{"id":"https://openalex.org/W4382198546","doi":"https://doi.org/10.1021/acscatal.3c02301","title":"Photoredox and Vanadate Cocatalyzed Hydrolysis of Aryl Ethers at Ambient Temperature","display_name":"Photoredox and Vanadate Cocatalyzed Hydrolysis of Aryl Ethers at Ambient Temperature","publication_year":2023,"publication_date":"2023-06-27","ids":{"openalex":"https://openalex.org/W4382198546","doi":"https://doi.org/10.1021/acscatal.3c02301"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.3c02301","doi":"https://doi.org/10.1021/acscatal.3c02301","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.3c02301","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Rong-Gui Hu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4391767999","display_name":"State Key Laboratory of Multiphase Flow in Power Engineering","ror":"https://ror.org/03dybbh68","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]},{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Rong-Gui Hu","raw_affiliation_strings":["Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China","institution_ids":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025242348","display_name":"Yueqian Sang","orcid":"https://orcid.org/0009-0008-4912-0691","observed_orcids":["https://orcid.org/0009-0008-4912-0691"]},"institutions":[{"id":"https://openalex.org/I4210112946","display_name":"Shanghai Institute of Organic Chemistry","ror":"https://ror.org/01y3hvq34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210112946"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yueqian Sang","raw_affiliation_strings":["Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032 P. R. China","institution_ids":["https://openalex.org/I4210112946","https://openalex.org/I4210165038"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059544587","display_name":"Fang\u2010Fang Tan","orcid":"https://orcid.org/0000-0001-6046-7671","observed_orcids":["https://orcid.org/0000-0001-6046-7671"]},"institutions":[{"id":"https://openalex.org/I4391767999","display_name":"State Key Laboratory of Multiphase Flow in Power Engineering","ror":"https://ror.org/03dybbh68","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]},{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Fang-Fang Tan","raw_affiliation_strings":["Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China","institution_ids":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088359840","display_name":"Yuan\u2010Li Sun","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4391767999","display_name":"State Key Laboratory of Multiphase Flow in Power Engineering","ror":"https://ror.org/03dybbh68","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]},{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuan-Li Sun","raw_affiliation_strings":["Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China","institution_ids":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058629788","display_name":"Xiao\u2010Song Xue","orcid":"https://orcid.org/0000-0003-4541-8702","observed_orcids":["https://orcid.org/0000-0003-4541-8702"]},"institutions":[{"id":"https://openalex.org/I4210112946","display_name":"Shanghai Institute of Organic Chemistry","ror":"https://ror.org/01y3hvq34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210112946"]},{"id":"https://openalex.org/I4210165038","display_name":"University of Chinese Academy of Sciences","ror":"https://ror.org/05qbk4x57","country_code":"CN","type":"education","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210165038"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xiao-Song Xue","raw_affiliation_strings":["Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032 P. R. China","School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou 310024 P. R. China"],"raw_orcid":"https://orcid.org/0000-0003-4541-8702","affiliations":[{"raw_affiliation_string":"Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032 P. R. China","institution_ids":["https://openalex.org/I4210112946","https://openalex.org/I4210165038"]},{"raw_affiliation_string":"School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou 310024 P. R. China","institution_ids":["https://openalex.org/I4210165038"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100393153","display_name":"Yang Li","orcid":"https://orcid.org/0000-0003-4724-4785","observed_orcids":["https://orcid.org/0000-0003-4724-4785"]},"institutions":[{"id":"https://openalex.org/I4391767999","display_name":"State Key Laboratory of Multiphase Flow in Power Engineering","ror":"https://ror.org/03dybbh68","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]},{"id":"https://openalex.org/I87445476","display_name":"Xi'an Jiaotong University","ror":"https://ror.org/017zhmm22","country_code":"CN","type":"education","lineage":["https://openalex.org/I87445476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Yang Li","raw_affiliation_strings":["Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China"],"raw_orcid":"https://orcid.org/0000-0003-4724-4785","affiliations":[{"raw_affiliation_string":"Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering, Xi\u2019an Jiaotong University, Xi\u2019an, Shaanxi 710054, P. R. China","institution_ids":["https://openalex.org/I4391767999","https://openalex.org/I87445476"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5058629788","https://openalex.org/A5100393153"],"corresponding_institution_ids":["https://openalex.org/I4210112946","https://openalex.org/I4210165038","https://openalex.org/I4391767999","https://openalex.org/I87445476"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":3.6005,"has_fulltext":false,"cited_by_count":37,"citation_normalized_percentile":{"value":0.94797882,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"13","issue":"13","first_page":"9264","last_page":"9273"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9740999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9740999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12136","display_name":"Vanadium and Halogenation Chemistry","score":0.016100000590085983,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10078","display_name":"Advanced Photocatalysis Techniques","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/c-o-bond-cleavage","display_name":"C\u2013O bond cleavage","score":0.9940000176429749},{"id":"https://openalex.org/keywords/photoredox-catalysis","display_name":"photoredox catalysis","score":0.9900000095367432},{"id":"https://openalex.org/keywords/vanadium-pentoxide","display_name":"vanadium pentoxide","score":0.6949999928474426},{"id":"https://openalex.org/keywords/radical-cations","display_name":"radical cations","score":0.6499999761581421},{"id":"https://openalex.org/keywords/nucleophilic-aromatic-substitution","display_name":"nucleophilic aromatic substitution","score":0.921999990940094},{"id":"https://openalex.org/keywords/meisenheimer-intermediate","display_name":"Meisenheimer intermediate","score":0.9020000100135803},{"id":"https://openalex.org/keywords/catalyst-recycling","display_name":"catalyst recycling","score":0.8849999904632568},{"id":"https://openalex.org/keywords/lignin-degradation","display_name":"lignin degradation","score":0.9359999895095825},{"id":"https://openalex.org/keywords/biomass-valorization","display_name":"biomass valorization","score":0.6740000247955322},{"id":"https://openalex.org/keywords/atom-economy","display_name":"atom economy","score":0.42100000381469727}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8788794279098511},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7436349987983704},{"id":"https://openalex.org/C2781116636","wikidata":"https://www.wikidata.org/wiki/Q426228","display_name":"Vanadate","level":2,"score":0.727025032043457},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.7163383960723877},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.6843554973602295},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.641562283039093},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.5953956246376038},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5869147777557373},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5435649156570435},{"id":"https://openalex.org/C96444392","wikidata":"https://www.wikidata.org/wiki/Q1993452","display_name":"Radical ion","level":3,"score":0.47202104330062866},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3861766457557678},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3545299768447876},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.13846507668495178},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.06448608636856079},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acscatal.3c02301","doi":"https://doi.org/10.1021/acscatal.3c02301","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.3c02301","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1282432936","display_name":null,"funder_award_id":"22193012","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G2045147184","display_name":null,"funder_award_id":"2022JC-07","funder_id":"https://openalex.org/F4320324173","funder_display_name":"Natural Science Foundation of Shaanxi Province"},{"id":"https://openalex.org/G30414415","display_name":null,"funder_award_id":"22171221","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G42322103","display_name":"\u5316\u5b66\u952e\u80fd\u7684\u6d4b\u5b9a\u3001\u9884\u6d4b\u4e0e\u76f8\u5173\u673a\u7406\u7814\u7a76","funder_award_id":"21933004","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G6965922775","display_name":null,"funder_award_id":"22122104","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7500704454","display_name":null,"funder_award_id":"xpt022022007","funder_id":"https://openalex.org/F4320335787","funder_display_name":"Fundamental Research Funds for the Central Universities"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320324173","display_name":"Natural Science Foundation of Shaanxi Province","ror":null},{"id":"https://openalex.org/F4320335787","display_name":"Fundamental Research Funds for the Central Universities","ror":null}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W1970418635","https://openalex.org/W1971144082","https://openalex.org/W1974417796","https://openalex.org/W1999057729","https://openalex.org/W2001040970","https://openalex.org/W2004462410","https://openalex.org/W2017728255","https://openalex.org/W2050037614","https://openalex.org/W2055022785","https://openalex.org/W2077102194","https://openalex.org/W2079298197","https://openalex.org/W2084971084","https://openalex.org/W2086997985","https://openalex.org/W2098155996","https://openalex.org/W2108659500","https://openalex.org/W2112375301","https://openalex.org/W2120446525","https://openalex.org/W2130138987","https://openalex.org/W2204748604","https://openalex.org/W2265362920","https://openalex.org/W2480067148","https://openalex.org/W2533242268","https://openalex.org/W2577138743","https://openalex.org/W2604642583","https://openalex.org/W2618572521","https://openalex.org/W2748499193","https://openalex.org/W2765487959","https://openalex.org/W2782590469","https://openalex.org/W2806260775","https://openalex.org/W2890597636","https://openalex.org/W2951641603","https://openalex.org/W2951666587","https://openalex.org/W2967572288","https://openalex.org/W2979127922","https://openalex.org/W3029470224","https://openalex.org/W3047078929","https://openalex.org/W3081373768","https://openalex.org/W3082601917","https://openalex.org/W3090772667","https://openalex.org/W3107347394","https://openalex.org/W3177197051","https://openalex.org/W4213355636"],"related_works":["https://openalex.org/W2329969175","https://openalex.org/W2063582568","https://openalex.org/W1999057729","https://openalex.org/W3107347394","https://openalex.org/W3005415570","https://openalex.org/W2069579320","https://openalex.org/W2166766378","https://openalex.org/W4385517161","https://openalex.org/W1970418635","https://openalex.org/W4205388316"],"abstract_inverted_index":{"Cleavage":[0],"of":[1,39,105,116,122],"aryl":[2,40,80],"ether":[3,81,98],"C\u2013O":[4,44,99,138],"bonds":[5,45],"is":[6,29],"significant":[7],"for":[8,137],"both":[9],"biomass":[10],"utilization":[11],"and":[12,22,35,141],"synthetic":[13],"chemistry.":[14],"However,":[15],"a":[16,50,58,63,76,134],"general":[17],"method":[18,132],"with":[19],"high":[20],"selectivity":[21],"atom":[23],"economy,":[24],"under":[25],"mild":[26],"reaction":[27],"conditions,":[28],"unavailable.":[30],"Herein,":[31],"we":[32],"describe":[33],"photoredox":[34],"vanadate":[36,64,109,112],"cocatalyzed":[37],"hydrolysis":[38,73,104],"ethers":[41],"to":[42,78,85,127,145],"cleave":[43],"at":[46],"ambient":[47],"temperature":[48],"via":[49],"cation":[51,83],"radical-accelerated":[52],"nucleophilic":[53,111],"aromatic":[54],"substitution":[55],"enabled":[56],"by":[57],"\u201chydroxyl":[59],"shuttle\u201d":[60],"pathway.":[61],"Specifically,":[62],"derived":[65],"from":[66,125],"V":[67],"2":[68],"O":[69],"5":[70],"in":[71,92],"situ":[72,103],"serves":[74],"as":[75],"nucleophile":[77],"an":[79],"radical":[82,129],"due":[84],"noncovalent":[86],"interactions.":[87],"A":[88],"favorable":[89],"V\u00b7\u00b7\u00b7O":[90],"interaction":[91],"the":[93,106,120],"corresponding":[94],"Meisenheimer-like":[95],"intermediate":[96],"facilitates":[97],"bond":[100,139],"cleavage.":[101],"In":[102],"resulting":[107],"phenyl":[108],"enables":[110],"catalyst":[113],"recycling.":[114],"Cooperation":[115],"these":[117],"processes":[118],"complete":[119],"transfer":[121],"hydroxyl":[123],"groups":[124],"water":[126],"arene":[128],"cations.":[130],"This":[131],"offers":[133],"preferred":[135],"option":[136],"cleavage":[140],"demonstrates":[142],"potential":[143],"application":[144],"lignin":[146],"degradation.":[147]},"counts_by_year":[{"year":2026,"cited_by_count":13},{"year":2025,"cited_by_count":11},{"year":2024,"cited_by_count":10},{"year":2023,"cited_by_count":3}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2023-06-28T00:00:00"}