],"Here,":[29],"we":[30],"revisit":[31],"OER":[33,164],"ORR":[35],"on":[36,177],"single-atom":[37],"catalysts":[38],"(SACs)":[39],"by":[40],"using":[41],"grand":[43],"canonical":[44],"fixed-potential":[45],"method.":[46],"It":[47],"revealed":[49],"that":[50],"charge":[52,74,97],"states":[53,75],"intermediates":[56,71],"are":[57],"linearly":[58,152],"related":[59],"to":[60],"potential":[62,125,175],"through":[63],"capacitance":[65],"surface":[67,91],"area,":[68],"different":[70,73],"exhibit":[72],"under":[76,192],"same":[78],"potential,":[79,156],"which":[80],"arises":[81],"from":[82,118],"adsorption-induced":[84],"change":[85],"in":[86,99,128,158],"work":[88],"function":[89],"dipole.":[92],"As":[93],"a":[94,110,123],"result,":[95],"transfer":[98],"each":[100],"proton-coupled":[101],"electron-transfer":[102],"step":[103],"no":[105],"longer":[106],"1e":[107],"\u2013,":[108],"yielding":[109],"deviation":[111],"potential-dependent":[114],"relative":[115],"free":[116],"energy":[117],"simple":[120],"expression":[121],"with":[122,153],"linear":[124],"correction":[126],"as":[127],"conventional":[130],"computational":[131],"hydrogen":[132],"model,":[134],"further":[135],"affecting":[136],"evaluation":[138],"overpotential":[140],"activity.":[143],"Importantly,":[144],"slopes":[146],"universal":[148],"scaling":[149,160],"relations":[150],"decrease":[151],"increasing":[154],"resulting":[157],"distinct":[159],"relationships":[161],"ORR.":[166],"These":[167],"findings":[168],"highlight":[169],"key":[171],"role":[172],"effects":[176],"OER/ORR":[179],"update":[181],"activity":[190],"trends":[191],"working":[193],"potential.":[194]},"counts_by_year":[{"year":2026,"cited_by_count":18},{"year":2025,"cited_by_count":10},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":2}],"updated_date":"2026-10-21T09:56:26.102985","created_date":"2023-08-17T00:00:00"}