{"id":"https://openalex.org/W4381054150","doi":"https://doi.org/10.1002/ange.202303119","title":"Auf dem Weg zu einer Formyl\u2010zu\u2010Phenyl\u2010Reaktion: Eine unerwartete photochemische Fulven\u2010Umlagerung","display_name":"Auf dem Weg zu einer Formyl\u2010zu\u2010Phenyl\u2010Reaktion: Eine unerwartete photochemische Fulven\u2010Umlagerung","publication_year":2023,"publication_date":"2023-06-17","ids":{"openalex":"https://openalex.org/W4381054150","doi":"https://doi.org/10.1002/ange.202303119"},"language":"de","primary_location":{"id":"doi:10.1002/ange.202303119","doi":"https://doi.org/10.1002/ange.202303119","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202303119","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://doi.org/10.1002/ange.202303119","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5081860392","display_name":"Monika M. Lindner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Monika M. Lindner","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009480542","display_name":"M. Wasim Alachraf","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"M. Wasim Alachraf","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5011243085","display_name":"Benjamin Mitschke","orcid":"https://orcid.org/0000-0002-2942-2448","observed_orcids":["https://orcid.org/0000-0002-2942-2448"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Benjamin Mitschke","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067348882","display_name":"Philipp Schulze","orcid":"https://orcid.org/0000-0001-5047-2354","observed_orcids":["https://orcid.org/0000-0001-5047-2354"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Philipp Schulze","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087497545","display_name":"Markus Leutzsch","orcid":"https://orcid.org/0000-0001-8171-9399","observed_orcids":["https://orcid.org/0000-0001-8171-9399"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Markus Leutzsch","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040055598","display_name":"Benjamin List","orcid":"https://orcid.org/0000-0002-9804-599X","observed_orcids":["https://orcid.org/0000-0002-9804-599X"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Benjamin List","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":"https://orcid.org/0000-0002-9804-599X","affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz\u20051 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5040055598"],"corresponding_institution_ids":["https://openalex.org/I4210090782"],"apc_list":{"value":5250,"currency":"USD","value_usd":5250},"apc_paid":{"value":5250,"currency":"USD","value_usd":5250},"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.04588388,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"135","issue":"35","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.5048999786376953,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.5048999786376953,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.24009999632835388,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11298","display_name":"Synthesis and Properties of Aromatic Compounds","score":0.09520000219345093,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photochemical-rearrangement","display_name":"photochemical rearrangement","score":0.9390000104904175},{"id":"https://openalex.org/keywords/platinum-catalysis","display_name":"platinum catalysis","score":0.8420000076293945},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7599999904632568}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8030205965042114},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.484406054019928},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.32037097215652466}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.202303119","doi":"https://doi.org/10.1002/ange.202303119","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202303119","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/ange.202303119","doi":"https://doi.org/10.1002/ange.202303119","is_oa":true,"landing_page_url":"https://doi.org/10.1002/ange.202303119","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":"cc-by-nc","license_id":"https://openalex.org/licenses/cc-by-nc","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320309608","display_name":"Verband der Chemischen Industrie","ror":"https://ror.org/00kvk1853"},{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":54,"referenced_works":["https://openalex.org/W89017188","https://openalex.org/W1976590104","https://openalex.org/W1978385196","https://openalex.org/W1981313247","https://openalex.org/W1982787747","https://openalex.org/W1987689924","https://openalex.org/W1994335614","https://openalex.org/W1998391496","https://openalex.org/W1999753112","https://openalex.org/W2002073118","https://openalex.org/W2003043480","https://openalex.org/W2003516675","https://openalex.org/W2006705017","https://openalex.org/W2008271247","https://openalex.org/W2014836158","https://openalex.org/W2019521159","https://openalex.org/W2022419571","https://openalex.org/W2025020044","https://openalex.org/W2040733451","https://openalex.org/W2041562090","https://openalex.org/W2046071863","https://openalex.org/W2048764142","https://openalex.org/W2059262392","https://openalex.org/W2066071481","https://openalex.org/W2066736458","https://openalex.org/W2078927004","https://openalex.org/W2084616247","https://openalex.org/W2084624701","https://openalex.org/W2086531787","https://openalex.org/W2087658941","https://openalex.org/W2089296447","https://openalex.org/W2102621939","https://openalex.org/W2105050546","https://openalex.org/W2112453592","https://openalex.org/W2124488725","https://openalex.org/W2125557290","https://openalex.org/W2138469456","https://openalex.org/W2139520918","https://openalex.org/W2162809119","https://openalex.org/W2319956247","https://openalex.org/W2327770401","https://openalex.org/W2328485423","https://openalex.org/W2330846974","https://openalex.org/W2330908425","https://openalex.org/W2531596349","https://openalex.org/W2584119932","https://openalex.org/W2949212383","https://openalex.org/W2951092036","https://openalex.org/W2952653954","https://openalex.org/W2971610571","https://openalex.org/W3118663852","https://openalex.org/W4211061887","https://openalex.org/W4240779256","https://openalex.org/W4253630917"],"related_works":["https://openalex.org/W4381054295","https://openalex.org/W2607473189","https://openalex.org/W2044611722","https://openalex.org/W2165919542","https://openalex.org/W1991079018","https://openalex.org/W4230021353","https://openalex.org/W2104024791","https://openalex.org/W264691895","https://openalex.org/W2049515887","https://openalex.org/W4417221237"],"abstract_inverted_index":{"Abstract":[0],"Um":[1],"Aldehyde":[2],"in":[3,33,57],"Arene":[4],"zu":[5,17,28,53,71],"\u00fcberf\u00fchren,":[6],"haben":[7],"wir":[8,47],"eine":[9],"Sequenz":[10],"entworfen,":[11],"bei":[12],"der":[13],"ein":[14,58],"Aldehyd":[15],"zun\u00e4chst":[16],"einem":[18,29],"Fulven":[19],"umgesetzt":[20],"wird.":[21],"Daraufhin":[22],"folgen":[23],"photochemische":[24],"und":[25,67],"platinkatalysierte":[26],"Umlagerungen":[27],"Dewar\u2010Benzol\u2010Derivat,":[30],"welches":[31],"schlie\u00dflich":[32],"das":[34],"gew\u00fcnschte":[35],"Aren":[36],"isomerisiert.":[37],"Obwohl":[38],"theoretische":[39],"Berechnungen":[40],"die":[41,51],"Plausibilit\u00e4t":[42],"dieses":[43],"Weges":[44],"nahelegen,":[45],"stellten":[46],"experimentell":[48],"fest,":[49],"dass":[50],"Fulven\u2010Bestrahlung":[52],"einer":[54],"unerwarteten":[55],"Isomerisierung":[56],"Spiro[2.4]heptadien":[59],"f\u00fchrt.":[60],"Diese":[61],"ungew\u00f6hnliche":[62],"Photoumlagerung":[63],"wurde":[64],"mechanistisch":[65],"untersucht":[66],"erm\u00f6glicht":[68],"den":[69],"Zugang":[70],"verschiedenen":[72],"Spiro[2.4]heptadienen":[73],"mit":[74],"unterschiedlichen":[75],"Substituenten.":[76]},"counts_by_year":[],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2023-06-18T00:00:00"}