{"id":"https://openalex.org/W4382140761","doi":"https://doi.org/10.1016/s1452-3981(23)15487-3","title":"Solute-Solvent Interactions in Biological Molecules: L-Cysteine","display_name":"Solute-Solvent Interactions in Biological Molecules: L-Cysteine","publication_year":2008,"publication_date":"2008-08-01","ids":{"openalex":"https://openalex.org/W4382140761","doi":"https://doi.org/10.1016/s1452-3981(23)15487-3"},"language":"en","primary_location":{"id":"doi:10.1016/s1452-3981(23)15487-3","doi":"https://doi.org/10.1016/s1452-3981(23)15487-3","is_oa":true,"landing_page_url":"https://doi.org/10.1016/s1452-3981(23)15487-3","pdf_url":null,"source":{"id":"https://openalex.org/S48583931","display_name":"International Journal of Electrochemical Science","issn_l":"1452-3981","issn":["1452-3981"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-d","jufo-1","norway-1","poland-40","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Electrochemical Science","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://doi.org/10.1016/s1452-3981(23)15487-3","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111931186","display_name":"C.V. Krishnan","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"C.V. Krishnan","raw_affiliation_strings":["Garnett McKeen Lab, Inc., 7 Shirley, Street, Bohemia, NY 11716-1735, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Garnett McKeen Lab, Inc., 7 Shirley, Street, Bohemia, NY 11716-1735, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073360958","display_name":"Merrill Garnett","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"M. Garnett","raw_affiliation_strings":["Garnett McKeen Lab, Inc., 7 Shirley, Street, Bohemia, NY 11716-1735, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Garnett McKeen Lab, Inc., 7 Shirley, Street, Bohemia, NY 11716-1735, USA","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5000613784","display_name":"Benjamin Chu","orcid":"https://orcid.org/0000-0003-2775-2336","observed_orcids":["https://orcid.org/0000-0003-2775-2336"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"B. Chu","raw_affiliation_strings":["Department of Chemistry, Stony Brook University, Stony Brook, NY11794-3400, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Stony Brook University, Stony Brook, NY11794-3400, USA","institution_ids":["https://openalex.org/I59553526"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5111931186"],"corresponding_institution_ids":[],"apc_list":{"value":1670,"currency":"USD","value_usd":1670},"apc_paid":{"value":1670,"currency":"USD","value_usd":1670},"fwci":2.86,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.90657769,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"3","issue":"8","first_page":"854","last_page":"872"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.492900013923645,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.492900013923645,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.14090000092983246,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.04170000180602074,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cysteine","display_name":"cysteine","score":1.0},{"id":"https://openalex.org/keywords/solute-solvent-interactions","display_name":"solute-solvent interactions","score":0.9980000257492065},{"id":"https://openalex.org/keywords/cyclic-voltammetry","display_name":"cyclic voltammetry","score":0.9200000166893005},{"id":"https://openalex.org/keywords/counterions","display_name":"counterions","score":0.6389999985694885},{"id":"https://openalex.org/keywords/chloride","display_name":"chloride","score":0.6100000143051147},{"id":"https://openalex.org/keywords/bromide","display_name":"bromide","score":0.968999981880188},{"id":"https://openalex.org/keywords/phosphate-buffer","display_name":"phosphate buffer","score":0.9340000152587891},{"id":"https://openalex.org/keywords/admittance","display_name":"admittance","score":0.5289999842643738},{"id":"https://openalex.org/keywords/impedance","display_name":"impedance","score":0.7170000076293945},{"id":"https://openalex.org/keywords/capacitance","display_name":"capacitance","score":0.9670000076293945},{"id":"https://openalex.org/keywords/self-assembly","display_name":"self-assembly","score":0.7580000162124634},{"id":"https://openalex.org/keywords/electric-double-layer","display_name":"electric double layer","score":0.5830000042915344}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7263867855072021},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6494899988174438},{"id":"https://openalex.org/C2778695967","wikidata":"https://www.wikidata.org/wiki/Q44791900","display_name":"Chloride","level":2,"score":0.6140615940093994},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6019059419631958},{"id":"https://openalex.org/C537181965","wikidata":"https://www.wikidata.org/wiki/Q658","display_name":"Sodium","level":2,"score":0.5304994583129883},{"id":"https://openalex.org/C2776300020","wikidata":"https://www.wikidata.org/wiki/Q422423","display_name":"Bromide","level":2,"score":0.5085312128067017},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.4861288070678711},{"id":"https://openalex.org/C2780780826","wikidata":"https://www.wikidata.org/wiki/Q2546","display_name":"Potassium bromide","level":2,"score":0.4858390986919403},{"id":"https://openalex.org/C89395315","wikidata":"https://www.wikidata.org/wiki/Q181232","display_name":"Anode","level":3,"score":0.47138458490371704},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.4588281810283661},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3287909924983978},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.11798107624053955},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0900459885597229},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.08298653364181519},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07513067126274109}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1016/s1452-3981(23)15487-3","doi":"https://doi.org/10.1016/s1452-3981(23)15487-3","is_oa":true,"landing_page_url":"https://doi.org/10.1016/s1452-3981(23)15487-3","pdf_url":null,"source":{"id":"https://openalex.org/S48583931","display_name":"International Journal of Electrochemical Science","issn_l":"1452-3981","issn":["1452-3981"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-d","jufo-1","norway-1","poland-40","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Electrochemical Science","raw_type":"journal-article"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.655.4981","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.655.4981","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://electrochemsci.org/papers/vol3/3080854.pdf","raw_type":"text"},{"id":"pmh:oai:doaj.org/article:8b868d62d31d443a86d476184db57289","doi":null,"is_oa":false,"landing_page_url":"https://doaj.org/article/8b868d62d31d443a86d476184db57289","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"International Journal of Electrochemical Science, Vol 3, Iss 8, Pp 854-872 (2008)","raw_type":"article"}],"best_oa_location":{"id":"doi:10.1016/s1452-3981(23)15487-3","doi":"https://doi.org/10.1016/s1452-3981(23)15487-3","is_oa":true,"landing_page_url":"https://doi.org/10.1016/s1452-3981(23)15487-3","pdf_url":null,"source":{"id":"https://openalex.org/S48583931","display_name":"International Journal of Electrochemical Science","issn_l":"1452-3981","issn":["1452-3981"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-d","jufo-1","norway-1","poland-40","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"International Journal of Electrochemical Science","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1482643283","https://openalex.org/W1596401706","https://openalex.org/W1604673603","https://openalex.org/W1644362692","https://openalex.org/W1967406694","https://openalex.org/W1976592326","https://openalex.org/W1982811967","https://openalex.org/W1991912016","https://openalex.org/W2020095758","https://openalex.org/W2020853044","https://openalex.org/W2024048530","https://openalex.org/W2024247096","https://openalex.org/W2026723459","https://openalex.org/W2035611129","https://openalex.org/W2043018997","https://openalex.org/W2044310923","https://openalex.org/W2044964630","https://openalex.org/W2051526760","https://openalex.org/W2055882569","https://openalex.org/W2058549182","https://openalex.org/W2064662425","https://openalex.org/W2066367452","https://openalex.org/W2074574689","https://openalex.org/W2093561314","https://openalex.org/W2110048351","https://openalex.org/W2318013796","https://openalex.org/W2318114164","https://openalex.org/W2321448480","https://openalex.org/W2739447434","https://openalex.org/W3216186527","https://openalex.org/W4243670586","https://openalex.org/W4382397121","https://openalex.org/W4382398618","https://openalex.org/W4382582956","https://openalex.org/W4382584556"],"related_works":["https://openalex.org/W2737925954","https://openalex.org/W3024703778","https://openalex.org/W7096657369","https://openalex.org/W2615494980","https://openalex.org/W2513360525","https://openalex.org/W4249153173","https://openalex.org/W32428999","https://openalex.org/W2085863102","https://openalex.org/W2757669061","https://openalex.org/W4382397121"],"abstract_inverted_index":{"The":[0,198],"cyclic":[1],"voltammetric":[2],"behavior":[3],"of":[4,15,108,126,131,143,149,152,160,167,181,195,208,222,231,263],"L-cysteine":[5,62],"at":[6,115,188,214],"different":[7,189],"pH":[8],"values":[9],"in":[10,105,123,135,225,241,271,291],"the":[11,33,47,50,55,61,66,72,94,106,111,124,136,141,161,165,179,186,193,196,220,226,229,256,260,280,288],"absence":[12,137,166,227],"and":[13,30,40,74,84,90,128,228,252],"presence":[14,107,125,142,180,221,230],"ions":[16],"such":[17],"as":[18,58,60,138,140],"chloride":[19],"from":[20,27,32,36,172],"hydrochloric":[21],"acid":[22],"or":[23,235,245],"sodium":[24,28,41],"chloride,":[25],"bromide":[26],"bromide,":[29],"phosphate":[31,39,248],"buffer":[34],"made":[35],"potassium":[37],"dihydrogen":[38],"hydroxide":[42],"have":[43],"been":[44],"investigated.":[45],"In":[46,164,178],"active":[48,76],"region,":[49],"cathodic":[51,73,83,102,118],"current":[52,103,119],"depended":[53],"on":[54,192,276],"starting":[56,67,114],"potential":[57,68,113],"well":[59,139],"concentration.":[63],"Also":[64],"if":[65],"was":[69],"more":[70,80],"anodic,":[71],"anodic":[75,85],"regions":[77],"extended":[78],"much":[79],"into":[81],"both":[82],"regions.":[86],"While":[87],"scans":[88],"2":[89],"3":[91],"gave":[92,100],"nearly":[93],"same":[95],"current,":[96],"scan":[97],"1":[98],"always":[99],"higher":[101],"especially":[104],"counter-ions.":[109],"With":[110],"scanning":[112],"0.0":[116],"V,":[117],"oscillations":[120,213],"were":[121],"observed":[122],"counter-ions":[127,144,182],"high":[129,215],"concentrations":[130],"L-cysteine.":[132,209],"Admittance":[133],"data":[134,200,211,218,254],"indicated":[145,201,212],"a":[146,158],"competing":[147],"influence":[148],"orientational":[150],"effects":[151],"water":[153],"with":[154],"decreasing":[155],"frequencies,":[156,190],"indicating":[157],"characteristic":[159],"self-assembly":[162],"behavior.":[163],"counter-ions,":[168],"admittance":[169,199,253],"increased":[170],"continuously":[171],"1000":[173],"Hz":[174],"to":[175,258,273,287],"10":[176],"Hz.":[177],"this":[183],"trend":[184],"changed":[185],"direction":[187],"depending":[191],"concentration":[194],"counter-ion.":[197],"strong":[202],"interactions":[203,278],"between":[204],"\u03b1-COO-and":[205],"\u03b1-NH3+":[206],"groups":[207],"Impedance":[210],"frequencies.":[216],"Capacitance":[217],"suggested":[219,255],"two":[223],"species":[224],"5":[232,236],"mM":[233,237],"NaCl":[234],"NaBr":[238],"but":[239],"not":[240],"0.1":[242],"M":[243,247],"HCl":[244],"0.059":[246],"buffer.":[249],"Cyclic":[250],"voltammetry":[251],"need":[257],"investigate":[259],"electrochemical":[261],"behaviour":[262],"molecules":[264],"without":[265],"any":[266],"background":[267],"electrolytes,":[268],"whenever":[269],"possible,":[270],"order":[272],"gain":[274],"information":[275],"solute-solvent":[277],"near":[279],"double":[281],"layer.":[282],"This":[283],"finding":[284],"is":[285],"contrary":[286],"accepted":[289],"practice":[290],"electrochemistry.":[292]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2023-06-27T00:00:00"}