{"id":"https://openalex.org/W4384069786","doi":"https://doi.org/10.1002/ejoc.202300528","title":"Photoinduced Regioselective Perfluoroalkylation/Cyclization Cascade of 3\u2010Aza\u20101,5\u2010Dienes: Access to Pentasubstituted 3\u2010Perfluoroalkyl\u20101,3\u2010Dihydropyrrol\u20102\u2010Ones","display_name":"Photoinduced Regioselective Perfluoroalkylation/Cyclization Cascade of 3\u2010Aza\u20101,5\u2010Dienes: Access to Pentasubstituted 3\u2010Perfluoroalkyl\u20101,3\u2010Dihydropyrrol\u20102\u2010Ones","publication_year":2023,"publication_date":"2023-07-12","ids":{"openalex":"https://openalex.org/W4384069786","doi":"https://doi.org/10.1002/ejoc.202300528"},"language":"en","primary_location":{"id":"doi:10.1002/ejoc.202300528","doi":"https://doi.org/10.1002/ejoc.202300528","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejoc.202300528","pdf_url":null,"source":{"id":"https://openalex.org/S21317199","display_name":"European Journal of Organic Chemistry","issn_l":"1099-0690","issn":["1099-0690","1434-193X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101603556","display_name":"Ruihan Yang","orcid":"https://orcid.org/0000-0002-5042-1351","observed_orcids":["https://orcid.org/0000-0002-5042-1351"]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ruihan Yang","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068320632","display_name":"Danna Chen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Danna Chen","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038579126","display_name":"Shi\u2010Yi Lin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shiyi Lin","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5086396828","display_name":"Xuege Yang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xuege Yang","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008940990","display_name":"Lou Shi","orcid":"https://orcid.org/0000-0002-4613-9628","observed_orcids":["https://orcid.org/0000-0002-4613-9628"]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Lou Shi","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-4613-9628","affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112288298","display_name":"Qiaowen Chang","orcid":"https://orcid.org/0000-0001-8724-4304","observed_orcids":["https://orcid.org/0000-0001-8724-4304"]},"institutions":[{"id":"https://openalex.org/I4210141919","display_name":"Kunming Institute of Precious Metals","ror":"https://ror.org/03t12ts08","country_code":"CN","type":"other","lineage":["https://openalex.org/I4210141919"]},{"id":"https://openalex.org/I4405272335","display_name":"State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals","ror":"https://ror.org/040pp4j24","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405272335"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qiaowen Chang","raw_affiliation_strings":["State Key Laboratory of Advanced Technologies, for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, 988 Keji Road, Kunming, Yunnan Province, 650106 P.R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"State Key Laboratory of Advanced Technologies, for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, 988 Keji Road, Kunming, Yunnan Province, 650106 P.R. China","institution_ids":["https://openalex.org/I4210141919","https://openalex.org/I4405272335"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5003355736","display_name":"Deqiang Liang","orcid":"https://orcid.org/0000-0003-0482-0527","observed_orcids":["https://orcid.org/0000-0003-0482-0527"]},"institutions":[{"id":"https://openalex.org/I146071755","display_name":"Kunming University","ror":"https://ror.org/035rhx828","country_code":"CN","type":"education","lineage":["https://openalex.org/I146071755"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Deqiang Liang","raw_affiliation_strings":["Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China"],"raw_orcid":"https://orcid.org/0000-0003-0482-0527","affiliations":[{"raw_affiliation_string":"Yunnan Key Laboratory of Metal-Organic, Molecular Materials and Device, School of Chemistry and Chemical Engineering, Kunming University, 2 Puxin Road, Kunming, Yunnan Province, 650214 P. R. China","institution_ids":["https://openalex.org/I146071755"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5003355736","https://openalex.org/A5008940990","https://openalex.org/A5112288298"],"corresponding_institution_ids":["https://openalex.org/I146071755","https://openalex.org/I4210141919","https://openalex.org/I4405272335"],"apc_list":{"value":4120,"currency":"USD","value_usd":4120},"apc_paid":null,"fwci":0.7785,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.59561977,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"26","issue":"31","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9916999936103821,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9916999936103821,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.005499999970197678,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12562","display_name":"Synthesis and Characterization of Pyrroles","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/perfluoroalkylation","display_name":"perfluoroalkylation","score":0.9380000233650208},{"id":"https://openalex.org/keywords/cascade-reactions","display_name":"cascade reactions","score":0.5789999961853027},{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.8669999837875366},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.7879999876022339},{"id":"https://openalex.org/keywords/sunlight","display_name":"sunlight","score":0.3790000081062317},{"id":"https://openalex.org/keywords/radical-addition","display_name":"radical addition","score":0.5529999732971191}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.926346480846405},{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.8024241924285889},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.7902920842170715},{"id":"https://openalex.org/C20327893","wikidata":"https://www.wikidata.org/wiki/Q7280479","display_name":"Radical cyclization","level":2,"score":0.6267091035842896},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.5981205701828003},{"id":"https://openalex.org/C2780615836","wikidata":"https://www.wikidata.org/wiki/Q2471869","display_name":"USable","level":2,"score":0.5091747641563416},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.49779582023620605},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.4751282036304474},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.37051719427108765},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3207259178161621},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.0},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ejoc.202300528","doi":"https://doi.org/10.1002/ejoc.202300528","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejoc.202300528","pdf_url":null,"source":{"id":"https://openalex.org/S21317199","display_name":"European Journal of Organic Chemistry","issn_l":"1099-0690","issn":["1099-0690","1434-193X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Organic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4146012606","display_name":null,"funder_award_id":"22061024","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":90,"referenced_works":["https://openalex.org/W1953260324","https://openalex.org/W1999830429","https://openalex.org/W2001634933","https://openalex.org/W2019298069","https://openalex.org/W2037181532","https://openalex.org/W2057438618","https://openalex.org/W2117258693","https://openalex.org/W2144869962","https://openalex.org/W2331533611","https://openalex.org/W2735405787","https://openalex.org/W2787149025","https://openalex.org/W2807171586","https://openalex.org/W2810924785","https://openalex.org/W2905101225","https://openalex.org/W2941420609","https://openalex.org/W2943734189","https://openalex.org/W2953036026","https://openalex.org/W2980968393","https://openalex.org/W2996085633","https://openalex.org/W3041742794","https://openalex.org/W3091909024","https://openalex.org/W3099394468","https://openalex.org/W3118548281","https://openalex.org/W3125297731","https://openalex.org/W3130210032","https://openalex.org/W3133820957","https://openalex.org/W3135160027","https://openalex.org/W3143093277","https://openalex.org/W3161463674","https://openalex.org/W3163698793","https://openalex.org/W3167808759","https://openalex.org/W3176999648","https://openalex.org/W3192288675","https://openalex.org/W3193950964","https://openalex.org/W3194725720","https://openalex.org/W3195024747","https://openalex.org/W3200199225","https://openalex.org/W3202444499","https://openalex.org/W3202537001","https://openalex.org/W3203050184","https://openalex.org/W3208144044","https://openalex.org/W3209013381","https://openalex.org/W3209903191","https://openalex.org/W3212953030","https://openalex.org/W4200405480","https://openalex.org/W4200458846","https://openalex.org/W4205795561","https://openalex.org/W4206411093","https://openalex.org/W4210368278","https://openalex.org/W4210389192","https://openalex.org/W4210498033","https://openalex.org/W4210750389","https://openalex.org/W4210935933","https://openalex.org/W4212782791","https://openalex.org/W4213168658","https://openalex.org/W4214656645","https://openalex.org/W4220718769","https://openalex.org/W4220746744","https://openalex.org/W4223525126","https://openalex.org/W4224248129","https://openalex.org/W4224287193","https://openalex.org/W4226077781","https://openalex.org/W4226113631","https://openalex.org/W4243831129","https://openalex.org/W4280613796","https://openalex.org/W4280653794","https://openalex.org/W4281660172","https://openalex.org/W4282961250","https://openalex.org/W4283643000","https://openalex.org/W4285200770","https://openalex.org/W4285291482","https://openalex.org/W4287965141","https://openalex.org/W4288052051","https://openalex.org/W4289355451","https://openalex.org/W4289537155","https://openalex.org/W4291669688","https://openalex.org/W4292187369","https://openalex.org/W4295233495","https://openalex.org/W4295359111","https://openalex.org/W4296327389","https://openalex.org/W4306249893","https://openalex.org/W4306250634","https://openalex.org/W4309234849","https://openalex.org/W4310564904","https://openalex.org/W4310784959","https://openalex.org/W4311070372","https://openalex.org/W4319845186","https://openalex.org/W4362466886","https://openalex.org/W4362711855","https://openalex.org/W4378745135"],"related_works":["https://openalex.org/W2607152950","https://openalex.org/W4394863949","https://openalex.org/W2953079194","https://openalex.org/W4281660172","https://openalex.org/W4383652199","https://openalex.org/W4412039591","https://openalex.org/W2944296961","https://openalex.org/W4386468442","https://openalex.org/W4403612587","https://openalex.org/W4407397012"],"abstract_inverted_index":{"Abstract":[0],"A":[1],"visible":[2],"light\u2010induced":[3],"perfluoroalkylative":[4],"cyclization":[5],"of":[6,56],"3\u2010aza\u20101,5\u2010dienes":[7],"leading":[8],"to":[9],"pentasubstituted":[10],"1,3\u2010dihydropyrrole\u20102\u2010ones":[11],"is":[12,16,49],"presented.":[13],"The":[14],"reaction":[15,62],"regiospecific,":[17],"for":[18],"the":[19,23,27,47,57],"radical":[20,35],"adds":[21],"across":[22],"acrylamido":[24],"moiety,":[25],"whereas":[26],"enaminic":[28],"double":[29],"bond":[30],"functions":[31],"as":[32],"a":[33,43,50,60,64,71],"built\u2010in":[34],"trap.":[36],"It":[37],"could":[38],"be":[39],"carried":[40],"out":[41],"on":[42],"2\u2010gram":[44],"scale,":[45],"and":[46,70],"sunlight":[48],"usable":[51],"light":[52],"source.":[53],"Other":[54],"virtues":[55],"protocol":[58],"include":[59],"short":[61],"time,":[63],"low":[65],"catalyst":[66],"loading,":[67],"mild":[68],"conditions":[69],"broad":[72],"substrate":[73],"scope.":[74]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":5}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2023-07-13T00:00:00"}